Search NASA⌕ Search

SEARCH · Search NASA

Results for “Electron transfer”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 217 records · Page 12

Quantitative PLIF Imaging in High-Pressure Combustion

This is the final report for a research project aimed at developing planar laser-induced fluorescence (PLIF) techniques for quantitative 2-D species imaging in fuel-lean, high-pressure combustion gases, relevant to modem aircraft gas turbine combustors. The program involved both theory and experiment. The theoretical activity led to spectroscopic models that allow calculation of the laser-induced fluorescence produced in OH, NO and 02 for arbitrary excitation wavelength, pressure, temperature, gas mixture and laser linewidth. These spectroscopic models incorporate new information on line- broadening, energy transfer and electronic quench rates. Extensive calculations have been made with these models in order to identify optimum excitation strategies, particularly for detecting low levels (ppm) of NO in the presence of large 02 mole fractions (10% is typical for the fuel-lean combustion of interest). A promising new measurement concept has emerged from these calculations, namely that excitation at specific wavelengths, together with detection of fluorescence in multiple spectral bands, promises to enable simultaneous detection of both NO (at ppm levels) and 02 or possibly NO, 02 and temperature. Calculations have been made to evaluate the expected performance of such a diagnostic for a variety of conditions and choices of excitation and detection wavelengths. The experimental effort began with assembly of a new high-pressure combustor to provide controlled high-temperature and high-pressure combustion products. The non-premixed burner enables access to postflame gases at high temperatures (to 2000 K) and high pressures (to 13 atm), and a range of fuel-air equivalence ratios. The chamber also allowed use of a sampling probe, for chemiluminescent detection of NO/NO2, and thermocouples for measurement of gas temperature. Experiments were conducted to confirm the spectroscopic models for OH, NO and 02.

Hanson, R. K.↗

Reversible non-volatile switch based on a TCNQ charge transfer complex

A solid-state synaptic memory matrix (10) having switchable weakly conductive connections at each node (24) whose resistances can be selectably increased or decreased over several orders of magnitude by control signals of opposite polarity, and which will remain stable after the signals are removed, comprises an insulated substrate (16), a set of electrical conductors (14) upon which is deposited a layer (18) of an organic conducting polymer, which changes from an insulator to a conductor upon the transfer of electrons, such as polymerized pyrrole doped with 7,7,8,8-tetracyanoquinodimethane (TCNQ), covered by a second set of conductors (20) laid at right angles to the first.

Nagasubramanian, Ganesan↗

Development of an e-VLBI Data Transport Software Suite with VDIF

We have developed a software library (KVTP-lib) for VLBI data transmission over the network with the VDIF (VLBI Data Interchange Format), which is the newly proposed standard VLBI data format designed for electronic data transfer over the network. The software package keeps the application layer (VDIF frame) and the transmission layer separate, so that each layer can be developed efficiently. The real-time VLBI data transmission tool sudp-send is an application tool based on the KVTP-lib library. sudp-send captures the VLBI data stream from the VSI-H interface with the K5/VSI PC-board and writes the data to file in standard Linux file format or transmits it to the network using the simple- UDP (SUDP) protocol. Another tool, sudp-recv , receives the data stream from the network and writes the data to file in a specific VLBI format (K5/VSSP, VDIF, or Mark 5B). This software system has been implemented on the Wettzell Tsukuba baseline; evaluation before operational employment is under way.

Sekido, Mamoru↗

The Two-Column Aerosol Project: Phase I - Overview and Impact of Elevated Aerosol Layers on Aerosol Optical Depth

The Two-Column Aerosol Project (TCAP), conducted from June 2012 through June 2013, was a unique study designed to provide a comprehensive data set that can be used to investigate a number of important climate science questions, including those related to aerosol mixing state and aerosol radiative forcing. The study was designed to sample the atmosphere be tween and within two atmospheric columns; one fixed near the coast of North America (over Cape Cod, MA) and a second moveable column over the Atlantic Ocean several hundred kilometers from the coast. The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF) was deployed at the base of the Cape Cod column, and the ARM Aerial Facility was utilized for the summer and winter intensive observation periods. One important finding from TCAP is that four of six nearly cloud-free flight days had aerosol layers aloft in both the Cape Cod and maritime columns that were detected using the nadir pointing second-generation NASA high-spectral resolution lidar (HSRL-2).These layer s contributed up to 60 of the total observed aerosol optical depth (AOD). Many of these layers were also intercepted by the aircraft configured for in situ sampling, and the aerosol in the layers was found to have increased amounts of biomass burning material and nitrate compared to aerosol found near the surface. In addition, while there was a great deal of spatial and day-to-day variability in the aerosol chemical composition and optical properties, no systematic differences between the two columns were observed.

aerosols↗

Challenges and Opportunities in Gen3 Embedded Cooling with High-Quality Microgap Flow

Gen3, Embedded Cooling, promises to revolutionize thermal management of advanced microelectronic systems by eliminating the sequential conductive and interfacial thermal resistances which dominate the present 'remote cooling' paradigm. Single-phase interchip microfluidic flow with high thermal conductivity chips and substrates has been used successfully to cool single transistors dissipating more than 40kW/sq cm, but efficient heat removal from transistor arrays, larger chips, and chip stacks operating at these prodigious heat fluxes would require the use of high vapor fraction (quality), two-phase cooling in intra- and inter-chip microgap channels. The motivation, as well as the challenges and opportunities associated with evaporative embedded cooling in realistic form factors, is the focus of this paper. The paper will begin with a brief review of the history of thermal packaging, reflecting the 70-year 'inward migration' of cooling technology from the computer-room, to the rack, and then to the single chip and multichip module with 'remote' or attached air- and liquid-cooled coldplates. Discussion of the limitations of this approach and recent results from single-phase embedded cooling will follow. This will set the stage for discussion of the development challenges associated with application of this Gen3 thermal management paradigm to commercial semiconductor hardware, including dealing with the effects of channel length, orientation, and manifold-driven centrifugal acceleration on the governing behavior.

microchannel↗

Electronic excitation of ground state atoms by collision with heavy gas particles

Most of the important chemical reactions which occur in the very high temperature air produced around space vehicles as they enter the atmosphere were investigated both experimentally and theoretically, to some extent at least. One remaining reaction about which little is known, and which could be quite important at the extremely high temperatures that will be produced by the class of space vehicles now contemplated - such as the AOTV - is the excitation of bound electron states due to collisions between heavy gas particles. Rates of electronic excitation due to free electron collisions are known to be very rapid, but because these collisions quickly equilibrate the free and bound electron energy, the approach to full equilibrium with the heavy particle kinetic energy will depend primarily on the much slower process of bound electron excitation in heavy particle collisions and the subsequent rapid transfer to free electron energy. This may be the dominant mechanism leading to full equilibrium in the gas once the dissociation process has depleted the molecular states so the transfer between molecular vibrational energy and free electron energy is no longer available as a channel for equilibration of free electron and heavy particle kinetic energies. Two mechanisms seem probable in electronic excitation by heavy particle impact. One of these is the collision excitation and deexcitation of higher electronic states which are Rydberg like. A report, entitled 'Semi-Classical Theory of Electronic Excitation Rates', was submitted previously. This presented analytic expressions for the transition probabilities, assuming that the interaction potential is an exponential repulsion with a perturbation ripple due to the dipole-induced dipole effect in the case of neutral-neutral collisions, and to the ion-dipole interaction in the case of ion-neutral collisions. However the above may be, there is little doubt that excitation of ground state species by collision occurs at the point where the initial and final potentials cross, or at least come very close. Therefore, this mechanism would be applicable to the case where a gas is initially at very low temperature suddenly subjected to high energy heavy particle bombardment. This situation would model the measurement of excitation cross section by molecular beam techniques, for example. The purpose is to report values of cross sections and rate coefficients for collision excitation of ground state atoms estimated with the Landau-Zener transition theory and to compare results with measurement of excitation cross sections for a beam of Hydrogen atoms impacting Argon atom targets. Some very dubious approximations are used, and the comparison with measurement is found less than ideal, but results are at least consistent within order of magnitude. The same model is then applied to the case of N-N atom collisions, even though the approximations then become even more doubtful. Still the rate coefficients obtained are at least plausible in both magnitude and functional form, and as far as I am aware these are the only estimates available for such rate coefficients.

Hansen, C. Frederick↗

Charge Transfer Between Ground-State Si(3+) and He at Electron-Volt Energies

The charge-transfer rate coefficient for the reaction Si(3+)(3s(sup 2)S) + He yields products is measured by means of a combined technique of laser ablation and ion storage. A cylindrical radio-frequency ion trap was used to store Si(3+) ions produced by laser ablation of solid silicon targets. The rate coefficient of the reaction was derived from the decay rate of the ion signal. The measured rate coefficient is 6.27(exp +0.68)(sub -0.52) x 10(exp -10)cu cm/s at T(sub equiv) = 3.9 x 10(exp 3)K. This value is about 30% higher than the Landau-Zener calculation of Butler and Dalgarno and is larger by about a factor of 3 than the recent full quantal calculation of Honvault et al.

Fang, Z.↗

Measurement of Charge Transfer Rate Coefficient Between Ground-State N(2+) Ion and He at Electron-Volt Energies

The charge transfer rate coefficient for the reaction N(2+)(2p(sup 2)P(sup 0)) + He yields products is measured by recording the time dependence of the N(2+) ions stored in an ion trap. A cylindrical radio-frequency ion trap was used to store N(2+) ions produced by laser ablation of a solid titanium nitride target. The decay of the ion signals was analyzed by single exponential least-squares fits to the data. The measured rate coefficient is 8.67(0.76) x 10(exp -11)sq cm/s. The N(2+) ions were at a mean energy of 2.7 eV while He gas was at room temperature, corresponding to an equivalent temperature of 3.9 x 10(exp 3) K. The measured value is in good agreement with a recent calculation.

Fang, Z.↗

Effects of interhemisphere transport on plasma temperatures at low latitudes.

The thermal balance of the equatorial plasma between 300 and 800 km is examined. Steady state nighttime calculations are made for O+, H+, and electrons. The following features are included: collisional heat transfer between ions, electrons, and neutrals; ion and electron thermal conduction along the field lines; curvature of the field lines; nonlinear advection due to field-aligned ion and electron motions; and convective compression or expansion due to field-aligned and E x B motions. The ion velocities necessary to calculate the effects of convection are obtained from the work of Moffett and Hanson, who include a meridional wind across the magnetic equator in their calculations. It is shown that field-aligned interhemisphere plasma flows appreciably affect the plasma temperatures.

Bailey, G. J.↗

A new path for the electron bulk energization in solar flares: Fermi acceleration by magnetohydrodynamic turbulence in reconnection outflows

We recently proposed that a magnetohydrodynamic (MHD) turbulent cascade produces the bulk energization of electrons to approximately 25 keV in the impulsive phase of solar flares (LaRosa & Moore 1993). In that scenario, (1) the cascading MHD turbulence is fed by shear-unstable Alfvenic outflows from sites of strongly driven reconnection in the low corona, and (2) the electrons are energized by absorbing the energy that flows down through the cascade. We did not specify the physical mechanism by which the cascading energy is ultimately transferred to the electrons. Here we propose that Fermi acceleration is this mechanism, the process by which the electrons are energized and by which the cascading MHD turbulence is dissipated. We point out that in the expected cascade MHD fluctuations of scale 1 km can Fermi-accelerate electrons from 0.1 keV to approximately 25 keV on the subsecond timescales observed in impulsive flares, provided there is sufficient trapping and scattering of electrons in the MHD turbulence. We show that these same fluctuations provide the required trapping; they confine the electrons within the turbulent region until the turbulence eis dissipated. This results in the energization of all of the lectrons in each large-scale (5 x 10(exp 7)cm) turbulent eddy to 25 keV. The Fermi process also requires efficient scattering so that the pitch-angle distribution of the accelerating electrons remains isotropic. We propose that the electrons undergo resonant scattering by high-frequency plasma R-waves that, as suggested by others (Hamilton & Petrosian 1992), are generated by the reconnection. Ions are not scattered by R-waves. Provided that there is negligible generation of ion-scattering plasma turbulence (e.g., L-waves) by the reconnection or the MHD turbulence, the ions will not Fermi-accelerate and the cascading energy is transferred only to the electrons. We conclude that, given this situation, electron Fermi acceleration can plausibly account for the electron bulk energization in impulsive solar flares.

Larosa, T. N.↗

Geodetic positioning of the Aerospace Electronics Research Lab (ERL) Osborne Time Transfer Receiver (TTR) using the GPS NAVSTAR Block I satellites

Aerospace has routinely processed the Osborne Time Transfer Receiver (TTR) data for the purpose of monitoring the performance of ground and GPS atomic clocks in near real-time with on-line residual displays and characterizing clock stability with Allan Variance calculations. Recently, Aerospace added the ability to estimate the TTR's location by differentially correcting the TTR's location in the WGS84 reference system. This new feature is exercised on a set of TTR clock phase data and Sub-meter accurate station location estimates of the TTR at the Aerospace Electronic Research Lab (ERL) are obtained.

Liu, Anthony S.↗

Unsaturated Comptonization of isotropic photon spectra by relativistic electrons

The multiple scattering approach for evaluating the transformation of an arbitrary soft photon spectrum as a result of unsaturated Compton scatterings in a medium of relativistic electrons is explored. The medium is assumed to be infinite and spatially homogeneous but may be time-dependent, and the photons are isotropic. It is shown that the distortion of a radiation spectrum can be described analytically in a compact form using the Fourier transform of the single-scattering probability. In the nonrelativistic case, the validity of the known analytical results derived from the Kompaneets (1957) equation is extended to arbitrary electron distribution functions and photon spectra. For relativistic electrons, simple expressions are obtained for the total energy that is transferred from the electrons to the photons and for the distortion in the Rayleigh-Jeans regime of a blackbody spectrum. It is demonstrated that the treatment applies to Comptonization in a relativistic jet and that Comptonization of very soft trapped photons by semirelativistic electrons in an expanding medium leads naturally to a log Gaussian spectrum, of the form observed in blazars.

Loeb, Abraham↗

High density electronic packaging module with improved cooling assembly

Cold plate increases heat transfer within high density electronic module. Tapered pins improve heat transfer process by providing larger surface pressure with increased planar area. Cooling technique increases thermal contact where planar area is limited, interface pressure increases the heat transfer coefficient.

Martin, J. H.↗

Charge Transfer Between Ground-State N(2+) and H2, N2, and CO at Electron-Volt Energies

The charge-transfer rate coefficients for reactions of N(2+)(2 S(sup 2)2p(sup 2)P(sup 0)) with H2, N2, and CO are measured using ion storage. A cylindrical rf ion trap was used to store N(2+) ions produced by laser ablation of a solid titanium nitride target. The rate coefficients were derived from the decay rate of the ion signal. The rate coefficients for the above three reactions are 3.38(0.35) x 10(exp -11)sq sm/s at T(sub equiv.)=2.9 x 10(exp 3) K, 2.10(0.18) x 10(exp -9)sq sm/s at T(sub equiv.) = 1.3 x 10(exp 4) K, and 3.37(0.29) x 10(exp -9)sq cm/s at T(sub equiv.) = 1.3 x 10(exp 4) K, respectively. No theoretical or other experimental values are available at this energy range.

Fang, Z.↗