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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Improving Ni-Based SOFC Anode Resilience and Durability through Secondary Phase Formation

The project used a multi-disciplinary approach to test test if 2° materials, added to traditional cermet components, enhanced SOFC mechanical strength, anode resilience and durability when subjected to electrochemical and environmental redox cycling. Findings from fracture testing, electrochemical studies and operando Raman spectroscopy measurements demonstrated that aluminum titanate (Al 2 TiO 5 or ALT) mechanically mixed with NiO-YSZ cermets confers superior mechanical strength and slower degradation rates under polarization. No deleterious effects from ALT in conversion efficiency were observed. Specific accomplishments included the following: (1) Refined methods used to fabricate ALT enhanced anodes into bi-layer anode supports to achieve high power densities; (2) Compared the effects of adding ALT mechanically to Ni-YSZ powders prior to anode fabrication with adding ALT through infiltration and co-infiltration of YSZ scaffolds; (3) Tested the resilience of these novel materials to electrochemical and environmental redox cycling and thermal stresses commonly encountered in functioning SOFCs; and (4) Characterized the ability of ALT to improve the carbon tolerance of Ni-YSZ anodes operating with dry methane.

01 COAL, LIGNITE, AND PEAT↗

Geopolymer Cements: Resistance-Engineered Sewer Infrastructure for Longevity using Innovative, Energy-efficient, Synthesis Techniques (RESILIENT)

The primary objective of this project was to engineer an ultra-acid-resistant low-calcium alkali-activated cement paste for wastewater infrastructure applications to address the critical need for concrete materials with enhanced sulfuric acid resistance compared to ordinary Portland cement (OPC) concrete. In this project, the first milestone was to benchmark the sulfuric acid (SA) resistance of OPC and metakaolin-based geopolymer cement pastes. The second milestone was to model, select, and evaluate the efficacy of metal cation additions on the SA resistance of geopolymer cements. The third milestone was to create synthetic metakaolin that performed similarly to natural metakaolin. The fourth milestone was to design, build, and test the efficacy of four abiotic and biotic nano seeding agents. The fifth and final milestone was to quantify the breakeven material cost requirements and estimated environmental lifecycle costs of the most durable geopolymer cement formulations.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A study of the durability of beryllium rocket engines

An experimental test program was performed to demonstrate the durability of a beryllium INTEREGEN rocket engine when operating under conditions simulating the space shuttle reaction control system. A vibration simulator was exposed to the equivalent of 100 missions of X, Y, and Z axes random vibration to demonstrate the integrity of the recently developed injector-to-chamber braze joint. An off-limits engine was hot fired under extreme conditions of mixture ratio, chamber pressure, and orifice plugging. A durability engine was exposed to six environmental cycles interspersed with hot-fire tests without intermediate cleaning, service, or maintenance. Results from this program indicate the ability of the beryllium INTEREGEN engine concept to meet the operational requirements of the space shuttle reaction control system.

Paster, R. D.↗

Evaluation of Low Earth Orbit Environmental Effects on International Space Station Thermal Control Materials

Samples of International Space Station (ISS) thermal control coatings were exposed to simulated low Earth orbit (LEO) environmental conditions to determine effects on optical properties. In one test, samples of the white paint coating Z-93P were coated with outgassed products from Tefzel(R) (ethylene tetrafluoroethylene copolymer) power cable insulation as-may occur on ISS. These samples were then exposed, along with an uncontaminated Z-93P witness sample, to vacuum ultraviolet (VUV) radiation to determine solar absorptance degradation. The Z-93P samples coated with Tefzel(R) outgassing products experienced greater increases in solar absorptance than witness samples not coated with Tefzel(R) outgassing products. In another test, samples of second surface silvered Teflon(R) FEP (fluorinated ethylene propylene), SiO. (where x=2)-coated silvered Teflon(R) FEP, and Z-93P witness samples were exposed to the combined environments of atomic oxygen and VLTV radiation to determine optical properties changes due to these simulated ISS environmental effects. This test verified the durability of these materials in the absence of contaminants.

Dever, Joyce A.↗

CMC Research at NASA Glenn in 2018: Recent Progress and Plans

As part of NASA's Aeronautics research, Glenn Research Center has developed SiC/SiC Ceramic Matrix Composites for 2700 °F turbine engine applications in the next generation of ultra-efficient aircraft. In this presentation, the development of fiber and matrix constituents and fabrication processes that enabled this advancement will be reviewed, and characterization of the resulting improvements in CMC mechanical properties and durability will be summarized. Progress toward the development and validation of models predicting the effects of the engine environment on durability of Ceramic Matrix Composites and Environmental Barrier Coatings will be summarized. Results from current collaborative research with industry and other government agencies will be reviewed. Research plans for 2018 and opportunities for future collaborations with NASA will also be summarized.

Ceramic Matrix Composites↗

CMC Research at NASA Glenn in 2018: Recent Progress and Plans

As part of NASA's Aeronautics research, Glenn Research Center has developed SiC/SiC Ceramic Matrix Composites for 2700 °F turbine engine applications in the next generation of ultra-efficient aircraft. In this presentation, the development of fiber and matrix constituents and fabrication processes that enabled this advancement will be reviewed, and characterization of the resulting improvements in CMC mechanical properties and durability will be summarized. Progress toward the development and validation of models predicting the effects of the engine environment on durability of Ceramic Matrix Composites and Environmental Barrier Coatings will be summarized. Results from current collaborative research with industry and other government agencies will be reviewed. Research plans for 2018 and opportunities for future collaborations with NASA will also be summarized.

Ceramic Matrix Composites↗

CMC Research at NASA Glenn in 2018: Recent Progress and Plans

As part of NASA's Aeronautics research, Glenn Research Center has developed SiC/SiC Ceramic Matrix Composites for 2700°F turbine engine applications in the next generation of ultra-efficient aircraft. In this presentation, the development of fiber and matrix constituents and fabrication processes that enabled this advancement will be reviewed, and characterization of the resulting improvements in CMC mechanical properties and durability will be summarized. Progress toward the development and validation of models predicting the effects of the engine environment on durability of Ceramic Matrix Composites and Environmental Barrier Coatings will be summarized. Results from current collaborative research with industry and other government agencies will be reviewed. Research plans for 2018 and opportunities for future collaborations with NASA will also be summarized.

composites↗

CMC Research at NASA Glenn in 2019: Recent Progress and Plans

As part of NASA's Aeronautics research, Glenn Research Center has developed SiC/SiC Ceramic Matrix Composites (CMC) for 2700 degrees Fahrenheit turbine engine applications in the next generation of ultra-efficient aircraft. In this presentation, the development of fiber and matrix constituents and fabrication processes that enabled this advancement will be reviewed, and characterization of the resulting improvements in CMC mechanical properties and durability will be summarized. Progress toward the development and validation of models predicting the effects of the engine environment on durability of Ceramic Matrix Composites and Environmental Barrier Coatings will be summarized. Results from current collaborative research with industry and other government agencies will be reviewed. Research plans for 2019 and opportunities for future collaborations with NASA will also be summarized.

Composites↗

CMC / EBC Research at NASA Glenn in 2020: Recent Progress and Plans

As part of NASA's Aeronautics research, Glenn Research Center has developed SiC/SiC Ceramic Matrix Composites for 2700°F turbine engine applications in the next generation of ultra-efficient aircraft. In this presentation, the development of fiber and matrix constituents and fabrication processes that enabled this advancement will be reviewed, and characterization of the resulting improvements in CMC mechanical properties and durability will be summarized. Progress toward the development and validation of models predicting the effects of the engine environment on durability of Ceramic Matrix Composites and Environmental Barrier Coatings will be summarized. Results from current collaborative research with industry and other government agencies will be reviewed. Research plans for 2020 and opportunities for future collaborations with NASA will also be summarized.

Grady, Joseph E.↗

CMC / EBC Research at NASA Glenn in 2020: Recent Progress and Plans

As part of NASA's Aeronautics research, Glenn Research Center has developed SiC/SiC Ceramic Matrix Composites for 2700 °F turbine engine applications in the next generation of ultra-efficient aircraft. In this presentation, the development of fiber and matrix constituents and fabrication processes that enabled this advancement will be reviewed, and characterization of the resulting improvements in CMC mechanical properties and durability will be summarized. Progress toward the development and validation of models predicting the effects of the engine environment on durability of Ceramic Matrix Composites and Environmental Barrier Coatings will be summarized. Results from current collaborative research with industry and other government agencies will be reviewed. Research plans for 2020 and opportunities for future collaborations with NASA will also be summarized.

Grady, Joseph↗

CMC Research at NASA Glenn in 2021: Recent Progress and Plans

As part of NASA’s Aeronautics research, Glenn Research Center has developed SiC/SiC Ceramic Matrix Composites for 2700°F turbine engine applications in the next generation of ultra-efficient aircraft. In this presentation, the development and characterization of constituents and fabrication processes that enabled this advancement will be reviewed, and the resulting improvements in CMC mechanical properties and durability will be summarized. Progress toward the development and experimental validation of analytical models predicting the effects of engine operating conditions on the durability of Ceramic Matrix Composites with Environmental Barrier Coatings will be summarized. Results from current collaborative research with industry, universities and other government agencies will be reviewed. Research plans for 2021 and opportunities for future collaborations with NASA will also be summarized.

Ceramic Matrix Composites↗

NASA's Corrosion Technology Laboratory at the Kennedy Space Center: Anticipating, Managing, and Preventing Corrosion

Corrosion is the degradation of a material that results from its interaction with the environment. The marine environment at NASAs Kennedy Space Center (KSC) has been documented by ASM International (formerly American Society for Metals) as the most corrosive in the United States. With the introduction of the Space Shuttle in 1981, the already highly corrosive conditions at the launch pads were rendered even more severe by the 70 tons of highly corrosive hydrochloric acid that were generated by the solid rocket boosters. Numerous failures at the launch pads are caused by corrosion.The structural integrity of ground infrastructure and flight hardware is critical to the success, safety, cost, and sustainability of space missions. As a result of fifty years of experience with launch and ground operations in a natural marine environment that is highly corrosive, NASAs Corrosion Technology Laboratory at KSC is a major source of corrosion control expertise in the launch and other environments. Throughout its history, the Laboratory has evolved from what started as an atmospheric exposure facility near NASAs launch pads into a world-wide recognized capability that provides technical innovations and engineering services in all areas of corrosion for NASA and external customers.This presentation will provide a historical overview of the role of NASAs Corrosion Technology in anticipating, managing, and preventing corrosion. One important challenge in managing and preventing corrosion involves the detrimental impact on humans and the environment of what have been very effective corrosion control strategies. This challenge has motivated the development of new corrosion control technologies that are more effective and environmentally friendly. Strategies for improved corrosion protection and durability can have a huge impact on the economic sustainability of human spaceflight operations.

Corrosion↗

Overview of Space Environment Effects on Materials and GRC's Test Capabilities

The Electro-Physics Branch at NASA Glenn Research Center has been involved with evaluating the durability of materials and understanding environment interactions for over 20 years. A combination of flight experiments, ground based exposure facilities, and environmental modeling provide a well rounded approach to material durability evaluation and prediction for future missions. Ground based testing includes atomic oxygen exposure facilities (large and small area thermal facilities and directed atomic oxygen with and without VUV radiation, VUV and NUV exposure facility, and thermal cycling facility with and without UV radiation. A lunar dust exposure facility is also being brought on-line. Material reactions in these facilities is compared to that observed in space.

Banks, Bruce A.↗

Photovoltaic array environmental protection program

During the photovoltaic array environmental protection program, a coating material, application technique, and design approach intended to protect flexible solar array blankets during a nominal fifteen-year operating lifetime were developed. Numerous thin-film coatings for protecting the Kapton polyimide material used in the construction of the Space Station Freedom flexible solar array blanket were evaluated. The critical solar array design features and protection measures are discussed with special emphasis on the effects of solar array fabrication and flexible printed circuit manufacturing processes on coating durability. The results of the mechanical and environmental test evaluation, including oxygen plasma, neutral oxygen beam, and UV/charged-particle combined exposure, are discussed. These results led to the selection of a silicon dioxide thin-film coating to protect the solar array blanket from the low-earth-orbit atomic oxygen environment.

Bilger, Kevin M.↗

Durability of Geopolymer Lunar Concrete From Exposure in Low Earth Orbit

Constructing infrastructure autonomously with concrete materials through additive manufacturing techniques on the lunar surface is a feasible option. The environmental and exposure conditions that the lunar concrete material will undergo are more extreme than on Earth and studying the durability aspect is important to scaling up the implementation of such materials. Conditions that the material will be exposed to include a hard vacuum, extreme temperatures, and ultraviolet radiation. To that end, geopolymer lunar concrete and ordinary portland cement paste samples were placed outside the International Space Station (ISS) for an approximate six-month exposure period. The samples were part of the 15th Materials International Space Station Experiment (MISSE-15) mission and were mounted in the zenith direction. After the exposure time, results for the samples exhibited discoloration, microstructural cracking, and an overall reduction in volume compared to data collected beforehand. The intent of this work was to characterize geopolymer lunar concrete durability in terms of the lunar environmental conditions in LEO and potential exposure scenarios from a simulated subscale rocket engine plume. To understand the durability of samples in space environment conditions, samples were placed outside the International Space Station (ISS) for a six-month period on the MISSE-FF. Additionally, to test the material's durability if implemented for use in a landing pad, samples were created for an experiment that mimics the exposure of the material to a rocket engine associated with the human lander system. This work is essential to progressing and scaling up geopolymer lunar concrete for implementation as the material's durability is assessed.

Peter J Collins↗

Compact Multi-Gas Monitor for Life Support Systems Control in Space: Evaluation Under Realistic Environmental Conditions

Advanced space life support systems require lightweight, low-power, durable sensors for monitoring critical gas components. A luminescence-based optical flow-through cell to monitor carbon dioxide, oxygen, and humidity has been developed and was demonstrated using bench top instrumentation under environmental conditions relevant to portable life support systems, including initially pure oxygen atmosphere, pressure range from 3.5 to 14.7 psi, temperature range from 50 F to 150 F, and humidity from dry to 100% RH and under liquid water saturation. This paper presents the first compact readout unit for these optical sensors, designed for the volume, power, and weight restrictions of a spacesuit portable Life support system and the analytical characterization of the optical sensors interrogated by the novel optoelectronic system. Trace gas contaminants in a space suit, originating from hardware and material off-gassing and crew member metabolism, are from many chemical families. The result is a gas mix much more complex than the pure oxygen fed into the spacesuit, which may interfere with gas sensor readings. The paper also presents an evaluation of optical sensor performance when exposed to the most significant trace gases reported to be found in spacesuits. The studies were conducted with the spacecraft maximum allowable concentrations for those trace gases and the calculated 8-hr. concentrations resulting from having no trace contaminant control system in the ventilation loop. Finally, a profile of temperature, pressure, humidity, and gas composition for a typical EVA mission has been defined, and the performance of sensors operated repeatedly under simulated EVA mission conditions has been studied.

Delgado, Jesus↗

Durable and Versatile Immobilized Carbonic Anhydrase on Textile Structured Packing for CO 2 Capture

High-performance carbon dioxide (CO 2 )-capture technologies with low environmental impact are necessary to combat the current climate change crisis. Durable and versatile “drop-in-ready” textile structured packings with covalently immobilized carbonic anhydrase (CA) were created as efficient, easy to handle catalysts for CO 2 absorption in benign solvents. The hydrophilic textile structure itself contributed high surface area and superior liquid transport properties to promote gas-liquid reactions that were further enhanced by the presence of CA, leading to excellent CO 2 absorption efficiencies in lab-scale tests. Mechanistic investigations revealed that CO 2 capture efficiency depended primarily on immobilized enzymes at or near the surface, whereas polymer entrapped enzymes were more protected from external stressors than those exposed at the surface, providing strategies to optimize performance and durability. Textile packing with covalently attached enzyme aggregates retained 100% of the initial 66.7% CO 2 capture efficiency over 71-day longevity testing and retained 85% of the initial capture efficiency after 1-year of ambient dry storage. Subsequent stable performance in a 500 h continuous liquid flow scrubber test emphasized the material robustness. Biocatalytic textile packings performed well with different desirable solvents and across wide CO 2 concentration ranges that are critical for CO 2 capture from coal and natural gas-fired power plants, from natural gas and biogas for fuel upgrading, and directly from air.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗