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At least 217 records · Page 12

Studies of the scattering/absorption of minerals

Reflectance spectra were computed for water ice and ammonia ice mixtures as functions of weight fraction, grain size, and viewing geometry to simulate possible outer solar system satellite surfaces. Reflectance spectra of planetary surfaces are most affected by the weight fraction and grain sizes of the minerals in the surface. The reflectance can range from 1.0 to about 0.01 by changing the grain size or weight fraction, a factor of 100. Viewing geometry changes the reflectance by about 25 percent or less.

Clark, Roger N.↗

Toward an Improved Single-Particle Model for Large Irregular Grains

To interpret remote spectral observations, scattering and absorption in a particulate surface are simulated via radiative transfer models. The standard model for this purpose among the planetary science community is the Hapke model. This model (like many others) uses two parameters to characterize the optical behavior of individual grains in a particulate surface, the single-scattering albedo omega and phase function p(g). These terms describe, respectively, the quantity and the angular distribution of light scattered by an individual grain. Unfortunately, these parameters are strictly optical. They can be rather difficult to interpret in terms of more interesting particle properties such as grain sizes, shapes, and compositions, that a remote sensing experiment might seek to discover. An equivalent slab approximation is typically used to relate omega to the grain size and optical constants of the material. This approach can mimic the wavelength-dependent absorption behavior of irregular grains, as long as the imaginary index kappa is much less than 1, the shape is equant, and the grain size D is much larger than the wavelength lambda. Unfortunately, the equivalent slab approach provides no information about p(g), which also has a strong dependence on optical constants and particle form.

Grundy, W. M.↗

Ultimate intrinsic-coercivity samarium-cobalt magnet: An Earth-based feasibility study for space-shuttle missions

Techniques for containerless melting and solidification of the samarium-cobalt alloy without excessive oxidation were developed. The rationale for extending these experiments in a weightless environment is also discussed. The effect of oxygen content from 0.15 to 0.63 weight percent and grain size in the range of 2 to 10 micrometers has been examined on arc-plasma-sprayed SmCo5 magnets. Contrary to expectations, the larger grain sizes tended to improve the coercivities. This was attributed to an increase in homogeneity resulting from higher temperature treatments used to produce larger grain size. No significant differences in coercivity were observed on the basis of oxygen content in the range examined. It is expected that more meaningful data on the relationship between oxygen content and coercivity will be seen when the oxygen content can be lowered to less than 0.1 weight percent.

Das, D. K.↗

Apollo 16: Core 60004 - Preliminary study of less than 1 mm fines

The article studies the possible variation of mineralogy as a function of both grain size and depth within the core of less than 1 mm fines, for the core section 60004 from Apollo 16. Twelve samples of the fines were dry sieved. The grain size analysis showed a bimodal distribution for all samples, indicating a competing process of grain size degeneration and agglutinate formation. Approximately 99% of the minerals in the samples examined consisted of plagioclase feldspar, pyroxene and olivine, with plagioclase the dominant phase. The various minerals were analyzed, using standard electron microprobe techniques, as a function of size range for each sample, and the representative analyses are presented. Several types of glass were also analyzed, ranging in color from orange through yellow and green to colorless. The investigation of the chemical variations of mineral and lithic clasts from the top and the bottom of the core suggests that although minor variations are present, the regolith was derived from fairly homogeneous sources.

Meyer, H. O. A.↗

Magnetic properties of Apollo 14 breccias and their correlation with metamorphism.

The magnetic properties of Apollo 14 breccias can be explained in terms of the grain size distribution of the interstitial iron which is directly related to the metamorphic grade of the sample. In samples 14049 and 14313 iron grains less than 500 A in diameter are dominant as evidenced by a Richter-type magnetic aftereffect and hysteresis measurements. Both samples are of lowest metamorphic grade. The medium metamorphic-grade sample 14321 and the high-grade sample 14312 both show a logarithmic time-dependence of the magnetization indicative of a wide range of relaxation times and thus grain sizes, but sample 14321 contains a stable remanent magnetization whereas sample 14312 does not. This suggests that small multidomain particles (less than 1 micron) are most abundant in sample 14321 while sample 14312 is magnetically controlled by grains greater than 1 micron. The higher the metamorphic grade, the larger the grain size of the iron controlling the magnetic properties.

Gose, W. A.↗

Forging of Advanced Disk Alloy LSHR

The powder metallurgy disk alloy LSHR was designed with a relatively low gamma precipitate solvus temperature and high refractory element content to allow versatile heat treatment processing combined with high tensile, creep and fatigue properties. Grain size can be chiefly controlled through proper selection of solution heat treatment temperatures relative to the gamma precipitate solvus temperature. However, forging process conditions can also significantly influence solution heat treatment-grain size response. Therefore, it is necessary to understand the relationships between forging process conditions and the eventual grain size of solution heat treated material. A series of forging experiments were performed with subsequent subsolvus and supersolvus heat treatments, in search of suitable forging conditions for producing uniform fine grain and coarse grain microstructures. Subsolvus, supersolvus, and combined subsolvus plus supersolvus heat treatments were then applied. Forging and subsequent heat treatment conditions were identified allowing uniform fine and coarse grain microstructures.

Gabb, Timothy P.↗

Metallographic examination of TD-nickel base alloys

Techniques are evaluated for chemical, electrochemical, and thermal etching of thoria dispersed (TD) nickel alloys. An electrochemical etch is described which yielded good results only for large grain sizes of TD-nickel. Two types of thermal etches are assessed for TD-nickel: an oxidation etch and vacuum annealing of a polished specimen to produce an etch. It is shown that the first etch was somewhat dependent on sample orientation with respect to the processing direction, the second technique was not sensitive to specimen orientation or grain size, and neither method appear to alter the innate grain structure when the materials were fully annealed prior to etching. An electrochemical etch is described which was used to observe the microstructures in TD-NiCr, and a thermal-oxidation etch is shown to produce better detail of grain boundaries and to have excellent etching behavior over the entire range of grain sizes of the sample.

Kane, R. D.↗

Radiance Assimilation Shows Promise for Snowpack Characterization: A 1-D Case Study

We demonstrate an ensemble-based radiometric data assimilation (DA) methodology for estimating snow depth and snow grain size using ground-based passive microwave (PM) observations at 18.7 and 36.5 GHz collected during the NASA CLPX-1, March 2003, Colorado, USA. A land surface model was used to develop a prior estimate of the snowpack states, and a radiative transfer model was used to relate the modeled states to the observations. Snow depth bias was -53.3 cm prior to the assimilation, and -7.3 cm after the assimilation. Snow depth estimated by a non-DA-based retrieval algorithm using the same PM data had a bias of -18.3 cm. The sensitivity of the assimilation scheme to the grain size uncertainty was evaluated; over the range of grain size uncertainty tested, the posterior snow depth estimate bias ranges from -2.99 cm to -9.85 cm, which is uniformly better than both the prior and retrieval estimates. This study demonstrates the potential applicability of radiometric DA at larger scales.

Durand, Michael↗

The albedo of snow for partially cloudy skies

The albedo of snow is defined as the ratio of reflected to incident solar energy, and it is an important parameter in the earth's radiation budget analysis and in the study of snowpack's thermal conditions. An approximate model for calculating the incident spectral flux for partially cloudy skies is presented. The input parameters for the calculation are atmospheric precipitable water, turbidity, ozone content, surface pressure, the optical thickness of clouds, and the grain size of snow crystals. The spectral snow reflectance model considers both specular surface reflection and volumetric multiple scattering. The surface reflection is calculated by using a crystal-shape-dependent bidirectional reflectance distribution function; the volumetric multiple scattering is calculated by using a crystal-size-dependent approximate solution in the radiative transfer equation. The model yields spectral and integrated solar flux and snow reflectance as a function of solar elevation and fractional cloud-cover. The illustrative insolation and albedo values were obtained from spectral reflectance and incident flux for representative parameters of Antarctic coastal regions. A simple relationship between grain size and the overcast albedo was obtained. For a set of grain size and shape, the albedo as a function of solar elevation and fractional cloud cover was tabulated.

Choudhury, B. J.↗

Formation of Nanophase Iron in Lunar Soil Simulant for Use in ISRU Studies

For the prospective return of humans to the Moon and the extensive amount of premonitory studies necessary, large quantities of lunar soil simulants are required, for a myriad of purposes from construction/engineering purposes all the way to medical testing of its effects from ingestion by humans. And there is only a limited and precious quantity of lunar soil available on Earth (i.e., Apollo soils) - therefore, the immediate need for lunar soil simulants. Since the Apollo era, there have been several simulants; of these JSC-1 (Johnson Space Center) and MLS-1 (Minnesota Lunar Simulant) have been the most widely used. JSC-1 was produced from glassy volcanic tuff in order to approximate lunar soil geotechnical properties; whereas, MLS-1 approximates the chemistry of Apollo 11 high-Ti soil, 10084. Stocks of both simulants are depleted, but JSC-1 has recently gone back into production. The lunar soil simulant workshop, held at Marshall Space Flight Center in January 2005, identified the need to make new simulants for the special properties of lunar soil, such as nanophase iron (np-Fe(sup 0). Hill et al. (2005, this volume) showed the important role of microscale Fe(sup 0) in microwave processing of the lunar soil simulants JSC-1 and MLS-1. Lunar soil is formed by space weathering of lunar rocks (e.g., micrometeorite impact, cosmic particle bombardment). Glass generated during micrometeorite impact cements rock and mineral fragments together to form aggregates called agglutinates, and also produces vapor that is deposited and coats soil grains. Taylor et al. (2001) showed that the relative amount of impact glass in lunar soil increases with decreasing grain size and is the most abundant component in lunar dust (less than 20 micrometer fraction). Notably, the magnetic susceptibility of lunar soil also increases with the decreasing grain size, as a function of the amount of nanophase-sized Fe(sup 0) in impact-melt generated glass. Keller et al. (1997, 1999) also discovered the presence of abundant np-Fe(sup 0) particles in the glass patinas coating most soil particles. Therefore, the correlation of glass content and magnetic susceptibility can be explained by the presence of the np-Feo particles in glass: small particles contain relatively more np-Fe(sup 0) as glass coatings because the surface area versus mass ratio of the grain size is so increased. The magnetic properties of lunar soil are important in dust mitigation on the Moon (Taylor et al. 2005). Thus material simulating this property is important for testing mitigation methods using electromagnetic field. This np- Fe(sup 0) also produces a unique energy coupling to normal microwaves, such as present in kitchen microwave ovens. Effectively, a portion of lunar soil placed in a normal 2.45 GHz oven will melt at greater than 1200 C before your tea will boil at 100 C, a startling and new discovery reported by Taylor and Meek (2004, 2005). Several methods have been investigated in attempts to make nanophase-sized Feo dispersed within silicate glass; like in the lunar glass. We have been successful in synthesizing such a product and continue to improve on our recipe. We have performed extensive experimentation on this subject to date. Ultimately it will probably be necessary to add this np-Fe(sup 0) bearing silicate glass to lunar soil stimulant, like JSC-1, to actually produce the desired magnetic and microwave coupling properties for use in appropriate ISRU experimentation.

Liu, Yang↗

Determination of hydrogen abundance in selected lunar soils

Hydrogen was implanted in lunar soil through solar wind activity. In order to determine the feasibility of utilizing this solar wind hydrogen, it is necessary to know not only hydrogen abundances in bulk soils from a variety of locations but also the distribution of hydrogen within a given soil. Hydrogen distribution in bulk soils, grain size separates, mineral types, and core samples was investigated. Hydrogen was found in all samples studied. The amount varied considerably, depending on soil maturity, mineral types present, grain size distribution, and depth. Hydrogen implantation is definitely a surface phenomenon. However, as constructional particles are formed, previously exposed surfaces become embedded within particles, causing an enrichment of hydrogen in these species. In view of possibly extracting the hydrogen for use on the lunar surface, it is encouraging to know that hydrogen is present to a considerable depth and not only in the upper few millimeters. Based on these preliminary studies, extraction of solar wind hydrogen from lunar soil appears feasible, particulary if some kind of grain size separation is possible.

Bustin, Roberta↗

A study of spectrum fatigue crack propagation in two aluminum alloys. 2: Influence of microstructures

The important metallurgical factors that influence both constant amplitude and spectrum crack growth behavior in aluminum alloys were investigated. The effect of microstructural features such as grain size, inclusions, and dispersoids was evaluated. It was shown that a lower stress intensities, the I/M 7050 alloy showed better fatigue crack propagation (FCP) resistance than P/M 7091 alloy for both constant amplitude and spectrum testing. It was suggested that the most important microstructural variable accounting for superior FCP resistance of 7050 alloy is its large grain size. It was further postulated that the inhomogenous planar slip and large grain size of 7050 limit dislocation interactions and thus increase slip reversibility which improves FCP performance. The hypothesis was supported by establishing that the cyclic strain hardening exponent for the 7091 alloy is higher than that of 7050.

Telesman, J.↗

Sintering time and atmosphere influences on the microstructure and mechanical properties of tungsten heavy alloys

The present paper traces the microstructure and mechanical property variations vs sintering time under conditions where the atmosphere was adjusted to suppress pore generation. Attention is given to tracing the mechanical property links to the grain size under optimized sintering conditions. The optimal cycle is used to sinter two heavy alloy compositions (88 and 95 wt pct W) for times up to 600 minutes at 1480 C. The 88-pct-W samples slumped, but the 95-pct-W samples were fully densified and suitable for tensile testing. At long sintering times, the tungsten grains flattened and the tungsten contiguity decreased, indicating a transition to low-energy configurations for the solid-liquid interfaces. The cube of the mean grain size varied linearly with the isothermal sintering time. This allowed the determination of grain size effects on mechanical properties, showing a decreasing yield strength with increasing time in agreement with the Hall-Petch behavior. The tensile strength and elongation were highest for sintering times from 30 to 90 min, reflecting a minimum in the residual porosity.

German, R. M.↗

Are there detectable infrared arcs around supernova 1987A?

The possibility is examined that the recently discovered arcs of reflected light in the LMC around SN 1987A may be accompanied by detectable arcs of thermal IR emission from dust heated by the UV-visual output of the supernova. Detectability depends on the ratio Zeta = Q(a)/Q(p)P, where Q(a) and Q(s) are the visual absorption and scattering efficiencies of the dust and P is the small-angle scattering phase function. Calculations for spherical grains of graphite and silicate are presented. A Mathis-Rumpl-Nordsieck distribution of grain sizes has an effective Zeta of roughly 0.1. Some grain size distributions more heavily weighted toward small grains in the Galaxy have values of Zeta roughly one to two. With current instrumentation, the flux is below or at best close to the detection limit.

Dwek, Eli↗

High temperature compounds for turbine vanes

Fabrication and microstructure control studies were conducted on SiC, Si3N and composites based on Si3N. Charpy mode impact testing to 2400 F established that Si3N4/Mo composites have excellent potential. Attempts to fabricate composites of Si3N4 with superalloys, both by hot pressing and infiltration were largely unsuccessful in comparison to using Mo, Re, and Ta which are less reactive. Modest improvements in impact strength were realized for monolithic Si3N4; however, SiC strengths increased by a factor of six and now equal values achieved for Si3N4. Correlations of impact strength with material properties are discussed. Reduced MgO densification aid additions to Si3N4 were found to decrease densification kinetics, increase final porosity, decrease room temperature bend strength, increase high temperature bend strength, and decrease bend stress rupture properties. The decrease in bend strength at high temperature for fine grain size SiC suggested that a slightly larger grain size material with a nearly constant strength-temperature relation may prove desirable in the creep and stress rupture mode.

Rhodes, W. H.↗

Petrography of lunar soil 15601

Lunar soil 15601 has been studied petrographically using grain size analysis, modal analysis, and electron probe microanalysis of monomineralic fragments in the 90-150-micron size fraction. The soil is immature; the grain size distribution is unimodal and very symmetrical, indicating that the soil is a homogeneous product of a single set of processes. It is concluded that 15601 is mostly a simple Apollo 15 mare basalt soil, and its properties can be used to approximate an end product of the array of complex soils that the lunar sample missions have returned.

Basu, A.↗

Snow reflectance from thematic mapper

Calculations of snow reflectance in all 6 TM reflective bands (i.e., 1,2,3,4,5, and 7) using a delta Eddington model show that snow reflectance in bands 4,5, and 7 is sensitive to grain size. Efforts to interpret the surface optical grain size for the spectral extension of albedo are described. Results show the TM data include spectral channels suitable for snow/cloud discrimination and for snow albedo measurements that can be extended throughout the solar spectrum. Except for band 1, the dynamic range is large enough that saturation occurs only occasionally. The finer resolution gives much better detail on the snowcovered area and might make it possible to use textural information instead of the snowline as an index to the amount of snow melt runoff.

Dozier, J.↗

Snow Reflectance from Thematic Mapper

Calculations of snow reflectance in all 6 TM reflective bands (i.e., 1,2,3,4,5, and 7) using a delta Eddington model show that snow reflectance in bands 4,5, and 7 is sensitive to grain size. Efforts to interpret the surface optical grain size for the spectral extension of albedo are described. Results show the TM data include spectral channels suitable for snow/cloud discrimination and for snow albedo measurements that can be extended throughout the solar spectrum. Except for band 1, the dynamic range is large enough that saturation occurs only occasionally. The finer resolution gives much better detail on the snowcovered area and might make it possible to use textural information instead of the snowline as an index to the amount of snow melt runoff.

Dozier, J.↗