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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Enhancements of Nucleate Boiling Under Microgravity Conditions

This paper presents two means for enhancing nucleate boiling and critical heat flux under microgravity conditions: using micro-configured metal-graphite composites as the boiling surface and dilute aqueous solutions of long-chain alcohols as the working fluid. In the former, thermocapillary force induced by temperature difference between the graphite-fiber tips and the metal matrix plays an important role in bubble detachment. Thus boiling-heat transfer performance does not deteriorate in a reduced-gravity environment. In the latter cases, the surface tension-temperature gradient of the long-chain alcohol solutions turns positive as the temperature exceeds a certain value. Consequently, the Marangoni effect does not impede, but rather aids in bubble departure from the heating surface. This feature is most favorable in microgravity. As a result, the bubble size of departure is substantially reduced at higher frequencies. Based on the existing experimental data, and a two-tier theoretical model, correlation formulas are derived for nucleate boiling on the copper-graphite and aluminum-graphite composite surfaces, in both the isolated and coalesced bubble regimes. In addition, performance equations for nucleate boiling and critical heat flux in dilute aqueous solutions of long-chain alcohols are obtained.

Zhang, Nengli↗

Development and fabrication of bismaleimide-graphite composites

The successful fabrication of high temperature resistant composites depends mainly on the processability of the resin binder matrix. For two new bismaleimide type resins the processing of graphite fabric prepregs to composites is described. One resin coded M 751 has to be processed from N-Methylpyrrolidone, the other resin evaluated is a so-called hot melt solvent-less system. Commercial T300/3000 Graphite fabrics were used as reinforcement. The M 751 - Resin is a press grade material and laminates are therefore moulded in high pressure conditions (400 N/sq cm). The solvent-less resin system H 795 is an autoclave grade material and can be cured at 40 N/sq cm. The cure cycles for both the press grade and the autoclave grade material (Fiberite W 143 fabric prepregs) are provided and the mechanical properties of laminates at low (23 C) and high (232 C) temperatures were measured. For comparison, the neat resin flexural properties are also presented. The water absorption for the neat resins and the graphite fabric laminates after a 1000 hour period was evaluated.

Stenzenberger, H.↗

Probabilistic micromechanics and macromechanics of polymer matrix composites

A probabilistic evaluation of an eight ply graphite-epoxy quasi-isotropic laminate was completed using the Integrated Composite Analyzer (ICAN) in conjunction with Monte Carlo simulation and Fast Probability Integration (FPI) techniques. Probabilistic input included fiber and matrix properties, fiber misalignment, fiber volume ratio, void volume ratio, ply thickness and ply layup angle. Cumulative distribution functions (CDFs) for select laminate properties are given. To reduce the number of simulations, a Fast Probability Integration (FPI) technique was used to generate CDFs for the select properties in the absence of fiber misalignment. These CDFs were compared to a second Monte Carlo simulation done without fiber misalignment effects. It was found that FPI requires fewer simulations to obtain the cumulative distribution functions as opposed to Monte Carlo simulation techniques. Furthermore, FPI provides valuable information regarding the sensitivities of composite properties to the constituent properties, fiber volume ratio and void volume ratio.

Mase, G. T.↗

Probabilistic micromechanics and macromechanics of polymer matrix composites

A probabilistic evaluation of an eight ply graphite-epoxy quasi-isotropic laminate was completed using the Integrated Composite Analyzer (ICAN) in conjunction with Monte Carlo simulation and Fast Probability Integration (FPI) techniques. Probabilistic input included fiber and matrix properties, fiber misalignment, fiber volume ratio, void volume ratio, ply thickness and ply layup angle. Cumulative distribution functions (CDFs) for select laminate properties are given. To reduce the number of simulations, a Fast Probability Integration (FPI) technique was used to generate CDFs for the select properties in the absence of fiber misalignment. These CDFs were compared to a second Monte Carlo simulation done without fiber misalignment effects. It was found that FPI requires fewer simulations to obtain the cumulative distribution functions as opposed to Monte Carlo simulation techniques. Furthermore, FPI provides valuable information regarding the sensitivities of composite properties to the constituent properties, fiber volume ratio and void volume ratio.

Mase, G. T.↗

Hot Structure Concepts and Materials for Space Exploration Project

Hot structures are multifunctional material systems that integrate the functions of thermal protection systems (TPS) and primary structure to increase mass efficiency in aerospace vehicles. The goal of this project was to improve our capabilities for developing lightweight, reusable, and reliable hot structures concepts to enable advanced space exploration missions. Specifically, current hot structure carbon/carbon (C/C) composite material systems have low interlaminar strength, which can lead to material failures at low load levels, and large material property variability in as-fabricated parts. Two parallel paths were followed to address these shortcomings. First, analysis models were developed to identify the conditions under which excessive interlaminar stresses occur and to evaluate the potential of stitching the C/C laminae to improve the interlaminar thermal-structural response. This effort included the development of high-fidelity, fracture-based thermal-structural finite element analysis models to evaluate critical features needed to produce efficient hot structure concepts. The second path focused on developing atomistic and mesoscale simulation tools to model the fabrication process in an effort to reduce the time and cost of production while improving the quality of the resulting parts. Aspects of the process currently being investigated include the infusion of the matrix precursor into the fiber preform, the cure of the precursor molecules into their polymeric form, and the carbonization and graphitization of the polymer to form the carbon matrix material. Results of the 6-month study are presented herein.

thermal↗

Advanced composites: Environmental effects on selected resin matrix materials

The effects that expected space flight environment has upon the mechanical properties of epoxy and polyimide matrix composites were analyzed. Environmental phenomena covered water immersion, high temperature aging, humidity, lightning strike, galvanic action, electromagnetic interference, thermal shock, rain and sand erosion, and thermal/vacuum outgassing. The technology state-of-the-art for graphite and boron reinforced epoxy and polyimide matrix materials is summarized to determine the relative merit of using composites in the space shuttle program. Resin matrix composites generally are affected to some degree by natural environmental phenomena with polyimide resin matrix materials less affected than epoxies.

Welhart, E. K.↗

Electrodes for sealed secondary batteries

Self-supporting membrane electrode structures, in which active ingredients and graphite are incorporated in a polymeric matrix, improve performance of electrodes in miniature, sealed, alkaline storage batteries.

Boies, D. B.↗

Optimum design of structures of composite materials in response to aerodynamic noise and noise transmission

Elastic wave propagation and attenuation in a model fiber matrix was investigated. Damping characteristics in graphite epoxy composite materials were measured. A sound transmission test facility suitable to incorporate into NASA Ames wind tunnel for measurement of transmission loss due to sound generation in boundary layers was constructed. Measurement of transmission loss of graphite epoxy composite panels was also included.

Yang, J. C. S.↗

Space fabrication: Graphite composite truss welding and cap forming subsystems

An automated beam builder for the fabrication of space structures is described. The beam builder forms a triangular truss 1.3 meters on a side. Flat strips of preconsolidated graphite fiber fabric in a polysulfone matrix are coiled in a storage canister. Heaters raise the material to forming temperature then the structural cap section is formed by a series of rollers. After cooling, cross members and diagonal tension cords are ultrasonically welded in place to complete the truss. The stability of fabricated structures and composite materials is also examined.

Jenkins, L. M.↗

Determining Fiber Orientation in Graphite-Reinforced Composites

Orientation of fibers in graphite-fiber-reinforced plastics easily determined with new method. Materials scientists thus ensure that fibers, usually not visible after graphite/plastic composite has been cured, properly oriented in test specimens and test results accurately represent the characteristics of composite. Method based on fact that continuous graphite fibers embeded in cured polymer matrix actually parallel conductors. Thus, resistance measured across laminate is at minimum when probes of ohmmeter connected to opposite ends of fibers.

Daniels, J. G.↗

Development of Graphite/Epoxy Corner Fittings

Report documents development project aimed at improving design and load-carrying ability of complicated corner fitting for optical bench. New fitting made of graphite filaments in epoxy-resin matrix. Composite material selected as replacement for titanium because lighter and dimensions change little with temperature variations.

Faile, G.↗

High temperature, short term tensile strength of C6000/PMR-15 composites

Tensile tests were conducted on 0 unidirectionally reinforced Celion 6000 graphite fibers in PMR-15 polyimide matrix. Tensile strengths for coupons subjected to short and long term uniform temperatures were obtained. Thick coupons, heated on one side to produce significant transient through thickness temperature gradients, were tested and compared to the strength of specimens with uniform temperature distributions. All coupons were radiantly heated and reached maximum test temperatures within 15 sec. Tensile loads were applied to the coupons after 15 sec of elevated temperature exposure. Loading rates were selected so that specimen failures occurred within a maximum of 45 sec after reaching the test temperature. Results indicate that significant tensile strength remains beyond the material post cure temperature.

Digiovanni, P. R.↗

Delamination and debonding of materials

The general topics consist of stress analysis, mechanical behavior, and fractography/NDI of composite laminates. Papers are presented on a dynamic hybrid finite-element analysis for interfacial cracks in composites, energy release rate during delamination crack growth in composite laminates, matrix deformation and fracture in graphite-reinforced epoxies, and the role of delamination and damage development on the strength of thick notched laminates. In addition, consideration is given to a new ply model for interlaminar stress analysis, a fracture mechanics approach for designing adhesively bonded joints, the analysis of local delaminations and their influence on composite laminate behavior, and moisture and temperature effects on the mixed-mode delamination fracture of unidirectional graphite/epoxy.

Johnson, W. S.↗

PMR Resin Compositions For High Temperatures

Report describes experiments to identify polymer matrix resins suitable for making graphite-fiber laminates used at 700 degree F (371 degree C) in such applications as aircraft engines to achieve higher thrust-to-weight ratios. Two particular high-molecular-weight formulations of PMR (polymerization of monomer reactants) resins most promising. PMR compositions of higher FMW exhibit enhanced thermo-oxidative stability. Formation of high-quality laminates with these compositions requires use of curing pressures higher than those suitable for compositions of lower FMW.

Vannucci, Raymond D.↗

Probabilistic assessment of space trusses subjected to combined mechanical and thermal loads

A three-bay, space, cantilever truss is probabilistically evaluated to quantify the range of uncertainties of buckling loads and member forces due to nonuniform thermal loads, applied loads and moments (mechanical loads), and combination of both. The truss members are assumed to be made from Aluminum tubes or high modulus graphite-fiber/intermediate modulus epoxy-matrix composite tubes. Cumulative distribution function results show that certain combinations of thermal loads with mechanical loads reduce the probabilistic buckling loads and increase the magnitude of the member axial forces for the aluminum truss. The same trend is observed for the composite truss as well, as however, the thermal effects on the probabilistic buckling loads and member axial forces are not as substantial as that for an aluminum truss. This can be attributed to the large differences in the values of coefficient of thermal expansion. Finally, the sensitivities associated with the uncertainties in the structural, material, and load variables (primitive variables) are investigated. They show that buckling loads and member axial forces are most sensitive to the uncertainties in spacial (geometry) variables.

Pai, Shantaram S.↗

Nonuniform thermal environmental effects on space truss structural reliability

A three-bay, space, cantilever truss is probabilistically evaluated to quantify the range of uncertainties of buckling loads and member forces due to nonuniform thermal loads, applied loads and moments (mechanical loads), and combination of both. The truss members are assumed to be made from (1) aluminum tubes or (2) high modulus graphite-fiber/intermediate modulus epoxy-matrix composite tubes. Cumulative distribution function results show that certain combinations of thermal loads with mechanical loads reduce the probabilistic buckling loads and increase the magnitude of the member axial forces for aluminum truss. However, the reverse is true for composite truss due to very low coefficient of thermal expansion and higher stiffness of the composite. Finally, the sensitivities associated with the uncertainties in the structural, material, and load variables (primitive variables) are investigated. They show that buckling loads and member axial forces are most sensitive to the uncertainties in spacial (geometry) variables.

Pai, Shantaram S.↗

LDEF polymeric materials: 10 months versus 5.8 years of exposure

The chemical characterization of several polymeric materials which received 10 months of exposure and 5.8 years of exposure on a Row 9 Long Duration Exposure Facility (LDEF) experiment (A0134) is reported. Specimens include fluorinated ethylene propylene (FEP) teflon film, polysulfone film, and graphite fiber reinforced epoxy amd polysulfone matrix composites. The responses of these materials to the two LEO exposures are compared. The results of infrared, thermal, x-ray photoelectron, and scanning electron microscope analyses are reported. Solution property measurements of various molecular weight parameters are presented for the thermoplastic polysulfone materials. Molecular level effects attributable to exposure that were present in 10-month exposed specimens were not found in 5.8-year exposed specimens. This result suggests that increased atomic oxygen fluence toward the end of the LDEF mission may have eroded away selected environmentally induced changes in surface chemistry for 5.8-year exposure specimens.

Young, Philip R.↗