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NASA NTRS2001

Structural Fluctuations and Thermophysical Properties of Molten II-VI Compounds

Recently, in support of the microgravity experiment entitled "Crystal Growth of Selected 11-VI Semiconducting Alloys by Directional Solidification," the viscosity of HgZnTe pseudobinary melt was measured using an oscillating-cup viscometer at NASA/Marshall Space Flight Center (MSFC). An unexpected time drift of the measured viscosity, which shows a slow relaxation phenomena at temperatures near the liquidus point, was reproducibly observed. Two sets of data were obtained by cooling the Hg(0.84)Zn(0.16)Te melt from 850 C and stabilizing at temperatures of 790 C, which is just above the liquidus temperature, and stabilizing at temperature of 810 C. While it took one day to reach equilibration at 810 C, five days were required at 790 C A similar relaxation phenomenon was also observed in the measured density of the same liquid. Furthermore, in the density measurements of the HgCdTe melts, which is the pseudobinary system studied in another flight experiment entitled "Growth of Solid Solution Single Crystals," a negative thermal expansion was reported. The liquid density increases from the liquidus point to a maximum value at a temperature approximately 700 C above the liquidus, where normal thermal expansion progressively resumes.

Su, Ching-Hua↗
NASA NTRS2001

Computed Tomography Support for Microgravity Materials Science Experiments

The accurate measurement of density in both liquid and solid samples is of considerable interest to Principal Investigators with materials science experiments slated for the ISS. The work to be described is an innovative application of a conventional industrial nondestructive evaluation instrument. Traditional applications of industrial computed tomography (CT) rely on reconstructing cross sections of large structures to provide two-dimensional planar views which can identify defects such as porosity, or other material anomalies. This has been done on microgravity materials science experiments to check the integrity of ampoule-cartridge assemblies for safety purposes. With a substantially monoenergetic flux, as can be obtained with a radioactive cobalt source, there will be a direct correlation between absorption and density. Under such conditions it then becomes possible to make accurate measurements of density throughout a sample, and even when the sample itself is enclosed within a furnace and a safety required cartridge. Such a system has been installed at Kennedy Space Center (KSC) and is available to PIs to examine samples before and after flight. The CT system is being used to provide density information for two purposes. Firstly, the determination of density changes from liquid to solid is vital information to the PI for purposes of modeling the solidification behavior of his sample, and to engineers who have to design containment ampoules and must allow for shrinkage and other volume changes that may occur during processing. While such information can be obtained by pycnometric measurements, the possibility of using a furnace installed on the CT system enables one to examine potentially dangerous materials having high vapor pressures, while not needing visible access to the material. In addition, uniform temperature can readily be obtained, and the system can be controlled to ramp up, hold, and ramp down while collecting data over a wide range of parameters automatically. Results of initial tests on low melting point elements such as gallium, indium and tin will be presented, and the intent is to proceed to compounds such as InSb, HgCdTe and CdTe. Alloys such as Pb-Sb (PI - Poirier, U AZ) and Cu-Al (PI - Trivedi, Ames Lab.), which are the subjects of flight experiments, will also be examined. The second application is the conversion of measured density values directly to composition. This was successfully done with the mercury cadmium telluride alloys grown on the second and fourth United States Microgravity Payload (USMP-2 and USMP-4) missions by Lehoczky. CdTe values along the length of the boules were obtained at KSC prior to cutting the sample, and could have been obtained prior to its removal from the cartridge and ampoule. Examples of the data obtained will be shown. It is anticipated that several of the materials science PIs will avail themselves of the technique described, initially for determining densities prior to flight, and then to acquire early quantitative data on the compositional variation within their samples.

Gillies, Donald C.↗
NASA NTRS2001

Mid-Infrared Interferometry: Science and Technology

Interferometry in the mid-infrared atmospheric window (9-12 microns) is extremely challenging because of the high background due to emission from warm telescope optics and the atmosphere itself. During the past twelve years this challenge has been met by the U.C. Berkeley Infrared Spatial Interferometer (ISI), a heterodyne stellar interferometer comprised of two 1.65 m aperture telescopes mounted in custom semi-trailers. Carbon-dioxide laser local oscillators and LN2 cooled HgCdTe photodiodes are used to down-convert radiation at approx. 30 THz into an approximately 5 GHz (DSB) IF band. The maximum baseline at present is 65 m giving a nominal resolution of 16 milliarcsecs. A third telescope is being integrated with the other two and within the next year will operate as an imaging interferometer providing data with three simultaneous baselines and a closure phase, and baselines up to about 75 m.

Danchi, William C.↗
NASA NTRS1998

In situ CF3 Detection in Low Pressure Inductive Discharges by Fourier Transform Infrared Spectroscopy

The detection of CF(x) (x=1-3) radicals in low pressure discharges using source gases such as CF4 and CHF3 is of importance to the understanding of their chemical structure and relevance in plasma based etching processes. These radicals are known to contribute to the formation of fluorocarbon polymer films, which affect the selectivity and anisotropy of etching. In this study, we present preliminary results of the quantitative measurement of trifluoromethyl radicals, CF3, in low pressure discharges. The discharge studied here is an inductively (transformer) coupled plasma (ICP) source in the GEC reference cell, operating on pure CF4 at pressures ranging from 10 - 100 mTorr, This plasma source generates higher electron number densities at lower operating pressures than obtainable with the parallel-plate capacitively coupled version of the GEC reference cell. Also, this expanded operating regime is more relevant to new generations of industrial plasma reactors being used by the microelectronics industry. Fourier transform infrared (FTIR) spectroscopy is employed to observe the absorption band of CF3 radicals in the electronic ground state X2Al in the region of 1233-1270/cm. The spectrometer is equipped with a high sensitivity HgCdTe (MCT) detector and has a fixed resolution of 0.125/cm. The CF3 concentrations are measured for a range of operating pressures and discharge power levels.

Kim, J. S.↗
NASA NTRS2003

Independent Testing of JWST Detector Prototypes

The Independent Detector Testing Laboratory (IDTL) is jointly operated by the Space Telescope Science Institute (STScI) and the Johns Hopkins University (MU), and is assisting the James Webb Space Telescope (JWST) mission in choosing and operating the best near-infrared detectors under a NASA Grant. The JWST is the centerpiece of the NASA Office of Space Science theme, the Astronomical Search for Origins, and the highest priority astronomy project for the next decade, according to the National Academy of Science. JWST will need to have the sensitivity to see the first light in the Universe to determine how galaxies formed in the web of dark matter that existed when the Universe was in its infancy (z approx. 10 - 20). To achieve this goal, the JWST Project must pursue an aggressive technology program and advance infrared detectors to performance levels beyond what is now possible. As part of this program, NASA has selected the IDTL to verify comparative performance between prototype JWST detectors developed by Rockwell Scientific (HgCdTe) and Raytheon (InSb). The IDTL is charged with obtaining an independent assessment of the ability of these two competing technologies to achieve the demanding specifications of the JWST program within the 0.6 - 5 approx. mum bandpass and in an ultra-low background (less than 0.01 e'/s/pixel) environment. We describe results from the JWST Detector Characterization Project that is being performed in the IDTL. In this project, we are measuring first-order detector parameters, i.e. dark current, read noise, QE, intra-pixel sensitivity, linearity, as functions of temperature, well size, and operational mode.

Figer, D. F.↗
NASA NTRS2003

Status and Performance of HST Wide Field Camera 3

The HST Wide Field Camera 3 is a panchromatic UV-visible-near infrared camera whose development is currently nearing completion, for a planned installation into the Hubble Space Telescope during Servicing Mission 4. WFC3 provides two imaging channels. The UVIS channel features a 4096 x 4096 pixel CCD focal plane with sensitivity from 200 to 1000 nm and a 160 x 160 arcsec field of view. The UVIS channel provides unprecedented sensitivity and field of view in the near ultraviolet for HST. The IR channel features a 1014 x 1014 pixel HgCdTe focal plane covering 850 to 1700 nm with a 135 x 135 arcsec field of view, providing a substantial advance in IR survey efficiency for HST. The construction of WFC3 is nearly complete, and the instrument is well into its integration and test program. We present the current status of the instrument and its projected scientific performance when installed into HST.

Kimble, Randy↗
NASA NTRS2004

Semiconductor Crystal Growth in Static and Rotating Magnetic fields

Magnetic fields have been applied during the growth of bulk semiconductor crystals to control the convective flow behavior of the melt. A static magnetic field established Lorentz forces which tend to reduce the convective intensity in the melt. At sufficiently high magnetic field strengths, a boundary layer is established ahead of the solid-liquid interface where mass transport is dominated by diffusion. This can have a significant effect on segregation behavior and can eliminate striations in grown crystals resulting from convective instabilities. Experiments on dilute (Ge:Ga) and solid solution (Ge-Si) semiconductor systems show a transition from a completely mixed convective state to a diffusion-controlled state between 0 and 5 Tesla. In HgCdTe, radial segregation approached the diffusion limited regime and the curvature of the solid-liquid interface was reduced by a factor of 3 during growth in magnetic fields in excess of 0.5 Tesla. Convection can also be controlled during growth at reduced gravitational levels. However, the direction of the residual steady-state acceleration vector can compromise this effect if it cannot be controlled. A magnetic field in reduced gravity can suppress disturbances caused by residual transverse accelerations and by random non-steady accelerations. Indeed, a joint program between NASA and the NHMFL resulted in the construction of a prototype spaceflight magnet for crystal growth applications. An alternative to the suppression of convection by static magnetic fields and reduced gravity is the imposition of controlled steady flow generated by rotating magnetic fields (RMF)'s. The potential benefits of an RMF include homogenization of the melt temperature and concentration distribution, and control of the solid-liquid interface shape. Adjusting the strength and frequency of the applied magnetic field allows tailoring of the resultant flow field. A limitation of RMF's is that they introduce deleterious instabilities above a critical magnetic field value. Growth conditions in which static magnetic fields rotational magnetic fields, and reduced gravitational levels can have a beneficial role will be described.

Volz, Martin↗
NASA NTRS2004

The Case for Moderately-Cooled, Far-Infrared Thermal Detectors

There are moderately-cooled (around 77K) infrared detectors, for instance InSb (around 5 microns wavelength) and HgCdTe (around 15 to 20 microns wavelength). However for longer wavelengths there are either uncooled thermal-type detectors or highly cooled (about 4K and lower) quantum and thermal detectors, with the notable exception of high Tc superconductor detectors. We will describe certain long-wavelength applications in space where only moderate cooling is feasible, and where better sensitivity is required than possible with uncooled detectors. These requirements could be met with high Tc bolometers, but it may also be prudent to develop other technologies. Additionally, over the past 16 years a marketplace has not developed for the commercial production of high Tc bolometers, indicating their production may be a natural endeavor for government laboratories.

Brasunas, John C.↗
NASA NTRS2003

Uses of Computed Tomography for Characterizing Materials Grown Terrestrially and in Microgravity

Tomography (CT) has proved to be of inestimable use in providing a rapid evaluation of a variety of samples from Mechanics of Granular Materials (MGM) to electronic materials (Ge-Si alloys) to space grown materials such as meteorites. The system at Kennedy Space Center (KSC), because of its convenient geographical location, is ideal for examining samples before launch and immediately after returning to Earth. It also has the advantage of the choice of fluxes, and in particular the use of a radioactive cobalt source, which is basically monochromatic. This permits a reasonable measurement of density to be made from which chemical composition can be determined. Due to the current dearth of long duration space grown materials, the CT instrument has been used: (1) to characterize materials in preparation for flight, (2) to determine thermal expansion values, and (3) to examine long duration space grown materials, i.e. meteorites. This work will first describe the establishment of the protocol for obtaining the optimum density readings for any material. Included will be the effects of the hardware or instrumental parameters that can be controlled, and the techniques used to process the CT data. Examples will be given of the compositional variation along a single crystal of Ge-Si alloy. Density variation with temperature has been measured in preparation for future materials science experiments; this involved the fabrication at MSFC and installation of a single zone furnace at KSC incorporating a heat pipe to ensure high temperature uniformity. At the time of writing the thermal expansion of lead (Pb) has been measured from room temperature to 900 C. Three methods are available. Digital radiography enables length changes to be determined. Prior to melting the sample is smaller than the container and the diameter change can be measured. Most critical, however, is the density change in solid, through the melting region, and in the liquid state. These data are needed for engineering purposes to aid in the design of containment cartridges, and for enabling fluid flow calculations. A second sample, with the Pb alloyed with Sb is ready for scanning. This corresponds to the planned composition of Dr. Poirier s flight experiment. Other materials pertinent to NASA programs such as Al-Cu (Trivedi), CdTe (Banish), HgCdTe (Lehoczky) will be examined below and above the melting point. Finally, three-dimensional results will be shown of the structure of a two-phase metallic meteorite of metal and sulfide, in which the Fe-Ni phase has coarsened during slow cooling over hundreds of millions of years.

Source record↗
NASA NTRS2004

Exploring the Saturn System in the Thermal Infrared: The Composite Infrared Spectrometer

The Composite Inbred Spectrometer (CIRS) is a remote-sensing Fourier Transform Spectrometer on the Cassini orbiter that measures thermal radiation over two decades in wave number, from 10 to 1400 cm (1 mm to 7pm), with a spectral resolution that can be set from 0.5 to 20 cm. The far in portion of the spectrum (10 - 600 cm) is measured with a polarizing interferometer having thermopile detectors with a common 4-mrad field of view. The middle infrared portion is measured with a traditional Michelson interferometer having two focal planes (600 - 1100cm, 1100-1400 cm). Each focal plane is composed of a 1x10 array of HgCdTe detectors, each detector having a 0.3-mrad field of view. CIRS observations will provide three-dimensional maps of temperature, gas composition, and aerosols/condensates of the atmospheres of Titan and Saturn with good vertical and horizontal resolution, from deep in their tropospheres to high in their mesospheres. CIRS ability to observe atmospheres in the limb viewing mode (in addition to nadir) offers the opportunity to provide accurate and highly resolved vertical profiles of these atmospheric variables. The ability to observe with high-spectral resolution should facilitate the identification of new constituents. CIRS will also map the thermal and compositional properties of the surfaces of Saturn's icy satellites. It will similarly map Saturn's rings, characterizing their formation and evolution. The combination of broad spectral range, programmable spectral resolution, the small detector fields of view, and an orbiting spacecraft platform will allow CIRS to observe the Saturnian system in the thermal infrared at a level of detail not previously achieved.

Flasar, F. M.↗
NASA NTRS2004

Status and Performance of HST/Wide Field Camera 3

The HST Wide Field Camera 3 is a panchromatic UV-visible-near infrared camera whose development is currently nearing completion, for a planned installation into the Hubble Space Telescope during Servicing Mission 4. WFC3 provides two imaging channels. The UVIS channel features a 4096 x 4096 pixel CCD focal plane with sensitivity from 200 to 1000 nm and a 160 x 160 arcsec field of view. The UVIS channel provides unprecedented sensitivity and field of view in the near ultraviolet for HST. The IR channel features a 1014 x 1014 pixel HgCdTe focal plane covering 850 to 1700 nm with a 135 x 135 arcsec field of view, providing an order of magnitude increase in J+H band surveying efficiency for HST. WFC3 offers a rich complement of filters and grisms in each channel. The construction of WFC3 is nearly complete, and the instrument is well into its integration and test program. We present the current status of the instrument and its projected scientific performance.

Kimble, Randy↗
NASA NTRS2004

Status and Performance of HSTNVide Field Camera 3

The HST Wide Field Camera 3 is a panchromatic UV-visible-near infrared camera whose development is currently nearing completion, for a planned installation into the Hubble Space Telescope during Servicing Mission 4. WFC3 provides two imaging channels. The UVIS channel features a 4096 x 4096 pixel CCD focal plane with sensitivity from 200 to 1000 nm and a 160 x 160 arcsec field of view. The UVIS channel provides unprecedented sensitivity and field of view in the near ultraviolet for HST. The IR channel features a 1014 x 1014 pixel HgCdTe focal plane covering 850 to 1700 nm with a 135 x 135 arcsec field of view, providing an order of magnitude increase in J+H band surveying efficiency for HST. WFC3 offers a rich complement of filters and grisms in each channel. The construction of WFC3 is nearly complete, and the instrument is well into its integration and test program. We present the current status of the instrument and its projected scientific performance.

Kimble, Randy↗
NASA NTRS2004

Atmospheric Trace Gas Abundances and Stable Isotope Ratios via IR-LIF

We propose to develop new technologies with support provided by PIDDP that will enable the in situ measurements of abundances and stable isotope ratios in important radiatively and biogenically active gases such as carbon dioxide, carbon monoxide, water, methane, nitrous oxide, and hydrogen sulfide to very high precision (0.1 per mil or better for the isotopic ratios, for example). Such measurements, impossible at present, could provide pivotal new constraints on the global (bio)geochemical budgets of these critical species, and could also be used to examine the dynamics of atmospheric transport on Mars, Titan, and other solar system bodies. We believe the combination of solid state light sources with imaging of the IR laser induced fluorescence (IR-LIF) via newly available detector arrays will make such in situ measurements possible for the first time. Even under ambient terrestrial conditions, the LIF yield from vibrational excitation of species such as water and carbon dioxide should produce emission measures well in excess of ten billion photons/sec from samples volumes of order 1 c.c. These count rates can, in principle, yield detection limits into the sub-ppt range that are required for the in situ isotopic study of atmospheric trace gases. While promising, such technologies are relatively immature, but developing rapidly, and there are a great many uncertainties regarding their applicability to in situ IR-LIF planetary studies. We therefore feel PIDDP support will be critical to developing these new tools, and propose a three-year program to combine microchip near-IR lasers with low background detection axes and state-of-the-art HgCdTe detectors developed for astronomical spectroscopy to investigate the sensitivity of IR-LIF under realistic planetary conditions, to optimize the optical pumping and filtering schemes for important species, and to apply the spectrometer to the non-destructive measurement of stable isotopes in a variety of test samples. These studies form the necessary precursors to the development of compact, lightweight stable isotope/trace gas sensors for future planetary missions.

Blake, Geoffrey A.↗
NASA NTRS2004

Thermophysical Properties of Selected II-VI Semiconducting Melts

Thermophysical properties are essential for the accurate predication of the crystal growth process by computational modeling. Currently, the temperature dependent thermophysical property data for the II-VI semiconductor melts are scarce. This paper reports the results of the temperature dependence of melt density, viscosity and electrical conductivity of selected II-VI compounds, including HgTe, HgCdTe and HgZnTe. The melt density was measured using a pycnometric method, and the viscosity and electrical conductivity were measured by a transient torque method. The results were compared with and showed good agreement with the existing data in the literature.

Li, C.↗
NASA NTRS2004

Independent Testing of JWST Detector Prototypes

The Independent Detector Testing Laboratory (IDTL) is jointly operated by the Space Telescope Science Institute (STScI) and the Johns Hopkins University (JHU), and is assisting the James Webb Space Telescope (JWST) mission in choosing and operating the best near-infrared detectors. The JWST is the centerpiece of the NASA Office of Space Science theme, the Astronomical Search for Origins, and the highest priority astronomy project for the next decade, according to the National Academy of Science. JWST will need to have the sensitivity to see the first light in the Universe to determine how galaxies formed in the web of dark matter that existed when the Universe was in its infancy (z is approximately 10-20). To achieve this goal, the JWST Project must pursue an aggressive technology program and advance infrared detectors to performance levels beyond what is now possible. As part of this program, NASA has selected the IDTL to verify comparative performance between prototype JWST detectors developed by Rockwell Scientific (HgCdTe) and Raytheon (InSb). The IDTL is charged with obtaining an independent assessment of the ability of these two competing technologies to achieve the demanding specifications of the JWST program within the 0.6-5 micron bandpass and in an ultra-low background (less than 0.01 e(-)/s/pixel) environment. We describe results from the JWST Detector Characterization Project that is being performed in the LDTL. In this project, we are measuring first-order detector parameters, i.e. dark current, read noise, QE, intra-pixel sensitivity, linearity, as functions of temperature, well size, and operational mode.

Figer, Donald F.↗
NASA NTRS2004

Novel Infrared Phototransistors for Atmospheric CO2 Profiling at 2 Micron Wavelength

Two-micron detectors are critical for atmospheric carbon dioxide profiling using the lidar technique. The characterization results of a novel infrared AlGaAsSb/ InGaAsSb phototransistor are reported. Emitter dark current variation with the collector-emitter voltage at different temperatures is acquired to examine the gain mechanism. Spectral response measurements resulted in responsivity as high as 2650 A/W at 2.05 m wavelength. Bias voltage and temperature effects on the device responsivity are presented. The detectivity of this device is compared to InGaAs and HgCdTe devices.

Refaat, Tamer F.↗
NASA NTRS2004

Novel Infrared Phototransistors for Atmospheric CO2 Profiling at 2 microns Wavelength

Two-micron detectors are critical for atmospheric carbon dioxide profiling using the lidar technique. The characterization results of a novel infrared AlGaAsSb/ InGaAsSb phototransistor are reported. Emitter dark current variation with the collector-emitter voltage at different temperatures is acquired to examine the gain mechanism. Spectral response measurements resulted in responsivity as high as 2650 A/W at 2.05 microns wavelength. Bias voltage and temperature effects on the device responsivity are presented. The detectivity of this device is compared to InGaAs and HgCdTe devices.

Refaat, Tamer F.↗
NASA NTRS2005

Early Results on the Saturn System from the Composite Infrared Spectrometer

The Composite Infrared Spectrometer (CIRS) is a remote-sensing Fourier Transform Spectrometer on the Cassini orbiter that measures thermal radiation over two decades in wavenumber, from 10 to 1400 /cm (1 mm to 7 microns), with a spectral resolution that can be set from 0.5 to 15.5 /cm. The far infrared portion of the spectrum (10-600 /cm) is measured with a polarizing interferometer having thermopile detectors with a common 4-mrad field of view. The middle infrared portion is measured with a traditional Michelson interferometer having two focal planes (600-1100 /cm, 1100-1400 cm). Each focal plane is composed of a 1x10 array of HgCdTe detectors, each detector having a 0.3-mrad field of view. More complete descriptions of the instrument and investigation are given in and. A brief description of the first results from observations through the Saturn orbital insertion period can be found in.

Flasar, F. M.↗