Fir Spectroscopy of the Nucleus and IR-Ring of the AGN/Starburst NGC 4945
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far-infrared↗
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The AstroBiology Explorer (ABE) MIDEX Mission Concept: Using Infrared Spectroscopy to Identify Organic Molecules in Space
One of the principal means by which organic compounds are detected and identified in space is by infrared spectroscopy. Past IR telescopic and laboratory studies have shown that much of the carbon in the interstellar medium (ISM) is in complex organic species but the distribution, abundance and evolutionary relationships of these materials are not well understood. The Astrobiology Explorer (ABE) is a MIDEX mission concept designed to conduct IR spectroscopic observations to detect and identify these materials and address outstanding problems in astrobiology, astrochemistry, and astrophysics. ABE's core science program includes observations of planetary nebulae and stellar outflows, protostellar objects, Solar System objects, and galaxies, and lines of sight through dense molecular clouds and the diffuse ISM. ABE is a cryogenically-cooled 60 cm diameter space telescope equipped with 3 cross-dispersed R-2000 spectrometers that share a single common slit. Each spectrometer measures one spectral octave and together cover the entire 2.5-20 micron region simultaneously. The spectrometers use state-of-the-art InSb and Si:As 1024x1024 pixel detectors. ABE would operate in a heliocentric, Earth drift-away orbit and have a core science mission lasting approximately 1.5 years. ABE is currently under study at NASA's Ames Research Center in collaboration with Ball Aerospace and Technologies Corp.
Sandford, Scott A.↗
Coordinating Chemical and Mineralogical Analyses of Antarctic Dry Valley Sediments as Potential Analogs for Mars
The Antarctic Dry Valleys (ADV) provide a unique terrestrial analog for Martian surface processes as they are extremely cold and dry sedimentary environments. The surface geology and the chemical composition of the Dry Valleys that are similar to Mars suggest the possible presence of these soil-formation processes on Mars. The soils and sediments from Wright Valley, Antarctica were investigated in this study to examine mineralogical and chemical changes along the surface layer in this region and as a function of depth. Surface samples collected near Prospect Mesa and Don Juan Pond of the ADV were analyzed using visible/near-infrared (VNIR) and mid-IR reflectance spectroscopy and major and trace element abundances.
Patel, S. N.↗
Infrared Spectra and Optical Constants of Astronomical Ices: I. Amorphous and Crystalline Acetylene
Here we report recent measurements on acetylene (C2H2) ices at temperatures applicable to the outer Solar System and the interstellar medium. New near- and mid-infrared data, including optical constants (n, k), absorption coefficients (alpha), and absolute band strengths (A), are presented for both amorphous and crystalline phases of C2H2 that exist below 70 K. Comparisons are made to earlier work. Electronic versions of the data are made available, as is a computer routine to use our reported n and k values to simulate the observed IR spectra. Suggestions are given for the use of the data and a comparison to a spectrum of Makemake is made.
IR spectroscopy↗
Infrared Spectra and Optical Constants of Astronomical Ices: II. Ethane and Ethylene
Infrared spectroscopic observations have established the presence of hydrocarbon ices on Pluto and other TNOs, but the abundances of such molecules cannot be deduced without accurate optical constants (n, k) and reference spectra. In this paper we present our recent measurements of near- and mid-infrared optical constants for ethane (C2H6) and ethylene (C2H4) in multiple ice phases and at multiple temperatures. As in our recent work on acetylene (C2H2), we also report new measurements of the index of refraction of each ice at 670 nm. Comparisons are made to earlier work where possible, and electronic versions of our new results are made available.
Ices↗
Infrared Band Strengths for Amorphous and Crystalline Methyl Propionate, a Candidate Interstellar Molecule
Mid-infrared spectra of amorphous and crystalline methyl propionate, CH3CH2COOCH3, are presented for the first time from a single laboratory, along with measurements of the refractive index of each solid form. Density estimates are made and IR band strengths and absorption coefficients are calculated. Vapor pressures of crystalline methyl propionate at 140-150 K are reported along with an enthalpy of sublimation. Spectroscopic results are compared to a recent study of this compound, and the phase of methyl propionate in that work is identified. Several applications are described.
Astrochemistry↗
Solid-State Isomerization and Infrared Band Strengths of Two Conformational Isomers of Cyclopropanecarboxaldehyde, A Candidate Interstellar Molecule
At least a dozen of the known interstellar molecules possess a formyl group (HCO), suggesting that other such species exist and await discovery in the interstellar medium. Here, we examine the mid-infrared (mid-IR) spectrum and selected physical properties of one such candidate, cyclopropanecarboxaldehyde, in amorphous ices. Mid-IR transmission spectra of solid cyclopropanecarboxaldehyde are presented for the first time and used to determine the cis-to-trans ratio of conformational isomers present in amorphous samples. The measured ratio is compared to one from an electron-diffraction study of the gas-phase compound. The cis-to-trans isomerization in the amorphous compound is followed, and the activation energy is determined. The first IR band strengths for solid cyclopropanecarboxaldehyde are reported. Also presented are refractive indices and densities at 15 K for amorphous forms of two related compounds, cyclopropane and cyclopropanemethanol. Two low-temperature reactions for the interstellar formation of cyclopropanecarboxaldehyde are briefly described.
band strengths↗
Preparation, Identification, and Low-Temperature Infrared Spectra of Two Elusive Crystalline Nitrile Ices
Infrared (IR) spectra of the alkyl nitrile ices CH3CN and CH3CH2CN are relevant to the study of the low-temperature chemistry of objects within and beyond the Solar System, but the thermodynamically favored low-temperature crystalline phases of these compounds have not been presented and identified in the planetary-sciences literature. Moreover, there is a large variation in the published IR spectra of these two icy solids, including spectra that are used for the analyses of spacecraft data from the Voyager and Cassini missions. Here the IR spectra of the low-temperature crystalline forms of CH3CN and CH3CH2CN, which are the thermodynamically stable phases at Titan temperatures, are presented for the first time with all samples being made by vapor-phase deposition. Conditions are described for producing these ice phases for both compounds, and new measurements are reported of ice density and refractive index, quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, nitrile abundances in extraterrestrial environments. Comparisons are drawn between CH3CN and CH3CH2CN, an earlier prediction on their similar crystallization behaviors is verified, and previous work is examined in light of these new results, including a counter-intuitive observation in which the low-temperature phase of an ice is made by heating a high-temperature phase. Applications and extensions are described.
Ices, IR spectroscopy, Titan, organic chemistry, i↗
IR Spectra and Properties of Solid Acetone, an Interstellar and Cometary Molecule
Mid-infrared spectra of amorphous and crystalline acetone are presented along with measurements of the refractive index and density for both forms of the compound. Infrared band strengths are reported for the first time for amorphous and crystalline acetone, along with IR optical constants. Vapor pressures and a sublimation enthalpy for crystalline acetone also are reported. Positions of 13C-labeled acetone are measured. Band strengths are compared to gas-phase values and to the results of a density-functional calculation. A 73% error in previous work is identified and corrected.
IR spectroscopy, band strengths, astrochemistry, a↗
Cryovolcanic flooding in Viking Terra on Pluto
A prominent fossa trough (Uncama Fossa) and adjacent 28-km diameter impact crater (Hardie) in Pluto's Viking Terra, as seen in the high-resolution images from the New Horizons spacecraft, show morphological evidence of in-filling with a material of uniform texture and red-brown color. A linear fissure parallel to the trough may be the source of a fountaining event yielding a cryoclastic deposit having the same composition and color properties as is found in the trough and crater. Spectral maps of this region with the New Horizons LEISA instrument reveal the spectral signature of H2O ice in these structures and in distributed patches in the adjacent terrain in Viking Terra. A detailed statistical analysis of the spectral maps shows that the colored H2O ice filling material also carries the 2.2-μm signature of an ammoniated component that may be an ammonia hydrate (NH3·nH2O) or an ammoniated salt. This paper advances the view that the crater and fossa trough have been flooded by a cryolava debouched from Pluto's interior along fault lines in the trough and in the floor of the impact crater. The now frozen cryolava consisted of liquid H2O infused with the red-brown pigment presumed to be a tholin, and one or more ammoniated compounds. Although the abundances of the pigment and ammoniated compounds entrained in, or possibly covering, the H2O ice are unknown, the strong spectral bands of the H2O ice are clearly visible. In consideration of the factors in Pluto's space environment that are known to destroy ammonia and ammonia-water mixtures, the age of the exposure is of order ≤109 years. Ammoniated salts may be more robust, and laboratory investigations of these compounds are needed.
Pluto↗
Direct Measurements of Infrared Intensities of HCN and H2O + HCN Ices for Laboratory and Observational Astrochemistry
Hydrogen cyanide (HCN) is found in a wide variety of extraterrestrial environments within and beyond the solar system, and for that reason laboratory spectroscopists have studied this compound in many spectral regions, including the infrared (IR). However, one aspect that remains to be investigated is the intrinsic IR spectral intensities of solid HCN as opposed to relative band strengths, intrinsic intensities being needed to measure HCN abundances. Here we report measurements of IR absorption coefficients and band strengths, along with supporting refractive indices and densities, of both amorphous and crystalline HCN at two temperatures, one for interstellar work and one more relevant to the outer solar system. Spectra are presented at both temperatures, along with optical constants that can be used in numerical models. Despite widespread and longstanding interest in and investigations of solid HCN, this is the first time that the properties we are reporting have been measured in a single laboratory, avoiding the need for estimates or to combine results from various authors. We find that our measured band strength of ~1 × 1017 cm molecule1 for the CN vibration of HCN, in both amorphous HCN and in an H2O-rich ice, is substantially higher than an earlier estimate. Unless errors of 100% can be tolerated then our new value requires a rescaling of earlier work. Our results shed light on why HCN and other nitriles have been so difficult to identify in the solid state, in contrast to their many detections in the gas phase.
astrochemistry – methods: laboratory – solid state↗
Direct Measurements of Infrared Intensities of HCN and H2O + HCN Ices for Laboratory and Observational Astrochemistry
Hydrogen cyanide (HCN) is found in a wide variety of extraterrestrial environments within and beyond the solar system, and for that reason laboratory spectroscopists have studied this compound in many spectral regions, including the infrared (IR). However, one aspect that remains to be investigated is the intrinsic IR spectral intensities of solid HCN as opposed to relative band strengths, intrinsic intensities being needed to measure HCN abundances. Here we report measurements of IR absorption coefficients and band strengths, along with supporting refractive indices and densities, of both amorphous and crystalline HCN at two temperatures, one for interstellar work and one more relevant to the outer solar system. Spectra are presented at both temperatures, along with optical constants that can be used in numerical models. Despite widespread and longstanding interest in and investigations of solid HCN, this is the first time that the properties we are reporting have been measured in a single laboratory, avoiding the need for estimates or to combine results from various authors. We find that our measured band strength of ~1 × 1017 cm molecule1 for the CN vibration of HCN, in both amorphous HCN and in an H2O-rich ice, is substantially higher than an earlier estimate. Unless errors of 100% can be tolerated then our new value requires a rescaling of earlier work. Our results shed light on why HCN and other nitriles have been so difficult to identify in the solid state, in contrast to their many detections in the gas phase.
astrochemistry – methods: laboratory – solid state↗
CLEAR: Boosted Lyα Transmission of the Intergalactic Medium in UV-bright Galaxies
Reionization is an inhomogeneous process, thought to begin in small ionized bubbles of the intergalactic medium (IGM) around overdense regions of galaxies. Recent Lyα studies during the epoch of reionization show evidence that ionized bubbles formed earlier around brighter galaxies, suggesting higher IGM transmission of Lyα from these galaxies. We investigate this problem using IR slitless spectroscopy from the Hubble Space Telescope (HST) Wide-Field Camera 3 (WFC3) G102 grism observations of 148 galaxies selected via photometric redshifts at 6.0 < z < 8.2. These galaxies have spectra extracted from the CANDELS Lyα Emission at Reionization (CLEAR) survey. We combine the CLEAR data for 275 galaxies with the Keck Deep Imaging Multi-Object Spectrograph and MOSFIRE data set from the Texas Spectroscopic Search for Lyα Emission at the End of Reionization Survey. We constrain the Lyα equivalent width (EW) distribution at 6.0 < z < 8.2, which is described by an exponential form, dN / dEW ∝ exp(-EW) W(sub 0), with the characteristic e-folding scale width (W(sub 0)). We confirm a significant drop in the Lyα strength (i.e., W(sub 0)) at z > 6. Furthermore, we compare the redshift evolution of W(sub 0) between galaxies at different UV luminosities. UV-bright (M(sub UV) < −21 [i.e., L(sub UV) > L*]) galaxies show weaker evolution with a decrease of 0.4 ( ± 0.2) dex in W(sub 0) at z > 6, while UV-faint (M(sub UV) > −21 [LUV < L*]) galaxies exhibit a significant drop of 0.7–0.8 (±0.2) dex in W(sub 0) from z < 6 to z > 6. If the change in W(sub 0) is proportional to the change in the IGM transmission for Lyα photons, then this is evidence that the transmission is “boosted” around UV-brighter galaxies, suggesting that reionization proceeds faster in regions around such galaxies.
Reionization↗
Near-infrared photometry and spectroscopy of the unusual minor planet 5145 Pholus (1992AD)
Near-IR photometry and spectroscopy of 5145 Pholus reveals that the visual to IR colors are unusually red and appear to show evidence for complex organic solids and/or ices on the surface. No compelling match is found with any present measurements of single-component ice or tholin samples.
Davies, John K.↗
Absolute wind velocities in the lower thermosphere of Venus using infrared heterodyne spectroscopy
NASA's IR Telescope Facility and the McMath Solar Telescope have yielded absolute wind velocities in the Venus thermosphere for December 1985 to March 1987 with sufficient spatial resolution for circulation model discrimination. A qualitative analysis of beam-integrated winds indicates subsolar-to-antisolar circulation in the lower thermosphere; horizontal wind velocity was derived from a two-parameter model wind field of subsolar-antisolar and zonal components. A unique model fit common to all observing periods possessed 120 m/sec subsolar-antisolar and 25 m/sec zonal retrograde components, consistent with the Bougher et al. (1986, 1988) hydrodynamical models for 110 km.
Goldstein, Jeffrey J.↗
NASA Work Experience
I have had the opportunity to support the analytical laboratories in chemical analysis of unknown samples, using Optical Microscopy (OM), Polarizing Light Microscopy (PLM), Fourier-Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEMEDS), and X-ray Powder Diffraction (XPD). I have assisted in characterizing fibers pulled from a spacecraft, a white fibrous residue discovered in a jet refueler truck, brown residue from a plant habitat slated for delivery to the ISS (International Space Station), corrosion on a pipe from a sprinkler, and air filtration material brought back from the ISS. I also conducted my own fiber study in order to practice techniques and further my understanding of background concepts. Furthermore, I had the opportunity to participate in diverse work assignments, where I was assigned to work with other branches of the engineering department for 1-2 days each. The first was in the Materials Science branch where I participated in the construction of the plant habitat intended for use in research aboard the ISS. The second was in the Testing Design branch where I assisted with tensile and hardness testing of over 40 samples. In addition, I have had the privilege to attend multiple tours of the NASA KSC campus, including to the Astronaut Crew Quarters, the VAB (the main area, the Columbia room, and the catwalk), the Visitor Center housing the shuttle Atlantis, the Saturn-V exhibit, the Prototype laboratory, SWAMP WORKS, the Shuttle Landing Facility, the Crawler, and the Booster Fabrication Facility (BFF). Lastly, much of my coursework prepared me for this experience, including numerous laboratory courses with topics diverse as chemistry, physics, and biology.
Florida Tech↗
Complementary information from mm-wave-, infrared-, and gamma ray astronomy
An overview of the subdivision of wavelength ranges, importance of extinction, observing techniques, and scientific objectives in both IR broadband measurement and spectroscopy is given. Infrared and millimeter wave spectroscopy in the galaxy and IR and millimeter wave observations for Centaurus A are examined and discussed.
Rothermel, H.↗
Definition and detailed characterization of lunar surface units using remote observations
Remote sensing techniques are reviewed in terms of their application to the study of the lunar surface. These techniques include: reflectance spectroscopy (UV and IR), X-ray and gamma-ray analysis, alpha-particle spectroscopy, thermal emission, polarimetry, photography, and visual observation. Each technique is indexed with respect to its usefulness in either describing the appearance and location of a feature, classifying the feature in terms of a broader category, or supplying additional quantitative data. Special attention is given to the mare deposits of the Imbrium basin.
Head, J. W.↗