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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Influence of voids on the thermal and light stability of perovskite solar cells

The formation of voids in perovskite films close to the buried interface has been reported during film deposition. These voids are thought to limits the efficiency and stability of perovskite solar cells (PSCs). Here, we studied the voids formed during operation in perovskite films that were optimized during the solution deposition process to avoid voids. New voids formed during operation are found to assemble along grain boundaries at the bottom interface, caused by the loss of residual solvent and conversion of amorphous phase to crystalline phase. Unexpectedly, the formation of these voids did not negatively affect the stability of PSCs. Decreasing the amorphous region in perovskites by thermal annealing decreased the positive iodide interstitial density, and improved the light stability of PSCs. The annealed devices maintained 90% of their initial efficiency and light soaking for 1900 hours at open circuit condition under 1-sun illumination at 50°C.

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Multi-Messenger In-situ Tolerance Optimization of Mixed Perovskite Photovoltaics. Final Report

The main objectives for this project were to formulate, validate and disseminate a new procedure based on Environmental X-ray Photoelectron Spectroscopy (EXPS) for the accelerated degradation testing of metal hybrid perovskite (MHP) PV materials. With this capability, we can aid US efforts to improve MHP tolerance for illumination in damp heat conditions. This capability will benefit the public by supporting new industry efforts to create stable MHP formulations.

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Ambient-light-absorbing screen for front projection

Screen permits front surface projection of collimated light beam under conditions of high extraneous illumination. Screen has high reflective efficiency over any desired viewing area. Its optical properties are maintained when moisture droplets are present on the external front planar surface. Surface is easily cleaned and maintained.

Hilborn, E. H.↗

Variables in automatic classification over extended remote sensing test sites.

Four major causes of variation in response of multispectral scanner data were examined utilizing data from two large test sites. In one case, data throughout a 70-mile flightline was automatically classified with a high degree of accuracy (98%), utilizing training samples from a single small segment of the data. In the second case, spectral data for wheat and other cover types were calibrated and utilized to train the computer, resulting in data up to 90 miles away being classified with an acceptable degree of accuracy (91%), although significant changes in solar illumination and ground cover conditions existed.

Hoffer, R. M.↗

Updating coastal and navigational charts using ERTS-1 data

A successful processing algorithm for extracting water depth information from ERTS data has been developed. Depth charts for two geographical areas have been constructed representing different solar illumination and water transparency conditions. Absolute depth calculations for water depth to 4.5 fathoms have been demonstrated for the Little Bahama Bank. Depth Charts also were constructed using data in Band 4 and 5 of the ERTS-1 MSS for areas in Lake Michigan. This data represented a low sun angle, poor light transmission in water conditions and gave useful results to 200 meters. In both cases, the ERTS map represented an update in shallow water detail in comparison with available navigation charts for the areas tested. Present processing costs to provide MSS depth charts are estimated to be on the order of $1.50 per sq. mile. The updating of navigation charts for areas hazardous to shipping is an achievable direct application.

Polcyn, F. C.↗

Design considerations in the creation and maintenance of electrostatic cleanliness for solar electrically propelled spacecraft

Charge build-up on spacecraft surfaces and resulting zones of electrostatic contamination have been examined for electrically active and electrically passive spacecraft with both conducting and dielectric surface materials, illuminated and nonilluminated surface conditions, and for both inclusion and neglect of free charge effects from photocurrents and ambient space plasma particles. Techniques for measurement and reduction of electrostatic contamination zone extent have been developed for spacecraft with charge release capability. Indicated limitations for contamination cleanup are about 1 volt potential variation from spacecraft to ambient plasma. Bandwidths of electrostatic monitoring and clamping devices extend to several hundred kilohertz for both DC and 'broadband' AC electrostatic cleanliness.

Sellen, J. M., Jr.↗

Spectral reflectance and radiance characteristics of water pollutants

Spectral reflectance characteristics of water pollutants and water bodies were compiled using the existing literature. Radiance calculations were performed at satellite altitude for selected illumination angles and atmospheric conditions. The work described in this report was limited to the reflective portion of the spectrum between 0.40 micrometer to 1.0 micrometer.

Wezernak, C. T.↗

Geological and vegetational applications of Shuttle Imaging Radar-B, Mineral County, Nevada

Multiple-incidence angle and multi-azimuth radar data were acquired from a Shuttle platform over test sites in Nevada in October 1984. An attempt was made to correlate these data with ground features for the purpose of evaluating the use of such data for geological and vegetational assessment. Standard ecological parameters with respect to the flora (community composition, dominance, and relative cover) were recorded in the field at the time of overflight. Although a total of 33 species representing 11 plant families were recognized, and plant cover ranged from 13 to 26 percent, radar data could not be used to separate plant communities. The signal return is more a function of abiotic conditions than vegetative characteristics. Illumination geometry plays an important role in the ability to detect strike-slip and dip-slip faults. Local incidence angle is the most important parameter, and SIR-B data takes with small incidence angles are superior for identifying certain styles of faulting. Look direction is critical for detecting faults with a dip-slip component. New structural features were not observed. Problems with radar antenna power and recording significantly affected data quality.

Borengasser, M. X.↗

Orbital angular momentum loss in PSR 1957 + 20

It is suggested that the companion winds, excited by the radiation from the neutron star in PSR 1957 + 20 form only through the combined action of the radiation heat on the companion's atmosphere and the radiation force on the slowly lifting wind. Ballistic simulations suggest that these winds leave only from selected areas of the illuminated surface of the companion; surface currents channel into these regions relatively hot (but altogether cooler than the companion escape velocity) 'coronal' matter from the whole illuminated area. Under suitable conditions, wind particles spend some time trailing the companion at close distances before taking off to escape from the system. This can torque the binary into angular momentum loss that will be as efficient as the one recently observed in PSR 1957 + 20 if the companion is bloated to dimensions close to that of the Roche lobe.

Banit, Menashe↗

Microgravity Effecs During Fertilization, Cell Division, Development, and Calcium Metabolism in Sea Urchins

Calcium loss and muscle atrophy are two of the main metabolic changes experienced by astronauts and crew members during exposure to microgravity in space. For long-term exposure to space it is crucial to understand the underlying mechanisms for altered physiological functions. Fundamental occurrences in cell biology which are likely to depend on gravity include cytoskeletal dynamics, chromatin and centrosome cycling, and ion immobilization. These events can be studied during fertilization and embryogenesis within invertebrate systems. We have chosen the sea urchin system to study the effects of microgravity on cytoskeletal processes and calcium metabolism during fertilization, cell division, development, and embryogenesis. Experiments during an aircraft parabolic flight (KC-135) demonstrated: (1) the viability of sea urchin eggs prior to fertilization, (2) the suitability of our specimen containment system, (3) the feasibility of fertilization in a reduced gravity environment (which was achieved during 25 seconds of reduced gravity under parabolic flight conditions). Two newly developed pieces of spaceflight hardware made further investigations possible on a spaceflight (STS-77); (1) the Aquatic Research Facility (ARF), and (2) the Fertilization Syringe Unit (FSU). The Canadian Space Agency developed ARF to conduct aquatic spaceflight experiments requiring controlled conditions of temperature, humidity, illumination, and fixation at predetermined time points. It contained a control centrifuge which simulated the 1 g environment of earth during spaceflight. The FSU was developed at the Kennedy Space Center (KSC) by the Bionetics Corporation specifically to enable the crew to perform sea urchin fertilization operations in space.

Schatten, Heide↗

The HYDROS Mission: Requirements and Baseline System Design

The HYDROS mission is under development by NASA as part of its Earth System Science Pathfinder (ESSP) program. HYDROS is designed to provide global maps of the Earth's soil moisture and freezel/thaw state every 2-3 days, for weather and climate prediction, water and carbon cycle studies, natural hazards monitoring, and national security applications. HYDROS uses a unique active and passive L-band microwave system that optimizes measurement accuracy, spatial resolution, and coverage. It provides measurements in nearly all weather conditions, regardless of solar illumination. The designs of the radar and radiometer electronics, antenna feedhorn and reflector, and science data system, are driven by specific mission and science objectives. These objectives impose requirements on the frequencies, polarizations, sampling, spatial resolution, and accuracy of the system. In this paper we describe the HYDROS mission requirements, baseline design, and measurement capabilities.

soil moisture↗

Collaborative Pose Estimation of An Unknown Target Using Multiple Spacecraft

A reliable method for pose estimation of an unknown and uncooperative space target using monocular vision remains an open problem. Vision-based pose determination can be challenging in case of unfavorable illumination, time-varying conditions due to rotational motion and relative orbit, and scale ambiguity resolution. To address these challenges, we propose a novel collaborative pose determination algorithm called Multi- Spacecraft Simultaneous Estimation of Pose and Shape algorithm or M-SEPS.Within M-SEPS, a team of chaser spacecraft, each equipped with a monocular camera, exchange information over a local network to jointly estimate the relative kinematic state of the target and its sparse shape landmarks. In this approach, each spacecraft processes its own images and observes particular target landmarks in parallel and in a distributed fashion. Then, the local network is exploited by the spacecraft to share their consensus proposals and aggregate them to achieve the joint estimate. We validate our algorithm using simulations of relative orbits and observations, captured by each chaser spacecraft. To the best of the authors’ knowledge, this is the first cooperative, vision-based algorithm for estimating the pose and shape of a space object for an arbitrary number of spacecraft.

Chung, Soon-Jo↗

Understanding and Advancing Bifacial Thin Film Solar Cells under Dual Illumination

There is a great deal of interest in increasing the energy yield from thin film solar cells by implementing bifacial operation. However, deleterious band bending and high interface recombination at the back transparent electrode can cause problems. Herein, it is investigated how bifacial thin film devices perform when illuminated through the front, back, and simultaneously through both interfaces using numerical modeling. It is shown that the downward band bending near the back interface is reduced during illumination when the carrier concentration is low. This effect is not found when the doping is relatively high, but the minority carrier distribution is still modified. Under either condition, the power generated under bifacial illumination exceeds the sum of the power generated when the illumination is solely from the back or the front. It is also shown that the back-illuminated device performance is independent of the angle at which the light enters the back of the device, which provides accommodation for scattered light. Finally, the power enhancement is calculated for bifacial devices relative to front-illuminated devices, and is shown that any significant loss in frontside power generation is difficult to overcome with back illumination under real-world albedo conditions.

CdTe↗

In Situ Irradiation and Measurement of Triple Junction Solar Cells at Low Intensity, Low Temperature (LILT) Conditions

The performance of triple junction InGaP/(In)GaAs/Ge space solar cells was studied following high energy electron irradiation at low temperature. Cell characterization was carried out in situ at the irradiation temperature while using low intensity illumination, and, as such, these conditions reflect those found for deep space, solar powered missions that are far from the sun. Cell characterization consisted of I-V measurements and quantum efficiency measurements. The low temperature irradiations caused substantial degradation that differs in some ways from that seen after room temperature irradiations. The short circuit current degrades more at low temperature while the open circuit voltage degrades more at room temperature. A room temperature anneal after the low temperature irradiation produced a substantial recovery in the degradation. Following irradiation at both temperatures and an extended room temperature anneal, quantum efficiency measurement suggests that the bulk of the remaining damage is in the (In)GaAs sub-cell

Quantum Efficiency↗

Characterization of reflected light from the space power system

Sunlight reflected off large space structures is examined. To assure that this illumination does not exceed the irradiance tolerances of the eye, reflections from these satellites must be controlled by vehicle orientation and surface specifications. The components of various space power system vehicles to determine the reflectances which will significantly contribute to the ground illumination are evaluated. Calculations of reflected solar intensity from various satellite system elements requires description of the elements and of the geometry potential reflectance paths. Surface intensity and the conditions under which it will illuminate a portion of the Earth are also determined.

Liemohn, H. B.↗

Rheoceptive mediators of graviperception in a water flea: Morphological implications of antennal-socket setae in daphnia magna

Aquatic microcrustaceans of the genus Daphnia are known to orient to light during the day. At night, in the absence of visual cues, daphnids were suspected of maintaining equilibrium by monitoring the direction of gravity through their swimming antennae. Recent investigations using simulated, weightlessness conditions coupled with absence of illumination revealed hair like structures or setae on the basal, articulating socket of the antennae that, when surgically removed, resulted in disorientation. Given the simulated weightlessness or neutrally buoyant condition that eliminated sinking of the normally negatively buoyant Daphnia, it was proposed that the antennal socket setae function as rheoceptors stimulated by the upward rush of water currents during gravity induced, sinking phase of daphnid swimming movements. This rheoceptively mediated, gravity perception hypothesis is further supported by morphological investigations. Scanning electron micrographs indicate that antennal socket setae are anatomically similar to proprioceptors used by higher crustaceans to monitor gravitational direction.

Meyers, D. G.↗

In situ formation of pseudohalide anions induced by humid air and light passivates formamidinium‐based halide perovskites

Abstract Metal halide perovskites based on formamidinium (FA), or FA‐rich compositions have shown great promise for high‐performance photovoltaics. A deeper understanding of the impact of ambient conditions (e.g., moisture, oxygen, and illumination) on the possible reactions of FA‐based perovskite films and their processing sensitivities has become critical for further advances toward commercialization. Herein, we investigate reactions that take place on the surface of the FA 0.7 Cs 0.3 , mixed Br/I wide bandgap perovskite thin films in the presence of humid air and ambient illumination. The treatment forms a surface layer containing O, OH, and N‐based anions. We propose the latter originates from formamidine trapped at the perovskite/oxide interface reacting further to cyanide and/or formamidinate—an understudied class of pseudohalides that bind to Pb. Optimized treatment conditions improve photoluminescence quantum yield owing to both reduced surface recombination velocity and increased bulk carrier lifetime. The corresponding perovskite solar cells also exhibit improved performance. Identifying these reactions opens possibilities for better utilizing cyanide and amidinate ligands, species that may be expected during vapor processing of FA‐based perovskites. Our work also provides new insights into the self‐healing or self‐passivating of MA‐free perovskite compositions where FA and iodide damage could be partially offset by advantageous reaction byproducts. image

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