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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Surface Local Impurity Scattering as a Probe for Topological Kondo Insulators

Shortly after the discovery of topological band insulators, topological Kondo insulators (TKIs) is also theoretically predicted. The latter has ignited revival interest in the properties of Kondo insulators. Currently, the feasibility of topological nature in SmB 6 is intensively analyzed by several complementary probes. Here by starting with a minimal-orbital Anderson lattice model, the local electronic structure is explored in a Kondo insulator. It is showed that the two strong topological regimes sandwiching the weak topological regime give rise to a single Dirac cone, which is located near the center or corner of the surface Brillouin zone. It is further found that, when a single impurity is placed on the surface, low-energy resonance states are induced in the weak scattering limit for the strong TKI regimes and the resonance level moves monotonically across the hybridization gap with the strength of impurity scattering potential; while low energy states can only be induced in the unitary scattering limit for the weak TKI regime, where the resonance level moves universally toward the center of the hybridization gap. These impurity-induced low-energy quasiparticles will lead to characteristic signatures in scanning tunneling microscopy/spectroscopy, which has recently found success in probing into exotic properties in heavy fermion systems.

36 MATERIALS SCIENCE↗

Theory of Two-Level Tunneling Systems in Superconductors

We develop a field theory formulation for the interaction of an ensemble of two-level tunneling systems (TLSs) with the electronic states of a superconductor. Predictions for the impact of two-level tunneling systems on superconductivity are presented, including T c and the spectrum of quasiparticle states for conventional BCS superconductors. We show that nonmagnetic TLS impurities in conventional s-wave superconductors can act as pair-breaking or pair-enhancing defects depending on the level population of the distribution of TLS impurities. We present calculations of the enhancement of superconductivity, both T c and the order parameter, for TLS defects in thermal equilibrium with the electrons and lattice. The scattering of quasiparticles by TLS impurities leads to subgap states below the bulk excitation gap, Δ, as well as resonances in the continuum above Δ. The energies and spectral weights of these states depend on the distribution of tunnel splittings, while the spectral weights are particularly sensitive to the level occupation of the TLS impurities. Under microwave excitation, or decoupling from the thermal bath, a nonequilibrium level population of the TLS distribution generates subgap quasiparticle states near the Fermi level that contribute to dissipation and thus degrade the performance of superconducting devices at low temperatures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Theoretical investigation of charge transfer between the NV – center in diamond and substitutional N and P

The nitrogen-vacancy (NV) lattice defect in diamond, consisting of an N substitutional atom and an adjacent C vacancy, is commonly observed in two charge states, negative (NV – ) and neutral (NV 0 ). The NV – defect exhibits spin state-dependent fluorescence and is, therefore, amenable to optical methods for spin-state readout, while the NV 0 is not. Hence, the NV – defect is much more useful for quantum sensing and quantum information processing. However, only NV 0 electroluminescence has been observed, even from centers showing NV – in photoluminescence. In the present work, we use first-principles electronic structure calculations to determine adiabatic charge transition levels for the conversion of NV – to NV 0 in the presence of substitutional N or P impurities, which provide the charge of the NV center. Here, we find that the adiabatic charge transition levels in the presence of such impurities lie at energies close to or lower than the zero-phonon line of the NV – center and that these energies only decrease as the concentration of N donors increases. This work, therefore, elucidates the absence of observed electroluminescence from the NV – and proposes a path toward observation of the phenomenon.

36 MATERIALS SCIENCE↗

Exploring the Potential of Residual Impurities in Germanium Detectors for MeV-Scale Dark Matter Detection

Abstract The direct detection of MeV-scale dark matter (DM) particles hinges on achieving an exceptionally low-energy detection threshold. Germanium (Ge) detectors, meticulously tailored with precise impurity compositions, hold the potential to enhance sensitivity to energy levels below the sub-electronvolt (sub-eV) range. This study explores the behavior of residual impurities inherent to Ge detectors at helium temperatures, unveiling a captivating freeze-out phenomenon leading to the formation of excited localized states known as dipole states. Using compelling evidence from relative capacitance measurements obtained from two detectors, we elucidate the transition of impurity atoms from free charge states to these dipole states as the temperature drops from 11 to 6.5 K. Our investigation comprehensively covers the intricate formation of these dipole states in bothn-type andp-type impurities. Furthermore, we shed light on the electric field generated by these dipole states, revealing their ability to trap charges and facilitate the creation of cluster dipole states. Confirming findings from previous measurements, we establish that these excited dipole states exhibit a binding energy of less than 10 meV, offering an exceptionally low detection threshold for MeV-scale DM. Building upon this concept, we propose the development of a 1-kg Ge detector with internal charge amplification—an innovative approach poised to surpass electrical noise and enable the detection of MeV-scale DM with unprecedented sensitivity.

Physics↗

Comparisons of Air Radiation Model with Shock Tube Measurements

This paper presents an assessment of the predictive capability of shock layer radiation model appropriate for NASA s Orion Crew Exploration Vehicle lunar return entry. A detailed set of spectrally resolved radiation intensity comparisons are made with recently conducted tests in the Electric Arc Shock Tube (EAST) facility at NASA Ames Research Center. The spectral range spanned from vacuum ultraviolet wavelength of 115 nm to infrared wavelength of 1400 nm. The analysis is done for 9.5-10.5 km/s shock passing through room temperature synthetic air at 0.2, 0.3 and 0.7 Torr. The comparisons between model and measurements show discrepancies in the level of background continuum radiation and intensities of atomic lines. Impurities in the EAST facility in the form of carbon bearing species are also modeled to estimate the level of contaminants and their impact on the comparisons. The discrepancies, although large is some cases, exhibit order and consistency. A set of tests and analyses improvements are proposed as forward work plan in order to confirm or reject various proposed reasons for the observed discrepancies.

Bose, Deepak↗

Room temperature degradation of YBa2Cu3O(7-x) superconductors in varying relative humidity environments

An aging study was performed to determine the stability of YBa2Cu3O(7-x) ceramics in humid environments at 20 C. In this study, fired ceramic specimens were exposed to humidity levels ranging from 30.5 to 100 percent for 2-, 4-, and 6-week time intervals. After storage under these conditions, the specimens were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrical resistance measurements. At every storage condition evaluated, the fired ceramics were found to interact with H2O present in the surrounding environment, resulting in the decomposition of the YBa2Cu3O(7-x) phase. XRD data showed that BaCO3, CuO, and Y2BaCuO5 were present after aging and that the peak intensities of these impurity phases increased both with increasing humidity level and with increasing time of exposure. Additionally, SEM analyses of the ceramic microstructures after aging revealed the development of needle-like crystallites along the surface of the test specimens after aging. Furthermore, the superconducting transition temperature T(sub c) was found to decrease both with increasing humidity level and with increasing time of exposure. All the specimens aged at 30.5, 66, and 81 percent relative humidity exhibited superconducting transitions above 80 K, although these values were reduced by the exposure to the test conditions. Conversely, the specimens stored in direct contact with water (100 percent relative humidity) exhibited no superconducting transitions.

Hooker, M. W.↗

The properties of polycrystalline silicon solar cells with controlled titanium additions

By coupling the results of electrical measurements, such as spectral response, lighted and dark I-V determinations, and deep-level-transient spectroscopy with optical and laser scan photomicroscopy, the effects of grain boundaries and impurities on silicon solar cells were evaluated. Titanium, which produces two deep levels in silicon, degrades cell performance by reducing bulk lifetime and thus cell short-circuit current. Electrically active grain boundaries induce carrier recombination in the bulk and depletion regions of the solar cell. Experimental data imply a small but measurable segregation of titanium into some grain boundaries of the polycrystalline silicon containing high Ti concentration. However, for the titanium-contaminated polycrystalline material used in this study, solar cell performance is dominated by the electrically active titanium concentration in the grains. Microstructural impacts on the devices are of secondary importance

Rohatgi, A.↗

Quasiparticle spectroscopy in technologically relevant niobium using London penetration depth measurements: experiment and theory

Abstract The London penetration depth, λ ( T ) , was measured in various forms of niobium, including foils, thin films, single crystals, and samples from superconducting radio-frequency (SRF) cavities. We observed a significant difference in λ ( T ) at low temperatures, T < T c / 3 , due to low-energy quasiparticles. In particular, an unusual downturn of λ ( T ) on cooling in the SRF cavity samples required to take into account deep in-gap bound states. Theoretical modeling using the generalized Dynes density of states shows that such in-gap states lead to a downturn or a peak in λ ( T ) upon cooling. Combined, experimental and theoretical findings provide a method for detecting two-level systems or states related to magnetic impurities in the bulk of niobium. This result is particularly relevant for the quantum informatics sciences technologies used in qubits and circuit quantum electrodynamics architecture based on SRF cavities.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Time-dependent modeling of dust outburst into tokamak divertor plasma

The first self-consistent simulation studies of the impact of transient injection of tungsten dust on ITER-like edge plasma are presented. The simulations are performed using DUSTT and UEDGE codes coupled in a fully time-dependent manner. The evolution of the divertor and upstream plasma conditions, following the injection of tungsten dust of various quantities and sizes at the outer strike point, is investigated. The estimates of the core plasma impurity fraction and the core impurity screening factor associated with the dust injection are also obtained. Here, the simulations show that the bursts of even modest amounts of tungsten dust injected into the divertor plasmas can result in large perturbations of the divertor power load and unacceptable levels of the core plasma contamination with tungsten impurities.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Cryogenics and purification systems of the ICARUS T600 detector installation at Fermilab

This paper describes the cryogenic and purification systems of the ICARUS T600 detector in its present implementation at the Fermi National Laboratory, Illinois, U.S.A. The ICARUS T600 detector is made of four large Time Projection Chambers, installed in two separate containers of about 275 m 3 each. The detector uses liquid argon both as target and as active medium. For the correct operation of the detector, the liquid argon must be kept in very stable thermal conditions and the contamination of electronegative impurities must be consistently kept at the level of small fractions of parts per billion. The detector was previously operated in Italy, at the INFN Gran Sasso Underground Laboratory (LNGS), in a three-year run on the CERN to LNGS Long Baseline Neutrino Beam. For its operation on the Booster and NuMI neutrino beams at Fermilab, for the search of sterile neutrinos and measurements of neutrino-argon cross sections, the detector was moved from Gran Sasso to CERN for the upgrades required for operation at shallow depth with high intensity neutrino beams. The liquid argon containers, the thermal insulation and all the cryogenic equipment have been completely re-designed and rebuilt, following the schemes of the previous installation in Gran Sasso. The detector and all the equipment have been transported to Fermilab, where they have been installed, tested and recently put into operation. The work described in this paper has been conducted as a joint responsibility of CERN and Fermilab with the supervision provided by the ICARUS Collaboration. Design, installation, testing, commissioning and operation are the result of a common effort of CERN, Fermilab and INFN groups.

Cryogenic detectors↗

Lessons from commissioning of the cryogenic system for the Short-Baseline Neutrino Detector at Fermilab

Results from commissioning and first year of operations of the cryogenic system of the Short-Baseline Neutrino Detector (SBND) and its membrane cryostat installed at the Fermi National Accelerator Laboratory are described. The SBND detector is installed in a 200 m$^3$ membrane cryostat filled with liquid argon, which serves both as target and as active media. For the correct operation of the detector, the liquid argon must be kept in very stable thermal conditions while the contamination of electronegative impurities must be consistently kept at the level of small fractions of parts per billion. The detector is operated in Booster Neutrino Beams (BNB) at Fermilab for the search of sterile neutrinos and measurements of neutrino-argon cross sections. The cryostat and the cryogenic systems also serve as prototypes for the much larger equipment to be used for the LBNF/DUNE experiment. Since its installation in 2018-2023 and cooldown in spring of 2024, the cryostat and the cryogenic system have been commissioned to support the detector operations. The lessons learned through installation, testing, commissioning, cooldown, and initial operations are described.

43 PARTICLE ACCELERATORS↗

First-principles Studies of Tritium Reactivity and Diffusivity on Defective and Carbon Doped Surfaces of $\gamma$-LiAlO 2 Pellets (Tritium Science Program Report FY 2019 )

In tritium-producing burnable absorber rods (TPBARs), tritium ($^{3}_{1}$H,T) is produced in 6 Li isotope enriched γ-LiAlO 2 ceramic pellet. However, a better understanding of $^{3}_{1}$H transport through the pellets, getters and the barrier/cladding system is hampered by a lack of fundamental data about the $^{3}_{1}$H solubility and diffusivity. In the process of $^{3}_{1}$H diffusion from bulk γ-LiAlO 2 to its surface, it is possible that $^{3}_{1}$H atoms bind with surface atoms or become trapped at vacancies sites. By increasing the number of $^{3}_{1}$H diffused from bulk to surface, upon recombination and desorption from surface sites, they will escape from the γ-LiAlO 2 surface to form different $^{3}_{1}$H species (possibly being as T, T 2 , T 2 O, OT, or CT x (x=1-4, with C impurity present at a 100-600 ppm level in pellets) that need to be identified and can become captured by the getter. Therefore, exploring the $^{3}_{1}$H diffusion from bulk to surface, corroborated with surface adsorption, diffusion and recombination and followed by desorption from surface as various types of $^{3}_{1}$H species becomes a very important task as an integral part of the study of $^{3}_{1}$H solubility and diffusivity in the pellets.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Lessons from commissioning of the cryogenic system for the Short-Baseline Neutrino Detector at Fermilab

Results from commissioning and first year of operations of the cryogenic system of the Short-Baseline Neutrino Detector (SBND) and its membrane cryostat installed at the Fermi National Accelerator Laboratory are described. The SBND detector is installed in a 200 m3 membrane cryostat filled with liquid argon, which serves both as target and as active media. For the correct operation of the detector, the liquid argon must be kept in very stable thermal conditions while the contamination of electronegative impurities must be consistently kept at the level of small fractions of parts per billion. The detector is operated in Booster Neutrino Beams (BNB) at Fermilab for the search of sterile neutrinos and measurements of neutrino-argon cross sections. The cryostat and the cryogenic systems also serve as prototypes for the much larger equipment to be used for the LBNF/DUNE experiment. Since its installation in 2018-2023 and cooldown in spring of 2024, the cryostat and the cryogenic system have been commissioned to support the detector operations. The lessons learned through installation, testing, commissioning, cooldown, and initial operations are described.

Geynisman, Michael [Fermilab]↗

Effect of impurity doping concentration on solar cell output

Experimental measurements were made of solar cell and related photovoltaic parameters for silicon with high concentrations of dopant impurities. The cell output peaked for doping levels around 10 to the 17th power per cu cm. Independent measurements of diffusion length and open circuit voltage at high doping levels showed severe reductions at concentrations above 10 to the 18th power per cu cm. Theoretical reasons are given to explain these reductions. Indication is given of the problems requiring solution before increased cell output can be achieved at high doping levels.

Iles, P. A.↗

Experimental and theoretical investigations of the quality factor for N/+/P silicon solar cells

Many N(+)P silicon solar cells made with silicon from different growth techniques have current-voltage relations of the form: I = I(0) (exp(qV/AkT) - 1), where the quality factor A is nonintegral, is greater than 1, and shows a temperature dependence. The dark forward characteristics of such cells have been measured over a range of temperatures and the behavior of the factor A derived from them. Lack of agreement with previous models has led to the development of a new model, in which N(+) conduction electrons tunnel to deep levels near that side, these levels being due to junction contamination by impurities. Electron recombination then occurs with holes thermally assisted into the junction from the P side. This mechanism involves increased I(0) values over those for diffusion diode processes and thus reduces the cell power conversion efficiency.

Garlick, G. F. J.↗

Impact of Functionally Graded Cylinders: Theory

This final report summarizes the work funded under the Grant NAG3-2411 during the 04/05/2000-04/04/2001 period. The objective of this one-year project was to generalize the theoretical framework of the two-dimensional higher-order theory for the analysis of cylindrical functionally graded materials/structural components employed in advanced aircraft engines developed under past NASA Glenn funding. The completed generalization significantly broadens the theory's range of applicability through the incorporation of dynamic impact loading capability into its framework. Thus, it makes possible the assessment of the effect of damage due to fuel impurities, or the presence of submicron-level debris, on the life of functionally graded structural components. Applications involving advanced turbine blades and structural components for the reusable-launch vehicle (RLV) currently under development will benefit from the completed work. The theory's predictive capability is demonstrated through a numerical simulation of a one-dimensional wave propagation set up by an impulse load in a layered half-plane. Full benefit of the completed generalization of the higher-order theory described in this report will be realized upon the development of a related computer code.

Aboudi, Jacob↗

Method for Determination of Less Than 5 ppm Oxygen in Sodium Samples

Alkali metals used in pumped loops or heat pipes must be sufficiently free of nonmetallic impurities to ensure long heat rejection system life. Life issues are well established for alkali metal systems. Impurities can form ternary compounds between the container and working fluid, leading to corrosion. This Technical Memorandum discusses the consequences of impurities and candidate measurement techniques to determine whether impurities have been reduced to suf.ciently low levels within a single-phase liquid metal loop or a closed two-phase heat transfer system, such as a heat pipe. These techniques include the vanadium wire equilibration, neutron activation analysis, plug traps, distillation, and chemical analysis. Conceptual procedures for performing vanadium wire equilibration purity measurements on sodium contained in a heat pipe are discussed in detail.

Reid, R. S.↗

Reducing dielectric loss and enhancing electrical insulation for multilayer polymer films by nanoconfined ion transport under high poling electric fields

High temperature polar polymers have demonstrated potential for good thermal stability and high dielectric constant at the same time. However, polarization of contaminated impurity ions in polar polymers, even at the ppm level, can significantly increase the dielectric loss at high temperature and low frequencies. One effective strategy to mitigate this problem is to multilayer them with a high temperature nonpolar dielectric polymer to confine impurity ion transport at the nanometer scale. In this study, confined ion transport in high temperature polycarbonate (HTPC)/poly(vinylidene fluoride) (PVDF) multilayer films under high AC electric fields was studied using a direct analytical simulation method. Different from the ion transport under low fields, the ion diffusion model failed to describe the ion transport under high electric fields. An exponential ion distribution profile, which was observed for the DC poling situation, was employed to implement the direct analytical simulation. Confined impurity ion transport under high AC fields was quantitatively understood. As the AC field increased, the mobile ion concentration decreased whereas the diffusion coefficient increased. The decrease of mobile ion concentration was explained by the blockage of impurity ions by the HTPC layers. This knowledge helped in the determination of optimal conditions to polarize impurity ions from the PVDF layers into the HTPC layers. After cooling below the glass transition temperature of HTPC, polarized impurity ions were locked inside the HTPC layers. As a result, increased discharge efficiency and enhanced electrical insulation (i.e., increased dielectric breakdown strength) were achieved for the polarized multilayer films.

36 MATERIALS SCIENCE↗