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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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For the first time, protected metallic Li is employed as anode in halide-based all-solid-state batteries. A kinetically stable anode interface is realized by inserting an argyrodite interlayer between halide electrolyte and lithium metal.
This paper describes the design of the U.S. Space Station and explains the control factors used for internal and external interfaces among the various government and contractor participants. It discusses the documentation of the U.S. Space Station Program including the Program Approval Document (PAD), the Program Plans (PPs), the Program Requirements Document (PRD), the Program Definition and Requirements Document (PDRD), the Level III project plans, and the Level III project design requirements documents. It discusses the relationship of Space Station documentation to the international Memoranda of Understanding (MOUs) and the Joint PP, PRD, and PDRD, the interrelationship of the Architectural Control Documents (ACDs), the Baseline Control Document (BCD), and the Interface Requirement Documents (IRDs) and Interface Control Documents (ICDs). Also included are the controlling functions of the various NASA and contractor participants and the international partners.
All-solid-state batteries have emerged as promising alternatives to conventional Li-ion batteries owing to their higher energy density and safety, which stem from their use of inorganic solid-state electrolytes instead of flammable organic liquid electrolytes. Among various candidates, sulfide solid-state electrolytes are particularly promising for the development of high-energy all-solid-state Li metal batteries because of their high ionic conductivity and deformability. However, a significant challenge remains as their inherent instability in contact with electrodes forms unstable interfaces and interphases, leading to degradation of the battery performance. In this review article, we provide an overview of the key issues for the interfaces and interphases of sulfide solid-state electrolyte systems as well as recent progress in understanding such interface and interphase formation and potential solutions to stabilize them. In addition, we provide perspectives on future research directions in this field.
The growth of NiCo particles at low coverages over reducible CeO 2 (111) thin films producing a triple interface between Ni-Co-Ce was investigated by scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS), which was compared to that of monometallic Ni and Co particles. XPS data show that deposition of either Ni or Co on CeO 2 at 300 K causes a partial reduction of Ce 4+ cations to Ce 3+ ions. At 0.3 monolayer (ML), XPS detects Co 2+ on CeO 2 . However, both Ni 0 and Ni 2+ are present as major species at 300 K and annealing causes a significant increase of Ni 2+ in Ni particles. Deposition of 0.3 ML Co over 0.3 ML Ni on CeO 2 at 300 K induces reduction of Ni 2+ to metallic Ni and Ni 0 was found as predominant species. Unlike for Co/CeO 2 , metallic Co was also present over the Co-Ni/CeO 2 surface in addition to Co 2+ . Further, this behavior indicates the formation of NiCo bimetallic particles with the possibility of Co diffusion to the interface of Ni/ceria. With heating, the intermixing of Ni and Co atoms in bimetallic particles on CeO 2 was facilitated. Furthermore, oxidation of both metals and ceria occurred as a result of the diffusion of lattice oxygen from the bulk of ceria to the surface. A slight increase in Ni 2+ was observed after heating Co-Ni/CeO 2 to 500 K or higher. Co became Co 2+ with heating to 800 K. Our STM results confirm the formation of NiCo bimetallic particles on CeO 2 at 300 K and further suggest that the addition of Co can help inhibit the sintering of Ni particles at higher temperatures. Bimetallic particles were also obtained by depositing Ni over existing Co particles on CeO 2 . However, our XPS data demonstrate that the deposition order of Co and Ni plays a role in the chemical state of these two metals in bimetallic particles, likely attributed to the difference in their compositions at the bimetallic particle surface as well as the metal-support interface.
Interfacial issues impede the advancement of current solid state battery technology; thus, interface engineering approaches are necessary to enable solid-state configuration. The advantage of solid-state cells stems from their low flammability and high electrochemical stability. Ionic liquids are viscous and nonflammable compounds that possess the requisite physical properties while optimizing the interface between solid electrodes and solid electrolytes, accelerating interfacial ion transport and enabling the fabrication of engineered interphases via the supply of robust chemical building blocks. In conclusion, this review summarizes the roles of ionic liquids in solid-state batteries focusing on the interface, with insights into their functionality as well as highlighting their applicability in the next generation battery systems.
Abstract: This paper reports Bell-State Measurements using coherent light for testing the suitability of narrow band ion-cavity interfaces for high-fidelity ion-ion entanglement in the QUANT-NET testbed. It also presents automated control of the experiment setup.
X-ray photoemission spectroscopy has been used to examine the localization and crystallographic dependence of Si(+), Si(2+), and Si(3+) suboxide states at the SiO2/Si interface for (100)and (111)-oriented substrates with gate oxide quality thermal oxides. The Si(+) and Si(2+) states are localized within 6-10 A of the interface while the Si(3+) state extends about 30 A into the bulk SiO2. The distribution of Si(+) and Si(2+) states shows a strong crystallographic dependence with Si(2+) dominating on (100) substrates and Si(+) dominating on (111) substrates. This crystallographic dependence is anticipated from consideration of ideal unreconstructed (100) and (111) Si surfaces, suggesting that (1) the Si(+) and Si(2+) states are localized immediately within the first monolayer at the interface and (2) the first few monolayers of substrate Si atoms are not significantly displaced from the bulk. The total number of suboxide states observed at the SiO2/Si interface corresponds to 94 and 83 percent of a monolayer for these (100) and (111) substrates, respectively.
Here we introduce Interfacial Line Defect Analysis (ILDA), a method for identifying and extracting interfacial dislocations and disconnections with little-to-no input from the user on the nature of the interface. By simply providing the orientations and coherency strains for the crystals in a coherent reference state of the interface, ILDA provides exact Burgers vectors. Alternatively, these orientations and strains can be estimated using local atomic deformation gradients, making ILDA fully automated and providing estimated Burgers vectors. ILDA also determines the step height associated with each defect line segment, in case the associated defect is a disconnection. The heart of the method is the identification of atoms residing at co-incidence sites between the two crystals and the construction of a surface mesh connecting these sites that is used to compose Burgers circuits and insert defect line segments. We demonstrate the performance of ILDA in two test cases: a twist grain boundary and a phase boundary.
A method is proposed for the direct measurement of the thermodynamic properties of the alloy and oxide compound at the alloy/scale interface observed during steady-state oxidation. The thermodynamic properties of the alloy/scale interface define the driving force for solid-state transport in the alloy and oxide compound. Accurate knowledge of thermodynamic properties of the interface will advance our understanding of oxidation behavior. The method is based on the concept of local equilibrium and assumes that an alloy+scale equilibrium very closely approximates the alloy/scale interface observed during steady-state oxidation. The thermodynamics activities of this alloy+scale equilibrium are measured directly by Knudsen effusion-cell mass spectrometer (KEMS) using the vapor pressure technique. The theory and some practical considerations of this method are discussed in terms of beta-NiAl oxidation.
Tuning the atomic interface configuration of noble metals (NMs) and transition-metal oxides is an effective straightforward yet challenging strategy to modulate the activity and stability of heterogeneous catalysts. Herein, Pd supported on mesoporous Fe 2 O 3 with a high specific surface area was rationally designed and chosen to construct the Pd/iron oxide interface. As a versatile model, the physicochemical environments of Pd nanoparticles (NPs) could be precisely controlled by taming the reduction temperature. The experimental and density functional theory calculation results unveiled that the catalyst in the support–metal interface confinement (SMIC) state showed significantly enhanced catalytic activity and sintering resistance for CO oxidation. The constructed Fe sites at the interfaces between FeO x overlayers and Pd NPs not only provided additional coordinative unsaturated ferrous sites for the adsorption and activation of O 2 , thereby facilitating the activation efficiency of O 2 , but also impressively changed the reaction pathway of CO oxidation. As a result, the catalyst followed the Pd/Fe dual-site mechanism instead of the classical Mars–van Krevelen mechanism. For the catalyst in the strong metal–support interaction (SMSI) state, its catalytic activity was seriously suppressed because of the excessive encapsulation of the active Pd sites by FeO x overlayers. Thus, the present study therefore provides detailed insights into the SMIC and SMSI in ferric oxide-supported Pd catalysts, which could guide the preparation of highly efficient supported catalysts for practical applications.
In this work, we developed operando Kelvin probe force microscopy (KPFM) to study the electrostatic potential distribution across perovskite cells under light and forward bias to gain a deeper understanding of device operation physics. As a case study, we selected perovskite cells with a SnO 2 -based electron-selective layer (ESL), which showed great potential for fabricating high-efficiency, hysteresis-free devices due to the deeper conduction band and higher electron mobility of SnO 2 . The as-made device showed a main junction at the perovskite/spiro interface. After light soaking and applying forward bias, the junction quality improved, possibly explained by filling trap states at the interfaces and by the perovskite absorber perhaps having a self-poling effect; the main junction is observed at the ESL/perovskite interface. The results are consistent with current-voltage measurements, device performance improves mainly with fill factor enhancement. The operando KPFM results should more closely reflect the real case during current density-voltage measurements or solar cell operation. The operando KPFM technique that we have developed can be a powerful tool to provide a deeper understanding of the device operation mechanism and to further optimize the device.
A new decohesion element with mixed-mode capability is proposed and demonstrated. The element is used at the interface between solid finite elements to model the initiation and non-self-similar growth of delaminations. A single relative displacement-based damage parameter is applied in a softening law to track the damage state of the interface and to prevent the restoration of the cohesive state during unloading. The softening law for mixed-mode delamination propagation can be applied to any mode interaction criterion such as the two-parameter power law or the three-parameter Benzeggagh-Kenane criterion. To demonstrate the accuracy of the predictions and the irreversibility capability of the constitutive law, steady-state delamination growth is simulated for quasistatic loading-unloading cycles of various single mode and mixed-mode delamination test specimens.
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The Grand Challenge for the next generation of energy storage technologies is no longer the identification of electroactive cathode or anode materials thanks to extensive worldwide synthesis efforts along with theory and modeling like the Materials Project.1 Instead, the critical challenges revolve around assembling materials in the right architecture to achieve maximum performance and cell life at reasonable temperatures and pressures. Nowhere is this more critical than on the next generation of energy storage technologies revolving around all solid-state batteries. These batteries are the ultimate challenge for materials science requiring new ways to assemble multiple dissimilar materials such that: (1) interfaces are optimized to facilitate ion motion across the different compounds while (2) maintaining chemical stability and (3) simultaneously preserving the crystal structures of each phase during (4) large volume changes due to shuttling of lithium, at (5) room temperature and under (6) atmospheric pressure. To address these requirements will require insights and expertise from research fields outside the traditional lithium-ion battery community such as solid oxide fuel cells, synthesis science, barrier layers, interface formers, sintering, and mechanical properties.
A preflight analysis performed for verification of the ALT mated vehicle incidence angle which maximizes the post separation altitude attainment by the orbiter at the maximum approach and landing test (ALT) interface airspeed (300 KEAS) is discussed. In the analysis, altitude versus airspeed profiles are generated for each of the three incidence angles that include and bound the recommended incidence angle for both the forward and the aft cg tailcone on orbiter configurations. Results show that the recommended incidence angles maximize the orbiter post separation altitude attainable within an acceptable tradeoff between separation clearance capability and orbiter structural constraints. Within constraints, the incidence angle that maximizes the orbiter altitude at the maximum ALT interface airspeed for both the forward and aft cg orbiter tailcone on configurations is 6.0 deg. The requirement for a parametric analysis of orbiter altitude attainable at the maximum ALT interface airspeed is stated along with the specifications, assumptions, and analytical approach used to determine orbiter altitude attainable at the maximum ALT interface airspeed.
Garnet-structured Li 6.75 La 3 Zr 1.75 Ta 0.25 O 12 (LLZTO) is one of the most promising electrolyte materials for solid-state Li batteries (SS-LiB). The design and fabrication of a good cathode/electrolyte interface is an important criterion for the SS-LiB. In this work, we performed a systematic study on the impact of cathode crystal structure and chemical compositions on their chemical stabilities against the LLZTO at elevated temperatures, which are required for their adhesion during cell fabrication processes. X-ray Diffraction (XRD) and Rietveld refinement analyses revealed the chemical stabilities of various cathode materials in contact with the LLZTO. While layered LiCoO 2 cathode showed good stability in contact with LLZTO to 900 °C, LiNiO 2 or Ni-rich LiNi x Mn y Co 1–x–y O 2 (NMC) cathodes suffered from the formation of La 4 NiLiO 8 due to La-diffusion from LLZTO. Furthermore, Mn-rich LiMn 2 O 4 spinel and layered LiNi 1/3 Mn 1/3 Co 1/3 O 2 cathodes suffered from the formation of La 2 Zr 2 O 7 due to Li-diffusion and production of Li 2 MnO 3 . As a result, LiNi 0.6 Mn 0.2 Co 0.2 O 2 , having an ideal balance of Ni/Mn/Co composition, or Li 2 MnO 3 containing cathodes such as Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 were found to have excellent phase stability as the cathodes for LLZTO-based SS-LiBs.
All-solid-state batteries (ASSBs) using a ceramic fast Li-ion conductor as a solid-state electrolyte (SSE) have been proposed as a promising strategy to significantly increase the energy density of lithium batteries. Due to their high ion conductivity and excellent stability, Li-stuffed garnets exhibit the most promising physical and chemical properties for SSEs. However, the typical microstructure, thick (>100 μm) bulk electrolyte and simple planar electrode/electrolyte interfaces, combined with poor electrode wetting of the garnet result in excessively high area specific resistances (ASRs) that severely limit achievable current density and cell energy density. In this project, the team is building on their demonstrated expertise with garnet electrolytes and ASSBs to accomplish the following: (1) engineer interfaces to overcome high NMC/LLZ interfacial impedance and interfacial degradation; (2) develop processing and fabrication techniques to achieve high loading NMC/LLZ composite cathodes with low resistance and high cyclability; and (3) integrate the NMC/LLZ cathodes into all-solid-state Li-metal/LLZ cells to achieve high-energy-density batteries.
All-solid-state batteries with sulfide electrolytes and high-nickel layered oxide cathodes attract much interest due to their high specific energy. However, their cycling performance is primarily influenced by the interface between the sulfide electrolyte and the high-Ni layered oxide particles, which requires the use of composite cathodes with high ionic and electronic conductivities to achieve a kinetically stable interface inside the cathode. Here, we apply Ti 2 O 3 particles to the high-Ni cathode LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811), where Ti 2 O 3 not only acts as an electronic conductor to provide a fast diffusion path for electrons in the composite cathode, but also absorbs the lattice oxygen released from NCM811 cathode during cycling, stabilizing the Li 6 PS 5 Cl/NCM811 interface and suppressing electrolyte oxidation. The as-modified cathode exhibits an initial specific capacity of 192 mAh g -1 and retains 166 mAh g -1 after 140 cycles at 0.1C rate with a good capacity retention of 86.5%. Furthermore, the composite cathode displays high rate capability even at 1C rate. By contrast, the unmodified Li 6 PS 5 Cl/NCM811 cathode shows poor cycling performance with only 130 mAh g -1 remaining after 130 cycles. This work provides a new direction for the design of cathodes for all-solid-state batteries that can deliver high specific energy with long cycle life.