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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

The NASA Electric Propulsion program

It is pointed out that the NASA Electric Propulsion program is aimed at providing technology for auxiliary and primary propulsion functions for earth-orbital and planetary space missions. Efforts in electrostatic propulsion include analyses of ion propulsion for Geosynchronous (GEO) and planetary spacecraft, continued preflight efforts associated with the Ion Auxiliary Propulsion System (IAPS), and research and technology for advanced and simplified ion thruster systems. In the area of electromagnetic propulsion, studies were conducted regarding the feasibility and impacts of the use of electromagnetic launchers. Research on magnetoplasmadynamic (MPD) thrusters, electromagnetic launchers, and Hall current thrusters was also performed. Studies in the electrothermal sector included an evaluation of electric propulsion options for the Space Station, taking into account also resistojets, a pulsed electrothermal thruster, and arc jets.

Byers, D. C.↗
NASA NTRS1993

Pick-up ions at Pluto

Methane molecules escaping from Pluto's atmosphere are ionized, and the resulting ions are picked up by the solar wind. The mass loading associated with this ion pick-up can produce a cometlike interaction of the solar wind with Pluto. Heavy ion gyroradii are as large as a half million km in the weak interplanetary magnetic field that exists at 30 AU, which is about an order of magnitude larger than the size of the 'interaction region'. We have calculated velocity space distributions of pick-up ions using numerically determined ion trajectories. The predicted pick-up ion fluxes are high enough to be detectable by standard charged particle detectors as far upstream of Pluto as 10 exp 6 km.

Kecskemety, K.↗
NASA NTRS1975

SUMMA hot-ion plasma heating research at NASA Lewis Research Center

The SUMMA superconducting magnetic mirror facility and the associated hot-ion plasma research were described. SUMMA is characterized by intense magnetic fields and a large-diameter working bore (41 cm diameter) with room-temperature access. The goal of the plasma research program is to produce steady-state plasmas of fusion reactor densities and temperatures (but not confinement times). The program includes electrode development to produce a hot, dense, large-volume, steady-state plasma and diagnostics development to document the plasma properties. SUMMA and its hot-ion plasma are ideally suited to develop advanced plasma diagnostics methods. Two such methods whose requirements are well matched to SUMMA are: (1) heavy ion beam probing to measure plasma space potential; and (2) submillimeter wavelength laser Thomson scattering to measure local ion temperature.

Reinmann, J. J.↗
NASA NTRS1981

Upstream energetic ions and electrons - Bow shock-associated or magnetospheric origin

An analysis is made of 35 proton bursts observed with the Max-Planck-Institut/University of Maryland sensor system on ISEE 3 far upstream of the earth's bow shock. These upstream bursts are found to fall into two distinctive groups. The first is accompanied by energetic electrons (more than about 75 keV), and the proton spectrum extends up to energies greater than about 300 keV and higher and bends over toward lower energies (less than about 30 keV). The second group, which is unaccompanied by energetic electron bursts, exhibits spectra which can be represented extremely well by exponentials in energy with a mean e-folding energy of approximately 15 keV. The first group is thought to be of a magnetospheric origin, and the second to be bow-shock associated.

Scholer, M.↗
NASA NTRS1982

High resolution measurements of nightside ion troughs at Venus - Evidence of electrodynamic perturbations

The Bennett rf ion mass spectrometer of the Pioneer Venus Orbiter was expressly designed to provide variable temporal resolution for measurements of thermal ion composition and density. The Explore-Adapt mode is used to obtain priority for measuring the most prominent ion species; in the 2/16 configuration, the two dominant ions within the available range of 16 species are selectively sampled at the highest rate of 0.2 sec/sample. The high-resolution measurements are combined with independent observations from the magnetic field, neutral mass spectrometer, and electron temperature experiments in investigating sharply structured troughs in the low-altitude nightside ion concentrations. The results suggest a close correlation between the structure in the ion distributions and the structured configuration of the magnetic field that is draped about the planet. In the regions of the ion depletions, sharp fluctuations in electron temperature and anomalous increases in the density of neutral gases suggest that the ion depletion may be associated with dynamic perturbation in the ion and neutral flows and/or local joule heating.

Taylor, H. A., Jr.↗
DOE OSTI2026

Selectivity mechanisms of ion intercalation in Prussian blue analogs

Prussian blue analogs (PBAs) are a family of materials with facile, reversible, and selective ion transport capability for various ions via electrochemical intercalation, owing to their vacancy structure. The large tunable compositional space of PBAs allows for manipulation of intercalation behavior and selectivity by controlling structural vacancy level through choice of transition metal centers and modifications to the synthesis process. However, a lack of understanding of the mechanisms of ion selectivity hinders the material’s design process. Here, for this work, we investigated the origins of ion selectivity using a model PBA, copper hexacyanoferrate, and focused on eight technologically and biologically prominent ions, for which we determined a sequence of selectivity: Rb + > K + > Na + > Ba 2+ > Sr 2+ ≈ Ca 2+ > Mg 2+ > Li + . We provide electrochemical, structural, and redox evidence of strong correlation between the ion identity, the dominant charge-compensating redox, and preferred occupancy site. Specifically, using synchrotron anomalous X-ray diffraction (AXRD), we reveal that monovalent ions exhibit significant association with the corner sites of the unit cell and iron redox, whereas divalent ions display affinity toward the center site with higher ratios of copper redox. Informed by selectivity results, we applied CuHCFe to Li purification and achieved 99.9% purity. Our findings demonstrate an approach to elucidating ion intercalation behavior in order to distinguish and manipulate material properties to optimize separation performance.

Prussian blue analog↗
DOE OSTI2024

Net lithium deposition and dominant self-sputtering in lithium tokamak experiment-β with a liquid lithium wall

We observed enhanced net lithium deposition and lithium erosion, possibly dominated by physical sputtering of lithium by lithium-ion bombardment, on the outer plasma-facing surface in the Lithium Tokamak eXperiment-β (LTX-β) during liquid lithium wall operations. Silicon crystal samples with micro-trenches (30 μm × 30 μm × 2–7 μm deep) were exposed to hydrogen plasmas in LTX-β for solid and liquid lithium wall operations. Post-mortem analysis using X-ray photoelectron spectroscopy combined with argon ion sputtering measured net lithium deposition of 8.2 or 21 nm on the silicon crystal surface exposed for ~ 50 repeated shots of ~ 50-ms hydrogen plasma discharges during the liquid lithium wall operations at a vessel temperature of 475 K. Energy dispersive X-ray spectroscopy measured oxygen concentration patterns on the micro-trench floors, which were due to oxidized lithium deposition. Using the inhomogeneous oxygen concentration pattern caused by an ion-shadowing effect associated with the micro-trench’s geometric structure, we determined a polar incident ion direction of 68.4 ± 1.6° referenced to the surface normal direction. This observation was well-explained by the hypothesis that self-sputtering of Li was a dominant lithium erosion source in addition to lithium sputtering by hydrogen bombardment.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Role of Intradomain Heterogeneity on Ion and Polymer Dynamics in Block Polymer Electrolytes: Investigating Interfacial Mobility and Ion-Specific Dynamics and Transport

Block polymers show promise as solid-state battery electrolytes due to the optimization of conductive and mechanical properties enabled via tuning of block chemistry and length. We investigate a polystyrene-block-poly(oligo-oxyethylene methacrylate) (PS-b-POEM) electrolyte doped with various lithium salts to investigate the role of molecular structure on ion transport properties and on local ion dynamics and associations. Anion charge becomes more delocalized with increasing size, reducing the coupling between salt ions while increasing coupling between ion and polymer chain motions and creating a more mobile overall environment. We observe support for this ion-polymer coupling via 1 H, 7 Li and 19 F NMR spectroscopy, from which we obtain ion-specific mobility transition temperatures that differ from the polymer glass transition temperature. We also note faster transport and weaker local energetic interactions with anion size using temperature-dependent NMR diffusometry. 1 H NMR spectroscopy further elucidates polymer chain dynamics and enables quantification of the temperature-dependent fraction of the conducting block that is immobile near the PS-POEM domain interface. As a result, NMR thus represents a species-specific and timescale-specific platform to quantify phase and interface behavior, and to correlate ion-specific transport with polymer chain dynamics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1974

Observation of a two-temperature ion energy distribution in regions of polar wind flow

Study of deviations from thermal equilibrium among the ions in the ionosphere by considering that the 'light' ions H(+) and He(+) may be at a different temperature from the 'heavy' ion O(+). In particular, the case in which thermal protons are observed to be flowing relative to the assumed static ambient oxygen ions is considered. The proton flow is assumed to be along the direction of the magnetic field. Of the cases tested, it is found that the measured proton temperature is from one to ten times the measured oxygen ion temperature. Such temperature enhancements may be expected both because of the energy transfer associated with the ion flow and as a consequence of the preferential energy coupling from the light-ion distribution in the exosphere.

Maier, E. J.↗
NASA NTRS1982

Qualification test results of IAPS 8 cm ion thrusters

Two 8-cm-diameter 5-mN mercury ion thrusters with associated beam shields and gimbals have been fabricated and qualification-tested for the Ion Auxiliary Propulsion System (IAPS) flight test. Functional and performance tests of the thrusters, conducted before, during and after exposure to protoflight vibration and thermal vacuum conditions demonstrated no effects of the environmental exposure and little performance dispersion between the thrusters.

Collett, C.↗
NASA NTRS1987

The composition and radial dependence of cometary ions in the coma of comet P/Halley

The heavy ion analyzer, RPA2-PICCA, on board the Giotto spacecraft detected an increase in the densities of cometary ions within a cometocentric distance of 150,000 km. The composition of cometary ions changed dramatically as the comet's nucleus was approached, but it was clearly dominated by the water group. The second and third most abundant ions identified were associated with the CO- or S-group and the CO2-group, respectively. Ions of larger atomic mass units were also present closer to the comet, and they possibly correspond to sulphur compounds and/or various hydrocarbons. Radial profiles of various groups of heavy ions and certain abundance ratios are presented. The peak density for all mass groups was detected at a cometocentric distance of about 11,000 km. A distinct boundary, where the ion velocity and temperature dropped significantly, was identified at about 27,000 km.

Korth, A.↗
NASA NTRS1992

Precipitation of fast ion beams from the plasma sheet boundary layer

This paper presents a model of precipitated fluxes from the PSBL and CPS. Simulation results and data from Aureol-3 spacecraft indicate the presence of velocity dispersed precipitated ion structures (VDIS) at the poleward edge of the auroral oval. These structures are associated with fast ion beams in the PSBL region of the earth's magnetotail, confirming previous experimental results. The simulations also reveal possible substructuring of the VDIS. The bulk of the PSBL population which is not precipitated is very effectively thermalized and quasi-isotropized after multiple interactions with the magnetotail current layer. After each reflection cycle some part of the distribution is precipitated and forms multiple 'echoes' of VDIS. The CPS distributions occurring as a result of scattering, convection, multiple reflections and Fermi acceleration appear isotropic in the simulation model. This paper portrays the important role of the VDIS auroral region medium for complicated and energetically significant processes occurring in different regions of the distant magnetotail.

Ashour-Abdalla, M.↗