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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Mars Atmospheric Composition, Isotope Ratios and Seasonal Variations: Overview and Updates of the SAM Measurements at Gale Crater

We will summarize the in situ measurements of atmospheric composition and the isotopic ratios of D/H in water, C-13/C-12, O-18/O-16, O-17 / O-16, and C-13 O-18 / C-12 O-16 in carbon dioxide, and Ar-38 / Ar-36, Kr-x / Kr-84, and N-15 / N-14 made in the martian atmosphere at Gale Crater from the Curiosity Rover using the Sample Analysis at Mars (SAM)'s Quadrupole Mass Spectrometer (QMS) and Tunable Laser Spectrometer (TLS). With data over 700 sols since the Curiosity landing, we will discuss evidence and implications for changes on seasonal and other timescales. We will also present results for continued methane and methane enrichment experiments over this time period. Comparison between our measurements in the modern atmosphere and those of martian meteorites like ALH 84001 implies that the martian reservoirs of CO2 and H2O were largely established approximately 4 billion years ago, but that atmospheric loss or surface interaction may be still ongoing.

Niles, Paul↗
NASA NTRS2006

Heavy Isotope Composition of Oxygen in Zircon from Soil Sample 14163: Lunar Perspective of an Early Ocean on the Earth

Thirty oxygen analyses of a large (sub-millimetre) zircon grain from the lunar soil sample 14163 have been determined using CAMECA 1270 ion microprobe. The sample 14163 was returned form the Fra Mauro region by Apollo 14 mission. Zircon grain of 0.6-0.8 mm in size extracted from the sample was imaged using CL detector fitted to the Philips Electron Microscope in order to reveal internal structure. Oxygen isotopes have been analysed during two sessions. The first set of data was collected using the original mount where the grain was set in the resin attached to the glass slide. This resulted in the two complications: (i) standard zircon has to be analysed from the separate mount and (ii) the lunar zircon grain was rased in the holder compared to the standard. In order to investigate, if the elevated oxygen compositions observed during this session could have resulted from this difference in geometric configuration during the standard and sample analyses, the lunar zircon was extracted from the original mount, remounted with the standard chip in the new resin disk and reanalysed during the second session. All analyses made during the first session show delta O-18 values heavier than 6.0%. The second set of data has a wider spread of delta O-18 values with some values as low as 5.6%. Nevertheless, a half of observed delta O-18 values in this set is also higher than 6.0%. Slightly lighter oxygen compositions observed during the second session indicate possible dependence of measured delta O-18 values on the geometry of analysed samples. Presence of zircons with similar heavy oxygen isotope compositions on the Moon, which neither had liquid water or felic crust similar to that on the Earth nor ever developed regime similar to plate tectonics, suggests that other mechanisms can be responsible for elevated delta O-18 values in zircons. This implies that there is no support for the presence of an ocean on the surface of the early Earth and as the ocean appears to be an essential ingredient for the plate tectonics, there is no basis for belief that this mechanism was operating in the early history of the planet.

Nemchin, A. A.↗
NASA NTRS1975

The isotopic composition of galactic cosmic-ray lithium, beryllium, and boron

The isotopes of cosmic-ray Li, Be, and B near 100 MeV per nucleon have been measured with cosmic-ray telescopes on board the IMP-7 and IMP-8 satellites during 1973 and 1974. The measured isotopic abundances provide a stringent test for models of interstellar propagation and solar modulation. It is found that the isotopic abundances can be explained using a steady-state interstellar propagation model with a 5-g/sq cm leakage mean free path. These results, taken along with Be-10 abundance measurements, indicate a longer lifetime for cosmic rays than that predicted by the usual assumption of an average interstellar density of 1 to 3 atoms per cu cm.

Garcia-Munoz, M.↗
NASA NTRS1981

The low-energy galactic cosmic ray carbon, nitrogen, and oxygen isotopic composition

It is found that C, N, and O elemental and isotopic ratios in the galactic cosmic rays measured near the earth with the IMP 7 telescope of the University of Chicago have had the values N/O = 0.25 + or 0.02; C/O = 1.06 + or - 0.03; C-13/C = 0.04-0.10; N-15/N = 0.47 + or - 0.06; and O-18/O less than or equal to 0.03. It is noted that these results are confirmed by IMP 8 measurements. The measurements are extrapolated back to the cosmic ray source using exponential and truncated exponential path length distributions whose parameters have been determined by fitting cosmic ray B/C and sub-Fe/Fe ratios measured previously.

Guzik, T. G.↗
NASA NTRS1985

Multiple Scattering Effects in de/dx-E Instruments for Isotopic Composition Studies

The development of cosmic ray telescopes to separate individual isotopes of heavy elements using the dE/dx-vs.-E technique depends on the incorporation of precise trajectory sensing elements into these systems. In typical implementations the particle trajectory is derived from a set of position measurements made prior to a particle's entering the first energy loss detector. The use of the trajectory obtained in this way to correct energy loss signals for the actual pathlengths through the detectors depends on the assumption that the particle trajectory is a straight line. In order to resolve iron isotopes the angles of incidence, theta the particle track must be known rather accurately.

Wiedenbeck, M. E.↗
NASA NTRS1978

The isotopic composition of cosmic-ray helium from 123 to 279 MeV per nucleon - A new measurement and analysis

A description is given of an experiment which was designed to measure the spectra and composition of cosmic-ray hydrogen and helium isotopes in the interval 120-280 MeV per nucleon to compare with the recent values observed at low energies and also with the only earlier measurement in this high-energy regime. The results presented were obtained during a high-altitude balloon flight from Thompson, Manitoba, in 1973 August. This flight occurred during the period in which the presence of the anomalous component in the helium spectrum became apparent, and provides the opportunity of determining whether this component extends to higher energies than those studied by satellite experiments. The results place an upper limit on the flux of 'anomalous' He-4 (which appeared at low energy in 1972) of at most 15% in the energy range of this experiment, and combined with the low-energy observations of the Chicago group, show an energy dependence of the average ratio of the helium isotopes in the modulated cosmic rays which is difficult to reconcile with current modulation models.

Leech, H. W.↗
NASA NTRS1976

The isotopic composition of hydrogen and helium in low-energy cosmic rays

The isotopes H-2 and He-3 have been identified in low-energy cosmic rays during solar-quiet periods from 1973 January to 1974 October. These observations, made with the electron/isotope spectrometer on IMP-7, cover the energy intervals 5-29 MeV per nucleon for H-2 and 7-50 MeV per nucleon for He-3. The energy spectra of H-1, H-2, and He-3 fall rapidly with decreasing energy, giving H-2/H-1 and He-3/H-1 ratios which are essentially independent of energy as expected from current theories of the solar modulation of galactic cosmic rays. The measured He-4 spectrum, however, is essentially flat below 40 MeV per nucleon, suggesting that there may be contributions from a local, nonsolar source of He-4. Comparisons of the H-1, H-2, and He-3 observations with calculated spectra at 1 AU imply a mean interstellar path length of 7 plus or minus 2 g/sq cm. However, present low-energy measurements of H and He isotopes at 1 AU do not discriminate between possible cosmic-ray source spectra.

Mewaldt, R. A.↗
NASA NTRS1981

The isotopic composition of solar flare accelerated magnesium

Measurements of the abundances of three isotopes of magnesium in solar energetic particles are reported. Data were obtained from the Heavy Isotope Spectrometer Telescope on board the ISEE 3 spacecraft during a large solar particle event following the 2B solar flare of September 23, 1978. A two-dimensional maximum likelihood analysis of the mass determinations for each event, which were taken with a resolution of 0.23 amu, indicates a Mg-25/Mg-24 ratio of 0.14 (+0.05, -0.02) and a Mg-26/Mg-24 ratio of 0.15 (+0.04, -0.03) in the energy interval 12-36 MeV/n. The results are consistent with terrestrial magnesium isotope abundances.

Mewaldt, R. A.↗
NASA NTRS1984

The isotopic composition of the anomalous low-energy cosmic rays

Measurements of the isotopes of low energy cosmic ray He, C, N, O and Ne nuclei are analyzed, in concert with previous data, to examine relationships between galactic cosmic rays (GCR) and anomalous cosmic rays (ACR), which could arise from either extragalactic or interstellar sources. A ground-based heavy isotope spectrometer telescope was used for the survey, along with IMP-7 and IMP-8 data and ISEE-3 data. The data were recorded from 1973-78. Spectral and abundance data are provided for each element. Fragmentation was absent in the ACR data, unlike the GCR data. Differences were also observed in the Ne-22/Ne-20 ratios of ACR and GCR. It is suggested, therefore, that the low energy ACR isotopes have an interstellar origin and are useful for studies of the local interstellar medium.

Mewaldt, R. A.↗
NASA NTRS2000

The Isotopic Composition of Cosmic-Ray Iron and Nickel

Observations from the Cosmic Ray Isotope Spectrometer (CRIS) on ACE have been used to derive contraints on the locations, physical conditions, and time scales for cosmic-ray acceleration and transport.

cosmic ray composition advanced composition explor↗
NASA NTRS2018

Compound-Specific Carbon Isotope Compositions of Aldehydes and Ketones in the Murchison Meteorite

Compound-specific carbon isotope analysis (delta(exp 13)C) of meteoritic organic compounds can be used to elucidate the abiotic chemical reactions involved in their synthesis. The soluble organic content of the Murchison carbonaceous chondrite has been extensively investigated over the years, with a focus on the origins of amino acids and the potential role of Strecker-cyanohydrin synthesis in the early solar system. Previous delta(exp 13)C investigations have targeted alpha-amino acid and alpha-hydroxy acid Strecker products and reactant HCN; however, delta(exp 13)C values for meteoritic aldehydes and ketones (Strecker precursors) have not yet been reported. As such, the distribution of aldehydes and ketones in the cosmos and their role in prebiotic reactions have not been fully investigated. Here, we have applied an optimized O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) derivatization procedure to the extraction, identification, and delta(exp 13)C analysis of carbonyl compounds in the Murchison meteorite. A suite of aldehydes and ketones, dominated by acetaldehyde, propionaldehyde, and acetone, were detected in the sample. delta(exp 13)C values, ranging from -10.0(0/00) to +66.4(0/00), were more (exp 13)C-depleted than would be expected for aldehydes and ketones derived from the interstellar medium, based on interstellar (exp 12)C/(exp 13)C ratios. These relatively (exp 13)C-depleted values suggest that chemical processes taking place in asteroid parent bodies (e.g., oxidation of the IOM) may provide a secondary source of aldehydes and ketones in the solar system. Comparisons between delta(exp 13)C compositions of meteoritic aldehydes and ketones and other organic compound classes were used to evaluate potential structural relationships and associated reactions, including Strecker synthesis and alteration-driven chemical pathways.

meteoritic organic compounds↗
NASA NTRS1990

Primary and diagenetic controls of isotopic compositions of iron-formation carbonates

Results are presented on parallel analyses of carbonate and chert microbands in segments from the early Proterozoic Dales Gorge Member of the Brockman Iron Formation (western Australia), including data on isotopic, chemical, and mineralogic variations in microbanded carbonates, cherts, and coexisting minerals in four core segments from Paraburdoo and one from Wittenoom. It is shown that patterns of variation observed in isotopic abundance and mineral composition can be consistently explained in terms of diagenetic replacement of fine-grained primary precipitates by secondary ones, rather than by mineral-dependent fractionations, metamorphism, or the influence of large volumes of water in an open system.

Kaufman, Alan J.↗
NASA NTRS1975

The isotopic composition of galactic cosmic ray Li, Be, and B

New measurements are reported of the isotopes of cosmic-ray Li, Be, and B and of the elements C, N, and O, with cosmic ray telescopes on board the IMP-7 and IMP-8 satellites during 1973-74 in the energy range 35-210 MeV/nucleon. High mass resolution and stability together with a set of data more extensive than in previous experiments lead to a clear isotopic separation. The measured isotopic and chemical abundances provide a stringent test for models of interstellar propagation and solar modulation. We find not only that for a steady state propagation and solar modulation model all light isotopes and medium element abundances are explained by 5 g/sq cm average pathlengths, as was earlier found from element analysis, but that also these results, taken along with our Be-10 measurements, indicate a longer lifetime for cosmic rays than predicted by the usual assumption of an average interstellar density of 1 to 3 atoms/cu cm.

Garcia-Munoz, M.↗
NASA NTRS1974

Study of isotopic composition of helium in the fine fraction of Luna 16 lunar surface material

The content of He isotopes is measured in two samples of the lunar surface material returned by the Luna 16 automatic station. Both samples consist of a fine fraction of lunar surface material and were samples from zone A (sample 3-2k) and from zone V (sample 9-1r). The value of He4/He3 and the concentration of the He isotopes are identical for both samples, within the limits of experimental error.

Boltenkov, B. S.↗