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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
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NASA NTRS1976

Laser induced fluorescence applied to turbulent reacting flows

The saturated fluorescence method makes use of the great simplifications which occur when under conditions of intense radiation the excitation process becomes saturated. A description is presented of the saturated fluorescence method, taking into account rate equations and saturation, radiative transfer, the two-level system, a multilevel system, and measurements under saturation conditions. The detectability limits of the method are investigated. Fluorescence trapping is found to place an upper limit on the number density of the fluorescing species that can be measured without signal loss. Turbulence places time and spatial constraints on the measurements, but otherwise poses no difficulties. Saturated laser induced fluorescence spectroscopy appears to be a most promising method for measuring species concentrations in flames.

Daily, J. W.↗
NASA NTRS1977

Experimental measurements of the ground cloud effluents and cloud growth for the May 20, 1975, Titan 3C launch at Air Force Eastern Test Range, Florida

The experiment included surface level and airborne in situ cloud measurements of the exhaust effluents from the Titan IIIC solid rocket boosters. Simultaneous visible spectrum photographic pictures of the ground cloud as well as infrared imaging of the cloud were obtained to study the cloud rise, growth, and direction of travel within the earth's surface mixing layer. The NASA multilayer diffusion model predictions of cloud growth, direction of travel, and expected surface level effluent concentrations were made prior to launch and after launch using measured meteorological conditions. Prelaunch predictions were used to position the effluent monitoring instruments, and the postlaunch predictions were compared with the measured data. Measurement results showed that surface level effluent values were low, often below the detection limits of the instrumentation. The maximum surface level hydrogen chloride concentration measured 50 parts per billion at about 8 km from the launch pad. The maximum observed in-cloud (airborne measurement) hydrogen chloride concentration was 7 per million.

Gregory, G. L.↗
NASA NTRS1977

Atmospheric scavenging exhaust

Solid propellant rocket exhaust was directly utilized to ascertain raindrop scavenging rates for hydrogen chloride. The airborne HCl concentration varied from 0.2 to 10.0 ppm and the raindrop sizes tested included 0.55 mm, 1.1 mm, and 3.0 mm. Two chambers were used to conduct the experiments. A large, rigid walled, spherical chamber stored the exhaust constituents while the smaller chamber housing all the experiments was charged as required with rocket exhaust HCl. Surface uptake experiments demonstrated an HCl concentration dependence for distilled water. Sea water and brackish water HCl uptake was below the detection limit of the chlorine-ion analysis technique employed. Plant life HCl uptake experiments were limited to corn and soybeans. Plant age effectively correlated the HCl uptake data. Metallic corrosion was not significant for single 20 minute exposures to the exhaust HCl under varying relative humidity.

Fenton, D. L.↗
NASA NTRS1978

Atmospheric scavenging of solid rocket exhaust effluents

Solid propellant rocket exhaust was directly utilized to ascertain raindrop scavenging rates for hydrogen chloride. Two chambers were used to conduct the experiments; a large, rigid walled, spherical chamber stored the exhaust constituents, while the smaller chamber housing all the experiments was charged as required with rocket exhaust HCl. Surface uptake experiments demonstrated an HCl concentration dependence for distilled water. Sea water and brackish water HCl uptake was below the detection limit of the chlorine-ion analysis technique used. Plant life HCl uptake experiments were limited to corn and soybeans. Plant age effectively correlated the HCl uptake data. Metallic corrosion was not significant for single 20 minute exposures to the exhaust HCl under varying relative humidity. Characterization of the aluminum oxide particles substantiated the similarity between the constituents of the small scale rocket and the full size vehicles.

Fenton, D. L.↗
NASA NTRS1978

Summary of airborne chlorine and hydrogen chloride gas measurements for August 20 and September 5, 1977 Voyager launches at Air Force Eastern Test Range, Florida

Airborne chlorine and hydrogen chloride measurements were made in the tropospheric ground cloud following the Voyager launches of August 20 and September 5, 1977. The maximum observed hydrogen chloride concentration for both launches was about 25 to 30 parts per million (ppm) occurring typically 2 to 6 minutes after launch. By completion of the sampling mission (1-1/2 hours for August, 4-1/2 hours for September), the maximum in-cloud concentration decayed to about 1 to 2 ppm. Maximum observed chlorine concentrations were about 40 to 55 parts per billion (ppb) about 2 to 8 minutes after launch; by about 15 minutes after launch, chlorine concentrations were less than 10 ppb (detection limit). In-cloud chlorine concentrations were well below 1 percent of hydrogen chloride concentrations. The appendix of the report discusses the chlorine instrument and the laboratory evaluation of the detector.

Gregory, G. L.↗
NASA NTRS1977

The search for organic substances and inorganic volatile compounds in the surface of Mars

A total of four Martian samples, one surface and one subsurface sample at each of the two Viking landing sites, Chryse Planitia and Utopia Planitia, have been analyzed for organic compounds by a gas chromatograph-mass spectrometer. In none of these experiments could organic material of Martian origin be detected at detection limits generally of the order of parts per billion and for a few substances closer to parts per million. The evolution of water and carbon dioxide, but not of other inorganic gases, was observed upon heating the sample to temperatures of up to 500 C. The absence of organic compounds seems to preclude their production on the planet at rates that exceed the rate of their destruction. It also makes it unlikely that living systems that behave in a manner similar to terrestrial biota exist, at least at the two Viking landing sites.

Biemann, K.↗
NASA NTRS1977

Evaluation of a hydrogen chloride detector for environmental monitoring

The paper describes a hydrogen chloride detector designed to monitor concentrations of hydrogen chloride gas in the ambient environment. The detector was developed for NASA for use in launch vehicle effluent monitoring. The detector operates on chemiluminescence principles with a lower detection limit of less than 5 x 10 to the -3rd ppm (by volume). The hydrogen chloride in the air sample reacts with a bromide-bromate coating in the inlet tube of the instrument producing bromine. Bromine is then quantitated by chemiluminescent oxidation of luminol. The visible light generated in the chemiluminescent reaction is proportional to the hydrogen chloride concentration of the sampled airstream. The detector is most suited to laboratory or field studies where hydrogen chloride is the dominant pollutant, as compared to the interfering species. Interferences include strong acids, acid-forming gases, and halogen gases. Of the interferences investigated the most serious in these groups are hydrochloric and sulfuric acid, sulfur dioxide, and chlorine, respectively. The detector has been in use since 1974 and has been found to be highly portable, rugged, and stable under extreme environmental conditions.

Gregory, G. L.↗
NASA NTRS1978

On the detectability of millimeter wavelength spectral lines from planetary atmospheres

This paper adopts a simple line-formation model to estimate detection limits on the fractional absorption produced by molecular lines in the spectra of the planets, when observed with the 14-m antenna and low-noise receivers of the Five College Radio Astronomy Observatory. The results, which can readily be adjusted for receiver and telescope characteristics of other observatories, indicate that three kinds of observing programs may prove fruitful: (1) programs to monitor temporal variations of the strong CO absorption in the spectrum of Venus and Mars; (2) searches for weak absorption lines of other molecules, which are particularly promising for Venus: and (3) efforts to measure broad features in the continuous spectra of Venus, and possibly Jupiter, produced by molecules deep in the planetary atmospheres. Except for delineation of broad features of NH3 and possibly H2O near 25 GHz, hardly any useful observations can be made at frequencies less than 60 GHz.

White, R. E.↗
NASA NTRS1980

Evaluation of composite bolometers at 0.4 Kelvin

Composite bolometer structures have provided the most sensitive IR detectors for operation at helium-4 temperatures of 1.5K. Below 1.5K the electrical and thermal properties change significantly and the performance characteristics cannot be accurately extrapolated for composite bolometers at helium-3 temperatures of 0.4K. The paper deals with experimentally assessed performance of composite bolometers at 0.4K. It is found that sensitivity estimates derived from electrical or load curve properties can overestimate the responsivity to radiation by several orders of magnitude depending upon a particular material behavior. For many near-millimeter applications background power levels are several nanowatts and the associated photon noise plus Johnson and phonon noise components impose a fundamental detection limit of about 5 x 10 to the -15thW/Hz to the -1/2. We have successfully fabricated composite bolometers which at 0.4 K and millimeter wavelengths achieve a noise equivalent power of 7 x 10 to the -15thW/Hz to the -1/2 coupled with a large absorbing area (0.3 sq cm) and a fast response time (2 msec.).

El-Ataway, S.↗
NASA NTRS1980

Detection and tracking of a low energy swell system off the U.S. East Coast with the Seasat SAR

It is noted that on the morning of September 28, 1978, at 1520 GMT, Seasat approached the East Coast of the U.S. with the 100 km swath of its synthetic aperture radar (SAR) running approximately parallel to the coast but displayed eastward by about 20 km. This pass is analyzed and the following conclusions are drawn: (1) the SAR can successfully detect low-energy swell systems with wave heights under 1 m (actually 0.65 + or - 0.25 m); (2) the refraction of low-energy but well-organized swells deriving from changes in the local depth of the ocean is clearly detectable in both wavelength and direction; and (3) the complexity of the ocean spectrum (whether composed of more than one system or spread in direction and wave number) appears to have little bearing on the threshold detection limits.

Beal, R. C.↗
NASA NTRS1980

A proposed search on the solar neighborhood for substellar objects

The Infrared Astronomical Satellite (IRAS) program will produce an extremely sensitive all-sky survey over the wavelength region 8 to 120 microns when the mission is flown in 1982. These data will provide a novel opportunity to detect planetary-sized objects having masses smaller than 0.08 solar masses in or near the solar system. The improved detection limit of the IRAS will greatly increase the volume of space searched for such objects, as compared with previous optical and infrared studies.

Reynolds, R. T.↗
NASA NTRS1981

Concentration of hydrocarbons associated with particles in the shelf waters adjacent to the entrance of Chesapeake Bay

Particulate hydrocarbon concentrations were measured in 94 water samples. The concentrations ranged from below the detection limit ( 0.7 micro-G/L) to 32 micro-g/l. The mean for all samples was 5.6 micro-g/l. Particulate hydrocarbon concentrations are higher in the Bay mouth and lower in the shelf waters adjacent to the entrance of Chesapeake Bay. No coherent particulate hydrocarbon distribution is seen with depth in the water column. The Bay is postulated as one of the possible chronic sources of particulate hydrocarbons for the adjacent shelf waters.

Wade, T. L.↗
NASA NTRS1982

Electron microprobe analysis of trace elements in minerals at 10 PPM concentrations

An improved technique is developed for measuring backgrounds during trace element analysis of crystals and glass using electron microprobes. This technique overcomes major difficulties encountered with conventional techniques, such as the problem of obtaining the net X-ray intensity of the characteristic emission line of interest with sufficient precision and accuracy, as well as the error due to the inability to directly measure the intensity at the wavelength of the characteristic line on the sample being analyzed. It is shown that this technique can yield reproducible results to within 4 ppm in olivine, and has a minimum uncertainty and detection limit of 10 ppm Nd in olivine.

Mckay, G. A.↗
NASA NTRS1981

1.0 to 2.5 micrometer short wavelength infrared /SWIR/ linear array technology for low background applications

A design concept is presented for a hybrid linear focal plane array operating in the 1.0 to 2.5 micron band under low background conditions such as encountered in spaceborne missions. The concept is based on direct gate coupling of the input from a photovoltaic mercury-cadmium telluride detector into a CCD multiplexer. Theoretical analysis indicates a specific detectivity at peak wavelength on the order of 10 to the 12th cm sq rt Hz/W when the system is operating at 200 K. Values of the voltage responsivity, specific detectivity and the relative voltage noise levels of the coupled system obtained in experimental studies with direct-gate-coupled 4.0-micron detectors support the theoretical analysis performed for the case of system detectivity limited by the CCD 1/f noise.

Stobie, J.↗
NASA NTRS1984

The role of surface generated radicals in catalytic combustion

The role of surface generated OH radicals in determining the catalytic ignition characteristics for propane oxidation on platinum were studied. The experiments were conducted in a stacked-plate, catalyst bed. Transient measurements, during catalytic ignition, of the catalyst's axial temperature profile were made and the effect of equivalence ratio, inlet temperature and inlet velocity was investigated. These measurements will provide insights which will be useful in planning and interpreting to OH measurements. Attempts to measure OH concentration in the catalyst bed using resonance absorption spectroscopy were unsuccessful, indicating that OH concentrations are below 10 to the 16th power/cc but still possibly above equilibrium values. Measurements are currently underway using forward scatter laser induced fluorescence which should extend the OH detection limits several orders of magnitude below the equilibrium concentrations.

Santavicca, D. A.↗
NASA NTRS1984

Recent comet impacts on the moon: The evidence from spectral reflectance studies

The results of analyses of near infrared reflectance spectra are inconsistent with numerous previous interpretations of the Reiner Gamma Formation. These include: (1) nue ardente or volcanic ash deposits, (2) volcanically derived sublimates, (3) high albedo volcanic deposits, and (4) highlands debris emplaced as impact ejecta. These results, strongly suggest that the selective preservation of high albedo features (formed by secondaries) by a local magnetic field enhancement is not a viable hypothesis. The results are generally consistent with, but place constraints on, the cometary impact hypothesis of Schultz and co-workers. While the presence of a magnetized component was not detected in either the bright or dark portions of the Reiner Gamma Formation, this material may be present in amounts under the current detection limits.

Hawke, B. R.↗
NASA NTRS1984

The dual-frequency scatterometer reexamined

The utility of dual frequency scatterometers in measuring ocean wave directional spectra can be increased by adding third frequency to the system. The background which effectively limits signal detectability in dual frequency operation can be made a part of the signal through the addition of this third frequency. Signal detectability is limited only by system thermal noise and space based operation becomes more feasible.

Plant, W. J.↗
NASA NTRS1983

NASA Global Tropospheric Experiment

The rationale and program design for the NASA Global Tropospheric Experiment (GTE) are described. The GTE is intended to characterize the global tropospheric chemistry and its interaction with the stratosphere, the land, and the ocean. The program emphasis is laid on the potential global impact of human activities, particularly those which release CH4, N2O, and chlorofluorocarbons into the atmosphere. Specific tasks defined thus far include characterizing the tropospheric gas-phase chemistry of OH, NO, and NO2, determining concentrations and distributions of CO, CH4, O3, and N2O, as well as halogens, trace metals, and reduced sulfur species. Techniques are needed for measuring the chemical fluxes between earth surface sources and sinks, the boundary layer, the free troposphere, and the stratosphere. The first phase of the GTE will be to test and develop techniques and assay the detection limits for OH, NO, and NO2 and assess the reliability of laboratory calibrations. Improvements in modelling global-scale tropospheric processes will also be pursued.

Mcneal, R. J.↗