Second spectrum of Manganese (Mn II), Part I: Fine and hyperfine structure analysis of even-parity levels
We have taken advantage of the existence of some experimental Mn II hyperfine magnetic dipole constant (A) values given in literature with low uncertainties to achieve for a first time an accurate hyperfine structure (hfs) parametric study. The monoelectronic hfs parameter values were extracted in their entirety for the alone stable {sup 55}Mn II. For example for 3d{sup 4}4s configuration we obtain: a{sub 4s}{sup 10}=198.08 mk and a{sub 3d}{sup 01}=17.14 mk. These semi-empirically extracted single-electron parameters were analyzed and compared with ab-initio calculations. In this first part of a global work, devoted particularly to even-parity levels we have at beginning studied a fine structure of two hundred levels, giving their leading eigenvector percentages and their calculated Landé-factor g{sub J}. We present also predicted singlet, triplet and quintet positions of missing experimental levels up to 120 000 cm{sup −1}, not far from Mn II ionization energy of 126 000 cm{sup −1}. We close this work by giving predicted values of magnetic dipole hfs constants of all known levels of the most relevant Mn II even-parity configuration: 3d{sup 4}4s, whose splitting is not yet measured.