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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
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NASA NTRS2018

The Imaging X-ray Polarimetry Explorer (IXPE): Technical Overview

The Imaging X-ray Polarimetry Explorer (IXPE) will expand the information space for study of cosmic sources, by adding linear polarization to the properties (time, energy, and position) observed in x-ray astronomy. Selected in 2017 January as a NASA Astrophysics Small Explorer (SMEX) mission, IXPE will be launched into an equatorial orbit in 2021. The IXPE mission will provide scientifically meaningful measurements of the x-ray polarization of a few dozen sources in the 2-8 keV band, including polarization maps of several x-ray-bright extended sources and phase-resolved polarimetry of many bright pulsating x-ray sources.

O'Dell, Stephen L.↗
NASA NTRS2018

Diverging Importance of Drought Stress for Maize and Winter Wheat in Europe

Understanding the drivers of yield levels under climate change is required to support adaptation planning and respond to changing production risks. This study uses an ensemble of crop models applied on a spatial grid to quantify the contributions of various climatic drivers to past yield variability in grain maize and winter wheat of European cropping systems (1984-2009) and drivers of climate change impacts to 2050. Results reveal that for the current genotypes and mix of irrigated and rainfed production, climate change would lead to yield losses for grain maize and gains for winter wheat. Across Europe, on average heat stress does not increase for either crop in rainfed systems, while drought stress intensifies for maize only. In low-yielding years, drought stress persists as the main driver of losses for both crops, with elevated CO2 offering no yield benefit in these years.

Europe↗
NASA NTRS2019

Energetic Particles of Cosmic Accelerators II: Active Galactic Nuclei and Gamma-ray Bursts

The high-energy universe has revealed that energetic particles are ubiquitous in the cosmos and play a vital role in the cultivation of cosmic environments on all scales. Our pursuit of more than a century to uncover the origins and fate of these cosmic energetic particles has given rise to some of the most interesting and challenging questions in astrophysics. Within our own galaxy, we have seen that energetic particles engage in a complex interplay with the galactic environment and even drive many of its key characteristics (for more information, see the first white paper in this series). On cosmological scales, the energetic particles supplied by the jets of active galactic nuclei (AGN) are an important source of energy for the intracluster and intergalactic media, providing a mechanism for regulating star formation and black hole growth and cultivating galaxy evolution (AGN feedback). Gamma-ray burst (GRB) afterglows encode information about their circumburst environment, which has implications for massive stellar winds during previous epochs over the stellar lifecycle. As such, GRB afterglows provide a means for studying very high-redshift galaxies since GRBs can be detected even if their host galaxy cannot. It has even been suggest that GRB could be used to measure cosmological distance scales if they could be shown to be standard candles. Though they play a key role in cultivating the cosmological environment and/or enabling our studies of it, there is still much we do not know about AGNs and GRBs, particularly the avenue in which and through which they supply radiation and energetic particles, namely their jets. Despite the enormous progress in particle-in-cell and magnetohydrodynamic simulations, we have yet to pinpoint the processes involved in jet formation and collimation and the conditions under which they can occur. For that matter, we have yet to identify the mechanism(s) through which the jet accelerates energetic particles – is it the commonly invoked diffusive shock acceleration process or is another mechanism, such as magnetic reconnection, required? Do AGNs and GRBs accelerate hadrons, and if so, do they accelerate them to ultra-high energies and are there high-energy neutrinos associated with them? MeV gamma-ray astronomy, enabled by technological advances that will be realized in the coming decade, will provide a unique and indispensable perspective on the persistent mysteries of the energetic universe. This White Paper is the second of a two-part series highlighting the most well-known high-energy cosmic accelerators and contributions that MeV gamma-ray astronomy will bring to understanding their energetic particle phenomena. Specifically, MeV astronomy will: 1. Determine whether AGNs accelerate CRs to ultra-high energies; 2. Provide the missing pieces for the physics of the GRB prompt emission; 3. Measure magnetization in cosmic accelerators and search for acceleration via reconnection.

Venters, Tonia M.↗
NASA NTRS2019

Energetic Particles of Cosmic Accelerators I: Galactic Accelerators

The high-energy universe has revealed that energetic particles are ubiquitous in the cosmos and play a vital role in the cultivation of cosmic environments on all scales. Our pursuit of more than a century to uncover the origins and fate of these cosmic energetic particles has given rise to some of the most interesting and challenging questions in astrophysics. Energetic particles in our own galaxy, galactic cosmic rays (GCRs), engage in a complex interplay with the interstellar medium and magnetic fields in the galaxy, giving rise to many of its key characteristics. For instance, GCRs act in concert with galactic magnetic fields to support its disk against its own weight. GCR ionization and heating are essential ingredients in promoting and regulating the formation of stars and protostellar disks. GCR ionization also drives astrochemistry, leading to the build up of complex molecules in the interstellar medium. GCR transport throughout the galaxy generates and maintains turbulence in the interstellar medium, alters its multi-phase structure, and amplifies magnetic fields. GCRs could even launch galactic winds that enrich the circumgalactic medium and alter the structure and evolution of galactic disks. As crucial as they are for many of the varied phenomena in our galaxy, there is still much we do not understand about GCRs. While they have been linked to supernova remnants (SNRs), it remains unclear whether these objects can fully account for their entire population, particularly at the lower (approximately less than 1 GeV per nucleon) and higher (~PeV) ends of the spectrum. In fact, it is entirely possible that the SNRs that have been found to accelerate CRs merely re-accelerate them, leaving the origins of the original GCRs a mystery. The conditions for particle acceleration that make SNRs compelling source candidates are also likely to be present in sources such as protostellar jets, superbubbles, and colliding wind binaries (CWBs), but we have yet to ascertain their roles in producing GCRs. For that matter, key details of diffusive shock acceleration (DSA) have yet to be revealed, and it remains to be seen whether DSA can adequately explain particle acceleration in the cosmos. This White Paper is the first of a two-part series highlighting the most well-known high-energy cosmic accelerators and contributions that MeV gamma-ray astronomy will bring to understanding their energetic particle phenomena. For the case of GCRs, MeV astronomy will: 1) Search for fresh acceleration of GCRs in SNRs; 2) Test the DSA process, particularly in SNRs and CWBs; 3) Search for signs of CR acceleration in protostellar jets and superbubbles.

Venters, Tonia M.↗
NASA NTRS2019

The Imaging X-Ray Polarimetry Explorer (IXPE): Technical Overview II

The Imaging X-ray Polarimetry Explorer (IXPE) will add polarization to the properties (time, energy, and position) observed in x-ray astronomy. A NASA Astrophysics Small Explorer (SMEX) in partnership with the Italian Space Agency (ASI), IXPE will measure the 2–8-keV polarization of a few dozen sources during the first 2 years following its 2021 launch. The IXPE Observatory includes three identical x-ray telescopes, each comprising a 4-m-focal-length (grazingincidence) mirror module assembly (MMA) and a polarization-sensitive (imaging) detector unit (DU), separated by a deployable optical bench. The Observatory’s Spacecraft provides typical subsystems (mechanical, structural, thermal, power, electrical, telecommunications, etc.), an attitude determination and control subsystem for 3-axis stabilized pointing, and a command and data handling subsystem communicating with the science instrument and the Spacecraft subsystems.

X-ray astronomy↗
NASA NTRS2019

Climatology of Transient Luminous Events and Lightning Observed Above Europe and the Mediterranean Sea

In 1999, the first sprites were observed above European thunderstorms using sensitive cameras. Since then, Eurosprite campaigns have been conducted to observe sprites and other transient luminous events (TLEs), expanding into a network covering large parts of Europe and coastal areas. In 2009 through 2013, the number of optical observations of TLEs reached a peak of 2000 per year. Because of this unprecedented number of European observations, it was possible to construct a climatology of 8394 TLEs observed above 1018 thunderstorm systems and study for the first time their distribution and seasonal cycle above Europe and parts of the Mediterranean Sea. The number of TLEs per thunderstorm was found to follow a power law, with less than 10 TLEs for 801 thunderstorms and up to 195 TLEs above the most prolific one. The majority of TLEs were classified as sprites, 641 elves, 280 halos, 70 upward lightning, 2 blue jets and 1 gigantic jet. The climatology shows intense TLE activity during summer over continental areas and in late autumn over coastal areas and sea. The two seasons peak, respectively, in August and November, separated by March and April with almost no TLEs, and a relative minimum around September. The observed TLE activity, i.e. mostly sprites, is shown to be largely consistent with lightning activity, with a 1/1000 of observed TLE-to-lightning ratio in regions with most observations. The overall behaviour is consistent among individual years, making the observed seasonal cycle a robust general feature of TLE activity above Europe.

Arnone, Enrico↗
NASA NTRS2019

Estimation of coarse dead wood stocks in intact and degraded forests in the Brazilian Amazon using airborne lidar

Coarse dead wood is an important component of forest carbon stocks, but it is rarely measured in Amazon forests and is typically excluded from regional forest carbon budgets. Our study is based on line intercept sampling for fallen coarse dead wood conducted along 103 transects with a total length of 48 km matched with forest inventory plots where standing coarse dead wood was measured in the footprints of larger areas of airborne lidar acquisitions. We developed models to relate lidar metrics and Landsat time series variables to coarse dead wood stocks for intact, logged, burned, or logged and burned forests. Canopy characteristics such as gap area produced significant individual relations for logged forests. For total fallen plus standing coarse dead wood (hereafter defined as total coarse dead wood), the relative root mean square error for models with only lidar metrics ranged from 33 % in logged forest to up to 36 % in burned forests. The addition of historical information improved model performance slightly for intact forests (31 % against 35 % relative root mean square error), not justifying the use of a number of disturbance events from historical satellite images (Landsat) with airborne lidar data. Lidar-derived estimates of total coarse dead wood compared favorably with independent ground-based sampling for areas up to several hundred hectares. The relations found between total coarse dead wood and variables quantifying forest structure derived from airborne lidar highlight the opportunity to quantify this important but rarely measured component of forest carbon over large areas in tropical forests.

Brazilian Amazon↗
NASA NTRS2021

The Imaging X-Ray Polarimetry Explorer (IXPE): Technical Overview IV

Scheduled to launch in late 2021,the Imaging X-ray Polarimetry Explorer (IXPE) is a Small Explorer Mission designed to open up a new window of investigation --X-ray polarimetry. The IXPE observatory features 3 identical telescopes each consisting of a mirror module assembly with a polarization-sensitive imaging x-ray detector at its focus. An extending boom, deployed on orbit, provides the necessary 4 m focal length. The payload sits atop a 3-axis stabilized spacecraft which, among other things, provides power, attitude determination and control, commanding, and telemetry to the ground. During its 2-year baseline mission, IXPE will conduct precise polarimetry for samples of multiple categories of x-ray sources, with follow-on observations of selected targets. IXPE is a partnership between NASA and the Italian Space Agency (ASI).

X-ray polarimetry↗
NASA NTRS2020

Projection-Based Inter-Agent Collision Avoidance in Dual Agent Systems

Inter-agent collisions can occur in otherwise dynamically-stable (i.e., Lyapunov stable) dual-agent leaderfollower systems. These inter-agent collisions between the leader and the follower happen during the transient phase of the system’s evolution, although the steady-state behavior of the system is asymptotically/exponentially stable. Therefore, to avoid such inter-agent collisions, it is essential to control the relative error trajectory between the leader and the follower during the transient phase of the system’s evolution. In this paper, we introduce a novel projection operator based modelreference control architecture that can mitigate impending inter-agent collisions by modifying the transient dynamics of relative trajectories. This controller augments the follower’s baseline controller and consists of two essential components: a collision-free reference model based on the projection operator and a model reference tracking controller to guide the follower to follow the reference-model. This paper defines the concept of transient-instability in leader-follower systems, introduces collision mitigation controller architecture, and presents an illustrative example demonstrating its effectiveness.

Bayard, David S.↗
NASA NTRS2021

Liana optical traits increase tropical forest albedo and reduce ecosystem productivity

Lianas are a key growth form in tropical forests. Their lack of self-supporting tissues and their vertical position on top of the canopy make them strong competitors of resources. A few pioneer studies have shown that liana optical traits differ on average from those of colocated trees. Those trait discrepancies were hypothesized to be responsible for the competitive advantage of lianas over trees. Yet, in the absence of reliable modelling tools, it is impossible to unravel their impact on the forest energy balance, light competition, and on the liana success in Neotropical forests. To bridge this gap, we performed a meta-analysis of the literature to gather all published liana leaf optical spectra, as well as all canopy spectra measured over different levels of liana infestation. We then used a Bayesian data assimilation framework applied to two radiative transfer models (RTMs) covering the leaf and canopy scales to derive tropical tree and liana trait distributions, which finally informed a full dynamic vegetation model. According to the RTMs inversion, lianas grew thinner, more horizontal leaves with lower pigment concentrations. Those traits made the lianas very efficient at light interception and significantly modified the forest energy balance and its carbon cycle. While forest albedo increased by 14% in the shortwave, light availability was reduced in the understorey (−30% of the PAR radiation) and soil temperature decreased by 0.5°C. Those liana-specific traits were also responsible for a significant reduction of tree (−19%) and ecosystem (−7%) gross primary productivity (GPP) while lianas benefited from them (their GPP increased by +27%). This study provides a novel mechanistic explanation to the increase in liana abundance, new evidence of the impact of lianas on forest functioning, and paves the way for the evaluation of the large-scale impacts of lianas on forest biogeochemical cycles.

Félicien Meunier↗
NASA NTRS2022

Observation of a Magnetic Switchback in the Solar Corona

Switchbacks are sudden, large radial deflections of the solar wind magnetic field, widely revealed in interplanetary space by the Parker Solar Probe. The switchbacks’ formation mechanism and sources are still unresolved, although candidate mechanisms include Alfvénic turbulence, shear-driven Kelvin–Helmholtz instabilities, interchange reconnection, and geometrical effects related to the Parker spiral. This Letter presents observations from the Metis coronagraph on board a Solar Orbiter of a single large propagating S-shaped vortex, interpreted as the first evidence of a switchback in the solar corona. It originated above an active region with the related loop system bounded by open-field regions to the east and west. Observations, modeling, and theory provide strong arguments in favor of the interchange reconnection origin of switchbacks. Metis measurements suggest that the initiation of the switchback may also be an indicator of the origin of slow solar wind.

Solar corona↗
DOE OSTI2026

Brightest Cluster Galaxy ellipticity as proxy for halo shape: Orientation bias, assembly bias, and potential selection effects in SZ-selected clusters

The orientation of triaxial galaxy clusters with respect to the line-of-sight is expected to be one of the prime sources of scatter and potential bias in optical observables (e.g., richness and weak-lensing signal) of galaxy clusters. In this work, we use the observed shape of the central Brightest Cluster Galaxy (BCG) as proxy for the orientation along the line-of-sight for clusters selected via the Sunyaev-Zel'dovich (SZ) effect from the South Pole Telescope (SPT) and Atacama Cosmology Telescope (ACT) surveys, matched to optically selected clusters from the Dark Energy Survey Year 3 (DES). We construct two samples of clusters that are designed to be identical in SZ mass estimate and redshift but with the roundest vs. the most elliptical BCGs, which we expect to correspond to BCGs (and clusters) with major axes aligned along the line-of-sight vs. in the plane of the sky, respectively. We find that the optical richness of round-BCG clusters is $\sim 10$% larger than that of elliptical-BCG clusters, in agreement with the expectation from projection effects and presenting the first such detection in data. The density profiles, however, are not in agreement with the expectation from projection effects: the 1-halo term (below $6~h^{-1}\rm{Mpc}$) of both the weak-lensing and galaxy density profiles are the same for the subsamples, contrary to previous studies based on X-ray selected clusters. In the 2-halo regime (above $6~h^{-1}\rm{Mpc}$), we find a significant excess of the elliptical-BCG cluster profiles compared to the round-BCG cluster profiles, which is the opposite of the expectation from numerical simulations. We hypothesize that the intrinsic shape of the BCG reflects not just the orientation angle, but also intrinsic properties of the cluster which can affect both the SZ signal and the amplitude of the 2-halo term.

Srinivasan, Radhakrishnan [SUNY, Stony Brook] (ORC↗
DOE OSTI2024

Ligand‐Mediated Quantum Yield Enhancement in 1‐D Silver Organothiolate Metal–Organic Chalcogenolates

X-ray free electron laser (XFEL) microcrystallography and synchrotron single-crystal crystallography are used to evaluate the role of organic substituent position on the optoelectronic properties of metal–organic chalcogenolates (MOChas). MOChas are crystalline 1D and 2D semiconducting hybrid materials that have varying optoelectronic properties depending on composition, topology, and structure. While MOChas have attracted much interest, small crystal sizes impede routine crystal structure determination. A series of constitutional isomers where the aryl thiol is functionalized by either methoxy or methyl ester are solved by small molecule serial femtosecond X-ray crystallography (smSFX) and single crystal rotational crystallography. While all the methoxy examples have a low quantum yield (0-1%), the methyl ester in the ortho position yields a high quantum yield of 22%. Here, the proximity of the oxygen atoms to the silver inorganic core correlates to a considerable enhancement of quantum yield. Four crystal structures are solved at a resolution range of 0.8–1.0 Å revealing a collapse of the 2D topology for functional groups in the 2- and 3- positions, resulting in needle-like crystals. Further analysis using density functional theory (DFT) and many-body perturbation theory (MBPT) enables the exploration of complex excitonic phenomena within easily prepared material systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Dual Optical Hyperbolicity of PdCoO 2 and PdCrO 2 Delafossite Single Crystals

Hyperbolic materials exhibit a very peculiar optical anisotropy with simultaneously different signs of the dielectric tensor components. This anisotropy allows the propagation of exotic surface-wave excitations like hyperbolic phonons and plasmon polaritons. While hyperbolic materials hold promise for applications in subwavelength photonics and enhanced light-matter interactions, their natural occurrence is limited to a few materials, often accompanied by significant dielectric losses and limited hyperbolic spectral bandwidth. Focusing on PdCoO 2 and PdCrO 2 delafossite transition-metal oxides, in this paper unique dual hyperbolic regimes are demonstrated:: one localized around a phonon absorption in the mid-infrared spectral region, and the other extending into the visible range. Both hyperbolic regimes show exceptional properties including low dissipation and high hyperbolic quality factors. These results pave the way for innovative applications of delafossite layered metals in subwavelength photonics, imaging, and sensing.

36 MATERIALS SCIENCE↗
DOE OSTI2025

A New Family of Ternary Intermetallic Compounds with Dualistic Atomic Ordering – The ZIP Phases

A new family of nanostructured ternary intermetallic compounds − named the ZIP phases − is introduced in this work. The ZIP phases exhibit dualistic atomic ordering, i.e., they form two structural variants: one with the fcc diamond cubic structure (space group Fd$\bar{3}$m) and one with the hexagonal structure (space group P6 3 /mmc). They are also characterized by metallic behavior, ionic bonding, and atomic zigzagging. Powder metallurgical routes involving pressure-assisted densification are adopted to demonstrate ZIP phase synthesis in the Nb-Si-Ni, Nb-Si-Co, Ta-Si-Ni, V-Si-Ni, and Nb-Si-Fe ternary systems. Crucially, reactive hot pressing is capable of producing high-purity ZIP phase materials after the judicious, elemental system-specific optimization of the processing route. Synthesis of phase-pure materials – demonstrated in the Nb-Si-Ni ternary system by the synthesis of quasi phase-pure Nb 3 SiNi 2 and Ni 3 SiNb 2 ZIP phase-based materials – is a steppingstone to the prospective exploitation of the ZIP phases. Characterization of Nb 3 SiNi 2 and Ni 3 SiNb 2 involves crystal structure determination, spatially resolved chemical analysis, and determination of select thermal, electrical, magnetic, mechanical, and physical properties. Density functional theory is used to assess the stability of Nb 3 SiNi 2 & Ni 3 SiNb 2 and derivative binary compounds at different temperatures, also exploring the exfoliation of these two ZIP phases along specific surfaces to produce 2D derivatives.

Intermetallic compounds (IMCs)↗
DOE OSTI2024

Colossal Strain Tuning of Ferroelectric Transitions in KNbO 3 Thin Films

Strong coupling between polarization ( P ) and strain (ɛ) in ferroelectric complex oxides offers unique opportunities to dramatically tune their properties. Here colossal strain tuning of ferroelectricity in epitaxial KNbO 3 thin films grown by sub‐oxide molecular beam epitaxy is demonstrated. While bulk KNbO 3 exhibits three ferroelectric transitions and a Curie temperature ( T c ) of ≈676 K, phase‐field modeling predicts that a biaxial strain of as little as −0.6% pushes its T c > 975 K, its decomposition temperature in air, and for −1.4% strain, to T c > 1325 K, its melting point. Furthermore, a strain of −1.5% can stabilize a single phase throughout the entire temperature range of its stability. A combination of temperature‐dependent second harmonic generation measurements, synchrotron‐based X‐ray reciprocal space mapping, ferroelectric measurements, and transmission electron microscopy reveal a single tetragonal phase from 10 K to 975 K, an enhancement of ≈46% in the tetragonal phase remanent polarization ( P r ), and a ≈200% enhancement in its optical second harmonic generation coefficients over bulk values. These properties in a lead‐free system, but with properties comparable or superior to lead‐based systems, make it an attractive candidate for applications ranging from high‐temperature ferroelectric memory to cryogenic temperature quantum computing.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Ligand Substituent Effects on the Electronic Properties of Lindqvist‐Type Polyoxometalate Multi‐Level‐Switches in the Gas Phase, Solution and on Surfaces

Abstract Although the intrinsic electronic properties of polyoxometalates (POMs) can be greatly influenced by modifying them with organic substituents, their resistive switching behavior on surfaces dependent on the organic substituents remains largely unexplored. In this work, we assessed the importance of electron‐withdrawing and electron‐donating ligand substituents on the material properties of a series of hybrid Lindqvist‐type hexavanadates TBA 2 [V 6 O 13 ((OCH 2 ) 3 CCH 2 OH) 2 ] (TBA 2 V 6 ‐OH), TBA 2 [V 6 O 13 ((OCH 2 ) 3 CMe) 2 ] (TBA 2 V 6 ‐Me), TBA 2 [V 6 O 13 ((OCH 2 ) 3 CNHCOCH 2 Cl) 2 ] (TBA 2 V 6 ‐Cl), and TBA 2 [V 6 O 13 ((OCH 2 ) 3 CNHCOCH 2 ‐OOCC 10 H 15 ) 2 ] (TBA 2 V 6 ‐Ad) as potential resistive random‐access memory (ReRAM) components. Compared to their redox behavior in solution, changing the ligand substituents on surfaces results in no significant effect on the potential and, thus, no effect on the resistance steps in the current‐voltage profiles. However, while the current‐voltage characteristics do not change, the peripheral metal‐free substituents in the trisalkoxide framework of Lindqvist‐type hexavanadate molecules influence the adsorption and switching stability of these POMs on gold. This work highlights the noticeable differences between hexavanadate's redox properties in solution (which follow the trend observed in the gas phase) and hexavanadate's resistive switching properties on conducting surfaces. Importantly, their multi‐state switching behavior is not significantly altered by the different type of substituent at the periphery of the trisalkoxo ligands.

36 MATERIALS SCIENCE↗