Search NASASearch

SEARCH · Search NASA

Results for “Mass diffusivity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 217 records · Page 12

Tolerance of Mach 2.50 axisymmetric mixed-compression inlets to upstream flow variations

An investigation of the tolerances of two Mach 2.50 axisymmetric mixed-compression inlets to upstream flow variations was conducted. Tolerances of each inlet to angle of attack as a function of decreasing free-stream Mach number were obtained. A local region of overcompression was formed on the leeward side of the inlet at maximum angle of attack before unstart. This region of overcompression corresponded to local subsonic flow conditions ahead of the geometric throat. A uniform Mach number gradient of 0.10 at the cowl lip plane did not affect the inlet's pressure recovery, mass flow ratio, or diffuser exit total-pressure distortion.

Choby, D. A.

Mathematical modeling and computer simulation of isoelectric focusing with electrochemically defined ampholytes

A mathematical model of isoelectric focusing at the steady state has been developed for an M-component system of electrochemically defined ampholytes. The model is formulated from fundamental principles describing the components' chemical equilibria, mass transfer resulting from diffusion and electromigration, and electroneutrality. The model consists of ordinary differential equations coupled with a system of algebraic equations. The model is implemented on a digital computer using FORTRAN-based simulation software. Computer simulation data are presented for several two-component systems showing the effects of varying the isoelectric points and dissociation constants of the constituents.

Palusinski, O. A.

In situ observations of Io torus plasma

The physical properties of the Io plasma formation deduced from in situ observations are described. The torus plasma is characterized by spatially distinct regions with steep gradients in plasma parameters between them. The innermost region has a cool plasma which collapses toward the centrifugal equator and gives rise to a distinctive localized concentration of plasma well inside of Io's orbit. The next region has a warm plasma which includes the L-shell of Io and is the presumed injection region of the plasma. Other regions, known as the plasma ledge and ramp, are described. The changes in plasma characteristics are accounted for by centrifugally driven flux tube interchange diffusion to provide radial mass transport. The ramp is shown to result from impoundment of the plasma by the inner edge of the energetic particle population. It is also shown how the power required to excite the ultraviolet emissions of the torus and the Jovian aurora determines the rate at which new plasma is fed into the torus.

Sullivan, J. D.

Theoretical studies in isoelectric focusing

A mathematical model has been developed which describes the steady state in an isoelectric focusing (IEF) system with ampholytes or monovalent buffers. The model is based on the fundamental equations describing the component dissociation equilibria, mass transport due to diffusion and electromigration, electroneutrality, and the conservation of charge. The validity and usefulness of the model has been confirmed by using it to formulate buffer systems in actual laboratory experiments. The model has been recently extended to include the evolution of transient states not only in IEF but also in other modes of electrophoresis.

Mosher, R. A.

Investigation of temperature and concentration oscillations in the directional solidification of Pb-Sn-Te

Directional solidification of the pseudobinary compound semiconductor material Pb sub 1-x Sn sub x Te by the Bridgman crystal growth process will be studied. Natural convection in the molten sample will be visualized with a novel electrochemical cell technique that employs the solid electrolyte material yttria-stabilized zirconia. Mass transfer by both diffusion and convection will be measured by detecting the motion of oxygen tracer in the liquid. Additional applications for electrochemical cells in semiconductor crystal growth are suggested. Unsteady convection in the melt will also be detected by the appearance of temperature oscillations. The purpose of this study is to experimentally characterize the overstable conditions for a Pb sub 1-x Sn sub x Te melt in the vertical Bridgman crystal growth technique and use a linear analysis to predict the onset of convection for this system.

Anderson, T. J.

Thermochemical erosion

A quasi-steady multidimensional Stefan problem is treated by means of similarity, asymptotic methods, and numerical analysis. The continuous wearing away of a solid 'erodee' is effected by gradual consumption of a solid 'eroder'. In the process under study, the erodee melts and the (liquid) melt diffuses to the eroder, where an exothermic, indefinitely rapid, diffusion-controlled surface reaction occurs. The products of reaction convey some of the chemically-generated heat to the surface of the erodee, so that further melting may occur, and the process may proceed. The analysis seeks to estimate the quasi-steady rates of consumption of the erodee and eroder, for the (convenient) self-similar case of confocal parabolas defining the boundaries of the melt layer. The analysis is simplified by observing that the flow is of lubrication-theory type: creeping, primarily unidirectional motion owing to the thinness of the melt layer between the erodee and eroder, with diffusion of heat and mass predominantly perpendicular to the principal motion. The analysis is completed by consideration of the force balance on the eroder.

Butler, Gerald

Results from a compound semiconductor crystal growth experiment in a low gravity environment

A directional solidification experiment in the compound semiconductor lead tin telluride has been carried out in a low-gravity environment on board the Space Shuttle during a flight in October, 1985. Optical etching techniques and concentration profiles from wavelength dispersive electron microscopy indicate that there was a significant amount of convection during the solidifcation of the sample. A preliminary hypothesis of this result, that even at gravity levels on the order of 0.0001 g, the convective forces can be significant compared to mass transport due to diffusion, is being tested.

Crouch, Roger K.

A preliminary compressible second-order closure model for high speed flows

A preliminary version of a compressible second-order closure model that was developed in connection with the National Aero-Space Plane Project is presented. The model requires the solution of transport equations for the Favre-averaged Reynolds stress tensor and dissipation rate. Gradient transport hypotheses are used for the Reynolds heat flux, mass flux, and turbulent diffusion terms. Some brief remarks are made about the direction of future research to generalize the model.

Speziale, Charles G.

Energy and mass balance in the three-phase interstellar medium

Details of the energy and mass balances are considered in the context of a three-phase interstellar medium. The rates of mass exchange between the different phases are derived based on the pressure variations created by supernova remnant expansions. It is shown that the pressure-confined warm and cold gases have stable temperatures under a variety of interstellar conditions. The three-phase quasi-static configuration is found to be a natural outcome, and both warm and cold phases generally contribute about half of the total mass density to the diffuse interstellar gas. The model is also likely to be self-regulatory in the sense that variations of the input parameters do not strongly alter the general result, which is consistent with most current observations. The consequences of extreme conditions on this model are considered, and the possible implications for interstellar medium in other galaxies are briefly discussed.

Wang, Zhong

Effects of an Applied Magnetic Field on the Directional Solidification of Hg(1-x)Zn(x)Se Alloys

Directionally solidified Hg(0.9)Zn(0.1)Se alloys were studied as an alternative to HgCdTe for the detection of electromagnetic radiation because of predicted improvements in lattice stability. Several boules were grown using a modified Bridgman-Stockbarger method and in an applied magnetic field. Axial compositional profiles showed mass transfer was primarily diffusion controlled. Radial compositional variations were greatly reduced when solidification occurred in an applied magnetic field. Microstructural characteristics and dislocation etch pit densities were greatly improved over HgTe based alloys. The extreme importance of processing conditions on defect generation was illustrated by comparing ampoule configurations and thermal profiles.

Cobb, S. D.

Contactless Growth of ZnSe Single Crystals by Physical Vapor Transport

ZnSe crystals were grown by self-seeded physical vapor transport (PVT) technique in the horizontal configuration. The source materials were heat treated by H2 reduction to remove the oxide followed by baking under dynamic vacuum to adjust the source composition toward that of congruent sublimation. Contactless growth of ZnSe single crystals have been performed consistently using three different source materials. The crystals grew away from the wall during the later stage of the growth with large (110) facets tend to align parallel to the gravity direction. The Scanning Electron Micrography (SEM) micrographs and the Atomic Force Microscope (AFM) images showed that large (110) terraces and steps dominate the as-grown facets. The measured residual gas pressures in the processed ampoules agree well among various source materials and the major components were CO and H2. No preferred growth direction was found. The one-dimensional diffusion model on the mass flux of a multi-species PVT system was employed to analyze the conditions for contactless growth. The calculated thermal profile for supersaturation is very close to the thermal profile measured inside the empty furnace bore in the region of contactless growth. The effects of convective flows in the vapor phase inside the ampoule on the growth processes are discussed.

Su, Ching-Hua

Reduction of Acceleration to Effectively Microgravity Levels

Pressure gradients, i.e. pressure head, and buoyancy driven convection can be greatly decreased in experimental systems by acceleration of the laboratory reference frame at a rate consistent with the acceleration due to gravity. This may be done in a number of ways, the best known of which is the use of orbiting spacecraft. Other techniques include the use of aircraft following an appropriate parabolic trajectory or drop towers. The result is an experimental condition in which fluids experience virtually no outside forces relative to the laboratory reference frame. Such conditions are appropriate for the study of processes with diffusion dominated heat and/or mass Under, the study of phase transitions in the absence of pressure gradients, the study of solutal or thermal capillary convection, or containerless processes. Ways of achieving these conditions and complexities that arise in performing experiments in this environment are discussed.

Downey, James Patton

Computational Analysis of the Large Scale Low-Boom Supersonic Inlet

This presentation describes two computational fluid dynamic (CFD) analyses done in support of a supersonic inlet test performed at NASA Glenn Research Center in the fall of 2010. The large-scale-low-boom supersonic inlet was designed for a small supersonic aircraft that would cruise at a Mach number of 1.6. It uses an axisymmetric, external compression spike to reduce the Mach number to 0.65 at the fan face. The inlet was tested in the 8x6 supersonic wind tunnel at NASA GRC using conventional pressure probes, pressure sensitive paint, and high-speed schlieren. Two CFD analyses of the inlet were performed before the test, and compared to the experimental data afterwards. Both analyses used the WIND-US code. First, an axisymmetric analysis of the inlet, diffuser, cold pipe, and mass flow plug was performed to predict the performance of the entire system in the wind tunnel. Then a 3-D analysis of the inlet with all its interior struts was performed to predict details of the flow field and effects of angle of attack. Test results showed that the inlet had excellent performance, with a peak total pressure recovery of 96 percent, and a buzz point far outside the engine operating range. The computations agreed very well with the data, with predicted recoveries within 0.3 - 0.5 points of the measurements.

Chima, ROdrick V.

Axisymmetric Calculations of a Low-Boom Inlet in a Supersonic Wind Tunnel

This paper describes axisymmetric CFD predictions made of a supersonic low-boom inlet with a facility diffuser, cold pipe, and mass flow plug within wind tunnel walls, and compares the CFD calculations with the experimental data. The inlet was designed for use on a small supersonic aircraft that would cruise at Mach 1.6, with a Mach number over the wing of 1.7. The inlet was tested in the 8-ft by 6-ft Supersonic Wind Tunnel at NASA Glenn Research Center in the fall of 2010 to demonstrate the performance and stability of a practical flight design that included a novel bypass duct. The inlet design is discussed here briefly. Prior to the test, CFD calculations were made to predict the performance of the inlet and its associated wind tunnel hardware, and to estimate flow areas needed to throttle the inlet. The calculations were done with the Wind-US CFD code and are described in detail. After the test, comparisons were made between computed and measured shock patterns, total pressure recoveries, and centerline pressures. The results showed that the dual-stream inlet had excellent performance, with capture ratios near one, a peak core total pressure recovery of 96 percent, and a large stable operating range. Predicted core recovery agreed well with the experiment but predicted bypass recovery and maximum capture ratio were high. Calculations of offdesign performance of the inlet along a flight profile agreed well with measurements and previous calculations.

Chima, Rodrick V.

Flowfield Analysis of a Small Entry Probe (SPRITE) Tested in an Arc Jet

A novel concept of small size (diameter less than 15 inches) entry probes named SPRITE (Small Probe Re-entry Investigation for TPS Engineering) has been developed at NASA Ames Research Center (ARC). These flight probes have on-board data acquisition systems that have also been developed in parallel at NASA ARC by Greg Swanson1. Flight probes of this size facilitate testing over a wide range of conditions in arc jets available at NASA ARC, thereby fulfilling a 'test what you fly' paradigm. As indicated by the acronym, these probes, with suitably tailored trajectories, are primarily meant to be robotic flight test beds for TPS materials, although the design is flexible enough to accommodate additional objectives of flight-testing other vehicle subsystems. A first step towards establishing the feasibility of the SPRITE concept is to arc-jet test fully instrumented models at flight scale. In a follow-on to the Large-Scale Article Tests (LSAT2) performed in the 60 MW Interaction Heating Facility (IHF) in late 2008/early 2009, a full-scale model of Deep Space-2 (DS23) made of red oak was tested in the 20 MW Aerodynamic Heating Facility (AHF). There were no issues with mass capture by the diffuser for blunt bodies of roughly 15 inches diameter tested in the 18-inch nozzle of the AHF. Building on this initial success, two identical test articles - SPRITE-T1-1 and SPRITE-T1-2 (T1 indicating the choice of back shell geometry) - were fabricated, and one of them, SPRITE-T1-1, was tested in the AHF recently. Both these test articles, 14 inches in diameter, have a 45deg sphere-cone (like DS2) made of PICA bonded on to a 1/8th inch thick aluminum shell using RTV. The aft portion of the test article is a conical frustum (15deg cone angle) with LI-2200 bonded on to the aluminum shell. Each model is fully instrumented with: (a) thermocouples imbedded in plugs in the heat shield, (b) thermocouples bonded to the aluminum substructure; the thermocouples are distributed over the entire shell, and (c) a few strain gages. Data from some of the thermocouples and gages are acquired by the on-board data acquisition system (DAS), while data from the others are routed to the facility-provided DAS, thereby enabling a cross check on the in situ measurement capability. as inputs to v2.6.1 of the in-house materials thermal response code, FIAT

atmospheric entry

Vapor Growth of ZnSe-based Compound Semiconductors in Low Gravity environment on International Space Station

Six low-gravity experiments of crystal growth of ZnSe-based compound semiconductors by physical vapor transport (PVT) are scheduled to be processed inside Low Gradient Furnace (LGF) on Materials Science Research Rack (MSRR) in Material Science Laboratory (MSL) on International Space Station (ISS) starting from February 27th, 2023. The flight samples consist of three unseeded growths of ZnSe, Cr-doped ZnSe and ZnSeTe as well as growth of ZnSe on top of three single crystal ZnSe seeds with orientation of (100), (110) and (111). The main scientific objective of the flight experiments is to establish the effects of gravity-driven fluid flows on Earth to (i) the non-uniform incorporation of impurities and defects and (ii) the deviation from stoichiometry observed in the grown crystals caused by growth interface fluctuations and evolution as the results of buoyancy-driven convection and irregular fluid-flows. The investigation will also evaluate the effects of gravity on the PVT process by examining (i) the growth kinetics on various seed orientations, (ii) the dopant segregation and distribution in the Cr doped ZnSe, and (iii) the compositional segregation and distribution in the ternary ZnSeTe crystal grown by PVT. Additionally, from X-ray diffraction/topography and by measuring the density and distribution of various crystalline defects it will assess the self-induced strain effects developed during processing at elevated temperatures caused by the weight of the crystals. During the ground-based preparations, the following tasks have been accomplished: • Establish the thermodynamic properties of the ZnSe binary and related ternary systems by measuring the partial pressures of the vapor phase coexisting with the condensed phases and perform phase diagram calculations for comparison. • Evaluate the effects of gravity-driven convection in the growth process by performing experiments under various vapor transport orientations relative to gravity vector, i.e., horizontal, vertically stabilized and destabilized configurations. • Establish a quantitative correlation between growth parameters and the characteristics and properties of the grown crystals by characterizing the crystals using a variety of techniques. • Evaluate the fundamentals of the current theories on vapor transport and crystal growth kinetics by performing in-situ and real-time monitoring techniques during growth. • Develop a one-dimensional diffusion limited theory of mass transport and two- and three-dimensional numerical simulations of both mass transport and heat transfer and thus establish the microgravity requirements for the flight experiments and to predict the characteristics of the grown crystals such as the solid-vapor interface shapes… etc. and establish a fundamental understanding of the crystal growth process from the comparison with experimental results.

ZnSe

Modelling the Greenland Ice Sheet's Committed Contribution to Sea Level During the 21st Century

Mass loss from the Greenland Ice Sheet can be partitioned between surface mass balance and discharge due to ice dynamics through its marine-terminating outlet glaciers. A perturbation to a glacier terminus (e.g., a calving event) results in both an instantaneous response in velocity and mass loss and a diffusive response due to the evolution of ice thickness over time. This diffusive response means the total impact of a retreat event can take decades to be fully realized. Here we model the committed response of the Greenland Ice Sheet by applying perturbations to the marine-terminating glacier termini that represent recent observed changes, and simulating the response over the 21st century, while holding the climate forcing constant. The sensitivity of the ice sheet response to model parameter uncertainty is explored within an ensemble framework, and Gravity Recovery and Climate Experiment data is used to constrain the results using a Bayesian calibration approach. We find that the Greenland Ice Sheet's committed contribution to 21st century sea level rise is at least 33.5 [17.5 52.4] mm (25th and 75th percentiles in brackets), with at least 6 mm being attributable directly to terminus retreat that occurred between 2007 and 2015. The spread in our projections is driven by uncertainty in the basal friction coefficient. Our results complement the ISMIP6 Greenland projections, which report the ice sheet response to future forcing, excluding the background response. In this way, we can obtain estimates of Greenland's total contribution to sea level rise in 2100.

Isabel J. Nias

MOSCATO Development and Integration in Fiscal Year 2025: Implementation of Multiphase, Multiphysics Modeling Capabilities for Molten Salt Systems

MOSCATO (Molten Salt Chemistry and Transport) is a multiphysics code that provides high-fidelity, coupled simulations of fluid flow, heat transfer, mass transfer, chemistry, electrochemical phenomena, and alloy corrosion for molten salt systems. In FY25, significant developments were made to the code package, enhancing its capabilities for modeling all relevant phenomena within operating moltens salt reactors (MSRs). The developments and activities in FY25 included: 1. Implementation of Level-Set methods to enable modeling of single-bubble behavior in molten salts. In FY25, the Level-Set two-phase flow modeling implementation was improved to simulate single bubble behavior with molten salt media. The large density and viscosity ratios between typical gases and molten salt liquids present challenges for these types of numerical solvers. With enhancements to the pressure projection method, MOSCATO’s Level-Set solver was able to be successfully validated to experiments related to helium bubble rise in stagnant molten salt. The simulated bubble rising velocity showed reasonable good agreement with experimental measurements. The bubble shape and dynamics were also visually compared with experimental snapshots, demonstrating a good qualitative match. 2. Generation of mass transfer correlations for multiphase flow systems. To enable calculations of the tritium transport across the interface between gas bubbles and salt, we modeled high- Schmidt-number mass transfer around a sphere across a broad range of Reynolds numbers. The mesh near the sphere surface was highly refined to resolve steep concentration gradients caused by the low diffusion coefficient. Literature-based mass transfer correlations were compared with the numerical results, and modifications were proposed to improve agreement, particularly at higher Schmidt numbers. These mass transfer correlations were subsequently provided to other national laboratories to help enable high quality mass transfer simulations using lower-order solvers under development within the NEAMS program. 3. Preliminary implementation of a bubbly flow solver. To model bubbly flow in molten salt, we implemented a bubbly flow solver for void fractions less than 5%. To do so, an algebraic relative velocity model that assumes small bubbles with rapid momentum equilibration was added to MOSCATO to compute bubble velocities. Preliminary comparisons with experimental data showed reasonable agreement, and further improvements are underway. 4. Generation of mass transfer correlations for MSRE subchannel The Molten-Salt Reactor Experiment (MSRE) was a landmark historical project that demonstrated the feasibility of molten-salt reactor technology. The MSRE campaign also generated a significant body of experimental data and reports that continue to support molten-salt–related research. In this report, the MSRE core subchannel was used as the reference geometry for a mass transfer study performed with MOSCATO. The geometry and computational mesh were adapted from a previous study, providing adequate resolution for the relatively low Reynolds number in this case. Additional mesh refinement was applied to reach higher Schmidt numbers, enabling the derivation of a reliable mass-transfer correlation for the present scenario. 5. Simulations of oxygen ingressions into molten salt. In the previous fiscal year, we initiated a study to simulate oxygen ingression in stagnant salt. As oxygen enters the salt through its surface, it reacts with Ce 3+ to form solid CeO 2 and other reaction products. To more fully capture the complex diffusion-convection-reaction mechanisms, capabilities for modeling natural convection in the salt vessel were added. These were needed as the flow of the ingressed gas induced flow in the salt caused by surface shear and non-isothermal effects. With these updated physics in place, we were able to successfully reproduce the experimental results for the rate of change of CeCl 3 concentrations versus time. 6. Flow corrosion model validation. In FY24, MOSCATO’s corrosion model was validated against static corrosion experiments. In FY25, this work was extended to a flow corrosion experiment, where FLiNaK salt was driven by natural convection, with initial salt impurities to initiate corrosion. Despite uncertainties in parameters such as elemental diffusion coefficients in the alloy and unknown H + concentrations, the simulations achieved good agreement with experimental results, especially in predicting sample mass losses.

22 GENERAL STUDIES OF NUCLEAR REACTORS