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Results for “NITRIC OXIDE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Investigation of hydrogen-air ignition sensitized by nitric oxide and by nitrogen dioxide

The sensitization of stoichiometric hydrogen-air ignition by NO, NO2 and a mixture of NO and NO2 was investigated behind reflected shock waves in a shock tube. Induction times were measured in pressure range 0.27 to 2.0 atm, temperature range 800 to 1500 K, and for NO or NO2 mole percent between 0.0 and 4.5. Addition of both NO and NO2 reduced the measured induction times. The experimental data are interpreted in terms of H2-O2-NO(x) oxidation reaction mechanisms. The influence of NO(x) upon a supersonic combustion ramjet combustor test, conducted in an arc-heated facility, is assessed.

Slack, M.↗
NASA NTRS1977

Triple point determinations of monomethylhydrazine and nitrogen tetroxide, 2.2 percent by weight nitric oxide

A series of tests was performed to ascertain the triple points of monomethylhydrazine and nitrogen tetroxide. A laboratory method indicated a triple point for monomethylhydrazine, but tests in a large vacuum chamber indicated that a triple point does not occur in spacelike conditions because the mono-methylhydrazine tends to supercool. Instead, an effective freezing point (with agitation) was obtained. New experimental values for liquid monomethylhydrazine vapor pressure were determined for temperatures from 275.2 to 207.6 K. The values were used to derive vapor pressure equations. Tentative values were obtained for the effective freezing point of nitrogen tetroxide spacelike conditions.

Smith, Irwin D.↗
NASA NTRS1978

Effect of nitric oxide on photochemical ozone formation in mixtures of air with molecular chlorine and with trichlorofluoromethane

Ozone formation in a reaction chamber at room temperature and atmospheric pressure were studied for the photolysis of mixtures of NO with either Cl2 or CFCl3 in air. Both Cl2 + NO and CFCl3 + NO in air strongly inhibited O3 formation during the entire 3 to 4 hour reaction. A chemical mechanism that explains the results was presented. An important part of this mechanism was the formation and destruction of chlorine nitrate. Computations were performed with this same mechanism for CFCl3-NO-air mixtures at stratospheric temperatures, pressures, and concentrations. Results showed large reductions in steady-state O3 concentrations in these mixtures as compared with pure air.

Bittker, D. A.↗
NASA NTRS1978

A search for nitric oxide gamma band emission in an aurora

A strong emission feature at 2150 A has been observed by a rocket-borne spectrophotometer in an IBC II(+) aurora. This feature, commonly identified with the NO gamma (1,0) band, is comparable in intensity to the nearby N2 Vegard-Kaplan bands. Comparison of the observed spectra with a theoretically produced synthetic spectrum allows all but this feature to be assigned to N2 transitions. No bands of the v prime = 0 or 2 progressions or any other bands from v prime = 1 appear, casting serious doubt on the identification of this feature as the NO gamma (1,0) band.

Beiting, E. J., III↗
NASA NTRS1981

Fuel/air nonuniformity - Effect on nitric oxide emissions

An analytical and experimental study was performed to determine the effect of inlet fuel/air profile nonuniformity on NO(x) emissions. The theoretical NO(x) levels were verified in a flame-tube rig at inlet air temperatures of 600, 700, and 800 K, 0.3 MPa rig pressure, 25 m/sec reference velocity, overall equivalence ratio of 0.6 and residence time near 0.002 sec. The theory predicts an increase in NO(x) emissions for increased fuel/air nonuniformity for average equivalence ratios less than 0.7, while for average equivalence ratios near stoichiometric, increasing the nonuniformity will decrease NO(x) emissions. The results can be used to predict the degree of uniformity of fuel/air profiles necessary to achieve NO(x) emissions goals for actual engines that use lean premixed, prevaporized combustion systems.

Lyons, V. J.↗
NASA NTRS1981

Two-photon excitation of nitric oxide fluorescence as a temperature indicator in unsteady gasdynamic processes

A laser-induced fluorescence technique based on the pulsed two-photon excitation of NO is presented which is especially suited for the measurement of fluctuating temperatures in cold turbulent flows. The technique uses the fluorescence from the UV gamma bands of NO produced by two-photon excitation of NO (A 2 Sigma +, nu-prime = 0 - X 2 Pi, nu-double prime = 0) to obtain a rotational temperature. An analysis is presented of relevant aspects of the two-photon absorption process including microphysical processes, spectral intensities as a function of transition and laser spectral widths, line-shape integrals, the nonequilibrium response of the medium to a laser pulse, fluorescence energies, signal to noise ratio, and focusing effects. An analysis of absolute two-photon absorptivity measured in a nonflowing cell is then presented and used to predict signal to noise ratios greater than 50 for supersonic flows at temperatures below 300 K.

Mckenzie, R. L.↗
NASA NTRS1982

The two-photon absorptivity of rotational transitions in the A2 Sigma hyperon + (v prime = O) - X-2 pion (v prime prime = O) gamma band of nitric oxide

A predominantly single-mode pulsed dye laser system giving a well characterized spatial and temporal output suitable for absolute two-photon absorptivity measurements was used to study the NO gamma(0,0) S11 + R21 (J double prime = 7-1/2) transition. Using a calibrated induced-fluorescence technique, an absorptivity parameter of 2.8 + or - 1.4 x 10 to the minus 51st power cm to the 6th power was obtained. Relative strengths of other rotational transitions in the gamma(0,0) band were also measured and shown to compare well with predicted values in all cases except the O12 (J double prime = 10-1/2) transition.

Gross, K. P.↗
NASA NTRS1982

The seasonal effect of nitric oxide cooling on the thermospheric U.V. heat budget

The effects of (1) the radiative cooling of vibrationally-excited NO at 5.3 microns and (2) radiation entrapment at 63 microns on the UV heating efficiency 'epsilon' are examined. It is noted that the previously used heating efficiency definition contradicts its logical application, and that the two processes mentioned should be included as cooling phenomena in the energy equations. Comparisons are made with previous work by including O and NO radiative cooling in the calculation of epsilon, which is found to vary from 45 to 60%, depending on how the two radiative cooling mechanisms are included in the calculation. It is also found that the shape of the heating efficiency altitude profile varies with season, while the peak value is nearly invariant.

Richards, P. G.↗
NASA NTRS1982

The 2145 A dayglow and the high altitude nitric oxide density

It is argued that dissociative photoionization of N2 by solar ultraviolet radiation at wavelengths shorter than 329 A is a large source of atmospheric N(+)(5S 0 2) ions which radiate at 2143.6 A and 2139.7 A. Calculations of the daytime production of N(+)(5S 0 2) ions are carried out. The band pass of the instrument used to measure the intensity of the NO gamma band at 2150 A contains the N(+) emission wavelengths and we suggest that the NO densities at high altitudes may be affected.

Victor, G. A.↗
NASA NTRS1984

Variation of Derived Mesospheric Nitric Oxide in Relation to Wind and Temperature in Winter

As a good approximation, changes of the NO-density are solely responsible for changes of the non-auroral D-region. Under the assumption that other ion production processes are either known or negligible, one can derive (NO) from electron densities using a suitable effective electron loss rate. In the Winter Anomaly Campaign 1975/76 nineteen rocket payloads carried electron density measurements on fifteen days. On two of these days (NO) was measured in-situ by photometers. For these days one can establish the production not due to Lyman-alpha and NO. This rest production can then be applied to all (NO) derivations based on electron density measurements. In addition, in this campaign winds and temperatures were measured from the ground to approximately the base of the thermosphere. The derived field of NO densities between December 1975 and February 1976 from 70 to 100 km is compared to corresponding fields of winds (zonal and meridional), temperatures, pressure and Richardson numbers.

Friedrich, M.↗
NASA NTRS1984

Diurnal variations of atmospheric nitric oxide - Ground-based infrared spectroscopic measurements and their interpretation with time-dependent photochemical model calculations

Total vertical column amounts of NO have been derived from infrared solar absorption spectra recorded near sunrise and sunset with the 0.01 per cm resolution Fourier transform interferometer at the national Solar Observatory on Kitt peak (elevation 2095 m, latitude 31.9 degrees N) on February 23, 1981. The results show an increase in NO concentration in the morning, late afternoon values about 40 percent higher than in the morning, and a decrease in NO concentration prior to sunset. The measured diurnal changes in the total vertical column amount are compared with values obtained from time-dependent photochemical calculations.

Rinsland, C. P.↗
NASA NTRS1985

Fluorescence branching ratios in nitric oxide - Emission from the A2 Sigma(+) (v prime = 1)

The most complete set of branching ratios from the v-prime = 1 level of the A-state in NO measured to data is reported. The assumption that virtually all of the emitted radiation has been sampled is used to extract Franck-Condon factors from the v-prime = 1 manifold. A comparison with previously published results indicates that, except for the (1,0) band, there is reasonably good agreement.

Mcgee, T. J.↗
NASA NTRS1985

Radiative relaxation of molecular vibration of the nitric oxide molecule as a possible source of the infrared Shuttle glow

A model calculation to predict infrared Shuttle flow due to the radiative relaxation of vibration of the NO molecule is presented. Space Shuttles hit atmospheric NO molecules at a very high speed and excite vibrational and rotational motions up to the temperature of 54,000 K. With the electric dipole radiation of delta v = 1, 2, 3, and particularly 4 (v is the vibrational quantum number), the excited NO molecules emit infrared radiation before they collide with other molecules. The total radiation power is estimated to be 170 A micro-W, where A is the cross-section area of the Shuttle in sq m if no adsorption of the NO molecule takes place on the Shuttle surface. The intensity of each infrared line is calculated as a function of time, including all vibrational states up to v = 35.

Mizushima, M.↗
NASA NTRS1985

Operational overview of Wallops Island instrument intercomparison - Carbon monoxide, nitric oxide, and hydroxyl instrumentation

NASA has initiated the Global Tropospheric Experiment (GTE) for the study of the chemistry of the global troposphere. One phase of GTE, Chemical Instrumentation Test and Evaluation (CITE), is concerned with the development and validation of measurement techniques for trace species which play important roles in the tropospheric chemical cycles. In connection with CITE 1 an intercomparison of instruments is conducted for the measurement of CO, NO, and OH. These species have been identified as critical for an understanding of homogeneous gas-phase chemistry in the troposphere. The present paper provides an operational overview of the first of three instrument intercomparison field missions conducted as part of GTE/CITE 1. The missions include one ground-based and two airborne missions, and were designed to characterize current capability of measuring ambient levels of CO, NO, and OH.

Gregory, G. L.↗