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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Dynamics of fluorinated imide-based ionic liquids using nuclear magnetic resonance techniques

There is increasing interest in studying molecular motions in ionic liquids to gain better insights into their transport properties and to expand their applications. Here, in this study, we have employed the fast field cycling relaxometry and pulsed field gradient nuclear magnetic resonance techniques to investigate the rotational and translational dynamics of fluorinated imide-based ionic liquids (ILs) at different temperatures. We have studied a total of six ILs composed of the 1-butyl-3-methylimidazolium cation ([BMIM] + ) combined with chemically modified analogs of the bis((trifluoromethyl)sulfonyl)imide anion ([NTf 2 ] − or [TFSI] − ). The primary objective of this paper is to broaden the understanding of how the anion's conformational flexibility, fluorination, and mass affect the molecular dynamics of cations and anions. Our results indicate that flexibility has the most significant impact on the rotational and translational motions of ions. Meanwhile, the effect of fluorination and mass is only relevant when conformational flexibility does not change significantly between the ILs being compared.

25 ENERGY STORAGE↗
DOE OSTI2020

Mixtures of octanol and an ionic liquid: Structure and transport

Ionic liquids (ILs) with long alkyl substituents are amphiphilic, which leads to a bicontinuous liquid structure. The strongly interacting anionic and cationic head groups form a long range charge network, with the hydrocarbon tails forming a nonpolar domain. Such nonpolar domains have been shown to dissolve a variety of neutral organic solvents. In mixtures of ILs with solvents the neutral organic molecules residing in the nonpolar domains experience different environments and friction from the charged cations and anions. Thus, the neutral molecules diffuse much faster than predicted by hydrodynamic scaling using the average viscosity of the mixture. Here, we report studies on the structure and transport properties of mixtures of 1-octanol with the IL trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)imide (P 6,6,6,14 + /NTf 2 – ). The majority of the atom fraction in the P 6,6,6,14 + cation comprises four hydrocarbon substituents. The unique amphiphilic nature of ILs with the P 6,6,6,14 + cation makes 1-octanol fully miscible with the IL at ambient temperatures. X-ray scattering experiments show that the IL structure persists in the mixtures for 1-octanol mole fractions as large as x oct = 0.90. The self-diffusion coefficients of the three molecular species in the mixtures were measured by NMR experiments. The self-diffusion of the P 6,6,6,14 + cation is well described by the Stokes–Einstein equation, while the diffusivity of the NTf 2 – anion is slightly lower than the hydrodynamic prediction. The measured diffusivities of octanol in these mixtures are 1.3–4 times higher than the hydrodynamic predictions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1977

Instrumentation and data acquisition systems

A comprehensive and integrated measurement system was identified and a design and development effort initiated to meet the criteria imposed by the National Transonic Facility operating environment. Specific measurement areas receiving concentrated attention include: data acquisition, force measurement, pressure instrumentation, flow visualization techniques, model attitude and model deformation measurement, and temperature measurement. The NTF instrument complex will be centered around four 32-bit, 1-microsecond-cycle-time central processing units connected in a multipoint-distributed network configuration. The principal activities to be supported by these computers are: (1) data base management and processing; (2) research measurement data acquisition and display; (3) tunnel and model control; and (4) process monitoring and communication control. The distributed network approach was chosen to modularize the functional software into definable and implementable parts by the various groups involved in the design and to permit use of similar hardware configurations to improve reliability and maintainability.

Guarino, J. F.↗
NASA NTRS1977

Introductory Remarks

Advanced transonic configurations, such as the supercritical wing, are inherently more sensitive to Reynolds number than earlier configurations because the pressure recovery gradients imposed on the boundary layer are generally steeper. The results of two-dimensional supercritical airfoil investigations and theoretical calculations show this effect. A technique for approximately simulating full-scale Reynolds number characteristics at present wind-tunnel Reynolds numbers for near-cruise conditions is described. The transition strip, which in the past has been located near the leading edge of the wing, is rearward so that the relative displacement thickness of the boundary layer at the trailing edge of the wing is the same as might be expected on a full-scale configuration with the transition near the leading edge. Two-dimensional wind-tunnel results indicate that the technique provides a very good simulation of airfoil characteristics at full-scale Reynolds number. The need for sorting the effects of Reynolds number and aeroelasticity, which can be done in the NTF, is also addressed.

Whitcomb, R.↗
NASA NTRS1977

Report of the panel on dynamics and aeroelasticity

Model scaling for flutter analysis is reviewed. Characteristics of the Langley Transonic Dynamics Tunnel (TDT) are described and several features are recommended for inclusion in the National Transonic Facility. Problem areas suggested for the NTF include: Reynolds number effects on control surface unsteady aerodynamics; effects of Reynolds number on buffet onset and loads; transonic unsteady aerodynamics; and Reynolds number effects on flutter characteristics of wing planforms and airfoils.

Houbolt, J.↗
NASA NTRS1975

F-8 oblique wing structural feasibility study

The feasibility of fitting a rotating oblique wing on an F-8 aircraft to produce a full scale manned prototype capable of operating in the transonic and supersonic speed range was investigated. The strength, aeroelasticity, and fatigue life of such a prototype are analyzed. Concepts are developed for a new wing, a pivot, a skewing mechanism, control systems that operate through the pivot, and a wing support assembly that attaches in the F-8 wing cavity. The modification of the two-place NTF-8A aircraft to the oblique wing configuration is discussed.

Koltko, E.↗
NASA NTRS1979

Cryogenic wind tunnel force instrumentation

The paper outlines the work that has been accomplished at Langley Research Center (NASA) while investigating the effects of cryogenic environment on one-place multicomponent strain-gage balances. Particular emphasis is placed on cryogenic balances for use in the National Transonic Facility (NTF).

Ferris, J.↗
NASA NTRS1981

A summary of tests on Invar welded with 308L and 8N12 welding rods

The cost and difficulty in obtaining Invarod, the recommended welding rod to weld Invar, nessitated the investigation of substituting more readily available rods that would meet the cryogenic design criteria for the National Transonic Facility (NTF). Two weld rods, 308L and 8N12, were chosen as promising candidates. Four welded specimen plates were made; two plates for each type of weld rod. One plate from each of the 308L and 8N12 weldings was thermally cycled 50 times between 366 K and 89 K while the two remaining plates were not thermally cycled. Specimens were machined from all four plates for three types of tests: tensile, charpy impact, and guided-bend. The methods in making the specimen plates, conduction of the tests, test results, and conclusions leading to the selection of a weld rod are presented.

Cox, J. W.↗
NASA NTRS1981

High Reynolds number research - 1980

The fundamental aerodynamic questions for which high Reynolds number experimental capability is required were examined. Potential experiments which maximize the research returns from the use of the National Transonic Facility (NTF) were outlined. Calibration plans were reviewed and the following topics were discussed: fluid dynamics; high lit; configuration aerodynamics; aeroelasticity and unsteady aerodynamics; wind tunnel/flight correlation; space vehicles; and theoretical aerodynamics

Mckinney, L. W.↗
NASA NTRS1981

The National Transonic Facility: Review and status report

The status of the National Transonic Facility (NTF) Project and some of the pertinent performance characteristics and features of the new wind tunnel are reviewed. The liquid nitrogen supply, current views of user cost, and the activation schedule are discussed.

Howell, R. R.↗
NASA NTRS1981

Pathfinder model program for the National Transonic Facility

An overview of the Pathfinder Models Program is presented. The Pathfinder program is a major research and development activity in support of the National Transonic Facility Activation Plan. The program scope, models design approach, and Pathfinder model configurations are presented along with a discussion of major supportive program activities. The anticipated design criteria for NTF models are presented.

Young, C. P., Jr.↗
NASA NTRS1981

Aircraft design using the National Transonic Facility

The utility of the cryogenic high Reynolds number test facility as a production tunnel is evaluated. Aerodynamic performance evaluation, numerical wing design verification, and high Reynolds number theoretical extensions are considered. A priority ranking of NTF uses from an airframe development viewpoint is presented.

Bonner, E.↗
NASA NTRS1981

Report of the panel on fluid dynamics

Areas of investigation in fluid dynamics, recommended experiments, and use of the facility for theory evaluation are discussed. Tunnel flow quality and calibration of the NTF are considered. Recent technological advances affecting tunnel design are surveyed.

Bobbitt, P. J.↗
NASA NTRS1981

Configuration aerodynamics

Static aerodynamic research related to aircraft configurations in their cruise or combat modes is discussed. Subsonic transport aircraft, transonic tactical aircraft, and slender wing aircraft are considered. The status and plans of Langley's NTF configuration research program are reviewed. Recommendations for near term configuration research are made.

Polhamus, E. C.↗
NASA NTRS1982

A review of Reynolds number studies conducted in the Langley 0.3-m Transonic Cryogenic Tunnel

Initial proof-of-concept results obtained in a pilot transonic tunnel, led to a U.S. decision to apply the cryogenic tunnel concept to the National Transonic Facility (NTF). The pilot tunnel was reclassified as a 'permanent' facility and renamed the 0.3-m Transonic Cryogenic Tunnel (TCT). The 0.3-m TCT, with its ability to operate at temperatures ranging from about 78 K to 340 K, combined with a 6 atmospheres pressure capability, provides extremely high test Reynolds numbers at relatively low model loading. In addition, the ability to vary pressure and temperature independently of Mach number provides a unique capability to conduct studies at a constant dynamic pressure or at a constant Reynolds number with just one model. Attention is given to the simulation of flight conditions, the cryogenic-pressure tunnel concept, the characteristics of the 0.3-m TCT, Reynolds number studies in the three-dimensional test section including a Space Shuttle study, and Reynolds number studies in the two-dimensional test section.

Ray, E. J.↗
NASA NTRS1981

Force instrumentation for cryogenic wind tunnels using one-piece strain-gage balances

Materials and techniques for a transducer capable of obtaining accurate force measurements at cryogenic temperatures (down to 77 K) and high pressures (up to 9 atm) have been determined. Areas of high stress concentration are minimized by balance design, and model and sting attachment methods able to withstand cryogenic temperatures are used. Maraging 200 is the material used for the balances, due to its high impact strength and simple heat treatment procedure. Test results verify that the balances produce reliable, repeatable, and predictable data from 300 K to 110 K under steady state conditions. Techniques have been developed to reduce the temperature-induced bridge output, such as the use of bridges with two gages mounted transverse to the principal stress direction. Under these conditions, the results given by the balances should be equally good during transient temperatures on five of the six components. The work will be used at the National Transonic Facility (NTF) at NASA Langley.

Ferris, A. T.↗