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Optimal strategies for optical quantum memories using long-lived noble-gas spins

Nuclear spins of noble gases exhibit exceptionally long coherence times and can potentially serve as a long-lived storage medium for quantum information. We analyze and compare the performance of two mechanisms for mapping the quantum state of light onto the collective spin state of noble gases. The first mechanism utilizes collisional exchange with the electronic spin state of metastable noble-gas atoms, while the second relies on spin-exchange collisions with ground-state alkali-metal atoms. We describe the operation of an optical quantum memory relying on these two mechanisms using a compact model and study strategies that optimize the memory storage efficiency. Through numerical simulations, we identify optimal sequences for storing optical signals with different signal bandwidths and electronic spin relaxation rates. This work highlights the qualitative difference between the two approaches for using noble gases as long-lived quantum memories at noncryogenic conditions and outlines the regimes in which they are expected to be efficient.

atomic ensemble↗

Short-lived noble gas effluent trends from a research reactor

An understanding of anthropogenic sources of radioactive noble gases in the atmosphere is needed to enhance the discrimination ability of the International Monitoring System's sensors. These sources include commercial and research nuclear reactors and medical isotope production facilities. While abiding by local environmental ordinances these facilities all emit noble gas radioisotopes through normal operation. Here, this research presents measurements and analysis of noble gas isotopes ( 41 Ar, 135 Xe, 135m Xe, 137 Xe, 138 Xe, 87 Kr, 88 Kr, and 89 Kr) made directly at the stack of the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory. The Xe and Kr noble gases are concurrently observed with 41 Ar, a neutron activation product, when the reactor is operational. The magnitude of the Xe and Kr noble gases released is not constant over the HFIR cycle, but they temporally match the 41 Ar trend. An isotope activity ratio analysis of these shorter lived isotopes combined with the observation of the cycle's temporal trend helps understand the noble gas production mechanism at the HFIR. Isotopes with short half-lives are not useful for long-range environmental monitoring. However, these measurements could potentially be combined with atmospheric modeling to predict the background source term of the longer-lived Xe ratios at a monitoring station.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

On the presolar origin of the 'normal planetary' noble gas component in meteorites

Several components of planetary noble gases, including CCFXe (Xe-X), s-process Kr and Xe, and Ne-E, are now thought to have had a presolar origin. It is proposed that the 'normal planetary' noble gas component, which contains most of the planetary Ar, Kr, and Xe, is also presolar. This component was trapped in carbonaceous mantles as the mantles formed on grain surfaces in the molecular cloud. The presolar dust grains and their carbonaceous mantles were then incorporated into primitive meteorites. This model naturally explains: (1) the affinity of 'normal planetary' noble gases for carbonaceous material in primitive chondrites; (2) the near absence of He and Ne in the 'normal planetary' component; (3) the elemental fractionation patterns of the 'exotic' and 'normal planetary' components; (4) the similarity of the isotopic compositions of 'normal planetary' and trapped solar Ar, Kr, and Xe; (5) the high noble gas content of the 'normal planetary' gas carrier; (6) several aspects of the chemistry of the 'normal planetary' gas carrier; (7) the correlation of planetary noble gases with the fine-grained material in primitive chondrites; and (8) the widespread occurrence of the planetary fractionation pattern throughout the solar system.

Huss, Gary R.↗

Modeling the use of mobile modular gas samplers in near-field detection

The Wireless Independent Noble Gas Sampler (WINGS) is a mobile, modular gas sampling system designed for use in low infrastructure environments. In the case of a suspected underground nuclear explosion (UNE), WINGS units could be deployed to detect noble gases emanating from the suspected explosion site or identify gases originating from another source entering the local area from offsite. In conclusion, this work uses the atmospheric transport modeling tool inline WRF-HYSPLIT to test the effectiveness of WINGS units around a suspected UNE site as a function of sampler density and distance from the emission point of gases from a UNE.

Air sampling↗

On the origin of (4)He and (40)Ar in natural gold

In a first report on our investigations of noble gases in native gold we demonstrated that placer gold contains an excess of radiogenic (4)He and (40)Ar relative to the concentrations expected from in situ decay of U, Th, and K, respectively, during the geologic age of about 30 Ma of the samples. We also showed that the U/Th-(4)He age of 36 Ma of vein-type gold from the Southern Alps agrees with its K-Ar formation age derived from associated muscovite and biotite. We now studied the question of the origin of the (4)He and (40)Ar excesses of placer gold. We conclude that gold contains two components of noble gases, a low-temperature component from fluid inclusions or phases which release noble gases at less than 800 C and a high-temperature component released when gold melts (1064 C). In some samples extremely high U and K concentrations or an unreasonably high formation age would be required to explain the observed (4)He abundances. Thus, trapped (4)He and (40)Ar must be present in gold.

Eugster, O.↗

A long-term change of the AR/KR/XE fractionation in the solar corpuscular radiation

Solar noble gases in an ilmenite separate from breccia 79035 (antiquity greater than 1 Ga) were analyzed by closed system stepped etching (CSSE). All five gases show the familiar two-component structure: first solar-wind (SW) gases are released, followed by gases from solar energetic particles (SEP). Element patterns in 79035 are similar to those of 71501 ilmenite. SW-He-Ne were partly lost, but SEP-He-Ne-Ar are retained (nearly) unfractionated. Constant Ar/Kr/Xe ratios indicate that ilmenites contain an unfractionated sample of the heavy SW-SEP noble gases. Ar/Kr/Xe ratios in the solar corpuscular radiation are, however, different from 'solar system' values, whereby the Kr/Xe difference in 79035 is about twice as large as in 71501. We propose that Xe is less fractionated than Kr and Ar, though its first ionization potential (FIP) is higher than the 'cutoff' at approximately 11.5 eV, above which all elements in SEP are usually assumed to be depleted by a roughly constant factor. SW-Ne may be isotopically slightly heavier in the ancient SW trapped by 79035, as proposed earlier. In this work we extend our previous CSSE studies of solar noble gases including Kr and Xe to a lunar sample irradiated at least 1 Ga ago (breccia 79035, ilmenite separate, 42-64 microns). This sample was particularly gently etched in the first steps. Surprisingly, the first three steps, each releasing less than or equal to 0.5% of the total 36-Ar, showed an SEP-like trapped component plus relatively large concentrations of cosmogenic gases. Steps 4ff contain much less cosmogenic and more solar gas with a SW-like isotope pattern. Thus, a very minor easily etchable phase that has completely lost its SW-gases must be responsible for steps 1-3. We will not discuss these steps here and refer to the actual step 4 as the 'initial' etching step.

Wieler, R.↗

Signal-to-noise ratio comparison of encoding methods for hyperpolarized noble gas MRI

Some non-Fourier encoding methods such as wavelet and direct encoding use spatially localized bases. The spatial localization feature of these methods enables optimized encoding for improved spatial and temporal resolution during dynamically adaptive MR imaging. These spatially localized bases, however, have inherently reduced image signal-to-noise ratio compared with Fourier or Hadamad encoding for proton imaging. Hyperpolarized noble gases, on the other hand, have quite different MR properties compared to proton, primarily the nonrenewability of the signal. It could be expected, therefore, that the characteristics of image SNR with respect to encoding method will also be very different from hyperpolarized noble gas MRI compared to proton MRI. In this article, hyperpolarized noble gas image SNRs of different encoding methods are compared theoretically using a matrix description of the encoding process. It is shown that image SNR for hyperpolarized noble gas imaging is maximized for any orthonormal encoding method. Methods are then proposed for designing RF pulses to achieve normalized encoding profiles using Fourier, Hadamard, wavelet, and direct encoding methods for hyperpolarized noble gases. Theoretical results are confirmed with hyperpolarized noble gas MRI experiments. Copyright 2001 Academic Press.

Non-NASA Center↗

Fullerenes and the Nature of Planetary Gases

Over the past several decades, two issues have dominated the discussion of planetary noble gas patterns: 1) the general resemblance of the noble gas abundances in carbonaceous chondrites to those measured in the Earth s atmosphere and; 2) atmospheric inventories of argon and neon that fall off significantly with increasing distance from the Sun. The recognition of the latter has led to the conclusion that the planetary component is not found on planets. In particular, the inability to explain the missing xenon reservoir, once thought to be sequestered in crustal rocks has been extremely troublesome. Some models have focused on various fractionations of solar wind rather than condensation as the process for the evolution of noble gases in the terrestrial planets. However, these models cannot explain the observed gradient of the gases, nor do they account for the similar Ne/Ar ratios and the dissimilar planetary Ar/Kr ratios. More recent studies have focused on hydrodynamic escape to explain the fractionation of gases, like neon, in the atmosphere and the mantle. Escape theory also seems to explain, in part, the isotopically heavy argon on Mars, however, it does not explain the discrepancies observed for the abundances of argon and neon on Venus and the Earth. This has led to the assumption that some combination of solar wind implantation, absorption and escape are needed to explain the nature of planetary noble gases.

Becker, Luann↗

Characterizing Uranus with an Ice giant Planetary Origins Probe (Ice-POP)

We now know from studies of planetary transits and microlensing that Neptune-mass planets are ubitquitous and may be the most common class of planets in the Galaxy. As such it is crucial that we understand the formation and evolution of the ice giant planets in our own solar system so that we can better understand planet formation throughout the galaxy. An entry probe mission to Uranus would help accomplish this goal. In fact the Planetary Decadal Survey recommended a Uranus orbiter with entry probe but did not explore in detail the specifications for the entry probe. NASA Ames is currently studying thermal protection system requirements for such a mission and this has led to questions regarding the minimum interesting science payload of such an entry probe. The single most important in-situ measurement for an ice giant entry probe is a measurement of atmospheric composition. For Uranus this would specifically include the methane and noble gas abundances. An in situ measurement of the methane abundance, from below the methane cloud, would constrain the atmospheric carbon abundance, which is believed to be roughly 30 to 50 times solar. There are hints from the transiting planets that extrasolar ice giants show comparable or even greater enhancements of heavy elements compared to their primary stars. However the origin of this carbon enhancement is controversial. Is Uranus a "failed core" of a larger gas giant or was the atmosphere enhanced by accretion of icy planetesimals' Constraining atmospheric abundances of C and perhaps S or even N from below 5 bars would provide badly needed data to address such issues. A measurement of the N abundance would provide clues on the origin of the planetesimals that formed Uranus. Low N-abundance indicates planetesimals from 'warmer' regions where N was mainly in form of NH3, whereas a strong enrichment could indicate planetesimals / cometary material from the colder outer regions of the nebula. Furthermore CO and HCN have been detected in Neptune but not in Uranus. A measurement of the abundance of either would constrain the source mechanisms for these molecules (exogenic or internal). A major surprise from the Galileo Entry Probe was that the heavier noble gases Ar, Kr, and Xe are enhanced in Jupiter's atmosphere at a level comparable to what was seen for the chemically active volatiles N, C, and S. It had been generally expected that Ar, Kr, and Xe would be present in solar abundances, as all were expected to accrete with hydrogen during the gravitational capture of nebular gases. Enhanced abundances of Ar, Kr, and Xe is equivalent to saying that these noble gases have been separated from hydrogen. There are several mechanisms that could accomplish this but these hypotheses require further testing. Measurement of noble gas abundances in an ice giant would constrain the planetary formation and nebular mechanisms responsible for this enhancement. Standard three-layer models of Uranus find that the outer, predominantly H/He layer of Uranus does not reach pressures high enough (approximately 1 Mbar) for H2 to transition to liquid metallic hydrogen. However, valid models can also be constructed with a smaller intermediate water-rich layer, with hydrogen then reaching the metallic hydrogen phase. If this occurs, He should phase separate from the hydrogen and ``rain out," taking along a substantial abundance of Ne, as suggested for Jupiter (and likely also for Saturn). Hence He and Ne depletions could be probes of the planet's structure in the much deeper interior. A determination of Uranus' atmospheric abundances, particularly of the noble gasses, is thus critical to understanding the formation of Uranus, and giant planets in general. These measurements can only be performed with an entry probe. The second key measurement would be a temperature-pressure sounding to provide ground truth for remote measurements of atmospheric temperature and composition and to constrain the internal heat flow. This would also establish that the methane abundance measurements have indeed been made below any possible methane cloud. Finally an ultra stable oscillator would measure wind speeds and constrain atmospheric dynamics. In our presentation we will discuss the importance of all of these measurements and argue that an entry probe is a crucial component of any ice giant mission.

Marley, Mark S.↗

Short communication: Cosmogenic noble gas depletion in soils by wildfire heating

Measurements of cosmic-ray-produced beryllium-10, neon-21, and helium-3 in quartz in a soil profile from a forested landscape in the Oregon Coast Range show that the cosmogenic noble gases 21 Ne and 3 He are depleted relative to 10Be in the shallow subsurface. The noble gases are mobile in mineral grains via thermally activated diffusion and 10 Be is not, implying that noble gas depletion is the result of surface heating by wildfires and subsequent mixing of partially degassed quartz downward into the soil. Cosmogenic noble gas depletion by wildfire heating of soils is a potential means of estimating wildfire intensity and/or frequency over pre-observational timescales.

58 GEOSCIENCES↗

Cryogenic Vacuum Pump

System provides high pumping capacity even for noble gases. First stage, removes water and CO2 from input gas. Second stage, removes noble gases except helium and some lighter gases not trapped by first stage. Third stage, traps all remaining gases. All three stages mounted inside liquid-nitrogen Dewar that cools first stage. Pump small enough for general laboratory use.

Zachman, C. A.↗

Noble gas adsorption to tuff

For this report a method was developed to measure trace noble gas element adsorption to the surfaces of geologic materials in the presence of a background gas that could potentially compete for surface adsorption sites. Adsorption of four noble gas elements (Ne, Ar, Kr, and Xe) at a concentration of 100 ppm in helium and nitrogen were measured on a sample of crushed tuff at 0, 15, 30, and 45°C. In addition, Ne, Ar, Kr, and Xe at 250 ppm and 500 ppm in nitrogen at 15°C were measured. Noble gas adsorption was found to increase with increasing atomic mass and decreasing temperature. It was also observed that the relative increase in noble gas element adsorption with decreasing temperature tends to increase with increasing atomic mass. Noble gas adsorption from nitrogen was approximately an order of magnitude greater than for the noble gases in helium. As the noble gas concentrations in nitrogen increased, adsorption increased in a slightly non-linear fashion which could be modeled using a Freundlich isotherm. For noble gas concentrations that were ≤100 ppm Henry's Law constant were calculated.

58 GEOSCIENCES↗

Xenon Isotopic Analysis of Individual Intermediate Particles From the OSIRIS-REx Sample of Asteroid Bennu

The OSIRIS-REx mission sampled material from the B-type asteroid Bennu and delivered the sample to Earth on 24 September 2023. Here we present initial xenon isotopic analysis of individual intermediate particles of Bennu material collected by the OSIRIS-REx mission. Noble gases are key tracers of Solar System evolution. Xenon is particularly useful among the noble gases because its nine isotopes allow multiple contributing sources to be unambiguously identified. The sun, asteroids (as measured in meteorites), and comets (measured in the coma of comet 67P) have distinct xenon isotopic signatures reflecting different mixtures of nucleosynthetic components. In addition, 129 I, 238 U, and 244 Pu decay with different half-lives, producing characteristic xenon signatures. Exposure of samples containing light rare earth elements and barium to cosmic rays produces xenon from spallation and secondary neutron capture reaction. Noble gas analyses help address several of the driving hypotheses of the mission [9]. Particle-by-particle analysis can elucidate the diversity of material present and reveal distinct noble gas compositions, including the potential to detect presolar or cometary noble gas signatures on a small scale. The isotopic signature provides a fingerprint that can be used to constrain the sources of volatiles in planetary reservoirs and combined with other information (e.g. mineralogy and petrology of the material analyses) contributes to our understanding of the initial constituents, formation, and history of Bennu and its parent asteroid.

S A Crowther↗

Using 81 Kr and isotopic tracers to characterise old groundwater in the Bangkok metropolitan and vicinity areas

Krypton-81 was applied to investigate the age of groundwater in the aquifer system in the Bangkok metropolitan and vicinity areas. Stable ( 2 H, 18 O and 13 C) and radioactive ( 3 H, 85 Kr and 14 C) isotopes and noble gases were applied in parallel. Low levels of 14 C and significant radiogenic 4 He confirm that groundwater in the deep aquifers is older than 30 ka. 81 Kr analysis identified groundwater with ages ranging from 17 to 300 ka. At some sites, large age discrepancies between 81 Kr and 14 C indicated that inter-aquifer mixing is likely occurring. The interpretation of the noble gases suggests that groundwaters in the deeper aquifers, with apparent ages of 300 to 10 ka, have recharged in slightly colder and wetter climates than those found in the upper aquifers with apparent ages < 10 ka. Degradation of water quality from seawater intrusion was identified in the upper four aquifers. This was also evidenced by higher δ 18 O and δ 2 H values, typical of seawater. The four deeper aquifers contain high quality water characterised by less enriched 18 O and 2 H. In conclusion, this work presents new findings of very old groundwater in the Bangkok aquifer system.

54 ENVIRONMENTAL SCIENCES↗

Crystallizing Atomic Xenon in a Flexible MOF to Probe and Understand Its Temperature-Dependent Breathing Behavior and Unusual Gas Adsorption Phenomenon

Flexible metal–organic frameworks (MOFs) hold great promise as smart materials for specific applications such as gas separation. These materials undergo interesting structural changes in response to guest molecules, which is often associated with unique adsorption behavior not possible for rigid MOFs. Understanding the dynamic behavior of flexible MOFs is crucial yet challenging as it involves weak host–guest interactions and subtle structural transformation not only at the atomic/molecular level but also in a nonsteady state. Here we report an in-depth study on the adsorbate- and temperature-dependent adsorption in a flexible MOF by crystallizing atomic gases into its pores. Mn(ina)2 shows an interesting temperature-dependent response toward noble gases. Its nonmonotonic, temperature-dependent adsorption profile results in an uptake maximum at a temperature threshold, a phenomenon that is unusual. Full characterization of Xe-loaded MOF structures is performed by in situ single-crystal and synchrotron X-ray diffraction, IR spectroscopy, and molecular modeling. The X-ray diffraction analysis offers a detailed explanation into the dynamic structural transformation and provides a convincing rationalization of the unique adsorption behavior at the molecular scale. The guest and temperature dependence of the structural breathing gives rise to an intriguing reverse of Xe/Kr adsorption selectivity as a function of temperature. The presented work may provide further understanding of the adsorption behavior of noble gases in flexible MOF structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Measuring Gas Transport and Sorption in Large Intact Geologic Specimens via the Piezometric Method

Uptake of noble gases into heterogeneous geologic core samples was measured using a piezometric methodology. In addition to measuring accessible porosity—as with gas pycnometry—by monitoring the rate of pressure decay, this method can also be used to estimate the gas effective diffusivity in the sample. In contrast to previous applications of this method, where milligram quantities of fractured grains are characterized, here approximately kilogram core samples were left intact when tested. In doing so, a more representative sample of the heterogeneous field geology is provided. Additionally, alteration of the pore structure and connectivity during sample preparation is avoided. Furthermore, to scale the piezometric method from milligrams to kilograms, the system was designed to operate at medium vacuum (1 to 100 Pa) to restrict transport in pores less than approximately 60 µm to large Knudsen numbers. To test the system performance, two samples of interest were selected: a rhyolitic welded tuff from Blue Canyon Dome at the Energetic Materials Research and Testing Center and a zeolitized non-welded rhyolitic tuff from the Nevada National Security Site. Three noble gases were utilized in this test series; Argon and xenon as they are of direct interest to nuclear monitoring efforts and helium as it is a weakly adsorbing reference standard. Additionally, mercury intrusion porosimetry measurements were made on subsamples of the core to compare the observed porosity by the two methods and to discuss gas transport rates in the context of the measured pore distribution.

58 GEOSCIENCES↗

Lunar and Planetary Science XXXV: Achondrite Mishmash

The session "Achondrite Mishmash" included teh following presentations:Constraining the Formation and Evolution of IAB Irons - High Precision; 40Ar/39Ar Ages on Plagioclase Separates from Silicate Inclusions of the Campo Del Cielo Meteorite; Radiogenic 129-Xenon in Silicate Inclusions in the Campo Del Cielo Iron Meteorite; Significance of Iron Isotope Mineral Fractionation in Pallasite and Iron Meteorites; An Experimental Study of Phosphoran Olivine and Its Significance in Main Group Pallasites; Characterization of the Distribution of Siderophile and Highly Siderophile Elements in the Milton and Eagle Station Pallasites; Relationships Between HED and Mesosiderite Meteorites: An Iron Isotope Perspective; Production Rates for Noble-Gas Isotopes in Eucrites; Evidence for Subsolidus Metasomatism in the Eucrite Parent Body; Possible Contact Metamorphism of the Polymict Eucrite Petersburg; Early and Late Stage Metals and Sulfides in Diogenites; Constraints on the Lithological Variation near the Surface of the HED Planetoid from the Petrology of 91 & 92 Series Antarctic Achondrites; Cosmic Ray Exposure Ages, Ar-Ar Ages, and the Origin and History of Eucrites; Trace Elements Abundances Vs Closure Temperature in Orthopyroxenes from Howardites; The First Mesosiderite-like Clast in a Howardite; 39Ar-40Ar Dating of Unusual Eucrite NWA 011: Is it from Vesta?; Trace Element Systematics of Northwest Africa 011: A "Eucritic" Basalt from a Non-Eucrite Parent Body ; 33S Anomaly in Acapulcoites and Lodranites; Magnetic Force Microscopy of Primitive Achondrites; Experimental Constraints on Ureilite Petrogenesis; Reflectance Spectra of Ureilites: Nature of the Mafic Silicate Absorption Features; Nitrogen and Noble Gases in Two Monomict Ureilites Acfer 277 and FRO 90036 from Hot and Cold Deserts; Solar Noble Gases in the Angrite Parent Body - Evidence from Volcanic Volatiles Trapped in D'Orbigny Glass; Trace Element Distribution Between Phases of the D'Orbigny Angrite ; Petrological Study of Six Angrites Including New Type; and Manganese-Chromium Isotope Systematics of Basaltic Achondrite Northwest Africa 011.

Source record↗

Is Q for Quantum? From Quantum Mechanics to Formation of the Solar System

The realization in 1985 that fullerenes exist in nature [1] as a third form of carbon-carbon clustering, continues to inspire new areas of research. In particular, the study of closed-cage endohedral fullerenes [2-6] is of scientific interest because of its potential application in a number of promising fields from medical imaging to astrophysics. One of these is to provide a possible chronometer for studying the age and origin of certain astromaterials in the solar system. Fullerenes are closed carbon cages that are fundamentally related to a long-standing debate over the "Q-Phase" origin of planetary noble gases in carbonaceous chondrites [7]. Although Q-phase has been identified as the carrier of planetary noble gases [8- 10], its physical nature has not been explained. Our limited understanding of it is based primarily on the laboratory chemical processing which it survives as well as the fact that it must have been widely distributed in the solar nebula [11]. Yet as important as it might be while preoccupying some 30 years of research, the question of what actually is Q-phase remains unresolved.

Wilson, T. L.↗