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NASA NTRS1993

Global organization of tectonic deformation on Venus

The geographic organization of surface deformation on Venus as on Earth is a key to understanding the global tectonic system. To date we have mapped the distribution of three unambiguous tectonic land forms on Venus: (1) linear foldbelts analogous to those at plate margins of the Earth; (2) linear rift zones, analogous to continental rifts on the Earth; and (3) distributed plains deformation in the form of wrinkle ridges and extensional faults and fractures. The linear foldbelts are the dominant structural style in the Northern Hemisphere; ninety percent of the planet's foldbelts lie above the equator. In contrast, compressive deformation in the Southern Hemisphere is dominated by two large, sweeping patterns of wrinkle ridges. The two hemispheres are divided by an equatorial region that is largely covered by rift zones and several large tessera blocks. A tectonic model of generally poleward convergence of the Northern Hemisphere explains the distribution of foldbelts and rift zones. In our model, a northern hemispherical plate (or system of plates) moves poleward and deforms along discrete, predominately longitudinal bands. We recognize four types of foldbelts based on their relationships to other large-scale tectonic features on Venus. There are foldbelts that lie within the low plains, foldbelts associated with coronae, novae and chasmata, foldbelts that lie at the margins of poly-deformed tessera plateaus, and the folded mountain belts around Lakshmi Planum. We see a geometric increase in the area of fold belts when normalized to percent area at a given latitude. This increase is consistent with our model of poleward convergence. Also, the orientations of most foldbelts are either approximately north-south or parallel to lines of latitude in the northern hemisphere. This observation is also consistent with the model in that the longitudinal bands are the result of the decreasing area of the sphere as the plate moves poleward and the latitudinal belts are the direct result of poleward compression. The trends of wrinkle ridges have been mapped over the planet and several large, sweeping patterns evidently reflect long-wavelength topography. Using wrinkle ridges as paleostress indicators, we have developed local and regional stress trajectory maps.

Bilotti, Frank↗

NASA NTRS2016

High-Latitude Topside Ionospheric Vertical Electron Density Profile Changes in Response to Large Magnetic Storms

Large magnetic-storm-induced changes were detected in high-latitude topside vertical electron density profiles Ne(h) in a database of profiles and digital topside ionograms, from the International Satellites for Ionospheric Studies (ISIS) program, that enabled Ne(h) profiles to be obtained in nearly the same region of space before, during, and after a major magnetic storm (Dst -100nT). Storms where Ne(h) profiles were available in the high-latitude Northern Hemisphere had better coverage of solar wind parameters than storms with available Ne(h) profiles in the high-latitude Southern Hemisphere. Large Ne(h) changes were observed during all storms, with enhancements and depletions sometimes near a factor of 10 and 0.1, respectively, but with substantial differences in the responses in the two hemispheres. Large spatial andor temporal Ne(h) changes were often observed during Dst minimum and during the storm recovery phase. The storm-induced Ne(h) changes were the most pronounced and consistent in the Northern Hemisphere in that large enhancements were observed during winter nighttime and large depletions during winter and spring daytime. The limited available cases suggested that these Northern Hemisphere enhancements increased with increases of the time-shifted solar wind velocity v, magnetic field B, and with more negative values of the B components except for the highest common altitude (1100km) of the profiles. There was also some evidence suggesting that the Northern Hemisphere depletions were related to changes in the solar wind parameters. Southern Hemisphere storm-induced enhancements and depletions were typically considerably less with depletions observed during summer nighttime conditions and enhancements during summer daytime and fall nighttime conditions.

Benson, Robert F.↗

NASA NTRS1985

North-south asymmetry in activity on the Sun and cosmic ray density gradients

The marked N-S asymmetry in solar activity (with predominant activity in the Sun's Northern Hemisphere) during the 1960's could certainly account for a S-pointing cosmic ray gradient. It is also clear from the data that the response to this change in solar activity asymmetry, and the related change in the perpendicular cosmic ray density gradient, is different for cosmic ray telescopes in the Earth's Northern and Southern Hemispheres. Northern Hemisphere detectors see a S-pointing gradient in the 60's and a N-pointing gradient after 1971, while Southern Hemisphere telescopes see a S-pointing gradient both before and after the reversal.

Swinson, D. B.↗

NASA NTRS1994

Surface temperatures in the polar regions from Nimbus 7 temperature humidity infrared radiometer

Monthly surface temperatures in the Arctic and Antarctic regions have been derived from the 11.5 micrometer thermal infrared channel of the Nimbus 7 temperature humidity infrared radiometer (THIR) for a whole year in 1979 and for a winter and a summer month from 1980 through 1985. The data set shows interannual variability and provides spatial details that allow identification of temperature patterns over sea ice and ice sheet surfaces. For example, the coldest spot in the southern hemisphere is observed to be consistently in the Antarctic plateau in the southern hemisphere, while that in the northern hemisphere is usually located in Greenland, or one of three other general areas: Siberia, the central Arctic, or the Canadian Archipelago. Also, in the southern hemisphere, the amplitude of the seasonal fluctuation of ice sheet temperatures is about 3 times that of sea ice, while in the northern hemisphere, the corresponding fluctuations for the two surfaces are about the same. The main sources of error in the retrieval are cloud and other atmospheric effects. These were minimized by first choosing the highest radiance value from the set of measurements during the day taken within a 30 km by 30 km grid of each daily map. Then the difference of daily maps was taken and where the difference is greater than a certain threshold (which in this case is 12 C), the data element is deleted. Overall, the monthly maps derived from the resulting daily maps are spatially and temporally consistent, are coherent with the topograph y of the Antarctic continent and the location of the sea ice edge, and are in qualitative agreement with climatological data. Quantitatively, THIR data are in good agreement with Antarctic ice sheet surface air temperature station data with a correlation coefficient of 0.997 and a standard deviation of 2.0 C. The absolute values are not as good over the sea ice edges, but a comparison with Russian 2-m drift station temperatures shows very high correlation (with correlation coefficient at 0.998) and a standard deviation of 1.1 C. Overall, the rms error is estimated to be from 1 to 2 C, depending on the surface, while the average bias when compared with in situ data is less than 2 C.

Comiso, Josefino C.↗

NASA NTRS2020

Fast Responses on Pre-Industrial Climate from Present-Day Aerosols in A CMIP6 Multi-Model Study

In this work, we use Coupled Model Intercomparison Project Phase 6 (CMIP6) simulations from 10 Earth system models (ESMs) and general circulation models (GCMs) to study the fast climate responses on pre-industrial climate, due to present-day aerosols. All models carried out two sets of simulations: a control experiment with all forcings set to the year 1850 and a perturbation experiment with all forcings identical to the control, except for aerosols with precursor emissions set to the year 2014. In response to the pattern of all aerosols effective radiative forcing (ERF), the fast temperature responses are characterized by cooling over the continental areas, especially in the Northern Hemisphere, with the largest cooling over East Asia and India, sulfate being the dominant aerosol surface temperature driver for present-day emissions. In the Arctic there is a warming signal for winter in the ensemble mean of fast temperature responses, but the model-to-model variability is large, and it is presumably linked to aerosol-induced circulation changes. The largest fast precipitation responses are seen in the tropical belt regions, generally characterized by a reduction over continental regions and presumably a southward shift of the tropical rain belt. This is a characteristic and robust feature among most models in this study, associated with weakening of the monsoon systems around the globe (Asia, Africa and America) in response to hemispherically asymmetric cooling from a Northern Hemisphere aerosol perturbation, forcing possibly the Intertropical Convergence Zone (ITCZ) and tropical precipitation to shift away from the cooled hemisphere despite that aerosols' effects on temperature and precipitation are only partly realized in these simulations as the sea surface temperatures are kept fixed. An interesting feature in aerosol-induced circulation changes is a characteristic dipole pattern with intensification of the Icelandic Low and an anticyclonic anomaly over southeastern Europe, inducing warm air advection towards the northern polar latitudes in winter.

Pre-industrial climate↗

NASA NTRS2012

Gravity, Topography, and Magnetic Field of Mercury from Messenger

On 18 March 2011, the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft was inserted into a 12-hour, near-polar orbit around Mercury, with an initial periapsis altitude of 200 km, initial periapse latitude of 60 deg N, and apoapsis at approximately 15,200 km altitude in the southern hemisphere. This orbit has permitted the mapping of regional gravitational structure in the northern hemisphere, and laser altimetry from the MESSENGER spacecraft has yielded a geodetically controlled elevation model for the same hemisphere. The shape of a planet combined with gravity provides fundamental information regarding its internal structure and geologic and thermal evolution. Elevations in the northern hemisphere exhibit a unimodal distribution with a dynamic range of 9.63 km, less than that of the Moon (19.9 km), but consistent with Mercury's higher surface gravitational acceleration. After one Earth-year in orbit, refined models of gravity and topography have revealed several large positive gravity anomalies that coincide with major impact basins. These candidate mascons have anomalies that exceed 100 mGal and indicate substantial crustal thinning and superisostatic uplift of underlying mantle. An additional uncompensated 1000-km-diameter gravity and topographic high at 68 deg N, 33 deg E lies within Mercury's northern volcanic plains. Mercury's northern hemisphere crust is generally thicker at low latitudes than in the polar region. The low-degree gravity field, combined with planetary spin parameters, yields the moment of inertia C/MR2 = 0.353 +/- 0.017, where M=3.30 x 10(exp 23) kg and R=2440 km are Mercury's mass and radius, and a ratio of the moment of inertia of Mercury's solid outer shell to that of the planet of Cm/C = 0.452 +/- 0.035. One proposed model for Mercury's radial density distribution consistent with these results includes silicate crust and mantle layers overlying a dense solid (possibly Fe-S) layer, a liquid Fe-rich outer core of radius 2030 +/- 37 km, and an assumed solid inner core. Magnetic field measurements indicate a northward offset of Mercury's axial magnetic dipole from the geographic equator by 479 +/-3 km and provide evidence for a regional-scale magnetic field approximately collocated with the northern volcanic plains of possible crustal origin. These results from MESSENGER indicate a complex and asymmetric evolution of internal structure and dynamics in this end-member inner planet.

Neumann, Gregory A.↗

NASA NTRS1993

On the atmospheric branch of the hydrological cycle

Recently, HIRS2/MSU data have been used at the Goddard Laboratory for Atmospheres (GLA) to generate global precipitation estimates. A synergistic mix of the GLA precipitation, together with the global wind and moisture fields produced by the Global Data Assimilation System of the European Centre for Medium-Range Weather Forecasts, was employed to delineate the atmospheric branch of the hydrological cycle during the 1978/79 Northern Hemisphere winter and the 1979 Northern Hemisphere summer. The transport of water vapor from source to sink regions was illustrated geographically by a combination of the divergent component of water vapor transport and precipitation.

Chen, Tsing-Chang↗

NASA NTRS2000

Insolation and the Precession Index

Simple nonlinear climate models yield a precession index-like term in the temperature. Despite its importance in the geologic record, the precession index e sin omega, where e is the Earth's orbital eccentricity and omega is the Sun's perigee in the geocentric frame, is not present in the insolation at the top of the atmosphere. Hence there is no one-for-one mapping of 23,000 and 19,000 year periodicities from the insolation to the paleoclimate record; a nonlinear climate model is needed to produce these periods. Two such models, a grey body and an energy balance climate model with an added quadratic term, produce e sin omega terms in temperature. These terms, which without feedback mechanisms achieve extreme values of about plus or minus 0.48 K for the grey body and plus or minus 0.64 K for the energy balance model, simultaneously cool one hemisphere while they warm the other. Moreover, they produce long-term cooling in the northern hemisphere when the Sun's perigee is near northern solstice and long-term warming in the northern hemisphere when the perigee is near southern solstice. Thus this seemingly paradoxical mechanism works against the standard model which requires cool northern summers (Sun far from Earth in northern summer) to build up northern ice sheets, so that if the standard model is correct it may be more efficient than previously thought. Alternatively, the new mechanism could possibly be dominant and indicate southern hemisphere control of the northern ice sheets, wherein the southern oceans undergo a long-term cooling when the Sun is close to the Earth during southern summer. The cold water eventually flows north, cooling the northern hemisphere. This might explain why the northern oceans lag the southern ones when it comes to orbital forcing.

Rubincam, David Parry↗

NASA NTRS1984

The simulation of transient statistics of the Southern Hemispheric circulation by the GLAS seasonal cycle model: Preliminary results

The general circulation of the Southern Hemisphere is quite different from that of the Northern Hemisphere in many important ways. These include the barotropic nature of the stationary waves and the presence of a strong barotropic component to the mean zonal wind, the lack of a strong seasonal dependence of the transient eddies, and the dominant role played by eddies with periods less than 10 days compared to longer period fluctuations. Such differences attest to the importance of the altered nature of the orographic and thermal land-sea forcings in the Southern Hemisphere compared to the Northern Hemisphere. Some of the important features of the Southern Hemisphere circulation as simulated by the GLAS Seasonal Cycle Model (SCM) are presented. The geographical patterns of local variability and their seasonal shifts in the SCM are discussed and compared to observations.

Straus, D. M.↗

NASA NTRS1983

The simulation of the seasonal cycle of the Southern Hemispheric circulation by the GLAS Seasonal Cycle Model and a comparison to observations

Straus, D. M.↗

NASA NTRS2015

High-Latitude Topside Ionospheric Vertical Electron-Density-Profile Changes in Response to Large Magnetic Storms

Large magnetic-storm induced changes have been detected in high-latitude topside vertical electron-density profiles Ne(h). The investigation was based on the large database of topside Ne(h) profiles and digital topside ionograms from the International Satellites for Ionospheric Studies (ISIS) program available from the NASA Space Physics Data Facility (SPDF) at http://spdf.gsfc.nasa.gov/isis/isis-status.html. This large database enabled Ne(h) profiles to be obtained when an ISIS satellite passed through nearly the same region of space before, during, and after a major magnetic storm. A major goal was to relate the magnetic-storm induced high-latitude Ne(h) profile changes to solar-wind parameters. Thus an additional data constraint was to consider only storms where solar-wind data were available from the NASA/SPDF OMNIWeb database. Ten large magnetic storms (with Dst less than -100 nT) were identified that satisfied both the Ne(h) profile and the solar-wind data constraints. During five of these storms topside ionospheric Ne(h) profiles were available in the high-latitude northern hemisphere and during the other five storms similar ionospheric data were available in the southern hemisphere. Large Ne(h) changes were observed during each one of these storms. Our concentration in this paper is on the northern hemisphere. The data coverage was best for the northern-hemisphere winter. Here Ne(h) profile enhancements were always observed when the magnetic local time (MLT) was between 00 and 03 and Ne(h) profile depletions were always observed between 08 and 10 MLT. The observed Ne(h) deviations were compared with solar-wind parameters, with appropriate time shifts, for four storms.

solar wind↗

NASA NTRS2003

On the Eastward Travelling Wavenumber Two in the Northern Stratosphere

Disturbances in the middle atmosphere are often interpreted in the framework of waves superimposed on a zonal-mean flow. This paper presents an analysis of travelling waves in the northern hemisphere stratosphere, concentrating on planetary wavenumber two (W2). Space-time spectral analysis reveals the existence of a substantial eastward-travelling planetary W2 at high latitudes in winter. While a similar feature is well documented in the southern hemisphere stratosphere, where it is observed in most winters, this northern hemisphere counterpart is less common and has not been examined in detail. A climatology of occurrence of the wave is given for the northern stratospheric winter. It is denoted as the quasi-16-day eastward travelling W2, because of its dominant periodicity, which ranges from about one to three weeks. Although the wave has some similarities with the southern hemispheric wave, there is much larger interannual and intraseasonal variability in the northern hemisphere. will emphasize the variations in the spatial and temporal structure of this wave, as isolated in meteorological analyses of radiosonde and satellite data. The possible role of these travelling waves in preconditioning the stratosphere as a precursor to sudden stratospheric warmings in both hemispheres will be discussed.

Pawson, Steven↗

NASA NTRS2004

The Precession Index and a Nonlinear Energy Balance Climate Model

A simple nonlinear energy balance climate model yields a precession index-like term in the temperature. Despite its importance in the geologic record, the precession index e sin (Omega)S, where e is the Earth's orbital eccentricity and (Omega)S is the Sun's perigee in the geocentric frame, is not present in the insolation at the top of the atmosphere. Hence there is no one-for-one mapping of 23,000 and 19,000 year periodicities from the insolation to the paleoclimate record; a nonlinear climate model is needed to produce these long periods. A nonlinear energy balance climate model with radiative terms of form T n, where T is surface temperature and n less than 1, does produce e sin (omega)S terms in temperature; the e sin (omega)S terms are called Seversmith psychroterms. Without feedback mechanisms, the model achieves extreme values of 0.64 K at the maximum orbital eccentricity of 0.06, cooling one hemisphere while simultaneously warming the other; the hemisphere over which perihelion occurs is the cooler. In other words, the nonlinear energy balance model produces long-term cooling in the northern hemisphere when the Sun's perihelion is near northern summer solstice and long-term warming in the northern hemisphere when the aphelion is near northern summer solstice. (This behavior is similar to the inertialess gray body which radiates like T 4, but the amplitude is much lower for the energy balance model because of its thermal inertia.) This seemingly paradoxical behavior works against the standard Milankovitch model, which requires cool northern summers (Sun far from Earth in northern summer) to build up northern ice sheets, so that if the standard model is correct it must be more efficient than previously thought. Alternatively, the new mechanism could possibly be dominant and indicate southern hemisphere control of the northern ice sheets, wherein the southern oceans undergo a long-term cooling when the Sun is far from the Earth during northern summer. The cold water eventually flows north, cooling the northern hemisphere. This might explain why the northern oceans lag the southern ones when it comes to orbital forcing.

Rubincam, David↗

NASA NTRS1986

Zonal wind observations during a geomagnetic storm

In situ measurements taken by the Wind and Temperature Spectrometer (WATS) onboard the Dynamics Explorer 2 spacecraft during a geomagnetic storm display zonal wind velocities that are reduced in the corotational direction as the storm intensifies. The data were taken within the altitudes 275 to 475 km in the dusk local time sector equatorward of the auroral region. Characteristic variations in the value of the Dst index of horizontal geomagnetic field strength are used to monitor the storm evolution. The detected global rise in atmospheric gas temperature indicates the development of thermospheric heating. Concurrent with that heating, reductions in corotational wind velocities were measured equatorward of the auroral region. Just after the sudden commencement, while thermospheric heating is intense in both hemispheres, eastward wind velocities in the northern hemisphere show reductions ranging from 500 m/s over high latitudes to 30 m/s over the geomagnetic equator. After 10 hours storm time, while northern thermospheric heating is diminishing, wind velocity reductions, distinct from those initially observed, begin to develop over southern latitudes. In the latter case, velocity reductions range from 300 m/s over the highest southern latitudes to 150 m/s over the geomagnetic equator and extend into the Northern Hemisphere. The observations highlight the interhemispheric asymmetry in the development of storm effects detected as enhanced gas temperatures and reduced eastward wind velocities. Zonal wind reductions over high latitudes can be attributed to the storm induced equatorward spread of westward polar cap plasma convection and the resulting plasma-neutral collisions. However, those collisions are less significant over low latitudes; so zonal wind reductions over low latitudes must be attributed to an equatorward extension of a thermospheric circulation pattern disrupted by high latitude collisions between neutrals transported via eastward winds and ions convecting westward.

Miller, N. J.↗

NASA NTRS1995

The effect of moonlight on observation of cloud cover at night, and application to cloud climatology

Ten years of nighttime weather observations from the Northern Hemisphere in December were classified according to the illuminance of moonlight or twilight on the cloud tops, and a threshold level of illuminance was determined, above which the clouds are apparently detected adequately. This threshold corresponds to light from a full moon at an elevation angle of 6 deg, light from a partial moon at higher elevation, or twilight from the sun less than 9 deg bvelow the horizon. It permits the use of about 38% of the observations made with the sun below the horizon. The computed diurnal cycles of total cloud cover are altered considerably when this moonlight criterion is imposed. Maximum cloud cover over much of the ocean is now found to be at night or in the morning, whereas computations obtained without benefit of the moonlight criterion, as in our published atlases, showed the time of maximum to be noon or early afternoon in many regions. The diurnal cycles of total cloud cover we obtain are compared with those of the International Satellite Cloud Climatology Project (ISCCP) for a few regions; they are generally in better agreement if the moonlight criterion is imposed on the surface observations. Using the moonlight criterion, we have analyzed 10 years (1982-91) of surface weather observations over land and ocean, worldwide, for total cloud cover and for the frequency of occurrence of clear sky, fog, and precipitation. The global average cloud cover (average of day and night) is about 2% higher if the moonlight criterion is imposed than if all observations are used. The difference is greater in winter than in summer, because of the fewer hours of darkness in summer. The amplitude of the annual cycle of total cloud cover over the Arctic Ocean and at the South Pole is diminished by a few percent when the moonlight criterion is imposed. The average cloud cover for 1982-91 is found to be 55% for Northern Hemisphere land, 53% for Southern Hemisphere land, 66% for Northern Hemisphere ocean, and 70% for Southern Hemisphere ocean, giving a global average of 64%. The global average for daytime is 64.6%; for nighttime 63.3%.

Hahn, Carole J.↗

NASA NTRS1994

Global surface-based cloud observation for ISCCP

Visual observations of cloud cover are hindered at night due to inadequate illumination of the clouds. This usually leads to an underestimation of the average cloud cover at night, especially for the amounts of middle and high clouds, in climatologies on surface observations. The diurnal cycles of cloud amounts, if based on all the surface observations, are therefore in error, but they can be obtained more accurately if the nighttime observations are screened to select those made under sufficient moonlight. Ten years of nighttime weather observations from the northern hemisphere in December were classified according to the illuminance of moonlight or twilight on the cloud tops, and a threshold level of illuminance was determined, above which the clouds are apparently detected adequately. This threshold corresponds to light from a full moon at an elevation angle of 6 degrees or from a partial moon at higher elevation, or twilight from the sun less than 9 degrees below the horizon. It permits the use of about 38% of the observations made with the sun below the horizon. The computed diurnal cycles of total cloud cover are altered considerably when this moonlight criterion is imposed. Maximum cloud cover over much of the ocean is now found to be at night or in the morning, whereas computations obtained without benefit of the moonlight criterion, as in our published atlases, showed the time of maximum to be noon or early afternoon in many regions. Cloud cover is greater at night than during the day over the open oceans far from the continents, particularly in summer. However, near noon maxima are still evident in the coastal regions, so that the global annual average oceanic cloud cover is still slightly greater during the day than at night, by 0.3%. Over land, where daytime maxima are still obtained but with reduced amplitude, average cloud cover is 3.3% greater during the daytime. The diurnal cycles of total cloud cover we obtain are compared with those of ISCCP for a few regions; they are generally in better agreement if the moonlight criterion is imposed on the surface observations. Using the moonlight criterion, we have analyzed ten years (1982-1991) of surface weather observations over land and ocean, worldwide, for total cloud cover and for the frequency of occurrence of clear sky, fog and precipitation The global average cloud cover (average of day and night) is about 2% higher if we impose the moonlight criterion than if we use all observations. The difference is greater in winter than in summer, because of the fewer hours of darkness in the summer. The amplitude of the annual cycle of total cloud cover over the Arctic Ocean and at the South Pole is diminished by a few percent when the moonlight criterion is imposed. The average cloud cover for 1982-1991 is found to be 55% for northern hemisphere land, 53% for southern hemisphere land, 66% for northern hemisphere ocean, and 70% for southern hemisphere ocean, giving a global average of 64%. The global average for daytime is 64.6% for nighttime 63.3%.

Source record↗

NASA NTRS2019

Observation and Attribution of Temperature Trends near the Stratopause from HALOE

This study considers time series of temperature versus pressure, T(p), from the Halogen Occultation Experiment (HALOE) across the stratopause region, where the effects of radiative forcings from the greenhouse gases (CO2 and H2O) and from ozone are most pronounced. Trend analyses are from 1993-2005 for HALOE T(p) values at seven levels from 3.0 to 0.3 hPa with a vertical resolution of about 4 km and for eight latitude zones from 65°S to 65°N. The HALOE trends at 2.0 hPa are of the order of -1.0 K/decade across the tropics and subtropics, but then become smaller (-0.5 K/decade) at the middle latitudes. The near-global HALOE trend profile has a minimum cooling rate of -0.2 K/decade at 1.0 hPa, although it is more negative in the southern hemisphere and slightly positive in the northern hemisphere. The combined radiative forcings from CO2, H2O, and ozone are from -0.4 to -0.6 K/decade for 1993-2005 and are hemispherically symmetric. HALOE temperature trend and total radiative cooling profiles differ from those reported from observations and calculations for 1980-2000, mainly because the ozone trends changed from clearly negative in the 1980s through mid-1990s to slightly positive during the time of HALOE. Trends for the tracer, HALOE methane (CH4), increase from 2 to 4 %/decade from 50 hPa to 10 hPa, indicating an acceleration of the Brewer/Dobson circulation. Analyses of time series of CH4 across the stratopause reveal more variability in the northern hemisphere, where wave dissipation likely contributes to the heating.

Remsberg, Ellis↗

NASA NTRS1993

A photostationary state analysis of the NO2-NO system based on airborne observations from the subtropical/tropical North and South Atlantic

The Chemical Instrumentation Test and Evaluation 3 (CITE 3) NO-NO2 database has provided a unique opportunity to examine important aspects of tropospheric photochemistry as related to the rapid cycling between NO and NO2. Our results suggest that when quantitative testing of this photochemical system is based on airborne field data, extra precautions may need to be taken in the analysis. This was particularly true in the CITE 3 data analysis where different regional environments produced quite different results when evaluating the photochemical test ratio (NO2)(sub expt)/(NO2)(sub calc), designated here as R(sub E)/R(sub C). The quantity (NO2)(sub Calc) was evaluated using the following photostationary state expression: (NO2)(sub Calc) = k(sub 1)(O3) + k(sub 4)(HO2) + k(sub 5)(CH3O2) + k(sub 6)(RO2))(NO)(sub Expt)/J(sub 2). The four most prominent regional environmental data sets identified in this analysis were those labeled here as free-tropospheric northern hemisphere (FTNH), free-tropospheric tropical northern hemisphere (FTTNH), free-tropospheric southern hemisphere (FTSH), and tropical-marine boundary layer (plume) (TMBL(P)). The respective R(sub E)/R(sub C) mean and median values for these four data subsets were 1.74, 1.69; 3.00, 2.79; 1.01, 0.97; and 0.99, 0.94. Of the four data subsets listed, the two that were statistically the most robust were FTNH and FTSH; for these the respective R(sub E)/R(sub C) mean and standard deviation of the mean values were 1.74 +/- 0.07 and 1.01 +/- 0.04. The FTSH observations were in good agreement with theory, whereas those from the FTNH data set were in significant disagreement. An examination of the critical photochemical parameters O3, UV(zenith), NO, NO2, and non-methane hydrocarbons (NMHCs) for these two databases indicated that the most likely source of the R(sub E)/R(sub C) bias in the FTNH results was the presence of a systematic error in the observational data rather than a shortening in our understanding of fundamental photochemical processes. Although neither a chemical nor meteorological analyses of these data identified this error with complete certainty, they did point to the three most likely possibilities: (1) an NO2 interference from a yet unidentified NO(y) species: (2) the presence of unmeasured hydrocarbons, the integrated reactivity of which would be equivalent to approximately 2.7 parts per billion by volume (ppbv) of toluene; or (3) some combination of points (1) and (2). Details concerning hypotheses (1) and (2) as well as possible ways to minimize these problems in future airborne missions are discussed.

Davis, D. D.↗