Observations of Turbulent-burst Geometry and Growth in Supersonic Flow
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James, Carlton S↗
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A semiempirical study of the optimized ground and excited state potential energy surfaces of retinal and its protonated Schiff base
The electronic ground and first excited states of retinal and its Schiff base are optimized for the first time using the semiempirical AM1 Hamiltonian. The barrier for rotation about the C(11)-C(12) double bond is characterized by variation of both the twist angle delta(C(10)-C(11)-C(12)-C(13)) and the bond length d(C(11)-C(12)). The potential energy surface is obtained by varying these two parameters. The calculated ground state rotational barrier is equal to 15.6 kcal/mol for retinal and 20.5 kcal/mol for its Schiff base. The all-trans conformation is more stable by 3.7 kcal/mol than the 11-cis geometry. For the first excited state, S(1,) the 90 degrees twisted geometry represents a saddle point for retinal with the rotational barrier of 14.6 kcal/mol. In contrast, this conformation is an energy minimum for the Schiff base. It can be easily reached at room temperature from the planar minima since it is separated from them by a barrier of only 0.6 kcal/mol. The 90 degrees minimum conformation is more stable than the all-trans by 8.6 kcal/mol. We are thus able to present a reaction path on the S(1) surface of the retinal Schiff base with an almost barrier-less geometrical relaxation into a twisted minimum geometry, as observed experimentally. The character of the ground and first excited singlet states underscores the need for the inclusion of double excitations in the calculations.
Retinaldehyde/chemistry↗
The Effects of Thrust Uncertainty and Attitude Knowledge Errors on the MMS Formation Maintenance Maneuver
The Magnetospheric Multiscale (MMS) Mission will use a formation of four spinning spacecraft to study the Earth s magnetosphere. The science objectives of MMS require a near-regular tetrahedron formation to be maintained with side lengths ranging from ten kilometers to several thousand kilometers at orbit apogee. To reduce spacecraft complexity and cost, the current mission concept assumes MMS can achieve its formation goals through open-loop orbit control from the ground, rather than in-flight, closed-loop formation control that has been the subject of recent study. Significant analysis has been performed to provide optimal reference orbit and relative orbit designs. However, the feasibility of achieving these orbits, and maintaining them for an extended period of time in the presence of real world errors and perturbations has not been investigated. In particular, attitude knowledge and control errors, which may have a negligible effect on orbit control for conventional missions with spinning spacecraft, can contribute significant errors to the MMS orbits. In this work, a 6 degree-of-freedom (DOF) simulation is developed and used to analyze the effects of realistic errors on formation maintenance maneuver accuracy. Several realistic considerations including a finite-burn model, attitude perturbations, and thrust uncertainty are studied. The primary objective is to quantify the effects of realistic attitude and orbit control, knowledge, and actuator errors on the formation geometry by observing representative maneuver errors of a single spacecraft.
Tsai, Dean C.↗
Experimental Investigation of Solder Joint Defect Formation and Mitigation in Reduced-Gravity Environments
This paper documents a research effort on reduced gravity soldering of plated through hole joints which was conducted jointly by the National Center for Space Exploration Research, NASA Glenn Research Center, and NASA Johnson Space Center. Significant increases in joint porosity and changes in external geometry were observed in joints produced in reduced gravity as compared to normal gravity. Multiple techniques for mitigating the observed increase in porosity were tried, including several combinations of flux and solder application techniques, and demoisturizing the circuit board prior to soldering. Results were consistent with the hypothesis that the source of the porosity is a combination of both trapped moisture in the circuit board itself, as well as vaporized flux that is trapped in the molten solder. Other topics investigated include correlation of visual inspection results with joint porosity, pore size measurements, limited pressure effects (0.08 MPa - 0.1 MPa) on the size and number of pores, and joint cooling rate.
Watson, J. Kevin↗
SPICE: a real example of data system re-use to reduce the costs of ground data systems development and mission operations
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ancillary data observation geometry↗
SPICE: a real example of data system re-use to reduce the costs of ground data systems development and mission operations
NASA's SPICE ancillary informaton system is used by engineers and scientists to capture and access a variety of engineering and other ancillary information throughout the mission lifecycle.
observation geometry ancillary data↗
Solar System Calculator: A Mission-Independent Tool for Science and Mission Operation
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multimission tools↗
CANDELS: The Cosmic Assembly Near-Infrared Deep Extragalactic Legacy Survey
The Cosmic Assembly Near-IR Deep Extragalactic Legacy Survey (CANDELS) is designed to document the first third of galactic evolution, from z approx. 8 - 1.5. It will image > 250,000 distant galaxies using three separate cameras on the Hubble Space Tele8cope, from the mid-UV to near-IR, and will find and measure Type Ia supernovae beyond z > 1.5 to test their accuracy as standard candles for cosmology. Five premier multi-wavelength sky regions are selected, each with extensive ancillary data. The use of five widely separated fields mitigates cosmic variance and yields statistically robust and complete samples of galaxies down to a stellar mass of 10(exp 9) solar mass to z approx. 2, reaching the knee of the UV luminosity function of galaxies to z approx. 8. The survey covers approximately 800 square arc minutes and is divided into two parts. The CANDELS/Deep survey (5(sigma) point-source limit H =27.7mag) covers approx. 125 square arcminutes within GOODS-N and GOODS-S. The CANDELS/Wide survey includes GOODS and three additional fields (EGS, COSMOS, and UDS) and covers the full area to a 50(sigma) point-source limit of H ? or approx. = 27.0 mag. Together with the Hubble Ultradeep Fields, the strategy creates a three-tiered "wedding cake" approach that has proven efficient for extragalactic surveys. Data from the survey are non-proprietary and are useful for a wide variety of science investigations. In this paper, we describe the basic motivations for the survey, the CANDELS team science goals and the resulting observational requirements, the field selection and geometry, and the observing design.
Grogin, Norman A.↗
Investigation of Effects of Material Architecture on the Elastic Response of a Woven Ceramic Matrix Composite
To develop methods for quantifying the effects of the microstructural variations of woven ceramic matrix composites on the effective properties and response of the material, a research program has been undertaken which is described in this paper. In order to characterize and quantify the variations in the microstructure of a five harness satin weave, CVI SiC/SiC, composite material, specimens were serially sectioned and polished to capture images that detailed the fiber tows, matrix, and porosity. Open source quantitative image analysis tools were then used to isolate the constituents and collect relevant statistics such as within ply tow spacing. This information was then used to build two dimensional finite element models that approximated the observed section geometry. With the aid of geometrical models generated by the microstructural characterization process, finite element models were generated and analyses were performed to quantify the effects of the microstructure and its variation on the effective stiffness and areas of stress concentration of the material. The results indicated that the geometry and distribution of the porosity appear to have significant effects on the through-thickness modulus. Similarly, stress concentrations on the outer surface of the composite appear to correlate to regions where the transverse tows are separated by a critical amount.
Goldberg, Robert K.↗
Assessment of Polarization Effect on Efficiency of Levenberg-Marquardt Algorithm in Case of Thin Atmosphere Over Black Surface
The Levenberg-Marquardt algorithm [1, 2] provides a numerical iterative solution to the problem of minimization of a function over a space of its parameters. In our work, the Levenberg-Marquardt algorithm retrieves optical parameters of a thin (single scattering) plane parallel atmosphere irradiated by collimated infinitely wide monochromatic beam of light. Black ground surface is assumed. Computational accuracy, sensitivity to the initial guess and the presence of noise in the signal, and other properties of the algorithm are investigated in scalar (using intensity only) and vector (including polarization) modes. We consider an atmosphere that contains a mixture of coarse and fine fractions. Following [3], the fractions are simulated using Henyey-Greenstein model. Though not realistic, this assumption is very convenient for tests [4, p.354]. In our case it yields analytical evaluation of Jacobian matrix. Assuming the MISR geometry of observation [5] as an example, the average scattering cosines and the ratio of coarse and fine fractions, the atmosphere optical depth, and the single scattering albedo, are the five parameters to be determined numerically. In our implementation of the algorithm, the system of five linear equations is solved using the fast Cramer s rule [6]. A simple subroutine developed by the authors, makes the algorithm independent from external libraries. All Fortran 90/95 codes discussed in the presentation will be available immediately after the meeting from sergey.v.korkin@nasa.gov by request.
Korkin, S.↗
Advances in SPICE Support of Planetary Science
SPICE is the de facto international standard for determining the geometric conditions-parameters such as altitude, lighting angles, and LAT/LON coverage of an instrument footprint-pertaining to scientific observations acquired by instruments on board robotic spacecraft. This system, comprised of data and allied software, is used for planning science observations and for analyzing the data returned from those observations. Use of SPICE is not a NASA requirement but is recommended by NASA's Planetary Data System and by the International Planetary Data Alliance. Owing in part to its reliability, stability, portability and user support, the use of SPICE has spread to many national space agencies, including those of the U.S., Europe (ESA), Japan, Russia and India. SPICE has been in use since the Magellan mission to Venus and so has many well-known capabilities. But the NAIF Team responsible for implementing SPICE continues to add new features; this presentation describes a number of these.
computational capability↗
Characterizing Biomass Feedstock Transport Properties Using State of the Art Imaging and Computational Techniques
The microstructure of lignocellulosic biomass determines heat and mass transfer during conversion processes. We present a novel method for characterizing the transport properties of biomass using advanced imaging and computational techniques. The microstructure of two woody feedstocks, red oak and Douglas fir, before and after pyrolysis, is revealed using X-ray computed tomography (XCT). Transport properties are calculated from the XCT images, and principal permeability tensors are calculated using an immersed boundary-based finite volume solver to model gas flow through the geometries. We observe that the permeabilities of native biomass are distinctly anisotropic, however, this anisotropy is greatly reduced after pyrolysis.
adaptive mesh refinement↗
Surveillance Test Articles Development
Material degradation in Advance Test Reactors (ATR) is governed by irradiation, corrosion, elevated temperature exposure and cyclic mechanical creep-fatigue loads. This degradation information during reactor operation condition is limited. Hence, material damage monitoring is a key aspect of the design, analysis and licensing of ATR components. The idea is to monitor material component operation conditions of component by using a surveillance test article. This test article is fabricated with bi-metal configuration with two different thermal expansion coefficients, and design is motivated by Simplified Model Test (SMT) specimen which can capture structure-like mechanical response. Upon raising temperature of the bi-metal test article configuration, expansion mismatch results tensile load on specimen. Thus, temperature dependent passively actuated loading is achieved. The idea is to place this surveillance test article in reactor at location ‘x’ to surveil the mechanical response at critical location ‘y’. By calibrating the test article design, material degradation at critical location can be surveilled through assessing the degradation in surveillance test article. This study presents test article development with different material combinations and follow-up experimental testing work through passively loading test article with temperature history. The test article geometry and observed test results are presented in presentation slides.
36 MATERIALS SCIENCE↗
An alternative representation of the ice canopy for calculating microwave brightness temperatures over a thunderstorm
Passive microwave brightness temperatures (TBs) at 92 and 183 GHz from an aircraft thunderstorm overflight are compared with values calculated from radar-derived hydrometeor profiles and a modified proximity sounding. Two methods for modeling particles in the ice canopy are contrasted. The first is a 'traditional' approach employing Marshall-Palmer ice spheres. The second, or 'alternative', method partitions 20 percent of the ice water content into a Marshall-Palmer component for graupel and hail, and 80 percent into a modified gamma spherical particle size distribution function representing ice crystals. Results from the alternative approach are superior to those from the traditional method in the anvil and mature convective core. In the decaying convective region, the traditional approach yields better agreement with observed magnitudes. Neither method, however, matches the geometry of the observed TB depression associated with the decaying convective core. This is likely due to the presence of graupel, which is not detected as a special signature in radar reflectivity, but does diminish TBs through scattering. Brightness temperatures at the relatively high microwave frequencies considered are shown to be very sensitive to the ice-particle size distribution.
Muller, Bradley M.↗
THREE-DIMENSIONAL EXPLOSION GEOMETRY OF STRIPPED-ENVELOPE CORE-COLLAPSE SUPERNOVAE. I. SPECTROPOLARIMETRIC OBSERVATIONS
We study the multi-dimensional geometry of supernova (SN) explosions by means of spectropolarimetric observations of stripped-envelope SNe, i.e., SNe without a hydrogen-rich layer. We perform spectropolarimetric observations of two stripped-envelope SNe, Type Ib SN 2009jf and Type Ic SN 2009mi. Both objects show non-zero polarization at the wavelength of the strong lines. They also show a loop in the Stokes Q - U diagram, which indicates a non-axisymmetric, three-dimensional ion distribution in the ejecta. We show that five out of six stripped-envelope SNe, which have been observed spectropolarimetrically so far, show such a loop. This implies that a three-dimensional geometry is common in stripped-envelope SNe. We find that stronger lines tend to show higher polarization. This effect is not related to the geometry, and must be corrected for to compare the polarization of different lines or different objects. Even after the correction, however, there remains a dispersion of polarization degree among different objects. Such a dispersion might be caused by three-dimensional clumpy ion distributions viewed from different directions.
79 ASTRONOMY AND ASTROPHYSICS↗
Analysis of simultaneous aerosol and ocean glint retrieval using multi-angle observations
Since early 2000, NASA's Multi-angle Imaging SpectroRadiometer (MISR) instrument has been performing remote sensing retrievals of aerosol optical properties from the polar-orbiting Terra spacecraft. A noteworthy aspect of MISR observations over the ocean is that, for much of the Earth, some of the multi-angle views have contributions from solar reflection by the ocean surface (glint, or glitter), while others do not. Aerosol retrieval algorithms often discard these glint-influenced observations because they can overwhelm the signal and are difficult to predict without knowledge of the (wind-speed-driven) ocean surface roughness. However, theoretical studies have shown that multi-angle observations of a location at geometries with and without reflected sun glint can be a rich source of information, sufficient to support simultaneous retrieval of both the aerosol state and the wind speed at the ocean surface. We are in the early stages of creating such an algorithm. In this paper, we describe our assessment of the appropriate level of parameterization for simultaneous aerosol and ocean surface property retrievals using sun glint. For this purpose, we use generalized nonlinear retrieval analysis (GENRA), an information content assessment (ICA) technique employing Bayesian inference, and simulations from the Ahmad–Fraser iterative radiative transfer code. We find that four parameters are suitable: aerosol optical depth (τ), particle size distribution (expressed as the fine mode fraction f of small particles in a bimodal size distribution), surface wind speed (w), and relative humidity (r, to define the aerosol water content and complex refractive index). None of these parameters define ocean optical properties, as we found that the aerosol state could be retrieved with the nine MISR near-infrared views alone, where the ocean body is strongly absorbing in the open ocean. We also found that retrieval capability varies with observation geometry and that as τ increases so does the ability to determine aerosol intensive optical properties (r and f, while it decreases for w). Increases in w decrease the ability to determine the true value of that parameter but have minimal impact on retrieval of aerosol properties. We explored the benefit of excluding the two most extreme MISR view angles for which radiative transfer with the plane-parallel approximation is less certain, but we found no advantage in doing so. Finally, the impact of treating wind speed as a scalar parameter, rather than as a two-parameter directional wind, was tested. While the simpler scalar model does contribute to overall aerosol uncertainty, it is not sufficiently large to justify the addition of another dimension to parameter space. An algorithm designed upon these principles is in development. It will be used to perform an atmospheric correction with MISR for coincident ocean color (OC) observations by the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument, also on the NASA Terra spacecraft. Unlike MISR, MODIS is a single-view-angle instrument, but it has a more complete set of spectral channels ideal for determination of optical ocean properties. The atmospheric correction of MODIS OC data can therefore benefit from MISR aerosol retrievals. Furthermore, higher-spatial-resolution data from coincident MISR observations may also improve glint screening.
Kirk Knobelspiesse↗
Magneto-optical studies of ensembles of semimagnetic self-organized Cd(Mn)Se/Zn(Mn)Se Quantum Dots
Ensembles of Cd(Mn)Se/ZnSe and CdSe/Zn(Mn)Se semimagnetic self-organized quantum dots with different Mn content have been studied by photoluminescence and resonant Raman scattering under strong magnetic fields in Faraday and Voigt geometries and with spectral and polarization selective excitation. Electron spin-flip Raman scattering has been observed in Voigt geometry in the structures with large Mn content. Narrow exciton peaks completely σ{sup −}σ{sup +} polarized have been observed under selective excitation in Faraday geometry in the structures with medium and small Mn content. A number of specific effects manifested themselves in the structures with a smallest Mn content where no Zeeman shift of the photoluminescence bands was observed.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Geometry Software Common to All Experiments
All imaging, remote sensing, and in situ experiments require information about the geometry and location of observations. An alterntive to collecting geometry data with a supplementary experiment data record is proposed. The new method involves identifying the fundamental information, that is, the geometric state upon which geometry calculations are based, and maintaining or delivering these calculations in separate packages which are easily replaced when improved information is available. Implementation of this method in spacecraft navigation is discussed along with software system requirements.
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