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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Aerosol scattering of ultraviolet sunlight in the tropical maritime atmosphere

The effects of atmospheric aerosol scattering on the vertical profile of solar ultraviolet radiation are investigated. Measurements of diffuse and total ultraviolet radiation were made using a rocketborne optical sonde in the marine atmosphere of Antigua. During observations, the sun was at zenith. Vertical profiles of directly transmitted solar radiation were calculated by subtraction of the diffuse component from the total radiance. Using these values of direct downward solar UV-flux, the optical thickness of the atmosphere was derived as a function of altitude. Absorption by ozone was also considered. In the troposphere the values of observed optical thickness were in general equal to or lower than those expected theoretically from Rayleigh scattering alone. The measured radiation profiles were compared with those computed for a multiple scattering model atmosphere. Some computations regarding the interaction of UV-sunlight with maritime aerosols are presented.

Ghazi, A.↗

Are aromatic hydrocarbons the carriers of the diffuse interstellar bands in the visible?

Large Polycyclic Aromatic Hydrocarbons (PAH) are the likely origin of the Unidentified Infrared Emission Feature. The molecules or their ions are also attractive candidates for the carriers of the Diffuse Interstellar Bands (DIBs) in the visible range. The PAHs have optically active transitions in the visible spectrum; have the ability to survive the ultraviolet photons in the Diffuse Interstellar Medium; and are the most abundant among the detected molecular species after H2 and CO. In particular, PAHs are better candidates than the long carbon chains that were proposed previously.

Leger, A.↗

Update on Advection-Diffusion Purge Flow Model

Gaseous purge is commonly used in sensitive spacecraft optical or electronic instruments to prevent infiltration of contaminants and/or water vapor. Typically, purge is sized using simplistic zero-dimensional models that do not take into account instrument geometry, surface effects, and the dependence of diffusive flux on the concentration gradient. For this reason, an axisymmetric computational fluid dynamics (CFD) simulation was recently developed to model contaminant infiltration and removal by purge. The solver uses a combined Navier-Stokes and Advection-Diffusion approach. In this talk, we report on updates in the model, namely inclusion of a particulate transport model.

purging↗

Continuum emission in active galactic nuclei; Proceedings of the Workshop, Tucson, AZ, January 11-14, 1986

Papers are presented on IRAS observations of active galactic nuclei, 0.3-100 micron continua of Seyfert 1 galaxies, the diverse soft X-ray slopes of QSOs, and the continuum variability of the optically-active radio-quiet quasar GQ Comae. Also considered are the polarization signatures of accretion disks in active galactic nuclei, X-ray spectra of BL Lacertae objects, diffusive shock acceleration and quasar variability, and radio-optical broadband spectra and variability of quasars. Other topics include the radio properties of optically selected Seyfert galaxies, and the structure of the emission region in blazars.

Sitko, Michael L.↗

High energy neutrinos from pulsar-powered optical transients: LFBOTs as potential origin of the KM3NeT event KM3-230213A

Recently, the KM3NeT Collaboration reported the detection of an ultra-high energy ($\sim 220$ PeV) neutrino event, KM3-230213A. In this work, we perform a detailed investigation into whether this event could originate from the diffuse neutrino flux produced by a class of pulsar-powered optical transients. In particular, we consider populations of ordinary supernovae (SNe), super-luminous supernovae (SLSNe), and luminous fast blue optical transients (LFBOTs) with a newly formed magnetar as the central engine. We discuss both the thermal electromagnetic and non-thermal neutrino emission from such sources. We scan the parameter space of the dipolar magnetic field strength and the initial spin period to determine characteristic optical emission properties and lightcurve timescales of these transients. Additionally, our scan identifies which classes of these transients can reproduce the required diffuse flux level and neutrino energies. Combining our results, we conclude that a diffuse neutrino flux from a population of LFBOTs can explain the KM3NeT event. Therefore, pulsar-powered optical transients may serve as promising sources for the current and upcoming high-energy and ultra-high energy neutrino telescopes.

Mukhopadhyay, Mainak [Fermilab; Chicago U., KICP] ↗

Heating of solid targets with laser pulses

Analytical and numerical solutions to the heat-conduction equation are obtained for the heating of absorbing media with pulsed lasers. The spatial and temporal form of the temperature is determined using several different models of the laser irradiance. Both surface and volume generation of heat are discussed. It is found that if the depth of thermal diffusion for the laser-pulse duration is large compared to the optical-attenuation depth, the surface- and volume-generation models give nearly identical results. However, if the thermal-diffusion depth for the laser-pulse duration is comparable to or less than the optical-attenuation depth, the surface-generation model can give significantly different results compared to the volume-generation model. Specific numerical results are given for a tungsten target irradiated by pulses of different temporal durations and the implications of the results are discussed with respect to the heating of metals by picosecond laser pulses.

Bechtel, J. H.↗

SWIM: A Semi-Analytical Ocean Color Inversion Algorithm for Optically Shallow Waters

In clear shallow waters, light that is transmitted downward through the water column can reflect off the sea floor and thereby influence the water-leaving radiance signal. This effect can confound contemporary ocean color algorithms designed for deep waters where the seafloor has little or no effect on the water-leaving radiance. Thus, inappropriate use of deep water ocean color algorithms in optically shallow regions can lead to inaccurate retrievals of inherent optical properties (IOPs) and therefore have a detrimental impact on IOP-based estimates of marine parameters, including chlorophyll-a and the diffuse attenuation coefficient. In order to improve IOP retrievals in optically shallow regions, a semi-analytical inversion algorithm, the Shallow Water Inversion Model (SWIM), has been developed. Unlike established ocean color algorithms, SWIM considers both the water column depth and the benthic albedo. A radiative transfer study was conducted that demonstrated how SWIM and two contemporary ocean color algorithms, the Generalized Inherent Optical Properties algorithm (GIOP) and Quasi-Analytical Algorithm (QAA), performed in optically deep and shallow scenarios. The results showed that SWIM performed well, whilst both GIOP and QAA showed distinct positive bias in IOP retrievals in optically shallow waters. The SWIM algorithm was also applied to a test region: the Great Barrier Reef, Australia. Using a single test scene and time series data collected by NASA's MODIS-Aqua sensor (2002-2013), a comparison of IOPs retrieved by SWIM, GIOP and QAA was conducted.

shallow waters↗

One Pot Synthesis of Cyan Emitting CdZnSSe Quantum Dots for Human Centric Lighting

A one pot synthesis of blue and green emissive CdZnSSe quantum dots (QDs) from thio- and selenoureas and Cd and Zn carboxylates is optimized using high throughput robotic optimization. A large set of spectral data (N = 192) is used to train machine learning models that accurately predict the photoluminescence emission wavelength (λmax) and full-width half-maximum, and the relative photoluminescence quantum yield (PLQY) from the S:Se and Zn:Cd stoichiometries and reaction time. ZnS shells are deposited on the crude QD heterostructures using 4-tert-butylbenzyl mercaptan, a more reactive source of sulfide that enables shell growth below the temperature where ion diffusion in the QD can broaden its optical spectrum (≤275 °C). These optimized procedures provide gram quantities of blue-green emitting QDs (PLQY = 85–99%) in a single reaction vessel. A solid state lighting device (4260 K) that incorporates cyan emissive QDs achieved a higher luminous efficacy of 179 lm/W and melanopic daylight efficiency ratio (0.71) than existing commercial human centric lighting devices.

Jordan, Abraham J↗

An unexpectedly shrunken bandgap in V2O5 nanoparticles

Synchrotron x-ray spectroscopy was employed to determine the effects of nanostructuring on electronic band structure in V2O5, a promising cathode material and widely used catalyst. V2O5nanoparticle and bulk powders were characterized via P-XRD, electron microscopy, and diffuse reflectance ultraviolet/visible/near-infrared spectroscopy to confirm the optical bandgap. X-ray emission spectroscopy revealed the nanoparticle valence band O 2pstates to be upshifted relative to the bulk, while x-ray absorption spectroscopy and resonant inelastic x-ray scattering showed the lowest V 3dconduction band states to be static. Together, these changes (in conjunction with an increased density of unoccupied lower conduction band states) produce a shrunken bandgap in the V2O5nanoparticles that defies the Burstein-Moss effect. Changes in nanoparticle band structure are generally attributed to oxygen vacancy defects. While nanostructure bandgap reduction is in line with much previous computational work, it is unexpected from most previous experimental results. To our knowledge, this is the first synchrotron x-ray spectroscopy study of a shrunken bandgap achieved in pure V2O5nanoparticles.

Anquillare, E L↗

Coastal Cloud Chemistry during EPCAPE Field Campaign Report

For this campaign, Principal Investigator Markus Petters deployed a suite of instruments inside Lynn Russell’s container that was sited at Mt. Soledad during the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE) campaign. Funding for this activity was provided by National Science Foundation Award 2410536. The instrument rack (Figure 1) included a differential mobility analyzer, a condensation particle counter, a portable optical particle spectrometer, and a continuous flow diffusion cloud condensation nuclei counter (CCN). The instruments sampled from a counterflow virtual impactor (CVI) inlet and an isokinetic inlet. The measurements provided aerosol size distribution, size-resolved CCN activity, and denuded versus undenuded CCN activity of aerosols and cloud drop residuals.

54 ENVIRONMENTAL SCIENCES↗

The Visible Airglow Experiment - A review

Contributions of the Visible Airglow Experiment (VAE) to the understanding of various airglow and auroral processes are reviewed. The impact of instrumental design and operation on the observations is discussed, and emphasis is placed on the relationship between observations and inversion for optical measurements of light emissions from a diffuse medium. VAE data are used to explain the physical mechanisms responsible for the production and destruction of excited species including O(+)(1P), O(1D), O(1S), N(2D), and Mg(+)2P1/2.

Hays, Paul B.↗

Small-scale structure in the diffuse interstellar medium

The initial results of a study to probe the small-scale structure in the diffuse interstellar medium (ISM) through IUE and optical observations of interstellar absorption lines toward both components of resolvable binary stars is reported. The binaries (Kappa CrA, 57 Aql, 59 And, HR 1609/10, 19 Lyn, and Theta Ser) observed with IUE have projected linear separations ranging from 5700 to 700 Au. Except for Kappa CrA, the strengths of the interstellar absorption lines toward both components of these binaries agree to within 10 percent. In the case of Kappa CrA, the optically thin interstellar Mg I and Mn II lines are about 50 percent stronger toward Kappa-2 CrA than Kappa-1 CrA. Higher resolution observations of interstellar Ca II show that this difference is concentrated in the main interstellar component at V(LSR) = 9 + or - 2 km/s. Interestingly, this velocity corresponds to an intervening cloud that may be associated with the prominent Loop I shell in the local ISM. Given the separation (23 arcsec) and distance (120 pc) of Kappa CrA, the line strength variations indicate that this cloud has structure on scales of 2800 AU or less.

Meyer, David M.↗

The Diffuse Infrared Background Experiment (DIRBE) - Understanding through test and simulation

Optical problems which arose during final integration and testing of the DIRBE instrument in the closed flight dewar before launch are discussed. Simulation based on the optical breadboard and engineering unit components showed that these problems (stray light signals) originated outside the instrument in the dewar dome lid. Excellent performance of the instrument confirmed this fact.

Wood, H. J.↗

Combustion Processes in Hybrid Rocket Engines

In recent years, there has been a resurgence of interest in the development of hybrid rocket engines for advanced launch vehicle applications. Hybrid propulsion systems use a solid fuel such as hydroxyl-terminated polybutadiene (HTPB) along with a gaseous/liquid oxidizer. The performance of hybrid combustors depends on the convective and radiative heat fluxes to the fuel surface, the rate of pyrolysis in the solid phase, and the turbulent combustion processes in the gaseous phases. These processes in combination specify the regression rates of the fuel surface and thereby the utilization efficiency of the fuel. In this paper, we employ computational fluid dynamics (CFD) techniques in order to gain a quantitative understanding of the physical trends in hybrid rocket combustors. The computational modeling is tailored to ongoing experiments at Penn State that employ a two dimensional slab burner configuration. The coordinated computational/experimental effort enables model validation while providing an understanding of the experimental observations. Computations to date have included the full length geometry with and with the aft nozzle section as well as shorter length domains for extensive parametric characterization. HTPB is sed as the fuel with 1,3 butadiene being taken as the gaseous product of the pyrolysis. Pure gaseous oxygen is taken as the oxidizer. The fuel regression rate is specified using an Arrhenius rate reaction, which the fuel surface temperature is given by an energy balance involving gas-phase convection and radiation as well as thermal conduction in the solid-phase. For the gas-phase combustion, a two step global reaction is used. The standard kappa - epsilon model is used for turbulence closure. Radiation is presently treated using a simple diffusion approximation which is valid for large optical path lengths, representative of radiation from soot particles. Computational results are obtained to determine the trends in the fuel burning or regression rates as a function of the head-end oxidizer mass flux, G=rho(e)U(e), and the chamber pressure. Furthermore, computation of the full slab burner configuration has also been obtained for various stages of the burn. Comparisons with available experimental data from small scale tests conducted by General Dynamics-Thiokol-Rocketdyne suggest reasonable agreement in the predicted regression rates. Future work will include: (1) a model for soot generation in the flame for more quantitative radiative transfer modelling, (2) a parametric study of combustion efficiency, and (3) transient calculations to help determine the possible mechanisms responsible for combustion instability in hybrid rocket motors.

Venkateswaran,S.↗

Real-time optical laboratory solution of parabolic differential equations

An optical laboratory matrix-vector processor is used to solve parabolic differential equations (the transient diffusion equation with two space variables and time) by an explicit algorithm. This includes optical matrix-vector nonbase-2 encoded laboratory data, the combination of nonbase-2 and frequency-multiplexed data on such processors, a high-accuracy optical laboratory solution of a partial differential equation, new data partitioning techniques, and a discussion of a multiprocessor optical matrix-vector architecture.

Casasent, David↗

Verification of RadCAD: Specular Capabilities

As part of the RadCAD's development process, it is necessary to compare RadCAD's results with other radiation tools and exact solutions when and where possible. Form factor algorithms have been previously verified with exact solutions. This paper will consider RadCAD's specular capabilities. First, radiation exchange factors will be compared against exact solutions and results from TRASYS for various geometries. Critical dimensions and optical properties are changed for each geometry. Second, a specular adjunct plate system will be used to verify absorbed heat fluxes. This particular geometric problem has had some attention in the literature. Previous authors have used this problem to validate software results with exact analytical solution. This paper will compare absorbed heat rates against the exact solution and other published results from other thermal radiation tools. The agreement between RadCAD and the exact solutions is good. The maximum error for both specular and diffuse exchange factors for both geometries and all optical properties was 3%. The absorbed fluxes differed by a maximum of 4% for the adjunct plate problem.

Lucas, Sam↗

Effect of a magnetic field on the diffusion of an electron-hole plasma in germanium.

Study in germanium of an optically injected electron-hole plasma, parallel and perpendicular to an applied magnetic field. The density gradient within the crystal was measured directly by an infrared-beam-absorption technique. Diffusion measurements made parallel to the magnetic field are adequately explained by the theory.

Gurnee, M. N.↗