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At least 217 records · Page 12

Kinetic Suppression of Photoinduced Halide Migration in Wide Bandgap Perovskites via Surface Passivation

In this work, we study the kinetics of photoinduced halide migration in FA 0.8 Cs 0.2 Pb(I 0.8 Br 0.2 ) 3 wide (~1.69 eV) bandgap perovskites and show that halide migration slows down following surface passivation with (3-aminopropyl) trimethoxysilane (APTMS). We use scanning Kelvin probe microscopy (SKPM) to probe the contact potential difference (CPD) shift under illumination and the kinetics of surface potential relaxation in the dark. Our results show that APTMS-passivated perovskites exhibit a smaller CPD shift under illumination and a slower surface potential relaxation in the dark. We compare the evolution of the photoluminescence spectra of APTMS-passivated and unpassivated perovskites under illumination. We find that APTMS-passivated perovskites exhibit more than 5 times slower photoluminescence red-shift, consistent with the slower surface potential relaxation as observed by SKPM. In conclusion, these observations provide evidence for kinetic suppression of photoinduced halide migration in APTMS-passivated samples, likely due to reduced halide vacancy densities, opening avenues to more efficient and stable devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Passivation of Germanium by Graphene for Stable Graphene/Germanium Heterostructure Devices

The scalable integration of graphene onto semiconductor platforms is an important step towards utilizing the exceptional structural, electronic, thermal, and mechanical properties of graphene in state-of-the-art technologies. Specifically, graphene films grown on Ge are an exciting materials system for high-performance electronics; however, the device performance depends sensitively on the structural, electronic, and chemical nature of the graphene/Ge interface. We have recently discovered that graphene grown directly on Ge via chemical vapor deposition (CVD) can passivate the Ge surface, preventing its oxidation for months—longer than alternate passivation methods reported in the literature. Yet, the factors that govern passivation are not understood. Here, we elucidate how the CVD growth conditions and Ge surface orientation affect Ge oxidation below graphene. We find that growing graphene with a high H2:CH4 flux ratio minimizes formation of defects in graphene, enhancing Ge passivation. While minimizing defects is important, surprisingly, we find that passivation depends much stronger on the Ge surface orientation. These results provide a route for the integration of graphene films with a pristine graphene/substrate interface on Ge, an important step towards stabilizing the Ge surface and realizing graphene-based or hybrid graphene/Ge heterostructure devices integrated directly on conventional semiconductor wafers.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Passive Radiative “Thermostat” Enabled by Phase-Change Photonic Nanostructures

A thermostat senses the temperature of a physical system and switches heating or cooling devices on or off, regulating the flow of heat to maintain the system’s temperature near a desired set point. Taking advantage of recent advances in radiative heat transfer technologies, here we propose a passive radiative “thermostat” based on phase-change photonic nanostructures for thermal regulation at room temperature. By self-adjusting their visible to mid-IR absorptivity and emissivity responses depending on the ambient temperature, the proposed devices use the sky to passively cool or heat during day-time using the phase-change transition temperature as the set point, while at night-time temperature is maintained at or below ambient. We simulate the performance of a passive nanophotonic thermostat design based on vanadium dioxide thin films, showing daytime passive cooling (heating) with respect to ambient in hot (cold) days, maintaining an equilibrium temperature approximately locked within the phase transition region. Furthermore, passive radiative thermostats can potentially enable novel thermal management technologies, for example, to moderate diurnal temperature in regions with extreme annual thermal swings.

47 OTHER INSTRUMENTATION↗

Tunnel oxide passivating contact enabled by polysilicon on ultra-thin SiO 2 for advanced silicon radiation detectors

Conventional silicon junction detectors encounter significant carrier recombination within the heavily doped p⁺ and n⁺ layers, as well as beneath the metal contact regions, creating the so-called “dead layers”, especially on the detector side. In this study, we present the tunnel oxide passivating contact with doped polysilicon on oxide, which demonstrates exceptional surface passivation and carrier selectivity. The key innovation lies in an ultra-thin (~ 1.5 nm) interfacial oxide layer that facilitates efficient majority carrier transportation via tunneling while effectively block minority carriers. Remarkably low saturation current densities, ranging from 5 to 10 fA/cm² even with the metal contact, underscore the superiority of both n-type and p-type tunnel oxide passivating contacts. In contrast, conventional p–n junction or high-low junction exhibit saturation current densities ranging from 10 to 90 fA/cm² in the studied p⁺ and n⁺ layers with surface passivation schemes due to Auger recombination and surface recombination, and 1000–6000 fA/cm² with metal contacts due to intense metal-induced recombination at the interface. These findings indicate the potential and superiority of implementing n-type tunnel oxide passivating contact on the detector side and p-type contact on the back side for advanced silicon radiation detectors. This approach would enable thorough collection of generated charge carriers along the track of incident ionizing radiation particles, leading to improved energy resolution and reduced noise levels.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Catalytic open-circuit passivation by thin metal oxide films of p-Si anodes in aqueous alkaline electrolytes

Ni and NiO x -based protective thin films are shown to catalyze the oxidation of Si in the presence of O 2 in strongly alkaline KOH(aq) even in the absence of illumination. The O 2 in solution drove the open-circuit potential of the electrode to >0.4 V, which is positive of the Si passivation potential. The elevated electrochemical potential of the surface promoted formation of passive oxides on exposed Si regions of Si/Ni electrodes. Catalytic passivation of Si extended the durability of an np + -Si(100)/NiO x photoanode to >400 h while operating under simulated day/night cycles. In contrast, electrodes without a Ni(O x ) layer and/or without O 2 in solution displayed direct etching of the Si and corrosion pitting during non-illuminated, simulated nighttime episodes of day/night cycling. The O 2 -derived catalyzed passivation of Si using thin films can be generalized to multiple phases of NiO x as well as to materials other than Ni. Finally, relative to operation in aqueous alkaline conditions, decreasing the pH of the electrolyte decreased the dissolution rate of the protective oxide layer formed by the catalyzed passivation process, and consequently increased the durability of the photoanode, but yielded lower photoelectrode fill factors for water oxidation due to the relatively large kinetic overpotentials for the electrocatalyzed oxygen-evolution reaction at near-neutral pH.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Transport dynamics of self-consistent, near-marginal drift-wave turbulence. II. Characterization of transport by means of passive scalars

From theoretical and modeling points of view, following Lagrangian trajectories is the most straightforward way to characterize the transport dynamics. In real plasmas, following Lagrangian trajectories is difficult or impossible. Using a blob of passive scalar (a tracer blob) allows a quasi-Lagrangian view of the dynamics. Using a simple two-dimensional electrostatic plasma turbulence model, this work demonstrates that the evolution of the tracers and the passive scalar field is equivalent between these two fluid transport viewpoints. When both the tracers and the passive scalar evolve in tandem and closely resemble stable distributions, namely, Gaussian distributions, the underlying turbulent transport character can be recovered from the temporal scaling of the second moments of both. This local transport approach corroborates the use of passive scalar as a turbulent transport measurement. The correspondence between the local transport character and the underlying transport is quantified for different transport regimes ranging from subdiffusive to superdiffusive. In conclusion, this correspondence is limited to the initial time periods of the spread of both the tracers and the passive scalar in the given transport regimes

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Measurement of the passive fast-ion D-alpha emission on the NSTX-U tokamak

On National Spherical Torus Experiment Upgrade, the passive fast-ion D-alpha (passive-FIDA) spectra from charge exchange (CX) between the beam ions and the background neutrals are measured and simulated. The results indicate that the passive-FIDA signal is measurable and comparable to the active-FIDA on several channels, such as at the major radius R = 117 cm. For this, active-FIDA means the active D-alpha emission from the fast ions that CX with the injected neutrals. The shapes of measured spectra are in agreement with FIDASIM simulations on many fibers. Furthermore, the passive-FIDA spatial profile agrees with the simulation. When making measurements of active-FIDA in the edge region using time-slice subtraction, variations in the passive-FIDA contribution to the signal should be considered.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A tandem radiative/evaporative cooler for weather-insensitive and high-performance daytime passive cooling

Radiative cooling and evaporative cooling with low carbon footprint are regarded as promising passive cooling strategies. However, the intrinsic limits of continuous water supply with complex systems for evaporative cooling, and restricted cooling power as well as the strict requirement of weather conditions for radiative cooling, hinder the scale of their practical applications. Here, we propose a tandem passive cooler composed of bilayer polymer that enables dual-functional passive cooling of radiation and evaporation. Specifically, the high reflectivity to sunlight and mid-infrared emissivity of this polymer film allows excellent radiative cooling performance, and its good atmospheric water harvesting property of underlayer ensures self-supply of water and high evaporative cooling power. Consequently, this tandem passive cooler overcomes the fundamental difficulties of radiative cooling and evaporative cooling and shows the applicability under various conditions of weather/climate. It is expected that this design can expand the practical application domain of passive cooling.

54 ENVIRONMENTAL SCIENCES↗

Nanomotor-enhanced transport of passive Brownian particles in porous media

Artificial micro/nanomotors are expected to perform tasks in interface-rich and species-rich environments for biomedical and environmental applications. In these highly confined and interconnected pore spaces, active species may influence the motion of coexisting passive participants in unexpected ways. Using three-dimensional super-resolution single-nanoparticle tracking, we observed enhanced motion of passive nanoparticles due to the presence of dilute well-separated nanomotors in an interconnected pore space. This enhancement acted at distances that are large compared to the sizes of the particles and cavities, in contrast with the insignificant effect on the passive particles with the same dilute concentration of nanomotors in an unconfined liquid. Experiments and simulations suggested an amplification of hydrodynamic coupling between self-propelled and passive nanoparticles in the interconnected confined environment, which enhanced the effective energy for passive particles to escape cavities through small holes. This finding represents an emergent behavior of confined nanomotors and suggests new strategies for the development of antifouling membranes and drug delivery systems.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Enhanced Performance Fast Reactors with Engineered Passive Safety Systems

This report summarizes the work and results of NEUP Project #15-8251, "Enhanced Performance Fast Reactors with Engineered Passive Safety System," performed from 2015-2018 at UC Berkeley and Argonne National Laboratory. This project concerns the incorporation of a novel engineered passive safety system, called the Autonomous Reactivity Control (ARC) system, into Sodium-cooled Fast Reactors (SFRs) to improve their transient and economic performance. The first part of this project consisted of fleshing out the basic principles and the manufacturing process for an SFR fuel assembly with the ARC system installed, with the details provided in high-quality, step-by-step CAD drawings. Once the detailed design is laid out, high-fidelity simulations were performed to optimize the dimensions of important ARC system components and to quantify the standalone time-response of ARC systems in a typical SFR environment. These high-fidelity simulations were used to create reduced-order models of ARC system response which could be incorporated into the SAS4A/SASSYS-1 whole-core transient models. In order to accurately account for the time-response of ARC systems in whole-core transient simulations, modifications were made to the SAS4A/SASSYS-1 transient code. These new capabilities were tested and incorporated into the production version of the code, and have been used extensively in this analysis. Before performing whole-core transient calculations, the two reference cores selected for this study to cover a wide design space were simulated and characterized. The two reference cores, (1) a medium-sized oxide-fueled Advanced Burner Reactor and (2) a large metal-fueled Breed-and-Burn core, challenge conventional means of achieving passive safety. Because the two cores vary substantially, simulating the ARC system in both allows for conclusions to be drawn about the applicability of ARC systems in different SFRs. Once both cores were fully characterized, transient calculations were performed to understand the complicated interplay between the ARC system and other inherent reactivity feedback mechanisms. By performing parametric studies of the transient behavior, ARC system designs that best improve transient performance in each core were identified. Once transient improvements were established, the transient calculations were extended to improve reactor economics through design modifications. Upon establishing the potential benefits of ARC system inclusion, the study examines the negative neutronic implications of incorporating ARC systems into the reference cores. The study concludes by discussing a number of knowledge gaps that exist which may have important implications for ARC system implementation. Ultimately, the results of this project indicate that ARC systems may provide an effective means to improve transient performance in certain types of systems. The transient simulations in the oxide Advanced Burner Reactor showed that significant margin to coolant boiling and fuel melting could be gained through the use of a properly designed ARC system, thus improving inherent safety. While oscillatory behavior was induced in the transient response for certain combinations of ARC system parameters, the oscillation-free design space that can be effectively used to improve performance was found to be large, and the additional margin was demonstrated to allow economical improvements to the core design. Conversely, difficulties were encountered in the Breed-and-Burn core due to fundamental aspects of the core design. The combination of a particularly strong positive coolant void feedback and the use of metallic fuel allowed for diverging oscillations to manifest in response to certain transient initiators, and in the end it was found that the current ARC system design could not simultaneously enable passive safety in all transients examined. In order for complete passive safety to be achieved, a mechanism for slowing the reverse actuation of ARC systems is necessary. Regardless, the standard ARC system was able to improve the performance of two out of the three examined transients by increasing the margin to boiling in Loss of Heat Sink transients and avoiding boiling in Transient Overpower accidents. Additionally, no significant barriers to implementation were found, although the issue of tritium production should be closely monitored in any core incorporating ARC systems. Still, a number of technology gaps exist, and these are discussed at the conclusion of the report to recommend directions for future work.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Passive Ultrasonic Deterrents to Reduce Bat Mortality in Wind Farms (Final Report)

The overall objective of this project was to develop active and passive ultrasonic deterrent concepts to mitigate bat mortality at wind turbines. The research was supported by the US Department of Energy under the contract DE-EE0008731. Novel ultrasonic bat deterrents are investigated in this study. The deterrents are based on the idea of aerodynamic whistles wherein flow-acoustic resonance is used to produce high-amplitude tonal sound at desired ultrasonic frequencies. The deterrents can be grouped into active and passive. The active deterrents/whistles are driven by pressurized air supplied by an external source (e.g., an air compressor). The passive deterrents/whistles are designed to be mounted on wind turbine blades and are “powered” by the energy in the air moving past the rotor blades. Multiple active and passive deterrent ideas are proposed and investigated numerically and experimentally. The computational analysis involves solving the compressible unsteady Reynolds-averaged Navier-Stokes (URANS) equations and coupling the near-field aerodynamic solution with an integral method based on the Ffowcs Williams-Hawkings acoustic analogy to predict ultrasound in the farfield. Experiments are performed in the anechoic chamber at ISU (for the active whistles) and in the Stability wind tunnel at Virginia Tech (for the passive whistles).

17 WIND ENERGY↗

Characterization of Performance Degradation Mechanisms in Low-Cost High Throughput DI-O3 Layer for Passivated Contact Silicon Solar Cells

Characterization and mitigating performance limiting defects in Silicon (Si) PV is one of key areas to be addressed to improve PV hardware costs and energy yield in order to lower the levelized cost of energy (LCOE) of installed PV cost to $0.02/kWh. As Si PV cells efficiencies have surpassed 22% and approaching 23%, the recombination at the metal contacts have become the focus point to be addressed. Passivated contact technologies—having a heterojunction with a band-gap larger than silicon between the metal and silicon—have emerged as a great potential for future highand ultrahigh-efficiency solar cells, as it concurrently reduces recombination and increases carrier selectivity, by incorporating thin films within the contact structure. Passivated contact Si solar cell technologies use a wide variety of tunnel layers—playing a crucial role to passivate metal contacts and tunnel charge carriers—including stoichiometric silicon oxide (SiO 2 ) grown by thermal oxidation and Low-Pressure Chemical Vapor Deposition (LPCVD) technique and silicon oxide (SiO x ) by hot nitric acid. However, thorough investigations on understanding the failure and performance degradation mechanisms associated with tunnel layers are still limited to date. Unlocking those degradation characteristics in crucial tunnel layers could improve the reliability and energy yield of passivated contact Si solar cells. Besides, the technique of growing aforementioned tunneling layers are low throughput, and requires high temperature processes and/or a vacuum environment. In this project, we investigated the performance degradation mechanisms of a low-cost high-throughput ozonated oxide (DI-O 3 ) tunnel layer for the passivated contact Si solar cells.

14 SOLAR ENERGY↗

Non-Uniform Cylinder-to-Cylinder Combustion for Ammonia Generation in a New Passive SCR System

Lean burn gasoline engine is a promising technology for reducing the fuel consumption by passenger cars. However, cost-effective NOx emissions control for lean burn gasoline engines remains a great challenge for the commercialization of lean burn gasoline engines in the U. S. market. To address this issue, passive selective catalytic reduction (SCR), which utilizes a close-coupled three-way catalyst (TWC) as an on-board device for ammonia (NH3) production during rich engine operation, has attracted much attention in the past several years. The main purpose of this study is to reduce the cost of ammonia generation for a passive SCR system by proposing a new passive SCR system architecture and an innovative non-uniform cylinder-to-cylinder combustion (NUCCC) strategy. The new passive SCR system that consists of a two-stage TWC and a TWC bypass, together with the optimization of NUCCC strategy, can potentially enable more efficient engine combustion and more cost-effective ammonia production. Optimization results based on the experimental data from a physical engine platform, demonstrate that the proposed new passive SCR system coupled with the NUCCC strategy, can reduce the ammonia specific fuel consumption (ASFC) by up to 29.8%. Such a novel engine combustion strategy and innovative aftertreatment system can be very instrumental in significantly reducing the fuel penalty associated with NOx emission control for lean-burn engines in the future.

Chen, Pingen↗

Effects of NOX Storage Component on Ammonia Formation in TWC for Passive SCR NOX Control in Lean Gasoline Engines

A prototype three-way catalyst (TWC) with NOX storage component was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly-rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. Adding a NOX storage component to a TWC provides two benefits in the context of a passive SCR system: (1) enabling longer lean operation by storing NOX upstream and preserving NH3 inventory on the downstream SCR catalyst; and (2) increasing the quantity and rate of NH3 production during rich operation. Since the fuel penalty associated with passive SCR NOX control depends on the fraction of time that the engine is running rich rather than lean, both benefits (longer lean times and shorter rich times achieved via improved NH3 production) will decrease the passive SCR fuel penalty. However, these benefits are primarily realized at low to moderate temperatures (300-500 °C), where the NOX storage component is able to store NOX, with little to no benefit at higher temperatures (>500 °C), where NOX storage is no longer effective. This study discusses engine parameters and control strategies affecting the NH3 generation over a TWC with NOX storage component.

Prikhodko, Vitaly↗

Total Cost of Ownership Reduction Using Passive Pre-Chamber Ignition in Natural Gas Engines

Spark plug durability is a factor affecting the total cost of ownership (TCO) of spark-ignited natural gas engines, with some heavy-duty platforms requiring plug replacement after only 750 hours of operation. The high ignition energy demand under lean or diluted conditions accelerates electrode wear, shortening plug life and increasing maintenance frequency. This work evaluates passive pre-chamber (PC) ignition operating at lowered spark energies as a strategy to reduce spark energy requirements and extend plug durability, thereby lowering TCO. Experiments were conducted on a medium-duty Cummins 6.7L ISB engine at 1600 RPM and 50% load under varying exhaust gas recirculation (EGR) dilution levels (0–40%). Two passive pre-chambers with 1.1 mm and 1.6 mm nozzle diameters were compared with conventional spark ignition (SI). SI was operated with a fixed coil dwell of 4 ms (~90 mJ), while the PC configuration was tested across 2–4 ms dwell times (~30–90 mJ). Cylinder pressure analysis revealed that PC ignition sustained stable combustion at significantly lower spark energies than SI, with improved combustion stability at ~30 mJ compared with SI at ~90 mJ. The PC system also extended the dilution tolerance beyond that achievable with SI, while delivering up to ~2% higher indicated thermal efficiency and reducing the COV by nearly 90% at 30% EGR. A TCO analysis was conducted to assess the economic benefit of adopting a passive PC system operating at reduced spark energies compared to SI. It was found that adopting a passive PC system could reduce TCO by approximately $11,000 per engine over a five-year operational period, primarily due to fuel savings, extended spark plug life, and reduced maintenance frequency. These projections were weighed against the additional hardware cost of the pre-chamber, yielding a rapid estimated return on investment of ~300 operating hours. Therefore, this work motivates continued research and development of passive PC technology and its commercial adoption in natural gas engines used in transportation applications.

Dhotre, Akash [University of Minnesota]↗

PAMTRA 1.0: the Passive and Active Microwave radiative TRAnsfer tool for simulating radiometer and radar measurements of the cloudy atmosphere

Forward models are a key tool to generate synthetic observations given knowledge of the atmospheric state. In this way, they are an integral part of inversion algorithms that aim to retrieve geophysical variables from observations or in data assimilation. Their application for the exploitation of the full information content of remote sensing observations becomes increasingly important when these are used to evaluate the performance of cloud-resolving models (CRMs). Herein, CRM profiles or fields provide the input to the forward model whose simulation results are subsequently compared to the observations. This paper introduces the freely available comprehensive microwave forward model PAMTRA (Passive and Active Microwave TRAnsfer), demonstrates its capabilities to simulate passive and active measurements across the microwave spectral region for upward- and downward-looking geometries, and illustrates how the forward simulations can be used to evaluate CRMs and to interpret measurements to improve our understanding of cloud processes. PAMTRA is unique as it treats passive and active radiative transfer (RT) in a consistent way with the passive forward model providing upwelling and downwelling polarized brightness temperatures and radiances for arbitrary observation angles. The active part is capable of simulating the full radar Doppler spectrum and its moments. PAMTRA is designed to be flexible with respect to instrument specifications and interfaces to many different formats of input and output, especially CRMs, spanning the range from bin-resolved microphysical output to one- and two-moment schemes, and to in situ measured hydrometeor properties. A specific highlight is the incorporation of the self-similar Rayleigh–Gans approximation (SSRGA) for both active and passive applications, which becomes especially important for the investigation of frozen hydrometeors.

54 ENVIRONMENTAL SCIENCES↗

Enlightened Use of Passive Voice in Technical Writing

The passive voice as a normal, acceptable, and established syntactic form in technical writing is defended. Passive/active verb ratios, taken from sources including 'antipassivist' text books, are considered. The suitability of the passive voice in technical writing which involves unknown or irrelevant agents is explored. Three 'myths' that the passive (1) utilizes an abnormal and artificial word order, (2) is lifeless, and (3) is indirect are considered. Awkward and abnormal sounding examples encountered in text books are addressed in terms of original context. Unattractive or incoherent passive sentences are explained in terms of inappropriate conversion from active sentences having (1) short nominal or pronominal subjects or (2) verbs with restrictions on their passive use.

Trammell, M. K.↗

Passive damping concepts for free and forced member and grillage vibration

The performance of potential passive damping concepts is investigted for a long tubular aluminum alloy member, and a two-bar grillage structure. The members are restrained partially at the ends and are of the type being considered by NASA for possible use in the construction of a future space station. Four different passive damping concepts are studied and include nylon brush, wool swab, copper brush, and silly putty in chamber dampers. Both free and forced vibration tests are conducted. It is found that the silly putty in chamber damper concept provides considerably greater passive damping as compared to that of the other three concepts. For the grillage natural vibration, a five wool swab damper configuration provides greater damping than the five silly putty dampers in chamber configuration. Due to the constrained motion imposed by the vibrator used in the tests, the effectiveness of the passive dampers could not be adequately evaluated for the individual member. However, it is found that for the grillage under forced vibration, the five silly putty dampers in chamber damper configuration provides very effective passive damping although only at and around the resonant frequency. At resonance, these dampers provide a 51 percent reduction in the dynamic magnification factor for this case.

Razzaq, Zia↗