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NASA NTRS2005

Influence of Silicate Melt Composition on Metal/Silicate Partitioning of W, Ge, Ga and Ni

The depletion of the siderophile elements in the Earth's upper mantle relative to the chondritic meteorites is a geochemical imprint of core segregation. Therefore, metal/silicate partition coefficients (Dm/s) for siderophile elements are essential to investigations of core formation when used in conjunction with the pattern of elemental abundances in the Earth's mantle. The partitioning of siderophile elements is controlled by temperature, pressure, oxygen fugacity, and by the compositions of the metal and silicate phases. Several recent studies have shown the importance of silicate melt composition on the partitioning of siderophile elements between silicate and metallic liquids. It has been demonstrated that many elements display increased solubility in less polymerized (mafic) melts. However, the importance of silicate melt composition was believed to be minor compared to the influence of oxygen fugacity until studies showed that melt composition is an important factor at high pressures and temperatures. It was found that melt composition is also important for partitioning of high valency siderophile elements. Atmospheric experiments were conducted, varying only silicate melt composition, to assess the importance of silicate melt composition for the partitioning of W, Co and Ga and found that the valence of the dissolving species plays an important role in determining the effect of composition on solubility. In this study, we extend the data set to higher pressures and investigate the role of silicate melt composition on the partitioning of the siderophile elements W, Ge, Ga and Ni between metallic and silicate liquid.

Singletary, S. J.↗

NASA NTRS1988

Electron Diffraction Evidence for the Ordering of Excess Nickel Atoms by Relation to Stoichiometry in Nickel-Rich Beta'-Nial Formation of a Nickel-Aluminum (Ni2al) Superlattices

In electron diffraction patterns of nickel-rich beta-NiAl alloys, many anomalies are observed. One of these is the appearance of diffuse intensity maxima between the reflexions of the B2 structure. This is explained by the short-range ordering of the excess nickel atoms on the simple cubic sublattice occupied only by aluminum atoms in the stoichiometric, perfectly ordered NiAl alloy. After annealing Ni 37.5 atomic percent Al and Ni 37.75 atomic percent Al for 1 week at 300 and 400 C, the diffuse intensity maxima transformed into sharp superstructure reflexions. These reflexions are explained by the formation of the four possible variants of an ordered hexagonal superstructure corresponding to the Ni2Al composition. This structure is closely related to the Ni2Al3 structure (same space group) formed by the ordering of vacancies on the nickel sublattice in aluminum-rich beta-NiAl alloys.

Reynaud, F.↗

NASA NTRS1992

Effects of equatorially trapped ions on refilling of the plasmasphere

The kinetic aspects of shock formation in response to the equatorial heating of ions are reported by means of small-scale kinetic simulations of countersteaming plasma flows along a spatially varying magnetic field having the features of the dipolar magnetic field lines. Attention is given to the trapping of the field-aligned flowing ions in response to the simulated equatorial heating of ions and the associated self-consistent structures in the electric potentials and the f-plasma flow pattern. Trapping is found to lead to the formation of electrostatic shocks, which propagate away from the 'equator' as seen in the hydrodynamic model of Singh and Torr (1990). The shocks form near the mirror points of the 'equatorially' heated ions. The second stage of the refilling with equatorially trapped ions is reported. A variety of structures in density and temperature distributions as the refilling proceeds slowly is found.

Singh, Nagendra↗

NASA NTRS2012

Tiled WMS/KML Server V2

This software is a higher-performance implementation of tiled WMS, with integral support for KML and time-varying data. This software is compliant with the Open Geospatial WMS standard, and supports KML natively as a WMS return type, including support for the time attribute. Regionated KML wrappers are generated that match the existing tiled WMS dataset. Ping and JPG formats are supported, and the software is implemented as an Apache 2.0 module that supports a threading execution model that is capable of supporting very high request rates. The module intercepts and responds to WMS requests that match certain patterns and returns the existing tiles. If a KML format that matches an existing pyramid and tile dataset is requested, regionated KML is generated and returned to the requesting application. In addition, KML requests that do not match the existing tile datasets generate a KML response that includes the corresponding JPG WMS request, effectively adding KML support to a backing WMS server.

Plesea, Lucian↗

NASA NTRS2012

CometQuest: A Rosetta Adventure

Leon, Nancy J.↗

NASA NTRSDate not supplied

Mapping Organic-Mineral Associations in Jezero crater

The search for potential signs of life on Mars, a primary aim of the Mars 2020 mission, is greatly informed by the detection of organic matter1. The presence of organic matter also provides key information about the habitability and biological potential of the planet throughout its history. The Perseverance rover was designed for in situ science with the ability to collect a suite of promising samples for eventual return to Earth. One of its instruments, Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC), is a deep ultraviolet (DUV) Raman and fluorescence spectrometer designed to map the distribution of organic molecules and minerals on rock surfaces at a resolution of 100 μm2. With its unique spectral mapping capabilities, SHERLOC enables a novel understanding of organic-mineral relationships on Mars to better determine their formation, deposition, and preservation mechanisms. The rover’s landing site within Jezero crater combines a high potential for past habitability as the site of an ancient lake basin with a diverse set of minerals, including carbonates and clays, that may preserve organic materials and potential biosignatures. The Jezero crater floor includes three formations (fm); two of these, Máaz and Séítah, were explored as part of the mission’s first campaign. Here, we report the detection of multiple species of aromatic organic molecules using Raman and fluorescence spectroscopy across ten targets in the two formations. This is the first evidence of organic molecules in Martian materials obtained using Raman spectroscopy, and among the first using fluorescence spectroscopy, beyond Earth3. We report specific spatial patterns and classes of organic molecules in these compositionally distinct formations, potentially indicating different fates of carbon in these environments. Our findings indicate that there is a diversity of aromatic molecules prevalent on the Martian surface and these materials persist despite exposure to surface conditions. These organic molecules are largely found within minerals linked to aqueous processes, suggesting that these processes may have had a key role in organic synthesis, transport from their point of origin, or preservation.

Sunanda Sharma↗

NASA NTRS1996

Muscle organizers in Drosophila: the role of persistent larval fibers in adult flight muscle development

In many organisms muscle formation depends on specialized cells that prefigure the pattern of the musculature and serve as templates for myoblast organization and fusion. These include muscle pioneers in insects and muscle organizing cells in leech. In Drosophila, muscle founder cells have been proposed to play a similar role in organizing larval muscle development during embryogenesis. During metamorphosis in Drosophila, following histolysis of most of the larval musculature, there is a second round of myogenesis that gives rise to the adult muscles. It is not known whether muscle founder cells organize the development of these muscles. However, in the thorax specific larval muscle fibers do not histolyze at the onset of metamorphosis, but instead serve as templates for the formation of a subset of adult muscles, the dorsal longitudinal flight muscles (DLMs). Because these persistent larval muscle fibers appear to be functioning in many respects like muscle founder cells, we investigated whether they were necessary for DLM development by using a microbeam laser to ablate them singly and in combination. We found that, in the absence of the larval muscle fibers, DLMs nonetheless develop. Our results show that the persistent larval muscle fibers are not required to initiate myoblast fusion, to determine DLM identity, to locate the DLMs in the thorax, or to specify the total DLM fiber volume. However, they are required to regulate the number of DLM fibers generated. Thus, while the persistent larval muscle fibers are not obligatory for DLM fiber formation and differentiation, they are necessary to ensure the development of the correct number of fibers.

Non-NASA Center↗

NASA NTRS1998

Sea Ice on the Southern Ocean

Year-round satellite records of sea ice distribution now extend over more than two decades, providing a valuable tool to investigate related characteristics and circulations in the Southern Ocean. We have studied a variety of features indicative of oceanic and atmospheric interactions with Antarctic sea ice. In the Amundsen & Bellingshausen Seas, sea ice extent was found to have decreased by approximately 20% from 1973 through the early 1990's. This change coincided with and probably contributed to recently warmer surface conditions on the west side of the Antarctic Peninsula, where air temperatures have increased by approximately 0.5 C/decade since the mid-1940's. The sea ice decline included multiyear cycles of several years in length superimposed on high interannual variability. The retreat was strongest in summer, and would have lowered the regional mean ice thickness, with attendant impacts upon vertical heat flux and the formation of snow ice and brine. The cause of the regional warming and loss of sea ice is believed to be linked to large-scale circulation changes in the atmosphere and ocean. At the eastern end of the Weddell Gyre, the Cosmonaut Polyna revealed greater activity since 1986, a recurrence pattern during recent winters and two possible modes of formation. Persistence in polynya location was noted off Cape Ann, where the coastal current can interact more strongly with the Antarctic Circumpolar Current. As a result of vorticity conservation, locally enhanced upwelling brings warmer deep water into the mixed layer, causing divergence and melting. In the Ross Sea, ice extent fluctuates over periods of several years, with summer minima and winter maxima roughly in phase. This leads to large interannual cycles of sea ice range, which correlate positively with meridinal winds, regional air temperatures and subsequent shelf water salinities. Deep shelf waters display considerable interannual variability, but have freshened by approximately 0.03/decade since the late 1950's. That could have slowed the thermohaline circulation beneath the Ross Ice Shelf and the properties or volume of local bottom water production.

Jacobs, Stanley S.↗

NASA NTRS1988

Polynyas in the Southern Ocean

The formation of large regions of open ocean in the pack ice near Antarctica called polynyas is discussed. The role of the meridional circulation pattern of the Southern Ocean, of buoyancy, and of wind in the formation of polynyas is shown. The different characteristics and causes of coastal and open-ocean polynyas are pointed out.

Gordon, Arnold L.↗

NASA NTRS1974

Geologic information from satellite images

The author has identified the following significant results. Extracting geologic information from ERTS and Skylab/EREP images is best done by a geologist trained in photointerpretation. The information is at a regional scale, and three basic types are available: rock and soil, geologic structures, and landforms. Discrimination between alluvium and sedimentary or crystalline bedrock, and between units in thick sedimentary sequences is best, primarily because of topographic expression and vegetation differences. Discrimination between crystalline rock types is poor. Folds and fractures are the best displayed geologic features. They are recognizable by topographic expression, drainage patterns, and rock or vegetation tonal patterns. Landforms are easily discriminated by their familar shapes and patterns. It is possible to optimize the scale, format, spectral bands, conditions of acquisition, and sensor systems for best geologic interpretation. Several examples demonstrate the applicability of satellite images to tectonic analysis and petroleum and mineral exploration.

Lee, K.↗

NASA NTRS1982

Interface control document between the NASA Goddard Space Flight Center (GSFC) and Department of Interior EROS Data Center (EDC) for LANDSAT-D. Thematic mapper high resolution 241 mm film

The 241 mm photographic product produced by the Goddard Space Flight Center Data Management System for LANDSAT-D is described. Film type and format, image dimensions, frame ID, gray scale, resolution patterns, registration marks, etc. are addressed.

Source record↗

NASA NTRS1983

Statistical mechanics of neocortical interactions - Dynamics of synaptic modification

A recent study has demonstrated that several scales of neocortical interactions can be consistently analyzed with the use of methods of modern nonlinear nonequilibrium statistical mechanics. The formation, stability, and interaction of spatial-temporal patterns of columnar firings are explicitly calculated, to test hypothesized mechanisms relating to information processing. In this context, most probable patterns of columnar firings are associated with chemical and electrical synaptic modifications. It is stressed that synaptic modifications and shifts in most-probable firing patterns are highly nonlinear and interactive sets of phenomena. A detailed scenario of information processing is calculated of columnar coding of external stimuli, short-term storage via hysteresis, and long-term storage via synaptic modification.

Ingber, L.↗

NASA NTRS1983

Nickel-iron spherules in tektites - Non-meteoritic in origin

The concentrations of several diagnostic trace elements were determined in two comparatively large NiFe spherules extracted from tektites. The purpose of the study was to obtain some clues about the chemistry of the projectile that is presumed responsible for the formation of these tektites. However, the trace element pattern is distinctly terrestrial implying that the spherules are the result of in-situ reduction of the host rock and are not meteoritic in origin.

Ganapathy, R.↗

NASA NTRS1985

North American vegetation patterns observed with the NOAA-7 advanced very high resolution radiometer

Spectral vegetation index measurements derived from remotely sensed observations show great promise as a means to improve knowledge of land vegetation patterns. The daily, global observations acquired by the advanced very high resolution radiometer, a sensor on the current series of U.S. National Oceanic and Atmospheric Administration meteorological satellites, may be particularly well suited for global studies of vegetation. Preliminary results from analysis of North American observations, extending from April to November 1982, show that the vegetation index patterns observed correspond to the known seasonality of North American natural and cultivated vegetation. Integration of the observations over the growing season produced measurements that are related to net primary productivity patterns of the major North American natural vegetation formations. Regions of intense cultivation were observed as anomalous areas in the integrated growing season measurements. Significant information on seasonality, annual extent and interannual variability of vegetation photosynthetic activity at continental and global scales can be derived from these satellite observations.

Goward, S. N.↗

NASA NTRS1987

MHD aspects of magnetotail dynamics

The equations of ideal MHD represent the conservation of mass, momentum, and energy; thus, MHD must, in some broad sense, provide a correct description of large-scale structure of the earth's magnetosphere. However, steady-state, ideal MHD (the simplest description) allows only a static interaction between the solar wind and the magnetosphere. Hence an MHD theory of magnetospheric dynamics must involve unsteady flow turbulence, such as might be generated by Kelvin-Helmholtz turbulence at the magnetopause, and dissipative transport, such as reconnection, which violates ideal MHD. This brief review summarizes recent theoretical efforts to explore and extend the early MHD magnetospheric models of Axford and Petschek. Analytic calculations show that steady convection in the magnetotail is nearly impossible. Global magnetospheric simulations exhibit substorm reconnection phenomena for southward IMF and predict a novel convection pattern for northward IMF. Reconnection simulations show plasmoid formation and field-aligned current flows in the tail. The Kelvin-Helmholtz instability can provide a strong anomalous viscosity which can drive the viscous convection system.

Coroniti, F. V.↗

NASA NTRS1990

Temporal and vertical distribution of acidity and ionic composition in clouds - Comparison between modeling results and observations

Cyclic temporal variations of pH and ionic concentration in sampled clouds which traversed the Mt. Mitchell State Park (North Carolina) site during the summers of 1986, 1987, and 1988 are reported. These clouds typically had a measured pH minimum during their initial and final stages. The cause of this basic cylic pattern is attributed to sampling at different vertical levels of the cloud. This is substantiated by visual observations made while sampling. The results also suggest that the measured pH patterns do not always exhibit minima during the formative and dissipative stages of the cloud, apparently in response to the underlying dynamical processes. The relationship between temporal pH measurements made at a stationary site to vertical cloud levels provides insights into the physical processes (e.g., nucleation scavenging near cloud base, dry air entrainment near cloud top) influencing the observed cloud-water chemistry on a real-time basis and would improve cloud chemistry models.

Defelice, T. P.↗

NASA NTRS1994

Patches in the polar ionosphere: UT and seasonal dependence

The seasonal and Universal Time (UT) dependencies of patches in the polar ionosphere are simulated using the Utah State University time dependent ionospheric model (TDIM). Patch formation is achieved by changing the plasma convection pattern in response to temporal changes in the interplanetary magnetic field (IMF) B(sub y) component during periods of southwrd IMF. This mechanism redirects the plasma flow from the dayside high-density region, which is the source of the tongue of ionization (TOI) density feature, through the throat and leads to patches, rather than a continuous TOI. The model predicts that the patches are absent at winter solstice (northern hemisphere) between 0800 and 1200 UT and that they have their largest seasonal intensity at winter solstice between 2000 and 2400 UT. Between winter solstice and equinox, patches are strong and present all day. Patches are present in summer as well, although their intensity is only tens of percent above the background density. These winter-to-equinox findings are also shown to be consistent with observations. The model was also used to predict times at which patch observations could be performed to determine the contributions from other patch mechanisms. This observational window is +/- 20 days about winter solstice between 0800 and 1200 UT in the northern hemisphere. In this observational window the TOI is either absent or reduced to a very low density. Hence the time dependent electric field mechanism considered in this study does not produce patches, and if they are observed, then they must be due to some other mechanism.

Sojka, J. J.↗

NASA NTRS2001

Liquid Crystals Derived from 2-phenyl-isoindoles: Synthesis and Characterization

2-Phenyl-isoindole was investigated as the rigid core unit in a series of asymmetric mesogenic molecules. When the 2-phenyl-isoindole core was terminated with a hexyl tail, no mesophase formation could be observed. When 4-n-(tridecafluorohexyl) was used, however, we observed both monotropic and enantiotropic phase behavior. We found that most functionalities at the anhydride 5-position results in the formation of smectic A (SmA) phases in the temperature range of 70-180 C. Functionalities at the anhydride 4-position suppress mesophase formation. Large substituents (-Br, -NO2) and symmetric substitution patterns (5,6-dichloro, 4,7-dichloro and 4,5,6,7-tetrachloro) on the anhydride moiety increase the melting point and destabilize the mesophase. Temperature dependent X-ray diffraction experiments suggest an interdigitated SmA packing for this family of compounds.

Jow, Kenny G.↗