Investigation of hydrothermal carbonization and chemical activation process conditions on hydrogen storage in loblolly pine-derived superactivated hydrochars
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Increasing concerns about global carbon emissions due to fossil fuel use has created interest in renewable fuel alternatives, such as lignocellulosic biomass. With an estimated global biomass production probability ten-fold higher than projected need, functionalizing and scaling biomass conversion processes, like pyrolysis, is a promising component of a diverse sustainable energy program (Kan, Strezov, & Evans, 2016). Pyrolysis reactors employed in biomass conversion often encounter the known problem of screw feeder plugging, halting work and reducing efficiency of biorefineries. Although the screw feeder is not heated directly, conductive heat transfer from the fluidized bed pyrolysis reactor creates a temperature gradient, where particles experience temperatures between 22°C and 500°C from the time they enter the feeder to being emptied into the reactor (Digman, Joo, & Kim, 2009; Nieminen & Folke, 1982). The impact of unintentional heating on this highly variable feedstock may result in particle morphology modification, surface texture transformation, and the evolution of viscous compounds and may contribute to screw feeder plugging (Haas, Nimlos, & Donohoe, 2009; Ingram et al., 2008). We hypothesized that particles of various anatomical fractions (including needles, branches, bark, cambium, and whitewood) will experience dramatic changes during this heating regime, which will be characterized by decreased particle size, increased surface roughness, degradation of key structural macromolecules, and generation of viscous compounds that would result in increased particle friction and cohesion, contributing to screw feeder plugging.
The conversion of biomass feedstocks into fuels and chemicals using fast pyrolysis is a promising approach to renewable energy. Feed screws that convey biomass to pyrolysis reactors, however, often encounter plugging. Indirect heating of the feed screw occurs due to contact with the pyrolysis chamber, resulting in a heating gradient ranging from ambient temperature (22 °C) to reactor temperature (500 °C). Given that major cell wall macromolecules, such as lignin, cellulose, and hemicellulose, begin to produce bio-oils and volatile resin acid compounds within this temperature gradient, we hypothesized that indirect heating during feed screw conveyance is sufficient to cause premature degradation of biomass. We characterized this degradation by observing increases in surface roughness, changes in overall particle morphology, and the production and deposition of bio-oils on biomass particle surfaces. Correlative analysis between optical in situ hot-stage microscopy, confocal Raman spectroscopy, and SEM analysis revealed that heating at temperatures as low as 375 °C caused significant increases in surface roughness, with large fissures forming between and within cell walls. Additionally, droplets of bio-oil were observed on particles, especially in the bark and cambium samples. This work suggests that these phenomena contribute to particle agglomeration, leading to feed screw plugging, and that engineering a solution to cool the feed screw could prevent particle agglomeration and reduce plugging incidents, thereby increasing biomass processing efficiency.
Wildfires inject biomass burning organic aerosols (BBOA) into the atmosphere. During their lifetimes of weeks to months, they are exposed to ultraviolet (UV) irradiation. Viscosity and phase behaviour are essential properties for understanding their chemical and climate impacts. Here, we quantify changes in viscosity and phase behavior after UV exposure. After an atmospheric equivalent of 8.7 days of boundary layer UV exposure, BBOA develop a highly viscous (glassy) outer phase with a viscosity at least five orders of magnitude higher than unaged BBOA, which persists up to at least 58% relative humidity. High-resolution mass spectrometry indicates that UV-aging increases oxidation and molecular weight. Using our viscosity results, we predict that UV-aged BBOA are frequently glassy above ~2.5 km and can have viscosities up to eight orders of magnitude higher than unaged particles in some atmospheric regions, which may influence lifetimes of pollutants and brown carbon, and impact stratospheric ozone chemistry.
Iron (Fe) is crucial for metabolic functions of living organisms. Plants access occluded Fe through interactions with rhizosphere microorganisms and symbionts. Yet, the interplay between Fe addition and plant–mycorrhizal interactions, especially the molecular mechanisms underlying mycorrhiza-assisted Fe processing in plants, remains largely unexplored. Here, we conducted mesocosms in Pinus plants inoculated with different ectomycorrhizal fungi (EMF) Suillus species under conditions with and without Fe coatings. Meta-transcriptomic, biogeochemical, and X-ray fluorescence imaging analyses were applied to investigate early-stage mycorrhizal roots. While Fe addition promoted Pinus growth, it concurrently reduced mycorrhiza formation rate, symbiosis-related metabolites in plant roots, and aboveground plant carbon and macronutrient content. This suggested potential trade-offs between Fe-enhanced plant growth and symbiotic performance. However, the extent of this trade-off may depend on interactions between host plants and EMF species. Interestingly, dual EMF species were more effective at facilitating plant Fe uptake by inducing diverse Fe-related functions than single-EMF species. This subsequently triggered various Fe-dependent physiological and biochemical processes in Pinus roots, significantly contributing to Pinus growth. However, this resulted in a greater carbon allocation to roots, relatively reducing the aboveground plant carbon content. Our study offers critical insights into how EMF communities rebalance benefits of Fe-induced effects on symbiotic partners.
We evaluated area-based approaches (ABAs) to light detection and ranging (lidar) predictions of plot- and stand-level forest attributes (tree count, height, basal area, volume, aboveground biomass, broadleaf/conifer, and diameter at breast height — “diameter”). ABA methods included post-stratification (PS), ordinary least squares (OLSs) regression, k nearest neighbors ( kNN), and random forest (RF). This study was conducted on the Savannah River Site in South Carolina, USA. Plot- and stand-level predictions were validated against fixed-radius 0.04 ha (0.1 acre) plots in 49 ≈2.0 ha (5 acre) stands. Our findings demonstrate that lidar can be incorporated operationally into forest inventory systems to provide stand-level inferences for a wide range of forest attributes. Volume predictions for specific diameter classes, however, often fared poorly (root mean squared error (RMSE) > 100%) for the methods we explored, especially for larger (less common) diameter trees. Stand-level results were consistently better than pixel-level results (10–200+ percentage points). kNN and RF performed similarly and better than OLS and PS, but RF was the most robust to model configurations, while kNN has practical advantages such as simultaneous predictions of many attributes.
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Temporal partitioning of life history traits among syntopic reptiles can facilitate co-occurrence, but may be influenced by environmental factors and evolutionary history. We used 24 years of continuous capture data in the Florida sandhills to evaluate the timing and duration of hatching, maturation and/or surface activity for ten reptile species, spanning multiple clutch strategies, taxonomic relationships, and habits. We hypothesised: i) species would differ in seasonal timing of hatching and maturation; ii) hatching and maturation periods would be more seasonally-synchronised in fossorial than terrestrial or semi-aquatic reptiles; iii) monthly and annual temperature anomalies would be positively related to hatching, maturation, and surface activity anomalies, and iv) groupings of reptiles by clutch strategy, taxonomic relationship, and habit, would explain more variation in the timing and duration of hatching and maturation than species alone. Seasonal timing of response variables varied widely among species. Hatching peaked for > 1 species during most calendar months. Maturation and surface activity periods ranged from aseasonal to highly-seasonal among species. Hatching began 1.5 months earlier and was more prolonged for terrestrial than fossorial species overall. Hatching peaked in early to mid-summer for terrestrial and fossorial species, and winter for the semi-aquatic Kinosternon subrubrum. Terrestrial and fossorial species did not differ in average timing, duration, or overlap of maturation periods; semi-aquatic Liodytes pygaea matured more consistently across all seasons than other species. Monthly temperature anomalies were negatively correlated with monthly maturation for Plestiodon egregius. Annual temperature and precipitation anomalies were related to annual hatching, maturation, and surface activity trends for several species. Taxonomic relationship, habit, and species explained some variation in hatching and maturation timing and duration. Our results illustrate the influence of environment and evolutionary relationships on the timing of important life history traits. Keywords: Age class, Drift fence, Community, Interspecific, Life history
Abstract. Unambiguous identification of past episodes of ice sheet thinning below the modern surface and grounding line retreat inboard of present requires recovery and exposure dating of subglacial bedrock. Such efforts are needed to understand the significance and potential future reversibility of ongoing and projected change in Antarctica. Here we evaluate the suitability for subglacial bedrock drilling of sites in the Hudson Mountains, which are located in the Amundsen Sea sector of West Antarctica. We use an ice sheet model and field data – geological observations, glaciological observations and bedrock samples from nunataks, and ground-penetrating radar from subglacial ridges – to rate each site against four key criteria: (i) presence of ridges extending below the ice sheet, (ii) likelihood of increased exposure of those ridges if the grounding line was inboard of present, (iii) suitability of bedrock for drilling and geochemical analysis, and (iv) accessibility for aircraft and drilling operations. Our results demonstrate that although no site in the Hudson Mountains is perfect for this study when assessed against all criteria, the accessibility, N–S orientation and basaltic bedrock lithology of Winkie Nunatak's southernmost ridge (74.86° S, 99.77° W) make it a feasible site both for drilling and subsequent cosmogenic nuclide analysis. Furthermore, the ridge is strewn with glacial erratics at all elevations, providing valuable constraints on its early Holocene deglacial history. Based on our experiences during this study, we conclude with a series of recommendations for assessing site suitability for future bedrock drilling campaigns. We emphasise the importance of consulting a range of expertise prior to drilling and ensuring that sufficient field reconnaissance is undertaken (including obtaining detailed grids of radar survey data and bedrock samples).
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Ground and aerial imaging techniques to detect tree damage caused by bark beetles in forested areas
The author has identified the following significant results. In the Robinson mining district which included the Ruth porphyry copper mines, three large positive aeromagnetic anomalies exist over a Tertiary volcanic area north west of Ruth. Prior studies of this area have suggested that the volcanics may or may not be the cause of the anomalies. Skylab Sl90A imagery, however, indicates possible outcrops in the volcanic area of the Paleozoic sediments. Field studies or ground truth verify the existence of these inliers suggesting that the magnetic anomaly may be the result of a buried intrusive body for which potential mineralization has been covered by the post-ore blanket of volcanics. The area is being mapped in more detail and samples of mercury-bearing soil-gas area being collected within and outside the area.