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NASA NTRS2001

Stellar Evolution in Starburst Galaxies

The main thrust of the program was to obtain UV spectroscopy of a number of massive and hot luminous (OB type) stars in the nearby galaxy called the Small Magellanic Cloud (SMC). The objective was to analyze their atmospheres and winds so as to determine the effect of the lower abundance of the SIVIC on these parameters. Furthermore, the differences in evolution could be investigated. Additionally, the UV spectra themselves would be suitably weighted and systematically combined to provide a template for comparison to very distant galaxies formed in the early history of the Universe which also have a low abundance of elements. The spectra have been obtained and the analysis is proceeding, primarily by the groups in Munich and at STScl who are the leads for this project. Given the important role of the nearby SMC galaxy as a template of low metal abundance, I have begun to investigate the YOUNGEST phases of massive star birth, before the most massive and hottest stars become optically visible. Typically these stars form in clusters, in some cases having tens to hundreds of OB type stars. In this phase, each star is still buried in its natal cloud and visible only in the infrared (IR) from its self-heated dust and/or from radio free-free emission of the surrounding hydrogen (HII) region. Efforts to find and identify these buried clusters were conducted using a large radio telescope. A number of these were found and further analysis of the data is underway. These clusters are not visible optically, but ought to be seen in the IR, and are a likely topic for HST photometry on NICMOS. A proposal to do this will be made next semester. These objects are the precursors of the optically visible clusters that contain massive and hot luminous stars.

Conti, Peter↗

NASA NTRS2012

Compound-Specific Isotopic Analysis of Meteoritic Amino Acids as a Tool for Evaluating Potential Formation Pathways

Measurements of stable hydrogen, carbon, and nitrogen isotopic ratios (delta D, delta C-13, delta N-15) of organic compounds can reveal information about their origin and formation pathways. Several formation mechanisms and environments have been postulated for the amino acids detected in carbonaceous chondrites. As each proposed mechanism utilizes different precursor molecules, the isotopic signatures of the resulting amino acids may point towards the most likely of these proposed pathways. The technique of gas chromatography coupled with mass spectrometry and isotope ratio mass spectrometry provides compound-specific structural and isotopic information from a single splitless injection, enhancing the amount of information gained from small amounts of precious samples such as carbonaceous chondrites. We have applied this technique to measure the compound-specific C, N, and H isotopic ratios of amino acids from seven CM and CR carbonaceous chondrites. We are using these measurements to evaluate predictions of expected isotopic enrichments from potential formation pathways and environments, leading to a better understanding of the origin of these compounds.

Elsila, Jamie E.↗

NASA NTRS1997

Low Temperature Synthesis, Chemical and Electrochemical Characterization of LiNi(x)Co(1-x)O2 (0 less than x less than 1)

A new method of synthesis for the solid solution cathode materials LiNi(x)Co(1-x)O2 (0 less than x less than 1) involving enhanced reactions at temperatures less than or equal to 700 deg. C, between metal oxy-hydroxide precursors MOOH (M = Ni, Co) and Li-salts (Li2CO3, LiOH, and LiNO3) has been investigated. The effects of synthesis conditions and sources of Li, on phase purity, microstructure, and theoretical electrochemical capacity (total M(3+) content) are characterized by powder X-ray diffraction analysis, scanning electron microscopy, chemical analysis and room temperature magnetic susceptibility. An attempt has been made to correlate the electrochemical properties with the synthesis conditions and microstructure.

Nanjundaswamy, K. S.↗

NASA NTRSDate not supplied

Olivine Mineralogy of Asteroid Ryugu Samples and CI Chondrites: Further Evidence for their Common Origin

Initial analysis of asteroid Ryugu samples has revealed that they were mm-mm scale brecciamostly composed of aqueously altered phases (e.g., Mg-Fe phyllosilicates, carbonates) and showed remarkablesimilarities to CI chondrites in mineralogy and chemistry [e.g., 1,2]. Our detailed analysis of Ryugu samples hasdetected small amounts (<<1 vol.%) of unaltered silicates that would escape severe aqueous alteration [3]. Olivine isthe most abundant (>90 vol%) phase among such unaltered silicates. Although most Ryugu olivine grains aresmaller than 5 mm, they bear important information about the precursors of the parent Ryugu asteroid. In thisabstract we report additional results of olivine mineralogical study of Ryugu samples, and especially compare witholivine grains in CI chondrites (Ivuna and Orgueil) to further discuss their relationship and possible common origin.

T. Mikouchi↗

NASA NTRSDate not supplied

Simulation of Oxidative Etch Pit Formation and Growth on FiberForm

Erosion of carbon surfaces due to oxidation does not occur uniformly but through the formation of localized etch pits because of active surface sites. These active sites are formed due to the presence of atomic defects on the carbon surface and have much higher reactivity compared to average non-defective sites. Thus, these active sites are the first to react during ablation, resulting in their removal. This causes all the neighboring atoms to be defective, and increasing their reactivity, thus leading to localized carbon removal around these “active” sites. In this manner, these highly reactive defects serve as nucleation sites for the formation and growth of etch pits, with detrimental effects on the structural integrity. In order to understand the influence of these etch pits on the material properties of carbon fiber microstructures, we have developed a new capability within direct simulation Monte Carlo (DSMC) to capture the etch pit formation process. This capability is developed within the DSMC code SPARTA (Stochastic PArallel Rarefied-gas Time-accurate Analyzer) and can model the material removal in the presence of active sites leading to the formation of etch pits. The focus of the current work will be to study the effect of etch pits on the material properties of FiberForm, the precursor substrate of the PICA Thermal Protection System (TPS) material. The microstructure of virgin FiberForm obtained directly from X-ray microtomography scans is used within SPARTA to obtain the ablated geometries with etch pits. These pitted microstructures are then imported into the Porous Microstructure Analysis (PuMA) software and various material properties such as thermal conductivity, elasticity, and permeability are computed. The variation of these properties because of the complex evolution of the surface topology due to the formation of etch pits is studied and analyzed. Furthermore, the effect of pitting is compared to the case of uniform radial shrinking of fibers, which has been the standard for modelling ablation of carbon structures, and significant differences are observed. Thus, a physically realistic model of material removal through the formation of etch pits will be helpful in predicting the degradation of carbon-based TPS more accurately during oxidation; as well as other mechanisms such as spallation, which involves the removal of chunks of material into the flow due to the growth of etch pits. This will ultimately improve our understanding of the failure modes in these materials due to ablation.

DSMC↗

NASA NTRSDate not supplied

Simulation of Oxidative Etch Pit Formation and Growth on FiberForm

DSMC↗

NASA NTRS2002

Modeling of the HiPco process for carbon nanotube production. II. Reactor-scale analysis

The high-pressure carbon monoxide (HiPco) process, developed at Rice University, has been reported to produce single-walled carbon nanotubes from gas-phase reactions of iron carbonyl in carbon monoxide at high pressures (10-100 atm). Computational modeling is used here to develop an understanding of the HiPco process. A detailed kinetic model of the HiPco process that includes of the precursor, decomposition metal cluster formation and growth, and carbon nanotube growth was developed in the previous article (Part I). Decomposition of precursor molecules is necessary to initiate metal cluster formation. The metal clusters serve as catalysts for carbon nanotube growth. The diameter of metal clusters and number of atoms in these clusters are some of the essential information for predicting carbon nanotube formation and growth, which is then modeled by the Boudouard reaction with metal catalysts. Based on the detailed model simulations, a reduced kinetic model was also developed in Part I for use in reactor-scale flowfield calculations. Here this reduced kinetic model is integrated with a two-dimensional axisymmetric reactor flow model to predict reactor performance. Carbon nanotube growth is examined with respect to several process variables (peripheral jet temperature, reactor pressure, and Fe(CO)5 concentration) with the use of the axisymmetric model, and the computed results are compared with existing experimental data. The model yields most of the qualitative trends observed in the experiments and helps to understanding the fundamental processes in HiPco carbon nanotube production.

Validation Studies↗

NASA NTRS2016

Synthesis, Structure, Characterization, and Decomposition of Nickel Dithiocarbamates: Effect of Precursor Structure and Processing Conditions on Solid-State Products

Single-crystal X-ray structures of four nickel dithiocarbamate complexes, the homoleptic mixed-organic bis-dithiocarbamates Ni[S2CN(isopropyl)(benzyl)]2, Ni[S2CN(ethyl)(n-butyl)]2, and Ni[S2CN(phenyl)(benzyl)]2, as well as the heteroleptic mixed-ligand complex NiCl[P(phenyl)3][(S2CN(phenyl)(benzyl)], were determined. Synthetic, spectroscopic, structural, thermal, and sulfide materials studies are discussed in light of prior literature. The spectroscopic results are routine. A slightly distorted square-planar nickel coordination environment was observed for all four complexes. The organic residues adopt conformations to minimize steric interactions. Steric effects also may determine puckering, if any, about the nickel and nitrogen atoms, both of which are planar or nearly so. A trans-influence affects the Ni-S bond distances. Nitrogen atoms interact with the CS2 carbons with a bond order of about 1.5, and the other substituents on nitrogen display transoid conformations. There are no strong intermolecular interactions, consistent with prior observations of the volatility of nickel dithiocarbamate complexes. Thermogravimetric analysis of the homoleptic species under inert atmosphere is consistent with production of 1:1 nickel sulfide phases. Thermolysis of nickel dithiocarbamates under flowing nitrogen produced hexagonal or -NiS as the major phase; thermolysis under flowing forming gas produced millerite (-NiS) at 300 C, godlevskite (Ni9S8) at 325 and 350 C, and heazlewoodite (Ni3S2) at 400 and 450 C. Failure to exclude oxygen results in production of nickel oxide. Nickel sulfide phases produced seem to be primarily influenced by processing conditions, in agreement with prior literature. Nickel dithiocarbamate complexes demonstrate significant promise to serve as single-source precursors to nickel sulfides, a quite interesting family of materials with numerous potential applications.

microscopy↗

NASA NTRS1972

Summary of the nondestructive evaluation session

Advanced material systems and designs require improved nondestructive evaluation (NDE) techniques for quality control, failure analysis and properties monitoring. Some advanced NDE techniques such as infrared scanning systems, laser holographic applications and the use of the Mossbauer effect are outlined. Applications of these techniques are discussed for evaluating the new space shuttle external insulation materials, aircraft structures and engine components, and precursors to crack initiation and growth.

Stinebring, R. C.↗

NASA NTRS1974

Observation of a cosmic gamma-ray burst on Apollo 16. I - Temporal variability and energy spectrum

A cosmic gamma-ray event occurring April 27, 1972 at 10.68 UT was observed by gamma-ray and X-ray spectrometers on Apollo 16 as well as by Vela 6A. Analysis has yielded a detailed time profile of the entire event, an energy spectrum covering three order of magnitude (2.0 to 7.9 KeV and 0.067 to 5.1 MeV) and a source location. A well-defined onset prior to the main impulse period and a probable precursor are reported. The total energy of the event over the observed range was 2 x 10 to the minus 4th power ergs/sq cm. The data indicate the presence of a hard component which persists during the entire event, with a softer variable component becoming dominant during the most explosive burst portion.

Metzger, A. E.↗

NASA NTRS2002

Trajectories for High Specific Impulse High Specific Power Deep Space Exploration

Preliminary results are presented for two methods to approximate the mission performance of high specific impulse high specific power vehicles. The first method is based on an analytical approximation derived by Williams and Shepherd and can be used to approximate mission performance to outer planets and interstellar space. The second method is based on a parametric analysis of trajectories created using the well known trajectory optimization code, VARITOP. This parametric analysis allows the reader to approximate payload ratios and optimal power requirements for both one-way and round-trip missions. While this second method only addresses missions to and from Jupiter, future work will encompass all of the outer planet destinations and some interstellar precursor missions.

Polsgrove, T.↗

NASA NTRS1998

Comment on the Predicted Size of Cycle 23 Based on the Inferred Three-Cycle Quasi-Periodicity of the Planetary Index Ap

Recently, Ahluwalia [1998] reviewed the solar and geomagnetic data for the last 6 decades and remarked that these data "indicate the existence of a three-solar-activity-cycle quasi-periodicity in them." Futhermore, on the basis of this inferred quasi-periodicity, he asserted that cycle 23 represents the initial cycle in a new 3-cycle string, implying that it "will be more modest (a la cycle 17) with an annual mean sunspot number count of 119.3 +/- 30 at the maximum," a prediction that is considerably below the consensus prediction of 160 +/- 30 by Joselyn et al. [1997] and of similar predictions by others based on a variety of predictive techniques. Several major sticking points of Ahluwalia's presentation, however, must be redressed, and these issues form the basis of this comment. In particular, it is shown that Ahluwalia used inappropriate values of the Ap index in his analysis, that the inferred 3-cycle relationship which Ahluwalia claims for both Ap and SSN does not exist for the previous 6-cycle interval (prior to cycle 17) for SSN, that his inferred fit is only of marginal statistical significance (having r = 0.81), and that two alternative precursor fits (both with r = 0.96 or greater) exist which strongly suggest that R max for cycle 23 will be much larger than forecast by Ahluwalia (namely, about 168-187). Thus, caution must be exercised in accepting Ahluwalia's findings.

Hathaway, David H.↗

NASA NTRS2010

Towards Prognostics of Power MOSFETs: Accelerated Aging and Precursors of Failure

This paper presents research results dealing with power MOSFETs (metal oxide semiconductor field effect transistor) within the prognostics and health management of electronics. Experimental results are presented for the identification of the on-resistance as a precursor to failure of devices with die-attach degradation as a failure mechanism. Devices are aged under power cycling in order to trigger die-attach damage. In situ measurements of key electrical and thermal parameters are collected throughout the aging process and further used for analysis and computation of the on-resistance parameter. Experimental results show that the devices experience die-attach damage and that the on-resistance captures the degradation process in such a way that it could be used for the development of prognostics algorithms (data-driven or physics-based).

Celaya, Jose R.↗

NASA NTRS1984

Structural synthesis: Precursor and catalyst

More than twenty five years have elapsed since it was recognized that a rather general class of structural design optimization tasks could be properly posed as an inequality constrained minimization problem. It is suggested that, independent of primary discipline area, it will be useful to think about: (1) posing design problems in terms of an objective function and inequality constraints; (2) generating design oriented approximate analysis methods (giving special attention to behavior sensitivity analysis); (3) distinguishing between decisions that lead to an analysis model and those that lead to a design model; (4) finding ways to generate a sequence of approximate design optimization problems that capture the essential characteristics of the primary problem, while still having an explicit algebraic form that is matched to one or more of the established optimization algorithms; (5) examining the potential of optimum design sensitivity analysis to facilitate quantitative trade-off studies as well as participation in multilevel design activities. It should be kept in mind that multilevel methods are inherently well suited to a parallel mode of operation in computer terms or to a division of labor between task groups in organizational terms. Based on structural experience with multilevel methods general guidelines are suggested.

Schmit, L. A.↗

NASA NTRS1982

Exchange of sulfur between the free troposphere, marine boundary layer, and the sea surface

A steady state analysis has been made of the sources and sinks of sulfur in the remote marine atmosphere and of the steady state exhanges of SO2 and sulfate between the sea, boundary layer, and free troposphere. Two situations were examined: an area of high biological productivity (Gulf of Guinea) and an area of low productivity (tropical Atlantic). The results of the analysis suggest that about one-third of the background concentrations of SO2 and excess sulfate observed in the remote marine atmosphere mixes in from the free troposphere, with the balance, about 100 micrograms S/sq m per day, attributed to the local oxidation of reduced sulfur-bearing precursors in the boundary layer.

Kritz, M. A.↗

NASA NTRS1994

Comparison and analysis of aircraft measurements and mesoscale atmospheric chemistry model simulations of tropospheric ozone

The Regional Acid Deposition Model (RADM) has been applied to several of the field experiments which were part of the Acid Models Operational and Diagnostic Evaluation Study (Acid MODES). The experiment which was of particular interest with regards to ozone photochemistry involved horizontal zig-zag flight patterns (ZIPPER) over an area from the eastern Ohio River valley to the Adirondacks of New York. Model simulations by both the standard resolution RADM (delta x = 80 km) and the nested grid RADM (delta x = 26.7 km) compare well to measurements in the low emission regions in central Pennsylvania and upstate New York, but underestimate in the high emission upper Ohio River valley. The nested simulation does considerably better, however, than the coarse grid simulation in terms of horizontal pattern and concentration magnitudes. Analysis of NO(x) and HO(x) concentrations and photochemical products rates of ozone show that the model's response to large point source emissions is very unsystematic both spatially and temporally. This is due to the models instability to realistically simulate the small scale (subgrid) gradients in precursor concentrations in and around large point source plumes.

Pleim, Jonathan E.↗

NASA NTRS2006

Development of In Situ Instruments for Planetary Exploration - Unique Challenges in Design, Development, and Execution

A viewgraph presentation describing in situ instruments for NASA missions is shown. The topics include: 1) In Situ Instrumentation; 2) Planetary Extremes; 3) Mars Surface Environment; 4) Lunar Precursor Mission Environment; 5) Europa Surface Analogue; 6) Other Parameters; 7) Space In Situ Instrumentation still in its Infancy; 8) Needed Capabilities For In Situ Science; 9) Framework For Putting The Pieces Together; 10) The Wild World of Astrobiology; 11) Timeline; 12) Example: MOD; 13) In Situ Sample Analysis Laboratories are more complex; 14) technologies In Situ Sample Analysis Requires Integration of Many Emerging Advanced Concepts; 15) Supporting technologies for In Situ Laboratories; 16) Micro-laboratory example; 17) In Situ Instrument Classes; and 18) Key for Analytical Instrument:Sample Preparation.

In Situ Instrumentation↗

NASA NTRSDate not supplied

Flight Testing of In-Time Safety Assurance Technologies for UAS Operations

Ongoing research at NASA is driven by a strategic plan defined by the Aeronautics Research Mission Directorate and a vision for future In-Time Aviation Safety Management Systems (IASMS) as described by the National Academies. In both visions, system safety awareness and provision are expanded through increased access to relevant data; integrated analysis and predictive capabilities; improved real-time detection and alerting of domain-specific hazards; decision support, and in some cases, automated risk mitigation strategies. One primary research focus is to develop means by which more timely (i.e., “in-time”) actions may be taken to mitigate precursors, anomalies, or trends that are observed during operations. In this paper, we describe such means as a collection of Services, Functions, and Capabilities (SFCs) that are supported by an underlying information system. For example, an integrated risk assessment capability is envisioned that continuously monitors safety-related metrics and margins and recommends timely operational changes. Assessment functions and/or services can be based on data analytics and predictive models derived from heterogeneous data sets that span relevant indicator metrics and their time histories. Likewise, on-board functions can identify and reduce susceptibility to precursor conditions that have led (and can lead) to aircraft loss-of-control or out-of-control accidents. This paper summarizes development and testing of such an information system tailored to hazards anticipated for future highly autonomous flight missions near and over densely populated areas. Testing is accomplished via simulation and by using small, unmanned aircraft operating over a test range at NASA’s Langley Research Center. Flight plans and test scenarios are defined to emulate several use-cases, including package delivery; reconnaissance; fire management; and urban air taxi vertiport operations. Two test phases are summarized with Phase 1 occurring in (2019-2020) and Phase 2 ongoing (2021-present). Results focus on SFC performance, technology readiness level assessment, and requirements discovery/validation. Companion papers are cited throughout for additional details on the recent testing.

safety management↗