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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1996

Low Crossover Polymer Electrolyte Membranes for Direct Methanol Fuel Cells

Direct Methanol Fuel Cells (DMFC's) using polymer electrolyte membranes are promising power sources for portable and vehicular applications. State of the art technology using Nafion(R) 117 membranes (Dupont) are limited by high methanol permeability and cost, resulting in reduced fuel cell efficiencies and impractical commercialization. Therefore, much research in the fuel cell field is focused on the preparation and testing of low crossover and cost efficient polymer electrolyte membranes. The University of Southern California in cooperation with the Jet Propulsion Laboratory is focused on development of such materials. Interpenetrating polymer networks are an effective method used to blend polymer systems without forming chemical links. They provide the ability to modify physical and chemical properties of polymers by optimizing blend compositions. We have developed a novel interpenetrating polymer network based on poly (vinyl - difluoride)/cross-linked polystyrenesulfonic acid polymer composites (PVDF PSSA). Sulfonation of polystyrene accounts for protonic conductivity while the non-polar, PVDF backbone provides structural integrity in addition to methanol rejection. Precursor materials were prepared and analyzed to characterize membrane crystallinity, stability and degree of interpenetration. USC JPL PVDF-PSSA membranes were also characterized to determine methanol permeability, protonic conductivity and sulfur distribution. Membranes were fabricated into membrane electrode assemblies (MEA) and tested for single cell performance. Tests include cell performance over a wide range of temperatures (20 C - 90 C) and cathode conditions (ambient Air/O2). Methanol crossover values are measured in situ using an in-line CO2 analyzer.

Prakash, G. K. Surya↗

NASA NTRS1982

The effects of weld-repair and hot isostatic pressing on the fracture properties of Ti-5Al-2.5Sn ELI castings

The Ti-5Al-2.5Sn extremely low interstitial alloy employed in the large castings which form the critical attachment fittings of the Space Shuttle External Tank was selected because of its high fracture resistance at cryogenic temperatures. Casting was selected over alternative fabrication methods because of its lower cost and adaptability to design changes, although it was found necessary to weld-repair surface and subsurface casting defects in order to reduce the scrap rate and maintain the inherent cost advantage of the castings. Hot Isostatic Pressing was experimentally found to heal the surface and internal defects of the castings, but did not improve tensile or fracture properties and was therefore rejected as a production technique. Production castings are instead weld-repaired, without any mechanical property degradation.

Misra, M. S.↗

NASA NTRS1990

Multistep fluorescence gated proportional counters

A proportional counter is introduced in which the levels of energy and spatial resolutions and background rejection permit the application of the device to X-ray astronomy. A multistep approach is employed in which photons cause a signal that triggers the system and measures the energy of the incident photon. The multistep approach permits good energy resolution from parallel geometry and from the imaging stage due to coupling of the imaging and amplification stages. The design also employs fluorescence gating to reduce background, a method that is compatible with the multistep technique. Use of the proportional counter is reported for NASA's supernova campaign, and the pair background is below 0.0001 counts/sq cm sec keV at the xenon k-edge. Potential improvements and applications are listed including the CASES, POF, and EXOSS mission programs.

Ramsey, Brian D.↗

NASA NTRS1993

Numerical experiments with model monophyletic and paraphyletic taxa

The problem of how accurately paraphyletic taxa versus monophyletic (i.e., holophyletic) groups (clades) capture underlying species patterns of diversity and extinction is explored with Monte Carlo simulations. Phylogenies are modeled as stochastic trees. Paraphyletic taxa are defined in an arbitrary manner by randomly choosing progenitors and clustering all descendants not belonging to other taxa. These taxa are then examined to determine which are clades, and the remaining paraphyletic groups are dissected to discover monophyletic subgroups. Comparisons of diversity patterns and extinction rates between modeled taxa and lineages indicate that paraphyletic groups can adequately capture lineage information under a variety of conditions of diversification and mass extinction. This suggests that these groups constitute more than mere "taxonomic noise" in this context. But, strictly monophyletic groups perform somewhat better, especially with regard to mass extinctions. However, when low levels of paleontologic sampling are simulated, the veracity of clades deteriorates, especially with respect to diversity, and modeled paraphyletic taxa often capture more information about underlying lineages. Thus, for studies of diversity and taxic evolution in the fossil record, traditional paleontologic genera and families need not be rejected in favor of cladistically-defined taxa.

Non-NASA Center↗

NASA NTRS2004

Experiences with Probabilistic Analysis Applied to Controlled Systems

This paper presents a semi-analytic method for computing frequency dependent means, variances, and failure probabilities for arbitrarily large-order closed-loop dynamical systems possessing a single uncertain parameter or with multiple highly correlated uncertain parameters. The approach will be shown to not suffer from the same computational challenges associated with computing failure probabilities using conventional FORM/SORM techniques. The approach is demonstrated by computing the probabilistic frequency domain performance of an optimal feed-forward disturbance rejection scheme.

Kenny, Sean P.↗

NASA NTRS1994

Active Narrow-Band Vibration Isolation of Large Engineering Structures

We present a narrow-band tracking control method using a variant of the Least Mean Squares (LMS) algorithm to isolate slowly changing periodic disturbances from engineering structures. The advantage of the algorithm is that it has a simple architecture and is relatively easy to implement while it can isolate disturbances on the order of 40-50 dB over decades of frequency band. We also present the results of an experiment conducted on a flexible truss structure. The average disturbance rejection achieved is over 40 dB over the frequency band of 5 Hz to 50 Hz.

algorithm engineering structures noise vibration↗

NASA NTRS2016

Spiral Lamber's Problem with Generalized Logarithmic Spirals

Lambert’s problem subject to a continuous acceleration is solved using the family of generalized logarithmic spirals. Thanks to the existence of two first integrals related to the energy and angular momentum surprising analogies with the Keplerian case are found. A minimum-energy spiral transfer exists. Increasing the value of the constant of the generalized energy yields pairs of conjugate spiral trajectories. The properties of such spirals are strongly connected with the properties of conjugate Keplerian orbits. When the generalized constant of the energy reaches a critical value the two solutions degenerate into a pair of parabolic spirals, one of which connects the two vectors through infinity. From that point the spiral transfers become hyperbolic. Generalized logarithmic spirals admit closed-form solutions to all the required magnitudes including the time of flight, providing a deep insight into the dynamics of the problem. In addition, the maximum acceleration along the transfer is found analytically so the solutions that violate the design constraints on the maximum thrust acceleration can be rejected without any further computations. When the time of flight is fixed there is still a degree of freedom in the solution, related to a control parameter. Resonant transfers appear naturally thanks to the symmetry properties of the generalized logarithmic spirals. The problem of designing a low-thrust transfer between two bodies can be reduced to solving the corresponding spiral Lambert’s problem. In order to show the versatility of the method it is applied to the design of an asteroid tour and to explore launch opportunities to Mars.\

Roa, Javier↗

NASA NTRS2019

Thermal Environment Modeling Practices for the Descent Trajectory of Lunar Landers

With the current push to send landers back to the moon, properly modeling the thermal environment for the descent is critical. Descent in this paper is described as: descending from low lunar orbit to touch down on surface. There are several challenges during this period, including: many electronics (such as battery, avionics, transponder, etc…) have higher heat loads due to higher power levels, a significant portion of the view factor to space has been blocked out by the moon making heat rejection less efficient, components that normally do not have direct line of sight to the sun may get exposure due to the lander rotating to align for descent, and thruster firing will dump more heat into the lander. All of these factors combine during the most critical phase of a lander mission make it essential that the thermal environment has been properly set up during design and analysis. This paper presents one method of setting up the thermal environment during descent in Thermal Desktop and will also include some tips and tricks.

Szerszen, Alexander↗

NASA NTRS1992

New inertial actuator provides isolation and stabilization in microgravity conditions

Experiments in materials and fluids processing have been conducted, or are planned, that take advantage of the low-g environment offered by space-based platforms. While the specific goals of the experiments vary, a common objective is to see improved results from the processes over those that would be obtained from similar ground-based experiments. While the space-based processing environment does offer a low-g environment, it is not disturbance free. Results of experiments already conducted, particularly those in manned vehicles, show that spacecraft induced disturbances still limit what can be achieved in materials processing. The duration of actual micro-g level environments is shorter than desired and periods of milli-g activity levels are not uncommon. While small scale experiments can be configured to overcome some of the vehicle disturbance sources, larger scale processing devices and commercial activities will require alternative methods to reduce the influences of spacecraft vibrations. Applied Technology Associates, Inc., (ATA), in cooperation with NASA Lewis Research Center, is developing hardware to provide a sustained micro-g experiment environment. This work is being sponsored under a Small Business Innovation Research (SBIR) program, which is currently in the Phase 2 development stage. ATA's approach is based on an inertial actuator, which when used as part of a closed-loop stabilization system, rejects unwanted disturbances to the experiment package. A prototype of the actuator has been fabricated and used in a laboratory demonstration to prove the principle of operation. ATA's presentation emphasized the development and testing of the Digital Materials Processing Experiment (DAMPER) inertial actuator. Physical and performance characteristics of the device are presented. Technical issues, including further optimization of the actuator's performance and plans for additional laboratory experiments, are also covered.

Blackburn, John↗

NASA NTRS1986

Development of an emulation-simulation thermal control model for space station application

The orbiting space station being developed by NASA will have many thermal sources and sinks as well as requirements for the transport of thermal energy through large distances. The station is also expected to evolve over twenty or more years from an initial design. As the station evolves, thermal management will become more difficult. Thus, analysis techniques to evaluate the effects of changing various thermal loads and the methods utilized to control temperature distributions in the station are essential. Analysis techniques, including a user-friendly computer program, were developed which should prove useful to thermal designers and system analysts working on the space station. The program uses a data base and user input to compute costs, sizes, and power requirements for individual components and complete systems. User input consists of selecting mission parameters, selecting thermal acquisition configurations, transport systems and distances, and thermal rejection configurations. The capabilities of the program may be expanded by including additional thermal models as subroutines.

Hartley, James G.↗

NASA NTRSDate not supplied

ISS Wastewater Pretreatment via DNA Pattern Picofilter Using Inorganic Brine Stimulant

Astronauts in the International Space Station (ISS) need as much water as they can access, whether it comes from people's breath, sweat or urine, recycled shower water or hand washing. It is of vital importance that any type of water is recycled and filtrated through different methods so it can be re-used. Recently, Cerahelix Inc. offered a ceramic tubular membrane element that uses DNA strands as a pattern in a sol-gel process that allows the sintered product to have a pore size in the picometer scale and claims to achieve ten times higher purity than other commercially available ceramic filters. This should allow higher purities and yields at reduced energy costs and theoretically allow near total dewatering of the reject stream and greater than 80% removal of polyvalent ions. Trials were performed with Cerahelix Inc. filters using an inorganic brine simulant at two pHs to test the efficiency of Pico Helix TM membranes and determine their feasibility for spacecraft wastewater treatment processes. Emphasis was placed on the polyvalent ions: SO42-, PO43-, Mg2+, and Ca2+. These ions should be rejected almost entirely from the feed solution and, not permeate through the filter. Results show that at a pH of 4.2, permeation of the polyvalent ions varied from 59% to 74% and at pH of 8.0, permeation varied from 72% to 87%. An Extended Nernst Planck (ENP) approach that describes the mass transfer process for a pico-filtration membrane was used to construct a model to inform the experimental expectations and outcome.

Carolina Franco↗

NASA NTRS1986

Development of an Emulation-simulation Thermal Control Model for Space Station Application

Analysis techniques to evaluate the effects of changing thermal loads and the methods utilized to control temperature distributions in the orbital space station are essential. Analysis techniques including a user-friendly computer program, were developed which should prove useful in thermal design and system analysis of the the space station. The program uses a data base and user input to compute costs, sizes, and power requirements for individual components and complete systems. User input consists of selecting mission parameters, selecting thermal acquisition configurations, transport systems and distances, and thermal rejection configurations.

Colwell, G. T.↗

NASA NTRS1991

H(infinity) and H2 optimal controllers for periodic and multi-rate systems

The solutions to the optimal l2 to l2 disturbance rejection problem H(infinity) as well as to the LQG (linear quadratic Gaussian) H2 problem in periodic systems using the lifting technique are presented. Both problems involve a causality condition on the optimal LTI (linear time invariant) compensator when viewed in the lifted domain. The H(infinity) problem is solved using the Nehari's theorem, whereas in the H2 problem the solution is obtained using the projection theorem in Hilbert spaces. The authors demonstrate that exactly the same method of solution to the H(infinity) and H2 problems in periodic systems applies when considering the same problems in multirate sampled data systems.

Voulgaris, Petros G.↗

NASA NTRSDate not supplied

Machine-Learned Committor Functions for Reactive Molecular Dynamics

Reactive molecular dynamics (MD) is a powerful tool for atomistic-scale modeling of a diverse range of chemical processes. However, scaling these simulations to large systems and long times scales remains a challenge because of the complexity of the potential energy function required. The authors previously developed a heuristic approach, called REACTER, that incorporates reactivity in MD simulations in a less general but much more computationally efficient manner. REACTER uses standard, fixed valence force fields as the underlying potentialenergy surface for describing all interatomic interactions but adds a procedure for enforcing user-defined reactions that occur when certain geometric constraints on relative atomic positions are satisfied. Further, these bonding changes can be accepted or rejected with a probability related tothe local thermal energy. This work seeks to generalize this approach by replacing the set of user defined geometric constraints and energetic criteria with a committor function that specifies the probability of a reaction occurring on the basis of the local atomic configuration. The committor function is a useful mathematical tool for modeling rare events but, unfortunately, is very difficult to compute for realistic systems in a general way. This work describes a method for approximating the committor function using a machine learning approach, specifically a deep neural network trained with data from reactive MD and DFT-based dynamics simulations. This network is coupled to the existing REACTER protocol, as implemented in the LAMMPS MD package, and used to make on-the-fly predictions of reaction probabilities without the more extensive user input previously required. The new method is demonstrated using the polymerization of polystyrene as a case study. Although very dependent on the quality and quantity of training data, machine-learned committor functions show promise as a method for incorporating reaction probability from higher level calculations into highly scalable MD simulations.

polymer simulations↗

NASA NTRS2009

Fission Surface Power Technology Development Testing at NASA's Early Flight Fission Test Facility

Fission surface power (FSP) systems could be used to provide power anytime, anywhere on the surface of the Moon or Mars. FSP systems could be used at polar locations, at locations away from the poles, or in permanently shaded regions, with excellent performance at all sites. A potential reference 40 kWe option has been devised that is cost-competitive with alternatives while providing more power for less mass anywhere on the lunar surface. The reference FSP system (FSPS) is also readily extensible for use on Mars. At Mars the system would be capable of operating through global dust storms and providing year-round power at any Martian latitude. Under the NASA Exploration Technology Development Program (ETDP), NASA and the Department of Energy (DOE) have begun technology development on Fission Surface Power (FSP). The primary customer for this technology is the NASA Constellation Program which is responsible for the development of surface systems to support human exploration on the moon and Mars. The objectives of the FSP technology project are: 1) Develop FSP concepts that meet expected surface power requirements at reasonable cost with added benefits over other options. 2) Establish a hardware-based technical foundation for FSP design concepts and reduce overall development risk. 3) Reduce the cost uncertainties for FSP and establish greater credibility for flight system cost estimates. 4) Generate the key products to allow Agency decision-makers to consider FSP as a viable option for flight development. To be mass efficient, FSP systems must operate at higher coolant temperatures and use different types of power conversion than typical terrestrial systems. The primary reason is the difficulty in rejecting excess heat to space. Although many options exist, NASA s current reference FSP system uses a fast spectrum, pumped-NaK cooled reactor coupled to a Stirling power conversion subsystem. The reference system uses technology with significant terrestrial heritage while still providing excellent performance on the surface of the moon or Mars. Recent testing at NASA s Early Flight Fission Test Facility (EFF-TF) has helped assess the viability of the reference FSP system, and has helped evaluate methods for system integration. In June, 2009, a representative pumped NaK loop (provided by Marshall Space Flight Center) was coupled to a Stirling power converter (provided by Glenn Research Center) and tested at various conditions representative of those that would be seen during actual FSP system operation. In all areas, performance of the integrated system exceeded project goals. High-temperature NaK pump testing has also been performed at the EFF-TF, as has testing of methods for providing long-duration NaK purity.

Houts. Michael G.↗

NASA NTRS2013

Improving Sanitation and Health in Rural Alaska

In rural Alaskan communities personal health is threatened by energy costs and limited access to clean water, wastewater management, and adequate nutrition. Fuel-‐based energy systems are significant factors in determining local accessibility to clean water, sanitation and food. Increasing fuel costs induce a scarcity of access and impact residents' health. The University of Alaska Fairbanks (UAF) School of Natural Resources and Agricultural Sciences (SNRAS), NASA's Ames Research Center, and USDA Agricultural Research Service (ARS) have joined forces to develop high‐efficiency, low‐energy consuming techniques for water treatment and food production in rural circumpolar communities. Methods intended for exploration of space and establishment of settlements on the Moon or Mars will ultimately benefit Earth's communities in the circumpolar north. The initial phase of collaboration is completed. Researchers from NASA Ames Research Center and SNRAS, funded by the USDA‐ARS, tested a simple, reliable, low-energy sewage treatment system to recycle wastewater for use in food production and other reuse options in communities. The system extracted up to 70% of the water from sewage and rejected up to 92% of ions in the sewage with no carryover of toxic effects. Biological testing showed that plant growth using recovered water in the nutrient solution was equivalent to that using high‐purity distilled water. With successful demonstration that the low energy consuming wastewater treatment system can provide safe water for communities and food production, the team is ready to move forward to a full‐scale production testbed. The SNRAS/NASA team (including Alaska students) will design a prototype to match water processing rates and food production to meet rural community sanitation needs and nutritional preferences. This system would be operated in Fairbanks at the University of Alaska through SNRAS. Long‐term performance will be validated and operational needs of the system determined. The testbed will be a part of the university education and operator training program. The "Forgotten Alaska" has long awaited this technology to augment the traditional

Plant Growth↗

NASA NTRS2018

CALIPSO Lidar Level 3 Aerosol Profile Product: Version 3 Algorithm Design

The CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) level 3 aerosol profile product reports globally gridded, quality-screened, monthly mean aerosol extinction profiles retrieved by CALIOP (the Cloud-Aerosol Lidar with Orthogonal Polarization). This paper describes the quality screening and averaging methods used to generate the version 3 product. The fundamental input data are CALIOP level 2 aerosol extinction profiles and layer classification information (aerosol, cloud, and clear-air). Prior to aggregation, the extinction profiles are quality-screened by a series of filters to reduce the impact of layer detection errors, layer classification errors, extinction retrieval errors, and biases due to an intermittent signal anomaly at the surface. The relative influence of these filters are compared in terms of sample rejection frequency, mean extinction, and mean aerosol optical depth (AOD). The “extinction QC flag” filter is the most influential in preventing high-biases in level 3 mean extinction, while the “misclassified cirrus fringe” filter is most aggressive at rejecting cirrus misclassified as aerosol. The impact of quality screening on monthly mean aerosol extinction is investigated globally and regionally. After applying quality filters, the level 3 algorithm calculates monthly mean AOD by vertically integrating the monthly mean quality-screened aerosol extinction profile. Calculating monthly mean AOD by integrating the monthly mean extinction profile prevents a low bias that would result from alternately integrating the set of extinction profiles first and then averaging the resultant AOD values together. Ultimately, the quality filters reduce level 3 mean AOD by −24 and −31 % for global ocean and global land, respectively, indicating the importance of quality screening.

Tackett, Jason L.↗

NASA NTRS1980

The relative importance of noise level and number of events on human reactions to noise: Community survey findings and study methods

The data from seven surveys of community response to environmental noise are reanalyzed to assess the relative influence of peak noise levels and the numbers of noise events on human response. The surveys do not agree on the value of the tradeoff between the effects of noise level and numbers of events. The value of the tradeoff cannot be confidently specified in any survey because the tradeoff estimate may have a large standard error of estimate and because the tradeoff estimate may be seriously biased by unknown noise measurement errors. Some evidence suggests a decrease in annoyance with very high numbers of noise events but this evidence is not strong enough to lead to the rejection of the conventionally accepted assumption that annoyance is related to a log transformation of the number of noise events.

Fields, J. M.↗