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At least 217 records · Page 12

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NASA NTRS2012

Development of Carbon Dioxide Removal Systems for Advanced Exploration Systems

"NASA's Advanced Exploration Systems (AES) program is pioneering new approaches for rapidly developing prototype systems, demonstrating key capabilities, and validating operational concepts for future human missions beyond Earth orbit" (NASA 2012). These forays beyond the confines of earth's gravity will place unprecedented demands on launch systems. They must not only blast out of earth's gravity well as during the Apollo moon missions, but also launch the supplies needed to sustain a crew over longer periods for exploration missions beyond earth's moon. Thus all spacecraft systems, including those for the separation of metabolic carbon dioxide and water from a crewed vehicle, must be minimized with respect to mass, power, and volume. Emphasis is also placed on system robustness both to minimize replacement parts and ensure crew safety when a quick return to earth is not possible. Current efforts are focused on improving the current state-of-the-art systems utilizing fixed beds of sorbent pellets by seeking more robust pelletized sorbents, evaluating structured sorbents, and examining alternate bed configurations to improve system efficiency and reliability. These development efforts combine testing of sub-scale systems and multi-physics computer simulations to evaluate candidate approaches, select the best performing options, and optimize the configuration of the selected approach, which is then implemented in a full-scale integrated atmosphere revitalization test. This paper describes the carbon dioxide (CO2) removal hardware design and sorbent screening and characterization effort in support of the Atmosphere Resource Recovery and Environmental Monitoring (ARREM) project within the AES program. A companion paper discusses development of atmosphere revitalization models and simulations for this project.

Knox, James C.↗

NASA NTRS2012

Design, Development, Test, and Evaluation of Atmosphere Revitalization and Environmental Monitoring Systems for Long Duration Missions

The Advanced Exploration Systems Program's Atmosphere Resource Recovery and Environmental Monitoring (ARREM) project is working to mature optimum atmosphere revitalization and environmental monitoring system architectures. It is the project's objective to enable exploration beyond Lower Earth Orbit (LEO) and improve affordability by focusing on three primary goals: 1) achieving high reliability, 2) reducing dependence on a ground-based logistics resupply model, and 3) maximizing commonality between atmosphere revitalization subsystem components and those needed to support other exploration elements. The ARREM project's strengths include using existing developmental hardware and testing facilities, when possible, and and a well-coordinated effort among the NASA field centers that contributed to past ARS and EMS technology development projects.

Roman, Monsi C.↗

NASA NTRS2013

Functional Performance of an Enabling Atmosphere Revitalization Subsystem Architecture for Deep Space Exploration Missions

A subsystem architecture derived from the International Space Station's (ISS) Atmosphere Revitalization Subsystem (ARS) has been functionally demonstrated. This ISS-derived architecture features re-arranged unit operations for trace contaminant control and carbon dioxide removal functions, a methane purification component as a precursor to enhance resource recovery over ISS capability, operational modifications to a water electrolysis-based oxygen generation assembly, and an alternative major atmospheric constituent monitoring concept. Results from this functional demonstration are summarized and compared to the performance observed during ground-based testing conducted on an ISS-like subsystem architecture. Considerations for further subsystem architecture and process technology development are discussed.

Perry, Jay L.↗

NASA NTRS2014

Evaluating the Adsorptive Capabilites of Chemsorb 1000 and Chemsorb 1425

The removal of trace contaminants from spacecraft cabin air is necessary for crew health and comfort during long duration space exploration missions. The air revitalization technologies used in these future exploration missions will evolve from current ISS ISS State-of-Art (SOA) and is being designed and tested by the Advanced Exploration Systems (AES) Program's Atmosphere Resource Recovery and Environmental Monitoring (ARREM) project. The ARREM project is working to mature optimum atmosphere revitalization and environmental monitoring system architectures to enable exploration beyond Lower Earth Orbit (LEO). The Air Revitalization Lab at KSC is one of six NASA field centers participating in the ARREM that specializes in adsorbent and catalyst characterization with simulated spacecraft gas streams using combinations of pressure, O2 partial pressure, CO2 partial pressure, and humidity that are representative of a range of anticipated cabin atmospheric conditions and loads. On board ISS, the Trace Contaminant Control Subassembly (TCCS) provides active control of trace contaminants from the cabin atmosphere utilizing physical adsorption, thermal catalytic oxidation, and chemical adsorption processes. High molecular weight contaminants and ammonia (NH3) are removed a granular activated carbon treated with approx. 10% by weight phosphoric acid (H3PO4) (B-S Type 3032 4×6 mesh), which is expendable and is periodically refurbished. The Type 3032 granular activated carbon bed is no longer commercially available and therefore it is important to characterize the efficiency and capacity of commercially available NH3 sorbents. This paper describes the characterization of two Molecular Products LTD activated carbons: Chemsorb 1000 and Chemsorb 1425. Untreated activated carbons (e.g. Chemsorb 1000) remove contaminants by physisorption, which concentrates the contaminant within the pores of the carbon while letting air to pass through the sorbent4. Low molecular weight or polar gases (e.g. HCl, SO2, formaldehyde, and NH3) are not removed by physisorption and typically require chemisorption for removal. Treated activated carbons (e.g. Chemsorb 1425) are impregnated with a a chemical agent (e.g. phosphoric acid) that reacts with those gases, converting them to solids or salts within the carbon and removes them from the air stream. This process occurs via neutralization or catalysis reactions and adsorption capacity is exhaustedwhen the available impregnated chemicals are consumed. Moisture affects removal performance since adsorption sites within the pores are filled with water. The performance of impregnated carbons may be enhanced by moisture content because the mechanisms of contaminant removal are chemical reactions that occur in reagents contained within the pores. The adsorptive capacity data (mol/kg) of Chemsorb 1000 and 1425 for gas mixtures (ethanol, acetone, toluene, acetaldehyde, dichloromethane, and xylene) was measured with 40% relative humidity at 23 deg C air temperature. The adsorptive capacity data (mol/kg) of Chemsorb 1425 was measured using NH3 gas streams.

adsorptive capacities↗

NASA NTRS2015

Sorbent Structural Impacts Due to Humidity on Carbon Dioxide Removal Sorbents for Advanced Exploration Systems

Watson, David↗

NASA NTRS2015

Optimization of the Carbon Dioxide Removal Assembly (CDRA-4EU) in Support of the International Space System and Advanced Exploration Systems

The Life Support Systems Project (LSSP) under the Advanced Exploration Systems (AES) program builds upon the work performed under the AES Atmosphere Resource Recovery and Environmental Monitoring (ARREM) project focusing on the numerous technology development areas. The Carbon Dioxide (CO2) removal and associated air drying development efforts are focused on improving the current state-of-the-art system on the International Space Station (ISS) utilizing fixed beds of sorbent pellets by seeking more robust pelletized sorbents, evaluating structured sorbents, and examining alternate bed configurations to improve system efficiency and reliability. A component of the CO2 removal effort utilizes a virtual Carbon Dioxide Removal Assembly, revision 4 (CDRA-4) test bed to test a large number of potential operational configurations with independent variations in flow rate, cycle time, heater ramp rate, and set point. Initial ground testing will provide prerequisite source data and provide baseline data in support of the virtual CDRA. Once the configurations with the highest performance and lowest power requirements are determined by the virtual CDRA, the results will be confirmed by testing these configurations with the CDRA-4EU ground test hardware. This paper describes the initial ground testing of select configurations. The development of the virtual CDRA under the AES-LSS Project will be discussed in a companion paper.

Knox, James C.↗

NASA NTRS2020

Technical Risks Associated with Heat Melt Compaction Systems

The processing of trash and waste is a welcome and valuable addition to humans living and working in space. Besides the obvious desire to have a pleasant and productive habitation environment, trash management has many practicalbenefits for crew health, resource recovery, and volume reclamation through garbage compaction. The Trash Compaction and Processing System (TCPS), which is a NASA project to develop a trash processing system for long-duration spaceflight, is currently undergoing concept development with engineering prototype validation through two contracted efforts. The development efforts are being supported with activities associated with the NASA Generation 2 Heat Melt Compactor (HMC). The HMC is a facility that compacts trash, recovers water, heats the trash to eliminate biological activity, and manages gas and vapor effluents. The resulting residual processed trash is a compact tile that is free of biological growth and that can be used for augmenting radiation shields. The work being conducted with the HMC focuses on high risk technical areas with respect to operations, subsystem performance, and ISS effluent management interface requirements. This paper gives an overview of the technical risks and the current use of the HMC as a facility for reducing risk.

HMC↗

NASA NTRSDate not supplied

Mapping Inundation from Hurricane Florence (2018) with L-Band Synthetic Aperture Radar, Commercial Imagery, and Ancillary Data via Machine Learning Classification

During and after flooding events, mapping the extent of floodwaters aids in the distribution of resources, recovery efforts, and damage assessment practices. Development of a land cover classification system focused on mapping inundation after major hurricane events using synthetic aperture radar (SAR) data could allow for the production of near-real-time inundation mapping, enabling government and emergency response entities to get a preliminary idea of a developing situation. Complimentary optical and SAR images from domestic and foreign entities are brought together through activations of the International Charter: Space and Major Disasters to support response efforts, from true-color, near-infrared, and thermal remote sensing data obtained by NASA, NOAA, and international satellites to the collection of high-resolution true color aerial photography by NOAA and the National Geodetic Survey. In response to Hurricane Florence of 2018, NASA JPL collected numerous swaths of quad-pol L-band SAR data with the Uninhabited Aerial Vehicle Synthetic Aperture Radar (UAVSAR) instrument observing the record-setting river stages across North and South Carolina. The resulting fully-polarized SAR images allow for mapping of inundation extent at a high spatial resolution with a unique advantage over optical imaging stemming from the sensor’s ability to penetrate cloud cover and dense vegetation. In this study, true-color NOAA aerial and commercial satellite imagery are used in conjunction with four UAVSAR data swaths centered on the Lumberton and Cape Fear River basins in southeastern North Carolina to develop a Random Forest classification model focused on mapping open water and floodwater otherwise obscured by vegetation or lingering cloud cover. Ancillary building footprint, transportation route, and population data will also be incorporated into the classification scheme to estimate the societal impacts of flooding based on the proximity of features to detected inundation. Preliminary results from the Hurricane Florence case study will be discussed in addition to the limitations of available validation data for assessment of the classifier’s accuracy.

Alexander M Melancon↗

NASA NTRSDate not supplied

In-situ Raman Instrumentation and Measurements in Supercritical Water Oxidation Systems

Due to the advent of recent advances in reactor designs and operational procedures, renewed attention has been given to a host of supercritical water oxidation (SCWO) technology applications. This includes resource recovery, water reclamation, and solid waste destruction. SCWO is often recognized as a “green technology” because of its ability to extract useful energy while producing benign products from environmentally challenging waste streams (e.g., wet organic wastes, pharmaceutical wastes, military wastes). The present work was motivated by NASA’s interests in solid waste management and water recovery for long-duration space missions. To that end, the main focus of this paper is to present work on characterizing the behavior of supercritical water oxidation systems utilizing state of the art laser Raman spectroscopy. The main benefit of Raman diagnostics is its ability to identify chemical composition and to measure concentrations of the compounds involved in the reaction. Two separate Raman systems for SCWO measurements that have been developed for this study will be described. The first system is a 2-D traversing system useful for making in-situ measurements in conditions where spatial gradients of species and temperature are important and has been successfully utilized in making species (ethanol, oxygen, water, nitrogen and carbon dioxide) concentrations and temperature measurements in ethanol hydrothermal jet flames. The second system is a packaged modular Raman probe unit for portable deployment to different reactors and is more suitable for relatively homogeneous systems such as a batch reactor. The design, development, and examples of obtained results from both systems will be presented for various reactant streams. Reaction rate and fuel conversion estimates from chemistry models will also be presented.

supercritical water oxidation↗

NASA NTRSDate not supplied

Mapping Inundation from Hurricane Florence (2018) with L-Band Synthetic Aperture Radar, Commercial Imagery, and Ancillary Data via Random Forest Classification

Mapping the extent of floodwaters following extreme rainfall aids in the distribution of resources, recovery efforts, and damage assessment practices. Development of a land cover classification system focused on mapping inundation after major hurricane events using synthetic aperture radar (SAR) data could allow for the production of near-real-time inundation mapping, enabling government and emergency response entities to get a preliminary idea of a developing situation. In response to Hurricane Florence of 2018, NASA JPL collected numerous swaths of quad-pol L-band SAR data with the Uninhabited Aerial Vehicle Synthetic Aperture Radar (UAVSAR) instrument observing the record-setting river stages across North and South Carolina. The resulting fully-polarized SAR images allow for mapping of inundation extent at a high spatial resolution with a unique advantage over optical imaging stemming from the sensor’s ability to penetrate cloud cover and dense vegetation. This study seeks to determine how accurately maps of inundation can be generated from L-band SAR imagery through Random Forest classification. Once the extent of water and inundated vegetation is classified, cleanup operations are performed using fuzzy logic to reduce false detections. Estimates of water extent are then combined with datasets describing the distribution of population, buildings, and roads throughout the domain to evaluate societal impacts. Results from the Hurricane Florence case study will be discussed along with the limitations of available validation data for assessment of the classifier’s accuracy.

Alexander Melancon↗

NASA NTRSDate not supplied

Suborbital Testing of the OSCAR Trash-to-Gas System

With the sustained human exploration of nearby celestial bodies on the horizon, a renewed outlook on crew waste management must be realized. Current waste management strategies aboard the International Space Station become impractical as we venture beyond low Earth orbit. Furthermore, for future exploration missions, extracting resources from various waste streams becomes increasingly advantageous. One method of combatting the long-duration waste management problem is by thermally degrading solid and liquid crew waste items into a chemically inert, ventable gas stream, a process known as Trash-to-Gas. The Orbital Syngas/Commodity Augmentation Reactor (OSCAR) is the state-of-the-art Trash-to-Gas system which has been designed to explore microgravity Trash-to-Gas concepts for improved mass/volume reduction and resource recovery from waste. OSCAR is a subscale testbed design that supports the NASA Logistics Reduction project under the Advanced Exploration Systems Program and Space Technology Mission Directorate Flight Opportunities Program to determine the feasibility of Trash-to-Gas technology for future use on long duration space missions. OSCAR has flown on two suborbital flight demonstrations aboard Blue Origin’s New Shepard launch vehicle. This paper presents a high-level comparative analysis of these microgravity test campaigns with Earth gravity laboratory experiments. Solid-to-gas conversion, gas production & composition, and reactor temperature & pressure are compared to highlight the operational factors and performance differences within the microgravity environment for future optimization.

Ray P Pitts↗

NASA NTRSDate not supplied

Supercritical Water Oxidation: Testing of Ersatz Wastewater

Supercritical Water Oxidation (SCWO) technology is under consideration by NASA for treatment of wastewater and other wet waste streams. The dramatic changes in water's thermophysical properties near its critical point (374◦C and 22 MPa) result in nearly complete solubility of organics and gases. The absence of inter–phase transport processes and phase separation results in dramatically reduced reaction timescales and the elimination of complications of two–phase transport and processing in reduced gravity. Other advantages are that the product streams are microbially inert,benign, amenable to resource recovery and organic waste. This paper first described the design and construction of tubular SCWO reactor built at NASA Glenn. It consists of separate wastewater and oxidizer inlets, which are independently heated and pressurized to conditions approaching the critical point of water. These flows enter a reactor chamber having a volume of 62 ml. The reactor section is heated to the desired temperature in the range of 450 ◦C – 650 ◦C. A pressure regulator maintains the operating pressure nominally between 27.6 MPa and 28.3 MPa. The reacted fluid is captured downstream of the pressure regulator during an experiment run. A separate vent line may also be used for collection of the effluent. Next, the results of SCWO experiments using both a representative organic (ethanol) as well as a wastewater simulant provided by NASA Ames are presented. Raman analysis of the pre–reacted and post–reacted solutions are presented. Finally, initial efforts on supplementary chemical kinetics modeling of ethanol oxidation with and without inclusion of a nitrogenous compounds (ammonia) are presented.

Michael C Hicks↗

NASA NTRSDate not supplied

Mitigating Microbial Contamination Risks in CO 2 Removal Systems for Long-Duration Space Missions

Crewed missions to Mars and beyond pose new challenges for the crew and the technological solutions they depend upon. Crucial considerations in designing the next generation of Environmental Control and Life Support Systems (ECLSS) include enhanced reliability and autonomy, given the challenges of resupply and resource recovery in remote missions. One significant challenge faced in various sectors of the International Space Station and ECLSS is the phenomena of microbial growth, particularly biofilm formation. As such, microbial growth is a critical consideration in the design phase of new ECLSS systems. Two novel CO2 removal systems—Liquid-Amines CO2 Removal (LACR) and Cold-Surface CO2 Deposition (CDep)—are currently under development at the NASA Ames Research Center to meet the needs of extended space travel. In this presentation, the authors aim to make a risk assessment of microbial growth in LACR and CDep through: 1) a comprehensive literature review to identify LACR and CDep components most vulnerable to microbial contamination and 2) wet lab testing commencing with a subscale test of the most susceptible component of CDep. The literature review revealed that the hollow-fiber Liqui-Cel membrane employed in CDep exhibits the highest susceptibility to microbial growth. Our wet lab tests corroborated these findings, as airborne microbes introduced into the membrane led to considerable biomass accumulation. These results indicate a significant risk of microbial invasion into the membranes. To prevent microbial growth in CDep or other CO2 removal systems, proper ECLSS arrangement is essential—a CO2 removal system should remain behind the charcoal-HEPA filters, condensing heat exchanger, and Trace Contaminant Control System. In summary, anticipating potential microbial interactions within ECLSS for remote crewed missions is vital to mission success. It should, therefore, be included as one of the many factors when designing future ECLSS systems to perform reliably and consistently to support astronaut life.

A. Nicolas Whitlock↗

DOE OSTI2021

Comparison of Select Food Waste Utilization Options

This document provides a comparison of several food waste utilization options: landfill gas capture, anaerobic digestion, and composting, across various metrics. These options are the most prevalent pathways for energy and resource recovery. Other options, not considered here, include food donation, animal feed, incineration, and gasification. The table below describes the differences or similarities between these processes and provides information about products, the number of current projects in the United States, capital and operation and maintenance (O&M) costs, job development potential, emissions, and incentives associated with each pathway, as well as other parameters, such as level of complexity, land requirement, and revenue type. Sources for the data in the table are listed in the references at the end of the document.

09 BIOMASS FUELS↗

DOE OSTI2022

Integrated Urban Services

Integrated Urban Services (IUS) is a program under the United States-Association of Southeast Asian Nations (US-ASEAN) Smart Cities Partnership helping ASEAN cities build resilience in their energy, water, and food (EWF) provisioning systems. The program was launched by U.S. State Department and is jointly implemented by the U.S. Department of Energy's National Renewable Energy Laboratory (NREL), with an aim to promote systems integration and circular economy principles for resource recovery and reuse. This fact sheet summarizes the Integrated Urban Services program.

ASEAN↗

DOE OSTI2022

It's OK to be a Control Freak: Deploying machine learning algorithms and model-based controllers for WRRF optimization

Hybrid models are powerful predictors of performance in Water Resource Recovery Facilities (WRRFs). When used in controllers, hybrid models can help inform manipulated variable setpoints in feedforward controllers. This idea was tested for chlorine disinfection and ammonia-based aeration control.

Sparks, Jeff↗

DOE OSTI2023

Waste-to-Energy Technical Assistance for Local Governments

The goal of this project is to mobilize data, information, and knowledge generated about organic waste streams to local governments and support their decision-making. It builds on previous work related to wet organic waste resources (food waste, sludge, manure, waste fats and oils). The project provides an improved understanding of local waste challenges and priorities to inform BETO's R&D strategies and decision-making. It also supports local governments' goals and plans related to sustainable waste management, enables energy and/or resource recovery projects development at municipal level, and facilitates public-private partnerships. A key challenge is associated with more activities requested by entities than program allows which is mitigated by prioritization by requesting agency. All FY21 and FY22 TA requests have been completed. Major accomplishments include: 1). 34 requests managed in the past two years, 2) Distilled key challenges faced by communities. Key outcomes include strong community participation since inception of the program, dedicated program web site, deliverables tailored to communities' needs, and distribution materials (e.g., fact sheets, brochures) for a broader audience.

BIOMASS FUELS↗

DOE OSTI2023

Full-Scale Soft-Sensor Implementations Enable WRRF Hybrid Digital-Twins

Digital twins (DTs) are on the rise in the wastewater treatment industry and, with ever-increasinguse of online data in more complex applications, it is bringing us towards a digital revolution withinwater resource recovery facilities (WRRFs). An integral data requirement is dynamic real-timeinfluent concentrations. However, few WRRFs have the ability to deploy sensors to generate therequired dynamic influent concentrations. This paper presents an innovative approach to generatedynamic influent profiles with a soft sensor primarily using bioreactor airflow rates and DT models.It has been implemented on three different full-scale facilities and demonstrate it is feasible toretrieve 15-minute interval diurnal influent concentrations. This study overcomes a key bottleneckin DT applications - the lack of realistic high-resolution influent profiles - fostering the developmentof DTs. The fact that the data used in this study are commonly available ensures wide applicabilityfor most WRRFs and prepares them for the advanced controls that digital twins can unlock.

Johnson, Bruce↗