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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Constraints on crustal rheology and age of deformation from models of gravitational spreading in Ishtar Terra, Venus

Gravitational spreading is expected to lead to rapid relaxation of high relief due to the high surface temperature and associated weak crust on Venus. In this study, we use new Magellan radar and altimetry data to determine the extent of gravitational relaxation in Ishtar Terra, which contains the highest relief on Venus as well as areas of extremely high topographic slope. Within Ishtar Terra the only mountain belts found on Venus, Akna, Danu, Freyja, and Maxwell Montes, nearly encircle the smooth, high (3-4 km) plateau of Lakshmi Planum. Finite-element models of this process give expected timescales for relaxation of relief and failure at the surface. From these modeling results we attempt to constrain the strength of the crust and timescales of deformation in Ishtar Terra. Below we discuss observational evidence for gravitational spreading in Ishtar Terra, results from the finite-element modeling, independent age constraints, and implications for the rheology and timing of deformation.

Smrekar, Suzanne E.↗

Rheology and microstructure of magmatic emulsions - Theory and experiments

The rheological properties of a dilute mixture of melt plus vapor bubbles, referred to as emulsion, are investigated theoretically and in rheometric experiments on dilute viscous germanium dioxide emulsions at temperatures between 1100 and 1175 C and at 100 kPa pressure in a rotating rod rheometer at shear rates between 0.05/s and 7/s. The results indicate that the emulsions may be described by a power-law constitutive relation when observations cover a sufficient range of shear rates to resolve nonlinear flow.

Stein, Daniel J.↗

Thermal and rheological controls on magma migration in dikes: Examples from the east rift zone of Kilauea volcano, Hawaii

Long-lived eruptions from basaltic volcanoes involving episodic or steady activity indicate that a delicate balance has been struck between the rate of magma cooling in the dike system feeding the vent and the rate of magma supply to the dike system from a reservoir. We describe some key factors, involving the relationships between magma temperature, magma rheology, and dike geometry that control the nature of such eruptions.

Parfitt, E. A.↗

Rheology, tectonics, and the structure of the Venus lithosphere

Given the absence of ground truth information on seismic structure, heat flow, and rock strength, or short wavelength gravity or magnetic data for Venus, information on the thermal, mechanical and compositional nature of the shallow interior must be obtained by indirect methods. Using pre-Magellan data, theoretical models constrained by the depths of impact craters and the length scales of tectonic features yielded estimates on the thickness of Venus' brittle-elastic lithosphere and the allowable range of crustal thickness and surface thermal gradient. The purpose of this study is to revisit the question of the shallow structure of Venus based on Magellan observations of the surface and recent experiments that address Venus' crustal rheology.

Zuber, M. T.↗

Volatiles, rheology, and mantle convection: Comparing Earth, Venus, and Mars

Silicate rheology is controlled in part by volatile content. The variation of viscosity with position in the mantle will influence the nature of mantle convection; hence, modeling mantle convection and its effect on surface observables such as the geoid places constraints on the viscosity structure of a planet's mantle and may indirectly constrain the volatile distribution. Models of viscous mantle flow and the Earth's geoid indicate that there is roughly a two order of magnitude variation in viscosity between the upper and lower mantles, although there is some disagreement over the depth of the viscosity minimum in the upper mantle. Some studies of post-glacial rebound also support such a viscosity contrast between the upper and lower mantles. On Venus, several highland regions appear to be supported by mantle plumes. Modeling of the geoid and topography of these regions indicates that if these features are plume-related, then the mantle of Venus can not have an Earth-like low viscosity zone in its upper mantle. On Mars, the Tharsis volcanic province has alternatively been explained as supported either by mantle convection or by flexure of a thick lithosphere. If the convective model is correct, then the large geoid anomaly requires that Mars can not have a low viscosity zone in its upper mantle.

Kiefer, Walter S.↗

Shape Oscillations of Gas Bubbles With Newtonian Interfacial Rheological Properties

The oscillation frequency and damping rate for small-amplitude axisymmetric shape modes of a gas bubble in an ideal liquid are obtained, in the limit when the bubble interface possesses Newtonian interfacial rheology with constant surface shear and dilatational viscosities. Such results permit the latter surface properties to be measured by analyzing experimental data on frequency shift and damping rate of specific shape modes of suspended bubbles in the presence of surfactants.

Nadim, Ali↗

Microgravity Foam Structure and Rheology

The objective of this research was to exploit rheological and multiple-light scattering techniques, and ultimately microgravity conditions, in order to quantify and elucidate the unusual elastic character of foams in terms of their underlying microscopic structure and dynamics. Special interest was in determining how this elastic character vanishes, i.e. how the foam melts into a simple viscous liquid, as a function of both increasing liquid content and shear strain rate.

Durian, Douglas J.↗

Suspension of SiC Powders in Allyhydridopolycarbosilane (AHPCS): Control of Rheology

Inert particulate fillers can be blended with preceramic polymers prior to infiltration of composite preforms to increase pyrolysis yield and decrease shrinkage, thus reducing the number of infiltration/ pyrolysis cycles required for densification. However, particulate filler loadings and concentration of added dispersants necessary to maintain low viscosity (< 0.50 N.s/sq m) slurries vary with the characteristics of the particular AHPCS polymer batch. These batch to batch variations occur with alterations in the synthesis process and method of allyl substitution, which in turn alter polymer structure and molecular weight distribution. A number of different polymer batches were characterized by NMR, GPC and thermal analysis, and the influence of polymer structure on rheology of filled systems determined. When the high molecular weight fraction increased to too great a level, suitably fluid slurries could no longer be attained.

Hurwitz, Frances I.↗

Determination of Interfacial Rheological Properties through Microgravity Oscillations of Bubbles and Drops

This report summarizes our derivations of analytical expressions for the frequencies and damping constants for small-amplitude axisymmetric shape oscillations of a liquid drop suspended in an immiscible fluid host in microgravity. In particular, this work addresses large Reynolds number shape oscillations and focuses on the surface rheological effects that arise from the presence of insoluble surfactants at the interface. Parameters characterizing viscous effects from the bulk phases, surface viscous effects, Marangoni effects from the surface advection and diffusion of surfactants, and the Gibbs elasticity are all considered and analyzed to determine the relative importance of each contribution. Supplementing the analytical treatment for small-amplitude oscillations, a numerical boundary integral equation formulation is developed for the study of large-amplittide axisymmetric oscillations of a drop in vacuum. The boundary integral formulation is an extension of classical potential flow theory and approximately accounts for viscous effects in the bulk fluid as well as the surface viscous and Marangoni effects resulting from an insoluble surfactant contaminating the interface. Theoretical and numerical results are presented for four distinct cases. These, range from the case when the effects of the surfactants are 'negligible' to 'large' when compared to the viscous effects in the bulk phases. The feasibility of the non-contact measurement of the surface parameters, using experimental observations for the oscillation frequencies and damping constants of drops and bubbles, is discussed.

Nadim, Ali↗

Rheology of Foam Near the Order-Disorder Transition

The first part of our research results are summarized in the recent journal publication: J. Gregory McDaniel and R. Glynn Holt, 'Measurement of aqueous foam rheology by acoustic levitation', Phys. Rev. E 61, 2204 (2000). This aspect of the work was a combination of experiment and analysis. We built a levitation system capable of acoustically levitating small samples of aqueous foam of arbitrary gas and liquid volume fractions. We then modulated the acoustic field to induce normal mode oscillations of the foam samples. The observables from the experiment were frequency and mode number. For dry (roughly > 70% gas by volume) foams and small deformations, we developed an effective medium, normal-modes analysis which took the frequency and mode number from experiment, and gave us the shear elastic modulus of the foam as a function of Poisson's ratio. The second part of our results may be found in a soon-to-be submitted manuscript 'Dynamics of aqueous foam drops', I.Sh. Akhatov, J.G. McDaniel and R.G. Holt, describing our modeling in the wet foam limit by considering the acoustic problem. This aspect of the research is purely theoretical. Beginning from a mass-conserving mixture law, the fully nonlinear equations of motion for a wet (roughly < 10% gas by volume) foam drop of initially spherical shape were derived. The frequencies for normal mode oscillations were derived in the linear inviscid limit. The nonlinear equations were numerically solved to elicit the motion of a foam drop under acoustic excitation. The role of the time-varying void fraction in breathing-mode oscillations is of particular interest. As of the end of the current (NAG#3-2121) grant, this work was not yet concluded. We continue to work on this aspect in order to extend the analysis to cover the transition regime of gas volume fractions, as well as to compare to experiments in the wet regime.

Holt, R. Glynn↗

The Effect of Large Melt Fraction on the Deformation Behavior of Peridotite: Implications for the Rheology of Io' Mantle

One key constraint needed for refinement of the interior geochemical and geodynamic models of Io is the viscosity of the convecting partially- molten silicate mantle. To date, laboratory studies of partially molten mantle rocks have reached melt fractions up to approx.0.12, a value much smaller than thought to be appropriate for the asthenosphere of Io where the degree of partial melting may be 0.15 0.40 or higher. Therefore, we have performed a series of high temperature, triaxial compressive creep experiments on dry synthetic peridotites in a gas medium apparatus at a confining pressure of 300 MPa and temperatures from 1473 to 1573 K in order to understand the influence of large amounts of melt (0.15 < phi < 0.40) on the rheological behavior of partially molten rocks.

Scott, T.↗

Thermocapillary migration of a drop: an exact solution with Newtonian interfacial rheology and stretching/shrinkage of interfacial area elements for small Marangoni numbers

In this paper we analyze the effects of the following phenomena associated with the thermocapillary migration of a drop. The first is the influence of Newtonian surface rheology of the interface and the second is that of the energy changes associated with stretching and shrinkage of the interfacial area elements, when the drop is in motion. The former occurs because of dissipative processes in the interfacial region, such as when surfactant molecules are adsorbed at the interface in sufficient concentration. The interface is typically modeled in this instance by ascribing to it a surface viscosity. This is a different effect from that of interfacial tension gradients arising from surfactant concentration gradients. The stretching and shrinkage of interfacial area elements leads to changes in the internal energy of these elements that affects the transport of energy in the fluids adjoining the interface. When an element on the interface is stretched, its internal energy increases because of the increase in its area. This energy is supplied by the neighboring fluids that are cooled as a consequence. Conversely, when an element on the interface shrinks, the adjoining fluids are warmed. In the case of a moving drop, elements of interfacial area are stretched in the forward half of the drop, and are shrunk in the rear half. Consequently, the temperature variation on the surface of the drop and its migration speed are modified. The analysis of the motion of a drop including these effects was first performed by LeVan in 1981, in the limit when convective transport of momentum and energy are negligible. We extend the analysis of LeVan to include the convective transport of momentum by demonstrating that an exact solution of the momentum equation is obtained for an arbitrary value of the Reynolds number. This solution is then used to calculate the slightly deformed shape of the drop from a sphere.

Rheology/methods↗

Differential Dynamic Microscopy: A Novel Approach for Dynamics and Micro-rheology of Active Soft Matter

Differential dynamic microscopy (DDM) is a highly sensitive and cost-effective technique for studying the dynamics and micro-rheology of active soft matter in real time and at high resolution. In this work, we extend the capabilities of DDM, notably its size, to suit to space research and overcome challenges such as the environmental limited resources (e.g. Artemis, ISS, Cube sat, etc.).

Amine Missaoui↗

Rheology and engine performance of very low sulfur fuel oil blended with 10% fast pyrolysis and hydrothermal liquefaction oils in a 2-stroke crosshead engine

The performance and emissions for a downscaled single-cylinder 2-stroke crosshead engine were determined for a very low sulfur fuel oil (VLSFO) when blended with 10 wt.% fast pyrolysis (FP) or hydrothermal liquefaction (HTL) bio-intermediates. The FP and HTL oils were derived from biomass and were observed to contain lower molecular weight (MW) hydrocarbons than neat VLSFO (which was evaluated as a baseline comparison). The addition of either biofuel reduced the overall viscosity of the VLSFO. Aging tests at 50, 90, and 120°C showed that the dynamic viscosity of VLSFO increased with exposure time up to two weeks. Similar trends were observed for the FP and HTL blends, but a pronounced spike in viscosity occurred for these fuels during the early period of exposure. None of the viscosity increases exceeded the operational limits of fuel system pumps. Engine performance studies were conducted under low, medium and high load operational settings. The relative performance of the test fuels was highly dependent on operating condition. In general, the engine results for the three test fuels were similar, but modest improvements in brake thermal efficiency and brake specific fuel consumption were observed, which may be attributed to the heightened reactivity of low molecular weight fraction of the FP and HTL oils.

09 BIOMASS FUELS↗