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At least 217 records · Page 12

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NASA NTRS1997

Electron Paramagnetic Resonance Imaging of the Spatial Distribution of Free Radicals in PMR-15 Polyimide Resins

Prior studies have shown that free radicals generated by heating polyimides above 300 C are stable at room temperature and are involved in thermo-oxidative degradation in the presence of oxygen gas. Electron Paramagnetic Resonance Imaging (EPRI) is a technique to determine the spatial distribution of free radicals. X-band (9.5 GHz) EPR images of PMR-15 polyimide were obtained with a spatial resolution of about 0.18 mm along a 2 mm dimension of the sample. In a polyimide sample that was not thermocycled, the radical distribution was uniform along the 2 mm dimension of the sample. For a polyimide sample that was exposed to thermocycling in air for 300 one-hour cycles at 335 C, one-dimensional EPRI showed a higher concentration of free radicals in the surface layers than in the bulk sample. A spectral-spatial two-dimensional image showed that the EPR lineshape of the surface layer remained the same as that of the bulk. These EPRI results suggest that the thermo-oxidative degradation of PMR-15 resin involves free radicals present in the oxygen-rich surface layer.

Ahn, Myong K.↗

NASA NTRS1997

Electron Paramagnetic Resonance Imaging of the Spatial Distribution of Free Radicals in PMR-15 Polyimide Resins

Prior studies have shown that free radicals generated by heating polyimides above 300 C are stable at room temperature and are involved in thermo-oxidative degradation in the presence of oxygen gas. Electron paramagnetic resonance imaging (EPRI) is a technique to determine the spatial distribution of free radicals. X-band (9.5 GHz) EPR images of PMR-15 polyimide were obtained with a spatial resolution of approximately 0.18 mm along a 2-mm dimension of the sample. In a polyimide sample that was not thermocycled, the radical distribution was uniform along the 2-mm dimension of the sample. For a polyimide sample that was exposed to thermocycling in air for 300 1-h cycles at 335 C, one-dimensional EPRI showed a higher concentration of free radicals in the surface layers than in the bulk sample. A spectral-spatial two-dimensional image showed that the EPR lineshape of the surface layer remained the same as that of the bulk. These EPRI results suggest that the thermo-oxidative degradation of PMR-15 resin involves free radicals present in the oxygen-rich surface layer.

Ahn, Myong K.↗

DOE OSTI2022

Investigating the Impacts of Daytime Boundary Layer Clouds on Surface Energy Fluxes and Boundary Layer Structure During CHEESEHEAD19

Studies of land-atmosphere interactions under a clear sky and low cumulus cloud conditions are common from long-term observatories like at the southern great plains. How well the relationships and responses of surface radiative and turbulent heat fluxes determined from these investigations hold for more heterogeneous surfaces in other climate regimes, however, is uncertain. In this study, detailed observations of the surface energy budget and daytime boundary layer properties are analyzed using measurements from the Chequamegon Heterogenous Ecosystem Energy-Balance Study Enabled by a High-Density Extensive Array of Detectors 2019 (CHEESEHEAD19) field campaign, July-October 2019, across a heterogeneous forested landscape of northern Wisconsin. A cloud regime framework is employed to classify consecutive periods of clear skies from lower atmosphere stratiform and cumulus clouds. A seasonal transition from low cumulus to low stratiform periods occurred, together with a diurnal pattern in cloudy or clear sky period dominance. Radiative forcing was highly dependent on sky conditions, leading to changes in the redistribution efficiency of radiative energy by the surface turbulent heat fluxes. During CHEESEHEAD19, small Bowen ratios dominated with daytime latent heat fluxes three times as large as sensible heat fluxes for all sky conditions studied; the forested region, therefore, falls within an energy-limited regime. The depth of the daytime mixed layer depended upon the sky condition and thermodynamic setting; deeper mixed layers occurred during periods of low cumulus and not clear skies. Profiles of vertical velocity were found to have enhanced variance under low cumulus compared to clear sky periods, suggesting potential for cloud feedbacks on boundary layer structure and surface energy fluxes.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1996

Simultaneous Use Of Zr And Mg Anodes In XPS

Improved x-ray source for x-ray photoelectron spectroscopy (XPS) contains both zirconium anode with beryllium window and magnesium anode with aluminum window. Previously unresolvable peaks of electron-energy spectrum become resolvable. Developed specifically for use in analyzing distributions of chemical constituents in surface layers of specimens of 2219 aluminum alloy and in determining the depths of surface oxide layers and relative proportions of aluminum and oxide in layers. Also used to study chemical constituents of surface layers in other material systems - for example, thin oxide films on silicon-based semiconductor devices, oxide films on alloys, and surface layers affecting adhesion of paints or bonding materials.

Allgeyer, D. F.↗

NASA NTRS1982

Plastic deformation and wear process at a surface during unlubricated sliding

The plastic deformation and wear of a 304 stainless steel surface sliding against an aluminum oxide rider with a spherical surface (the radius of curvature: 1.3 cm) were observed by using scanning electron and optical microscopes. Experiments were conducted in a vacuum of one million Pa and in an environment of fifty thousandth Pa of chlorine gas at 25 C. The load was 500 grams and the sliding velocity was 0.5 centimeter per second. The deformed surface layer which accumulates and develops successively is left behind the rider, and step shaped proturbances are developed even after single pass sliding under both environmental conditions. A fully developed surface layer is gradually torn off leaving a characteristic pattern. The mechanism for tearing away of the surface layer from the contact area and sliding track contour is explained assuming the simplified process of material removal based on the adhesion theory for the wear of materials.

Yamamoto, T.↗

NASA NTRS1983

Plastic deformation and wear process at a surface during unlubricated sliding

Yamamoto, T.↗

NASA NTRS1986

Lithospheric necking - A dynamic model for rift morphology

Rifting is examined as the growth of a necking instability. A rift is nucleated by means of a small thickness perturbation imposed at the base of a strong layer which overlies a weaker substrate. The conditions for which the initial disturbance will amplify as the lithosphere extends are evaluated for a range of rheological parameters, and the associated pattern of near-surface deformation is determined. It was found that this unstable lithospheric extension results in a pattern of deformation that is consistent with the major morphological characteristics of rift zones. For an initial perturbation narrower than the dominant wavelength, deformation concentrates in a zone of width comparable to the dominant wavelength; for an initial thickness perturbation wider than the dominant wavelength, deformation develops periodically at the dominant wavelength in the region above the perturbation. It is noted that the width of a rift is essentially independent of the layer/substrate strength ratio. For a power law viscous surface layer (n = 3), the dominant wavelength varies with the layer/substrate strength ratio to the one-third power and is always larger than for a plastic surface layer of the same thickness. The unstable extension of a strong viscous surface layer may be responsible for the great width of rift zones on Venus.

Zuber, M. T.↗

NASA NTRS2013

Friction and Wear Modifiers Using Solvent Partitioning of Hydrophilic Surface-interactive Chemicals Contained in Boundary Layer-targeted Emulsions

A wear and/or friction reducing additive for a lubricating fluid in which the additive is a combination of a moderately hydrophilic single-phase compound and an anti-wear and/or anti-friction aqueous salt solution. The aqueous salt solution produces a coating on boundary layer surfaces. The lubricating fluid can be an emulsion-free hydrophobic oil, hydraulic fluid, antifreeze, or water. Preferably, the moderately hydrophilic single-phase compound is sulfonated castor oil and the aqueous salt solution additionally contains boric acid and zinc oxide. The emulsions produced by the aqueous salt solutions, the moderately hydrophilic single-phase compounds, or the combination thereof provide targeted boundary layer organizers that significantly enhance the anti-wear and/or anti-friction properties of the base lubricant by decreasing wear and/or friction of sliding and/or rolling surfaces at boundary layers.

Richmond, Robert Chafee↗

NASA NTRS2016

Friction and Wear Modifiers Using Solvent Partitioning of Hydrophilic Surface-Interactive Chemicals Contained in Boundary Layer-Targeted Emulsions

Richmond, Robert Chaffee↗

NASA NTRS2017

Friction and Wear Modifiers Using Solvent Partitioning of Hydrophilic Surface-Interactive Chemicals Contained in Boundary Layer-Targeted Emulsions

A wear and/or friction reducing additive for a lubricating fluid in which the additive is a combination of a moderately hydrophilic single-phase compound and an anti-wear and/or anti-friction aqueous salt solution. The aqueous salt solution produces a coating on boundary layer surfaces. The lubricating fluid can be an emulsion-free hydrophobic oil, hydraulic fluid, antifreeze, water, or a water-based lubricant. Preferably, the moderately hydrophilic single-phase compound is sulfonated castor oil and the aqueous salt solution additionally contains boric acid and zinc oxide. The emulsions produced by the aqueous salt solutions, the moderately hydrophilic single-phase compounds, or the combination thereof provide targeted boundary layer organizers that significantly enhance the anti-wear and/or anti-friction properties of the base lubricant by decreasing wear and/or friction of sliding and/or rolling surfaces at boundary layers.

Richmond, Robert Chaffee↗

NASA NTRS1990

Free convection in the Matian atmosphere

The 'free convective' regime for the Martian atmospheric boundary layer (ABL) was investigated. This state occurs when the mean windspeed at the top of the ABL drops below some critical value U(sub c) and positive buoyant forces are present. Such forces can arise either from vertical temperature or water vapor gradients across the atmospheric surface layer. During free convection, buoyant forces drive narrow plumes that ascend to the inversion height with a return circulation consisting of broad slower-moving downdraughts. Horizontal pressure, temperature, windspeed, and water vapor fluctuations resulting form this circulation pattern can be quite large adjacent to the ground (within the surface layer). The local turbulent fluctuations cause non-zero mean surface stresses, sensible heat fluxes, and latent heat fluxes, even when the mean regional windspeed is zero. Although motions above the surface layer are insensitive to the nature of the surface, the sensible and latent heat fluxes are primarily controlled by processes within the interfacial sublayer immediately adjacent to the ground during free convection. Thus the distinction between aerodynamically smooth and rough airflow within the interfacial sublayer is more important than for the more typical situation where the mean regional windspeed is greater than U(sub c). Buoyant forces associated with water vapor gradients are particularly large on Mars at low pressures and high temperatures when the surface relative humidity is 100 percent, enhancing the likelihood of free convection under these conditions. On this basis, Ingersol postulated the evaporative heat losses from an icy surface on Mars at 237 K and current pressures would exceed the available net radiative flux at the surface, thus prohibiting ice from melting at low atmospheric pressures. Schumann has developed equations describing the horizontal fluctuations and mean vertical gradients occurring during free convection. Schumann's model was generalized to include convection driven by water vapor gradients and to include the effects of circulation above both aerodynamically smooth and rough surfaces.

Clow, G. D.↗

DOE OSTI2023

Triboelectric nanogenerator for harvesting energy from water

An apparatus including a first member including a first electrode, a second member coupled to the first member about an axis, including a second electrode, and a surface layer between the first electrode and the second electrode, the second member is rotatable with respect to the axis by an energy flow to change triboelectric charges on the electrodes, and to affect a flow of electrons between the electrodes. A self-powered sensor for detecting a chemical including a generator having an electrode, and a superhydrophobic surface layer for receiving an energy flow carrying triboelectric charges, the surface layer includes a TiO 2 layer with nanostructures, and a power indicator indicative of whether the chemical is present based on power output of the triboelectric generator, the energy flow is a solution flow, the solution comprising the chemical and water, and the chemical removes at least one triboelectric charge from the water.

Wang, Zhong Lin↗

NASA NTRS1984

Recent studies of the ocean nitrogen cycle

The nitrogen cycle in the ocean is dominated by the activities of organisms. External nitrogen inputs from land and from the atmosphere are small compared with rates of consumption and production by organisms and with rates of internal rearrangements of nitrogen pools within the ocean. The chief reservoirs of nitrogen are, in decreasing order of size: nitrogen in sediments, dissolved N2, nitrate, dissolved organic nitrogen (DON), particulate organic nitrogen (PON) (mostly organisms and their by-products). The biogenic fluxes of nitrogen were reviewed. The rate of PON decomposition in the surface layer must be comparable to the rate of ammonium consumption; and at the same time the nitrate consumption rate will be similar to the rates of: (1) sinking of PON out of the surface layer and its decompositon at depth, (2) the rate of nitrification at depth, and (3) the rate of nitrate return to the surface layer by upwelling.

Eppley, R. W.↗

DOE OSTI2021

Surface Salinity Under Transitioning Ice Cover in the Canada Basin: Climate Model Biases Linked to Vertical Distribution of Fresh Water

Abstract The Canada Basin has exhibited a significant trend toward a fresher surface layer and thus a more stratified upper‐ocean over the past three decades. State‐of‐the‐art ice‐ocean models, by contrast, tend to simulate a surface layer that is saltier and less stratified than observed. Here, we examine decadal changes to seasonal processes that may contribute to this wide‐reaching model bias using climate model simulations from the Community Earth System Model and below‐ice observations from the Arctic Ice Dynamics Joint Experiment in 1975 and Ice Tethered Profilers in 2006–2012. In contrast to the observations, the models simulate salinity profiles that show relatively little variation between 1975 and 2012. We demonstrate that this bias can be mainly attributed to unrealistically deep vertical mixing in the model, creating a surface layer that is saltier than observed. The results provide insight for climate model improvement with broad implications for Arctic sea ice and ecosystem dynamics.

58 GEOSCIENCES↗

NASA NTRS1983

A critical study of the role of the surface oxide layer in titanium bonding

Scanning electron microscope/X-ray photoelectron spectroscopy (SEM/XPS) analysis of fractured adhesively bonded Ti 6-4 samples is discussed. The text adhesives incuded NR 056X polyimide, polypheylquinoxaline (PPQ), and LARC-13 polyimide. Differentiation between cohesive and interfacial failure was based on the absence of presence of a Ti 2p XPS photopeak. In addition, the surface oxide layer on Ti-(6A1-4V) adherends is characterized and bond strength and durability are addressed. Bond durability in various environmental conditions is discussed.

Dias, S.↗

NASA NTRS1985

Calculation of recoil implantation profiles using known range statistics

A method has been developed to calculate the depth distribution of recoil atoms that result from ion implantation onto a substrate covered with a thin surface layer. The calculation includes first order recoils considering projected range straggles, and lateral straggles of recoils but neglecting lateral straggles of projectiles. Projectile range distributions at intermediate energies in the surface layer are deduced from look-up tables of known range statistics. A great saving of computing time and human effort is thus attained in comparison with existing procedures. The method is used to calculate recoil profiles of oxygen from implantation of arsenic through SiO2 and of nitrogen from implantation of phosphorus through Si3N4 films on silicon. The calculated recoil profiles are in good agreement with results obtained by other investigators using the Boltzmann transport equation and they also compare very well with available experimental results in the literature. The deviation between calculated and experimental results is discussed in relation to lateral straggles. From this discussion, a range of surface layer thickness for which the method applies is recommended.

Fung, C. D.↗

DOE OSTI2021

Connection Between Mass Flux Transport and Eddy Diffusivity in Convective Atmospheric Boundary Layers

Turbulence parameterizations for convective boundary layer in coarse-scale atmospheric models usually consider a combination of the eddy-diffusive transport and a non-local transport, typically in the form of a mass flux term, such as the widely adopted eddy-diffusivity mass-flux (EDMF) approach. These two types of turbulent transport are generally considered to be independent of each other. Using results from large-eddy simulations, here, we show that a Taylor series expansion of the updraft and downdraft mass-flux transport can be used to approximate the eddy-diffusivity transport in the atmospheric surface layer and the lower part of the mixed layer, connecting both eddy-diffusivity and mass-flux transport theories in convective conditions, which also quantifies departure from the Monin-Obukhov similarity (MOS) in the surface layer. This study provides a theoretical support for a unified EDMF parameterization applied to both the surface layer and mixed layer and highlights important correction required for surface models relying on MOS

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1976

Remote sensing of soil moisture

The surface emissivity and reflectivity of soil are strong functions of its moisture content. Changes in emissivity, observed by passive microwave techniques (radiometry), and changes in reflectivity, observed by active microwave techniques (radar), can provide information on the moisture content of the 0 to 5 cm surface layer. In addition, the thermal inertia of the surface layer, which can be remotely sensed by observing the diurnal range of surface temperature, is an indicator of soil moisture content. The thermal infrared approach to remote sensing of soil moisture has little utility in the presence of cloud cover, but provides soil moisture data at high spatial resolutions and thermal data which are a potentially useful indicator of crop status. Microwave techniques can penetrate cloud covers. The passive technique has been demonstrated by both aircraft and spacecraft instruments, but spatial resolution is limited by the size of the antenna which can be flown. Active microwave systems offer the possibility of better spatial resolution, but have yet to be demonstrated from aircraft or spacecraft platforms.

Schmugge, T.↗