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Results for “Spectral mixture analysis”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

A unique method to study acoustic transmission through ducts using signal synthesis and averaging of acoustic pulses

An acoustic impulse technique using a loudspeaker driver is developed to measure the acoustic properties of a duct/nozzle system. A signal synthesis method is used to generate a desired single pulse with a flat spectrum. The convolution of the desired signal and the inverse Fourier transform of the reciprocal of the driver's response are then fed to the driver. A signal averaging process eliminates the jet mixing noise from the mixture of jet noise and the internal noise, thereby allowing very low intensity signals to be measured accurately, even for high velocity jets. A theoretical analysis is carried out to predict the incident sound field; this is used to help determine the number and locations of the induct measurement points to account for the contributions due to higher order modes present in the incident tube method. The impulse technique is validated by comparing experimentally determined acoustic characteristics of a duct-nozzle system with similar results obtained by the impedance tube method. Absolute agreement in the comparisons was poor, but the overall shapes of the time histories and spectral distributions were much alike.

Salikuddin, M.↗
NASA NTRS1993

Passive microwave remote sensing of thin sea ice using principal component analysis

The possibility of developing a satellite-based sea-ice-concentration algorithm which solves for the presence of thinner ice is explored on the basis of time sequences of surface-based measurements of passive MW emission from growing saline ice reported by Wensnahan et al. (1993). It is shown that two classes of thinner ice can be distinguished from mixtures of open water, first-year ice, and multiyear ice. Newly formed ice appears to be optically thick at 37 and 90 GHz and has a relatively dry surface. The thin ice spectrum occurs when the ice is greater than 4 cm thick and appears to result from the accumulation of brine at the ice surface. Thin ice has a relatively stable spectrum characterized by high brightness temperatures, a near-zero spectral gradient at vertical polarization, and a large difference between vertical and horizontal polarizations. It is concluded that thin ice can be detected using satellite data.

Wensnahan, Mark↗
DOE OSTI2016

Comprehensive Metabolite Identification Strategy Using Multiple Two-Dimensional NMR Spectra of a Complex Mixture Implemented in the COLMARm Web Server

Identification of metabolites in complex mixtures represents a key step in metabolomics. A new strategy is introduced, which is implemented in a new public web server, COLMARm, that permits the co-analysis of up to three 2D NMR spectra, namely 13C-1H HSQC, 1H-1H TOCSY, and 13C-1H HSQC-TOCSY for the comprehensive, accurate, and efficient performance of this task. The highly versatile and interactive nature of COLMARm permits its application to a wide range of metabolomics samples independent of the magnetic field. Database query is performed using the HSQC spectrum and the top metabolite hits are then validated against the TOCSY-type experiment(s) by superimposing the expected cross-peaks on the mixture spectrum. In this way the user can directly accept or reject candidate metabolites by taking advantage of the complementary spectral information offered by these experiments and their different sensitivities. The power of COLMARm is demonstrated for a human serum sample uncovering the existence of 14 metabolites that hitherto were not identified by NMR.

Bingol, Kerem↗
NASA NTRS1976

A correlation study based on Al/Si X-ray fluorescence data from southwestern part of Mare Serenitatis

A correlation study based on Al/Si intensity ratios, broad-spectrum visible-albedo measurements, color-difference photography, color-ratio images, and spectral-reflectivity curves was undertaken to understand why the Tacquet Formation in southwestern Mare Serenitatis has unusually low visible albedos for the Al/Si intensity ratios measured by the Apollo 15 X-ray fluorescence experiment. The statistical analysis of the Al/Si data is described, general correlations among all the remote-sensing data are noted, and correlations in the area of the Tacquet Formation are examined. It is shown that the discrepancy between visible albedos and Al/Si intensities may be due primarily to the presence of unevenly deposited highland-type ejecta from Menaleus crater, although the possibility cannot be excluded that the Tacquet Formation is more complex than a simple mixture of highland and mare materials.

Andre, C. G.↗
NASA NTRS1981

Analysis of condensates formed at the Viking 2 lander site - The first winter

Relative surface albedo, spectral reflectance estimates and a limited photometric function are reduced from Viking 2 lander data obtained during a 249 Mars day period, in the lander's first year, when a light ground covering appeared on the surface. During the deposition, surface broadband albedo more than doubled and blue reflectance increased by a factor of 4.0. Comparison of lander data with earlier laboratory measurements of CO2 and H2O frosts and snows shows that reflectance estimates do not resemble either of those solids. The condensate reflectance resembles that of the surface after the covering disappeared. The covering may have been colored by dust which fell before it, by dust mixed with it, or by dust on top of it; but the data strongly support a mixture of dust with H2O and CO2 solids. The covering thickness is estimated to be between 0.5 and a few millimeters.

Wall, S. D.↗
DOE OSTI2015

SPATIALLY RESOLVED SPECTROSCOPY OF EUROPA: THE DISTINCT SPECTRUM OF LARGE-SCALE CHAOS

We present a comprehensive analysis of spatially resolved moderate spectral resolution near-infrared spectra obtained with the adaptive optics system at the Keck Observatory. We identify three compositionally distinct end member regions: the trailing hemisphere bullseye, the leading hemisphere upper latitudes, and a third component associated with leading hemisphere chaos units. We interpret the composition of the three end member regions to be dominated by irradiation products, water ice, and evaporite deposits or salt brines, respectively. The third component is associated with geological features and distinct from the geography of irradiation, suggesting an endogenous identity. Identifying the endogenous composition is of particular interest for revealing the subsurface composition. However, its spectrum is not consistent with linear mixtures of the salt minerals previously considered relevant to Europa. The spectrum of this component is distinguished by distorted hydration features rather than distinct spectral features, indicating hydrated minerals but making unique identification difficult. In particular, it lacks features common to hydrated sulfate minerals, challenging the traditional view of an endogenous salty component dominated by Mg-sulfates. Chloride evaporite deposits are one possible alternative.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1992

Use of AVIRIS data to the definition of optimised specifications for land applications with future spaceborne imaging spectrometers

Recent experience with airborne imaging spectrometers demonstrated the advantages of narrow band sensors over broad band scanners for characterizing the nature, extent, and physical status of typical land surfaces. Information on key spectral features associated with various land surfaces can be obtained from the data of such instruments, which can be used to simulate spaceborne imaging spectrometer data and to assess their information content if comprehensive underpinning is provided by ground data. The collection of such information was an issue of airborne imaging spectrometer campaigns like the NASA MAC-Europe 1991. Airborne and ground data obtained from different test sites in Europe are utilized for a comparative analysis of the spectral signatures of various land surfaces (vegetation, bare soils and rocks, and mixed soil/rock-vegetation) as seen from different imaging spectrometers like Airborne Visible/Infrared Imaging Spectrometer (AVIRIS), GERIS 63 band scanner, and CASI. The following items are discussed: (1) the significance of different spectral regions within the wavelength interval between 0.4 m and 2.5 m for the differentiation of different land units; (2) recommendations on the optimum band selection and band-widths to be used for the application of future satellite-based imaging spectrometers for land applications; (3) the boundaries for the detection of plant features in mixed-soil plant spectra and the influence of different soil properties on the mixture of the spectra; (4) recommendations on the optimum spatial resolution and recording dates for the discrimination of spectral features of various surface types; and (5) evaluation of different data compressing techniques for the optimum extraction of spectral information from imaging spectrometry data.

Bodechtel, J.↗
NASA NTRS2000

The X-Ray Core of the Low-Luminosity Radio Galaxy 3C346 and ASCA Spectroscopy to Test BL LAC/Radio Galaxy Unification

Radio galaxies are relatively faint sources for Advanced Spacecraft for Cosmology Astrophysics (ASCA), and so in order to get the best possible results from the observations two things have been necessary, both of which delayed the fast preparation of papers. Firstly, the best possible data screening and background subtraction were necessary to improve the signal-to-noise, and all our several initial analysis trials were discarded in favor of using FTOOLS versions 4.1 and above. Secondly, we found that the ASCA spectra were statistically too poor to discriminate well between non-thermal and thermal models, never mind the mixture of the two which we expected on the basis of our ROSAT spatial separation of components in radio galaxies. This means that in each case we have needed to combine the ASCA spectroscopy with analysis of data from other X-ray or radio observations in order to exploit the ASCA data to the full. Our analysis for 3C 346 has yielded the cleanest final result. This powerful radio galaxy at a redshift of 0.161, lies in a poor cluster, which we have separated well from the dominant X-ray component of unresolved emission using a spatial analysis of archival ROSAT data. We were then able to fix the thermal component in our ASCA spectral analysis, and have found evidence that the unresolved emission varied by 32 +/- 13% over the 18 months between the ROSAT and ASCA observations. The unresolved X-ray emission does not suffer from intrinsic absorption, and we have related it to radio structures on both milliarcsecond scales and the arcsecond scales which Chandra can resolve. The source is a target of a Chandra AO2 proposal which we have recently submitted to follow up on our ASCA (and ROSAT) work. 3C 346's orientation to the line of sight is uncertain. However, the absence of X-ray absorption, and the radio/optical/X-ray colors, when combined with with previous radio evidence that the source is a foreshortened radio galaxy of the FRII class, suggest that the radio jets are seen at an angle to the line of sight of about 30 deg, intermediate between the radio-galaxy and quasar classes. The relatively hard ASCA response has allowed us to place an upper limit of 5.6 x 10(exp 43) ergs/ s on the 2-10 keV luminosity of any central X-ray component absorbed bN, gas which might be obscuring the broad-line emission region. Attached to this report is an almost final draft of a paper which we have prepared for submission to the Astrophysical Journal. Our combined ASCA and ROSAT results for NGC 6251 rule out our previously preferred flat-spectrum model and inverse-Compton interpretation for the source based on ROSAT data alone, but a softer X-ray spectrum and moderate absorption bring all the available data (including our early VLA HI measurements) into consistency, and we are reasonably confident that we understand the processes responsible for the X-ray emission. We have made some more sensitive HI absorption measurements which are currently being analyzed, and our plans are to publish our ASCA analysis in conjunction with the new HI results. The ASCA data for NGC 4261 have been difficult to interpret. A re-analysis of our ROSAT data with a wider range of physical parameters brings the ROSAT and ASCA results into reasonable agreement only if the emission from hot gas dominates more than suggested by our earlier work, which is itself unexpected since the radio core is bright and a large jet-related X-ray component would bring the source into agreement with results for others of its type. However, we have recently received our Chandra A01 data for this source, with the spatial resolution which allows us to separate thermal and non-thermal emission components. Our ASCA results will be re-interpreted once the analysis of our Chandra data is complete. The interpretation of the ASCA data for BL Lac object 3C 371 is ongoing, in conjunction with analysis of archival multifrequency data. Radio galaxies are complex in their X-ray properties, and hindsight has shown that the spatial resolution of ASCA is too poor for a reliable interpretation of the data without drawing on other observations. However, the ASCA spectra have made a useful contribution to the interpretation of these sources, and the groundwork is now there for more sensitive work using Chandra and XMM-Newton.

Worrall, Diana↗
DOE OSTI2023

Gaps labeling theorem for the bubble-diamond self-similar graphs

Abstract Motivated by the appearance of fractals in several areas of physics, especially in solid state physics and the physics of aperiodic order, and in other sciences, including the quantum information theory, we present a detailed spectral analysis for a new class of fractal-type diamond graphs, referred to as bubble-diamond graphs, and provide a gap-labeling theorem in the sense of Bellissard for the corresponding probabilistic graph Laplacians using the technique of spectral decimation. Labeling the gaps in the Cantor set by the normalized eigenvalue counting function, also known as the integrated density of states, we describe the gap labels as orbits of a second dynamical system that reflects the branching parameter of the bubble construction and the decimation structure. The spectrum of the natural Laplacian on limit graphs is shown generically to be pure point supported on a Cantor set, though one particular graph has a mixture of pure point and singularly continuous components.

Physics↗
DOE OSTI2016

SICK: THE SPECTROSCOPIC INFERENCE CRANK

There exists an inordinate amount of spectral data in both public and private astronomical archives that remain severely under-utilized. The lack of reliable open-source tools for analyzing large volumes of spectra contributes to this situation, which is poised to worsen as large surveys successively release orders of magnitude more spectra. In this article I introduce sick, the spectroscopic inference crank, a flexible and fast Bayesian tool for inferring astrophysical parameters from spectra. sick is agnostic to the wavelength coverage, resolving power, or general data format, allowing any user to easily construct a generative model for their data, regardless of its source. sick can be used to provide a nearest-neighbor estimate of model parameters, a numerically optimized point estimate, or full Markov Chain Monte Carlo sampling of the posterior probability distributions. This generality empowers any astronomer to capitalize on the plethora of published synthetic and observed spectra, and make precise inferences for a host of astrophysical (and nuisance) quantities. Model intensities can be reliably approximated from existing grids of synthetic or observed spectra using linear multi-dimensional interpolation, or a Cannon-based model. Additional phenomena that transform the data (e.g., redshift, rotational broadening, continuum, spectral resolution) are incorporated as free parameters and can be marginalized away. Outlier pixels (e.g., cosmic rays or poorly modeled regimes) can be treated with a Gaussian mixture model, and a noise model is included to account for systematically underestimated variance. Combining these phenomena into a scalar-justified, quantitative model permits precise inferences with credible uncertainties on noisy data. I describe the common model features, the implementation details, and the default behavior, which is balanced to be suitable for most astronomical applications. Using a forward model on low-resolution, high signal-to-noise ratio spectra of M67 stars reveals atomic diffusion processes on the order of 0.05 dex, previously only measurable with differential analysis techniques in high-resolution spectra. sick is easy to use, well-tested, and freely available online through GitHub under the MIT license.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Fuel Injection Dynamics and Composition Effects on RDE Performance

Rotating detonation engines (RDEs) provide a promising route to substantially increasing cycle efficiency in stationary gas turbines. Much of this increase relies on the ability to achieve consistent pressure gain within the combustor. In particular, the design of injectors that feed fuel and air into the detonation channel plays a crucial role. Such injectors have to ensure proper mixing of fuel and oxidizer, while minimizing backflow of detonation products into the feed plenums, and reduce susceptibility to the complex wave structures that exist within the combustor. From a practical perspective, such RDEs also need to operate with variable fuel composition. When fuel mixtures with components that possess vastly different oxidation pathways and time-scales are used, there could be additional losses through deflagrative burning instead of detonation-driven heat release. Such sensitivity to the complete flow path is akin to the physics of thermoacoustic instabilities in conventional gas turbines. In this sense, RDEs pose a unique research challenge: the performance of the device relies on the small-scale heat release process, which is highly dependent on the flow interactions within the full-scale system. As a result, canonical flow configurations, instrumented with detailed diagnostics or modeled using high-fidelity tools, but only focus on the small-scale processes will not contain the key system-level interactions. At the same time, macroscopic measurements and models that only capture system-level performance will not provide insight into the key sources of pressure losses. These couplings and sensitivities provide a formidable challenge to both experimental and simulation studies of the effects Thus, a joint experimental/computational program designed specifically to address these challenges was undertaken in this program. The focus of this program was on two key topics: a) the interaction between injector flow and the overall wave dynamics within the combustor, and b) the deflagration/detonation structure in multi-component fuels that are of practical interest. Both topics involve interaction of small-scale heat release processes with the geometry-dependent wave structure. Studies focused on the study of full-scale RDE systems, based on a 6-inch conventional annular geometry. Experimentally RDEs were studied using a combination of diagnostics. A combination of optical diagnostics and aero-thermo-acoustic analysis based on a combination of spectral and mode decomposition analysis was used to identify the dynamics of the detonation wave and other secondary waves that exist in the system. These studies have helped the identification and investigation of injector and detonation dynamics arising from coupling, and how they affect RDE mixing, detonation structure, operability and performance. Performance of RDEs was investigated through thrust stand measurements, which was used to evaluate the effective pressure gain generated by the system through the concept of equivalent available pressure. Optical diagnostics were developed and implemented to investigate the distribution of heat release, across the detonation wave. Novel optical diagnostics of NIR imaging was also developed and applied to investigate the high temperature / high pressure distribution across the detonation wave. In order to complement the experiments, the computational tools were geared to simulate the full experimental setup. GPU-based acceleration of the models and computations were developed to enable rapid simulation of the full system. In addition, the use of adaptive mesh refinement, and unstructured grid formulation, enabled the investigation of realistic geometries studied in the laboratory. The simulations produced a wealth of detail on the structure of the detonation wave under different operating conditions. Emphasis was placed on quantifying mixture pre-burning and the impact on wave propagation and structure.

03 NATURAL GAS↗
NASA NTRS1979

Investigation of surface fluctuating pressures on a 1/4 scale YC-14 upper surface blown flap model

Fluctuating pressures were measured at 30 positions on the surface of a 1/4-scale YC-14 wing and fuselage model during an outdoor static testing program. These data were obtained as part of a NASA program to study the fluctuating loads imposed on STOL aircraft configurations and to further the understanding of the scaling laws of unsteady surface pressure fields. Fluctuating pressure data were recorded at several discrete engine thrust settings for each of 16 configurations of the model. These data were reduced using the technique of random data analysis to obtain auto-and cross-spectral density functions and coherence functions for frequencies from 0 to 10 kHz, and cross-correlation functions for time delays from 0 to 10.24 ms. Results of this program provide the following items of particular interest: (1) Good collapse of normalized PSD functions on the USB flap was found using a technique applied by Lilley and Hodgson to data from a laboratory wall-jet apparatus. (2) Results indicate that the fluctuating pressure loading on surfaces washed by the jet exhaust flow was dominated by hydrodynamic pressure variations, loading on surface well outside the flow region dominated by acoustic pressure variations, and loading near the flow boundaries from a mixture of the two.

Pappa, R. S.↗
NASA NTRS1987

Preliminary analysis of recent 2.2-4.2 micrometers telescopic observations of Elysium, Mars: Implications for crystallinity and hydration state of surface materials

Comparisons of the telescopic reflectance spectrum of a Martian bright region, in the 2.2 to 4.2 micrometers region, with recent laboratory studies of materials in this same wavelength range are consistent with: terrestrial materials which are dehydrated relative to the terrestrial environment, and terrestrial materials which exhibit spectral behavior indicative of some degree of sample crystallinity which is greater than that of amorphous palagonites. This second conclusion is in agreement with recent suggestions concerning the Martian bright regions. However, additional laboratory research is required in order to constrain: the degree of crystallinity required to result in the 2.8 to 2.9 micrometers spectral behavior seen in the terrestrial samples, and the limit of crystalline material which can be accommodated in a mixture with measured telescopic data of Mars (0.3 to 4.2 micrometers).

Roush, T. L.↗
DOE OSTI2016

Morpheus Spectral Counter: A computational tool for label-free quantitative mass spectrometry using the Morpheus search engine

Label-free quantitative MS based on the Normalized Spectral Abundance Factor (NSAF) has emerged as a straightforward and robust method to determine the relative abundance of individual proteins within complex mixtures. Here, we present Morpheus Spectral Counter (MSpC) as the first computational tool that directly calculates NSAF values from output obtained from Morpheus, a fast, open-source, peptide-MS/MS matching engine compatible with high-resolution accurate-mass instruments. NSAF has distinct advantages over other MS-based quantification methods, including a higher dynamic range as compared to isobaric tags, no requirement to align and re-extract MS1 peaks, and increased speed. MSpC features an easy to use graphic user interface that additionally calculates both distributed and unique NSAF values to permit analyses of both protein families and isoforms/proteoforms. MSpC determinations of protein concentration were linear over several orders of magnitude based on the analysis of several high-mass accuracy datasets either obtained from PRIDE or generated with total cell extracts spiked with purified Arabidopsis 20S proteasomes. Lastly, the MSpC software was developed in C# and is open sourced under a permissive license with the code made available at http://dcgemperline.github.io/Morpheus_SpC/.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2018

Certification of Control Gas Mixtures Using Modern Spectroscopy: an Approach and Application

The possibility of using the available spectroscopic databases for high-precision measurements of spectral parameters of gases has been studied. A new approach to measuring concentrations of gaseous components (НCl, CO, NO, SO{sub 2}) in gas mixtures employing the HITRAN or GEISA spectroscopic databases has been proposed. A certification method of control gas mixtures using Fourier-transform IR spectroscopy has been developed to transfer the mole-fraction units to working standards in order to reduce the required number of reference standards and improve the accuracy of measurements.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2020

Optimized Profile Retrievals of Aerosol Microphysical Properties from Simulated Spaceborne Multiwavelength Lidar

This work is an expanded study of one previously published onretrievals of aerosol microphysical properties from space-borne multiwavelengthlidarmeasurements. The earlier studiesand this one weredone in the framework of the NASA Aerosol-Clouds-Ecosystems (now the Aerosol Clouds Convection and Precipitation) NASA mission. The focus here is on the capabilities of a simulated spacebornemultiwavelengthlidar system for retrieving aerosol complex refractive index (m = mr+ imi) and spectral single scattering albedo (SSA(λ)), although other bulk parameters such as effective (reff) radius and particle volume (V) and surface (S) concentrations are also studied. The novelty presented here is the use of recently published, case dependent optimized-constraints on the microphysical retrievals using three backscattering coefficients (β) at 355, 532 and 1064 nm and two extinction coefficients (α) at 355 and 532 nm, typically known as the stand-alone 3β+2α lidar inversion. Case-dependent optimized-constraints (CDOC) limit the ranges of refractive index, both real (mr) and imaginary (mi) parts, and of radii that are permitted in the retrievals. Such constraints are selected directly from the 3β+2α41measurements through an analysis of the relationship between spectral dependence of aerosol extinction-to-backscatter ratios (LR) and the Ångström exponent of extinction. The analyses presented here for different sets ofsize distributions and refractive indices reveal that the direct determination of CDOCareonly feasible for cases where the uncertaintiesin the input optical data areless than 15 %.Forthe same simulated spacebornesystem and yield than in Whiteman et al., (2018), we demonstrated that the use of CDOC as essential for the retrievals of refractive index and also largely improved retrieval of bulk parameters. A discussion of the global representativeness of CDOC is presented using simulated lidar data from a 24-hour satellite track using GEOS model output to initialize the lidar simulator.We found that CDOCare representative of many aerosol mixtures in spite of some outliers (e.g. highly hydrated particles) associatedwith the assumptions of bimodal size distributions and of the same refractive index for fine and coarse modes. Moreover, sensitivity tests performed using synthetic data reveal that retrievals of imaginary refractive index (mi) and SSA are extremely sensitive to β(355).

NASA Aerosol-Clouds-Ecosystems↗
DOE OSTI2016

Broadband multi-resonant strong field coherence breaking as a tool for single isomer microwave spectroscopy

Using standard hardware available in chirped-pulse Fourier transform microwave (CP-FTMW) spectroscopy, an experimental method is introduced to selectively extract from the microwave spectrum of an otherwise complicated multicomponent mixture a set of transitions due to a single component, thereby speeding spectral assignment. The method operates the broadband chirped-pulse used to excite the sample in the strong-field limit through a combination of high power and control of the sweep rate. A procedure is introduced that leads to selection of three transition frequencies that can be incorporated as a set of resonant sequential single-frequency microwave pulses that follow broadband chirped-pulse excitation, resulting in a reduction in the coherent signal from a set of transitions ascribable to the component of interest. The difference in the CP-FTMW spectrum with and without this set of multi-resonant single-frequency pulses produces a set of transitions that can confidently be assigned to a single component of the mixture, aiding the analysis of its spectrum. In conclusion, the scheme is applied to (i) selectively extract the spectrum of one of five singly 13 C-subsituted isotopologues of benzonitrile in natural abundance, (ii) obtain the microwave spectra of the two structural isomers (E)- and (Z)-phenylvinylnitrile, and (iii) obtain conformer-specific microwave spectra of methylbutyrate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2009

Multispectrum Analysis of 12CH4 in the v4 Band: I. Air-Broadened Half Widths, Pressure-Induced Shifts, Temperature Dependences and Line Mixing

Lorentz air-broadened half widths, pressure-induced shifts and their temperature dependences have been measured for over 430 transitions (allowed and forbidden) in the v4 band of (CH4)-12 over the temperature range 210 to 314 K. A multispectrum non linear least squares fitting technique was used to simultaneously fit a large number of high-resolution (0.006 to 0.01/cm) absorption spectra of pure methane and mixtures of methane diluted with dry air. Line mixing was detected for pairs of A-, E-, and F-species transitions in the P- and R-branch manifolds and quantified using the off-diagonal relaxation matrix elements formalism. The measured parameters are compared to air- and N2-broadened values reported in the literature for the v4 and other bands. The dependence of the various spectral line parameters upon the tetrahedral symmetry species and rotational quantum numbers of the transitions is discussed. All data used in the present work were recorded using the McMath-Pierce Fourier transform spectrometer located at the National Solar Observatory on Kitt Peak.

Smith, MaryAnn H.↗