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At least 217 records · Page 12

THz Spectroscopy of the Atmosphere

THz spectroscopy of the atmosphere has been driven by the need to make remote sensing measurements of OH. While the THz region can be used for sensitive detection on many atmospheric molecules, the THz region is the best region for measuring the diurnal behavior of stratospheric OH by remote sensing. The infrared region near 3 microns suffers from chemiluminescence and from spectral contamination due to water. The ultraviolet region near 300 nm requires solar illumination. The three techniques for OH emission measurements in the THz region include Fourier Transform interferometry, Fabry-Perot interferometry, and heterodyne radiometry. The first two use cryogenic direct detectors while the last technique uses a local oscillator and a mixer to down convert the THz signal to GHz frequencies. All techniques have been used to measure stratospheric OH from balloon platforms. OH results from the Fabry-Perot based FILOS instrument will be given. Heterodyne measurement of OH at 2.5 THz has been selected to be a component of the Microwave Limb Sounder on the Earth Observing System CHEM-1 polar satellite. The design of this instrument will be described. A balloon-based prototype heterodyne 2.5 THz radiometer had its first flight on, 24 May 1998. Results form this flight will be presented.

Pickett, Herbert M.↗

NASA GEOS Composition Forecast Modeling System GEOS-CF v1.0: Stratospheric Composition

The NASA Goddard Earth Observing System (GEOS) Composition Forecast (GEOS-29CF) provides recent estimates and five-day forecasts of atmospheric composition to the public in near-real time. To do this, the GEOS Earth system model is coupled with the GEOS-Chem tropospheric-stratospheric unified chemistry extension (UCX) to represent composition from the surface to the top of the GEOS atmosphere (0.01 hPa). The GEOS-CF system is described, including updates made to the GEOS-Chem UCX mechanism within GEOS-CF for improved representation of stratospheric chemistry. Comparisons are made against balloon, lidar and satellite observations for stratospheric composition, including measurements of ozone (O3) and important nitrogen and chlorine species related to stratospheric O3recovery. The GEOS-CF nudges the stratospheric O3towards the GEOS Forward Processing (GEOS FP) assimilated O3product; as a result the stratospheric O3in the GEOS-CF historical estimate agrees well with observations. During abnormal dynamical and chemical environments such as the 2020 polar vortexes, the GEOS-CF O3forecasts are more realistic than GEOS FP O3forecasts because of the inclusion of the complex GEOS-Chem UCX stratospheric chemistry. Overall, the spatial patterns of the GEOS-CF simulated concentrations of stratospheric composition agree well with satellite observations. However, there are notable biases – such as low NOx and HNO3 in the polar regions and generally low HCl throughout the stratosphere – and future improvements to the chemistry mechanism and emissions are discussed. GEOS-CF is a new tool for the research community and instrument teams observing trace gases in the stratosphere and troposphere, providing near-real-time three-dimensional gridded information on atmospheric composition.

GEOS-CF↗

Balloon-borne measurements of the ultraviolet flux in the Arctic stratosphere during winter

Filter radiometers sensitive from 280 to 320 nm and from 280 to 400 nm, respectively, were used for measurements of the actinic flux in the stratosphere. Since the instruments are calibrated for absolute spectral sensitivity the data can be compared with model calculations of the actinic flux. Data were obtained during seven balloon flights during the European Arctic Stratospheric Ozone Experiment (EASOE).

Schiller, Cornelius↗

A feasibility study for measuring stratospheric turbulence using metrac positioning system

The feasibility of obtaining measurements of Lagrangian turbulence at stratospheric altitudes is demonstrated by using the METRAC System to track constant-level balloons. The basis for current estimates of diffusion coefficients are reviewed and it is pointed out that insufficient data is available upon which to base reliable estimates of vertical diffusion coefficients. It is concluded that diffusion coefficients could be directly obtained from Lagrangian turbulence measurements. The METRAC balloon tracking system is shown to possess the necessary precision in order to resolve the response of constant-level balloons to turbulence at stratospheric altitudes. A small sample of data recorded from a tropospheric tetroon flight tracked by the METRAC System is analyzed to obtain estimates of small-scale three-dimensional diffusion coefficients. It is recommended that this technique be employed to establish a climatology of diffusion coefficients and to ascertain the variation of these coefficients with altitude, season, and latitude.

Gage, K. S.↗

Stratospheric minor species vertical distributions during polar winter by balloon borne UV-Vis spectrometry

A light, relatively cheap and easy to operate balloonborne UV-visible spectrometer was designed for investigating ozone photochemistry in the Arctic winter. The instrument was flown 11 times during the European Arctic Stratospheric Ozone Experiment (EASOE) in winter 1991-92 in Northern Scandinavia. The first simultaneous measurements of vertical distributions of aerosols, PSC's, O3, NO2 and OClO inside the vortex during flight no. 6 on 16 January, in cold conditions are reported, which show that nitrogen oxides were almost absent (lower than 100 ppt) in the stratosphere below 22 km, while a layer of relatively large OClO concentration (15 ppt) was present at the altitude of the minimum temperature.

Pommereau, J. P.↗

COS in the stratosphere

Carbonyl sulfide (COS) has been detected in the stratosphere, and mixing ratio measurements are reported for altitudes of 15.2 to 31.2 km. A large volume, cryogenic sampling system mounted on board a U-2 aircraft has been used for lower stratosphere measurements and a balloon platform for measurement at 31.2 km. These observations and measurements strongly support the concept that stratospheric COS is an important precursor in the formation of sulfuric acid aerosols.

Inn, E. C. Y.↗

Balloon-borne laser heterodyne radiometer for measurements of stratospheric trace species

A laser heterodyne radiometer has been flown to measure chlorine monoxide in the stratosphere, which has an important role in the catalytic destruction of ozone. The measured values in the 35-38 km region are found to be significantly higher than model predictions, and the drop-off at lower altitudes occurs at a higher rate, even after adjusting the profile to include the solar zenith angle effects.

Menzies, R. T.↗

Comparison of ozone profiles from ground-based lidar, electrochemical concentration cell balloon sonde, ROCOZ-A rocket ozonesonde, and Stratospheric Aerosol and Gas Experiment satellite measurements

A series of coordinated atmospheric ozone profile measurements was made during October and November 1988. Only SAGE II measurements made within 1000 km of both of the ground, sites were considered for this intercomparison study. It was found that, at least for the time of year of the study, SAGE II measurements agreed only when they were made much closer than 1000 km (less than 500 km) from the other sites, and this is explained in terms of the large latitudinal gradient observed in the ozone concentration profile. Agreement to 5 percent was seen between the instruments, over the altitude range from 20 to 50 km, when the measurements were made close together in both time and space.

Mcdermid, I. S.↗

Balloon borne in-situ detection of OH in the stratosphere from 37 to 23 km

The OH number density in the stratosphere has been measured over the altitude interval of 37 to 23 km at midday via a balloon-borne gondola launched from Palestine, Texas on July 6, 1988. OH radicals are detected with a laser-induced fluorescence instrument employing a 17-kHz-repetition-rate copper vapor laser-pumped dye laser optically coupled to an enclosed flow, in-situ sampling chamber. OH abundances ranged from 88 + or - 3l pptv in the 36 to 35 km interval to 0.9 + or - 0.8 pptv in the 24 to 23 km interval. The stated uncertainty includes that from both measurement precision and accuracy. Simultaneous detection of ozone and water vapor densities was carried out with separate on-board instruments.

Stimpfle, R. M.↗

A CONSIDERATION OF THE U.S. NAVY STRATO-LAB BALLOON PROGRAM AND ITS CONTRIBUTIONS TO MANNED SPACE FLIGHT

As the coined name Strato-Lab implies, it is a program which provides a stratospheric laboratory utilizing a plastic balloon platform for manned research investigations. The project was originated in 1954; actual work began early in 1955 and the first manned stratospheric flights were made in 1956. It was conceived and has been continued with the following three objectives: (1) Provide a high-altitude research system, a scientific laboratory, permitting man's active scientific participation (2) Provide an opportunity for studies of man's reactions to an actual environment of physiological and psychological stress (3) Allow an opportunity for man to conduct tests and evaluate specific components and/or techniques in an extremely high altitude environment.

Stratosphere↗

Intercomparison of remote measurements of stratospheric NO and NO2

During the 1982 and 1983 Balloon Intercomparison Campaigns, the vertical profile of stratospheric NO2 was measured remotely by nine instruments and that of NO by two. Total overhead columns were measured by two more instruments. Between 30 and 35 km, where measurements overlapped, agreement between NO profiles was within + or - 30 percent, which is better than the accuracies claimed by the experimenters. Between 35 and 40 km, there was similarly good agreement between NO2 profiles, but below 30 km, differences of greater than a factor of 3 were found. In the second campaign, NO2 values from most instruments agreed within their quoted errors, except that the Oxford radiometer gave much lower values; the first campaign and the column measurements show a more uniform spread of results.

Roscoe, H. K.↗

Balloon-borne diode-laser absorption spectrometer for measurements of stratospheric trace species

An instrument has been designed for the measurement of stratospheric trace species which utilizes tunable infrared diode lasers as sources for sensitive in situ absorption spectroscopy in selected wavelength regions. This instrument, the Balloon-Borne Laser In Situ Sensor (BLISS), is a high-resolution absorption spectrometer designed to provide measurements of the concentrations of stratospheric species and their diurnal variations. The instrument employs second-harmonic detection of the absorption of tunable diode laser (TDL) radiation (3-30 microns) in a 1 km path length defined by a retroreflector lowered 0.5 km below the BLISS gondola. Retroreflector tracking under microprocessor control is obtained using a He-Ne laser and coaligned TV camera with CID imaging. Simultaneous measurements of molecular species in the 20-40 km altitude range will be performed using four TDLs, with the predicted minimum-detectable mixing ratio at 30 km being typically less than or equal to 0.1 ppbv.

Menzies, R. T.↗

UV photon counting detectors for high-altitude balloon and sounding rocket experiments

We report on development of ultraviolet photon counting detectors based on the 2D-doped and atomic layer deposition (ALD) custom coated electron multiplying CCD (EMCCDs) and their deployment in a high-altitude balloon experiment Faint Intergalactic-medium Redshifted Emission Balloon (FIREBall)-2 that was launched on September 22, 2018. The detector quantum efficiency (QE) was optimized for the narrow stratospheric window of a balloon at 200 - 225 nm.

Jones, Todd J.↗

In situ Mars ozone detector

We propose sending a balloon-borne UV photometer sensor package to measure atmospheric ozone on Mars, and this package could be a Discovery Program sensor candidate. Past measurements of ozone on Mars are highly uncertain, perhaps a factor of 3 or so uncertain, due primarily to interference and masking by cloud and dust. In-situ balloon measurements would avoid these problems, and would provide 'ground truth' which remote sensing techniques cannot. We have explored this approach to measure ozone abundance in the terrestrial stratosphere with a balloon-borne UV absorption photometer. Atmospheric pressures and temperatures and ozone concentrations near the surface of Mars are similar to those in the terrestrial stratosphere.

Lindner, Bernhard Lee↗