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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Stability of Magnesium Sulfate Minerals in Martian Environments

Viking Lander, Pathfinder, and Mars Exploration Rover missions to Mars have found abundant sulfur in surface soils and rocks, and the best indications are that magnesium sulfates are among the key hosts. At Meridiani Planum, MgSO4 salts constitute 15 to 40 wt.% of sedimentary rocks. Additional S is hosted by gypsum and jarosite. Reflectance and thermal emission spectroscopy is consistent with the presence of kieserite (MgSO4 H2O) and epsomite (MgSO4*7H2O). Theoretically, the dodecahydrate (MgSO4*12H2O) should also have precipitated. We first examine theoretically which MgSO4 minerals should have precipitated on Mars, and then how dehydration might have altered these minerals.

Marion, G. M.↗
NASA NTRS2014

Calcium Sulfate Characterized by ChemCam/Curiosity at Gale Crater, Mars

Onboard the Mars Science Laboratory (MSL) Curiosity rover, the ChemCam instrument consists of :(1) a Laser-Induced Breakdown Spectrometer (LIBS) for elemental analysis of the targets [1;2] and (2) a Remote Micro Imager (RMI), for the imaging context of laser analysis [3]. Within the Gale crater, Curiosity traveled from Bradbury Landing through the Rocknest region and into Yellowknife Bay (YB). In the latter, abundant light-toned fracture-fill material were seen [4;5]. ChemCam analysis demonstrate that those fracture fills consist of calcium sulfates [6].

Nachon, M.↗
NASA NTRS2014

Calcium Sulfate Characterized by Chemcam/Curiousity at Gale Crater, Mars

Onboard the Mars Science Laboratory (MSL) Curiosity rover, the ChemCam instrument consists of : (1) a Laser-Induced Breakdown Spectrometer (LIBS) for elemental analysis of the targets and (2) a Remote Micro Imager (RMI), for the imaging context of laser analysis. Within the Gale crater, Curiosity traveled from Bradbury Landing through the Rocknest region and into Yellowknife Bay (YB). In the latter, abundant light-toned fracture-fill material occur. ChemCam analysis demonstrates that those fracture fills consist of calcium sulfates.[

Nachon, M.↗
NASA NTRS2016

Bright Stuff on Ceres = Sulfates and Carbonates on CI Chondrites

Recent reports of the DAWN spacecraft's observations of the surface of Ceres indicate that there are bright areas, which can be explained by large amounts of the Mg sulfate hexahydrate (MgSO4•6(H2O)), although the identification appears tenuous. There are preliminary indications that water is being evolved from these bright areas, and some have inferred that these might be sites of contemporary hydro-volcanism. A heat source for such modern activity is not obvious, given the small size of Ceres, lack of any tidal forces from nearby giant planets, probable age and presumed bulk composition. We contend that observations of chondritic materials in the lab shed light on the nature of the bright spots on Ceres

Zolensky, Michael↗
NASA NTRS2017

Calcium Sulfates at Gale Crater and Limitations on Gypsum Stability

The Mars Science Laboratory rover has been exploring sedimentary rocks of the Bradbury group and overlying Murray formation, as well as the unconformably overlying Stimson formation. Early in exploration, and continuing to present, there have been observations of many Ca-sulfate veins that cut all three stratigraphic units. The CheMin XRD instrument on Curiosity provides complete mineralogy for drilled or scooped samples, with explicit identification of gypsum, bassanite, and anhydrite (crystal structure of so-called "soluble anhydrite," or gamma-CaSO4, is so similar to bassanite that it can't be distinguished at CheMin 2-theta resolution; here we refer to these similar dehydrated forms simply as bassanite).

Vantiman, D. T.↗
NASA NTRS2017

Smectite Formation in Acid Sulfate Environments on Mars

Phyllosilicates of the smectite group detected in Noachian and early Hesperian terrains on Mars were hypothesized to form under aqueous conditions that were globally neutral to alkaline. These pH conditions and the presence of a CO2-rich atmosphere should have been favorable for the formation of large carbonate deposits. However, large-scale carbonate deposits have not been detected on Mars. We hypothesized that smectite deposits are consistent with perhaps widespread acidic aqueous conditions that prevented carbonate precipitation. The objective of our work was to investigate smectite formation under acid sulfate conditions in order to provide insight into the possible geochemical conditions required for smectite formation on Mars. Hydrothermal batch incubation experiments were performed with Mars-analogue, glass-rich, basalt simulant in the presence of sulfuric acid of variable concentration.

Peretyazhko, T. S.↗
NASA NTRS2020

Relative Importance of Greenhouse Gases, Sulfate, Organic Carbon, and Black Carbon Aerosol for South Asian Monsoon Rainfall Changes

The contribution of individual aerosol species and greenhouse gases to precipitation changes during the South Asian summer monsoon is uncertain. Mechanisms driving responses to anthropogenic forcings need further characterization. We use an atmosphere‐only climate model to simulate the fast response of the summer monsoon to different anthropogenic aerosol types and to anthropogenic greenhouse gases. Without normalization, sulfate is the largest driver of precipitation change between 1850 and 2000, followed by black carbon and greenhouse gases. Normalized by radiative forcing, the most effective driver is black carbon. The precipitation and moisture budget responses to combinations of aerosol species perturbed together scale as a linear superposition of their individual responses. We use both a circulation‐based and moisture budget‐based argument to identify mechanisms of aerosol and greenhouse gas induced changes to precipitation, and find that in all cases the dynamic contribution is the dominant driver to precipitation change in the monsoon region.

climate↗
NASA NTRS2022

Desulfovulcanus ferrireducens gen. nov., sp. nov., A Thermophilic Autotrophic Iron and Sulfate-reducing Bacterium from Subseafloor Basalt That Grows on Akaganeite and Lepidocrocite

A deep-sea thermophilic bacterium, strain Ax17T, was isolated from 25 °C hydrothermal fluid at Axial Seamount. It was obligately anaerobic and autotrophic, oxidized molecular hydrogen and formate, and reduced synthetic nanophase Fe(III) (oxyhydr)oxide minerals, sulfate, sulfite, thiosulfate, and elemental sulfur for growth. It produced up to 20 mM Fe2+ when grown on ferrihydrite but < 5 mM Fe2+ when grown on akaganéite, lepidocrocite, hematite, and goethite. It was a straight to curved rod that grew at temperatures ranging from 35 to 70 °C (optimum 65 °C) and a minimum doubling time of 7.1 h, in the presence of 1.5–6% NaCl (optimum 3%) and pH 5–9 (optimum 8.0). Phylogenetic analysis based on 16S rRNA gene sequences indicated that the strain was 90–92% identical to other genera of the family Desulfonauticaceae in the phylum Pseudomonadota. The genome of Ax17T was sequenced, which yielded 2,585,834 bp and contained 2407 protein-coding sequences. Based on overall genome relatedness index analyses and its unique phenotypic characteristics, strain Ax17T is suggested to represent a novel genus and species, for which the name Desulfovulcanus ferrireducens is proposed. The type strain is Ax17T (= DSM 111878T = ATCC TSD-233T).

Srishti Kashyap↗
NASA NTRSDate not supplied

Simulating Sulfate Aerosol Size in the Hunga Tonga Plume: Comparisons with Observations

Using the NASA GEOS Chemistry Climate Model (CCM) coupled to a detailed sectional aerosol microphysical model, we have simulated the January 2022 Hunga Tonga-Hunga Ha’apai (HTHH) plume. We have developed a version of the Global Modeling Initiative (GMI) chemistry mechanism to include the requisite sulfur chemistry and coupled it to the Community Aerosol and Radiation Model for Atmospheres (CARMA) sectional aerosol microphysics within the GEOS CCM. Our simulations focus on the lifecycle of stratospheric sulfur injected by the eruption–from the oxidation of the injected sulfur dioxide to the nucleation, growth, coagulation, hydration, and eventual settling of the volcanic sulfate aerosol particles. In order to constrain the simulated microphysics, we focus on comparing our model to observations with aerosol size information, namely in-situ particle counter observations and multi-wavelength satellite observations from OMPS-LP and SAGE-III. This eruption provides an interesting test case for our model; both the modeled gas-phase chemistry as well as the modeled aerosol microphysics are perturbed by the massive injection of water that accompanied the primary sulfur emissions from the eruption.

aerosols↗
NASA NTRS2015

Evaluating Ammonium, Nitrate and Sulfate Aerosols in 3-Dimensions

The effect aerosols have on climate and air quality is a func-on of their chemical composi-on, concentra-on and spa-al distribu-on. These parameters are controlled by emissions, heterogeneous and homogeneous chemistry, where thermodynamics plays a key role, transport, which includes stratospheric-­‐ tropospheric exchange, and deposi-onal sinks. In this work we demonstrate the effect of some of these processes on the SO4‐NH4­‐NO3 system using the GISS ModelE2 Global Circula-on Model (GCM).

Aerosols↗