Search NASA⌕ Search

SEARCH · Search NASA

Results for “Surface dynamics”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 217 records · Page 12

Spectral Similarity Masks Structural Diversity at Hydrophobic Water Interfaces

The air-water and graphene-water interfaces represent quintessential examples of the liquid-gas and liquid-solid boundaries, respectively. While the sum-frequency generation (SFG) spectra of these interfaces show similarities, a consensus on their signals and interpretations has yet to be reached. Leveraging deep learning, we computed first-principles SFG spectra for both systems, addressing experimental discrepancies. Here, our findings reveal that similarities in SFG signals do not translate into comparable interfacial microscopic properties. Instead, graphene-water and air-water interfaces exhibit fundamental differences in SFG-active thicknesses, hydrogen-bonding networks, and surface dynamics. These distinctions underscore roughness suppression and electronic interactions present at the solid-liquid interface but absent at the gas-liquid interface.

Wang, Yong [Princeton Univ., NJ (United States)] (↗

Kinetic and Mechanistic Understanding of Boron-Containing Catalysts for the Production of Light Olefins through Selective Oxidation

In recent years, an abundance of natural gas obtained from shale deposits has created opportunities for the US chemical industry to establish new and more efficient processes for the production of chemical intermediates and polymers. For example, the replacement of petroleum-derived naphtha as a to shale-derived ethane as feedstocks has made the production of ethylene/polyethylene less costly. However, this shift in feedstock has led to lower production of propylene from steam crackers, and new “on-purpose” light olefin production technologies have been implemented to bridge the gap between propylene supply and demand. The most important of these processes is direct propane dehydrogenation (PDH), but catalyst deactivation and high temperatures lead to high capital and operating costs. Oxidative dehydrogenation of propane (ODHP) is an efficient alternative to PDH, but high selectivity to CO2 from previous metal oxide catalyst prevents implementation. Hexagonal boron nitride (hBN) and other boron-containing materials have been recently developed as highly selective catalysts for both ODHP and oxidative cracking, surpassing previous systems. Much is still unknown in regard to the mechanism and the dynamic surface changes that occur under reaction conditions. This research project aims to combine in situ/operando spectroscopic investigation and kinetic studies to elucidate the interplay between the proposed gas-phase mechanism and the surface structures on the working catalyst. These insights will be leveraged to create a framework for optimizing reaction conditions and material synthesis for the next generation of boron-containing selective oxidation catalysts.

02 PETROLEUM↗

Performing In Situ Closed-Cell Gas Reactions in the Transmission Electron Microscope

Gas reactions studied by in situ electron microscopy can be used to capture the real-time morphological and microchemical transformations of materials at length scales down to the atomic level. In situ closed-cell gas reaction (CCGR) studies performed using (scanning) transmission electron microscopy (STEM) can separate and identify localized dynamic reactions, which are extremely challenging to capture using other characterization techniques. For these experiments, we used a CCGR holder that utilizes microelectromechanical systems (MEMS)-based heating microchips (hereafter referred to as "E-chips"). The experimental protocol described here details the method for performing in situ gas reactions in dry and wet gases in an aberration-corrected STEM. This method finds relevance in many different materials systems, such as catalysis and high-temperature oxidation of structural materials at atmospheric pressure and in the presence of various gases with or without water vapor. Here, several sample preparation methods are described for various material form factors. During the reaction, mass spectra obtained with a residual gas analyzer (RGA) system with and without water vapor further validates gas exposure conditions during reactions. Integrating an RGA with an in situ CCGR-STEM system can, therefore, provide critical insight to correlate gas composition with the dynamic surface evolution of materials during reactions. In situ/operando studies using this approach allow for detailed investigation of the fundamental reaction mechanisms and kinetics that occur at specific environmental conditions (time, temperature, gas, pressure), in real-time, and at high spatial resolution.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Evaluation and comparison of ERTS measurements of major crops and soil associations for selected sites in the central United States

The author has identified the following significant results. The most significant result was the use of the temporal overlay technique where the computer was used to overlay ERTS-1 data from three different dates (9 Oct., 14 Nov., 2 Dec.). The registration of MSS digital data from different dates was estimated to be accurate within one half resolution element. The temporal overlay capability provides a significant advance in machine-processing of MSS data. It is no longer essential to go through the tedious exercise of locating ground observation sites on the digital data from each ERTS-1 overpass. Once the address of a ground observation site has been located on a digital tape from any ERTS-1 overpass, the overlay technique can be used to locate the same address on a digital tape of MSS data from any other ERTS-1 pass over the same area. The temporal overlay technique also adds a valuable dimension for identifying and mapping changes in vegetation, water, and other dynamic surface features.

Baumgardner, M. F.↗

Mineral Resources, Geological Structure and Landform Surveys

Significant results are presented of ERTS-1 investigations of landform surveys, mineral resources, and geological structures. The report covers four areas: (1) mapping investigations; (2) dynamic surface processes and landforms; (3) structural elements; and (4) mineral deposits.

Short, M. N.↗

Electrohydrodynamically coupled Kelvin-Helmholtz instability

An inviscid model of the surface dynamics at the interface between two parallel-flowing insulating dielectric fluids, subject to a tangential electric field with a weak gradient, is developed. The two flows are oppositely directed, resulting in an electrohydrodynamically coupled Kelvin-Hemholtz instability. A simple stability criterion is used successfully to correlate experimental data obtained with a test configuration.

Perry, M. P.↗

Fluid physics, thermodynamics, and heat transfer experiments in space

An overstudy committee was formed to study and recommend fundamental experiments in fluid physics, thermodynamics, and heat transfer for experimentation in orbit, using the space shuttle system and a space laboratory. The space environment, particularly the low-gravity condition, is an indispensable requirement for all the recommended experiments. The experiments fell broadly into five groups: critical-point thermophysical phenomena, fluid surface dynamics and capillarity, convection at reduced gravity, non-heated multiphase mixtures, and multiphase heat transfer. The Committee attempted to assess the effects of g-jitter and other perturbations of the gravitational field on the conduct of the experiments. A series of ground-based experiments are recommended to define some of the phenomena and to develop reliable instrumentation.

Dodge, F. T.↗

The Viking Radio Science Investigations

The Viking radio science investigations utilize data from the radio tracking and communications systems of the orbiters and landers. The primary areas of research are: (1) dynamical, surface, and internal properties of Mars, (2) atmospheric and ionospheric properties of Mars, and (3) solar system properties. The instrumentation and facilities used are those required for trajectory and orbit determination, spacecraft control, and data transmission. The X-band downlink on the orbiters is also used for communications experiments and for the improvement of radio science capabilities.

Michael, W. H., Jr.↗

Seasat altimeter determination of ocean current variability

An experiment conducted in the Kuroshio Current, east of Japan, has confirmed the ability of radar altimeters of precision on the order of 10 cm, such as that of the Seasat satellite, to measure the small oceanic height variations associated with geostrophic ocean currents. Changes in surface dynamic height were inferred from data gathered by air-expendable barithermographs, which had been dropped to coincide with the Seasat subtrack, for the periods between the flights of September 25 and October 5 and 13, 1978. The changes registered generally agreed to within + or - 10 cm of the height changes observed in the altimeter data.

Bernstein, R. L.↗

Detailed studies of aviation fuel flowability

Six Jet A fuels, with varying compositions, were tested for low temperature flowability in a 190-liter simulator tank that modeled a section of a wing tank of a wide-body commercial airplane. The insulated tank was chilled by circulating coolant through the upper and lower surfaces. Flow-ability was determined as a function of fuel temperature by holdup, the fraction of unflowable fuel remaining in the tank after otherwise complete withdrawal. In static tests with subfreezing tank conditions, hold up varied with temperature and fuel composition. However, a general correlation of two or three classes of fuel type was obtained by plotting holdup as a function of the difference between freezing point and boundary-layer temperature, measured 0.6 cm above the bottom tank surface. Dynamic conditions of vibrations and slosh or rate of fuel withdrawal had very minor effects on holdup. Tests with cooling schedules to represent extreme, cold-day flights showed, at most, slight holdup for any combination of fuel type or dynamic conditions. Tests that superimposed external fuel heating and recirculation during the cooldown period indicates reduced hold up by modification of the low-temperature boundary layer. Fuel heating was just as effective when initiated during the later times of the tests as when applied continuously.

Mehta, H. K.↗

Influence of the Yukon River on the Bering Sea

The relationships between the discharge of the Yukon River to the currents and biological productivity in the northern Bering Sea were studied. Specific objectives were: to develop thermal, sediment, and chlorophyll surface maps using Thematic Mapper (TM) data of the discharge of the Yukon River and the Alaskan Coastal Current during the ice free season; to develop a historical model of the distribution of the Yukon River discharge and the Alaskan Coastal Current using LANDSAT Multispectral band scanner (MSS) and NOAA satellite imagery; and to use high resolution TM data to define the surface dynamics of the front between the Alaskan Coastal Current and the Bering Shelf/Anadyr Current. LANDSAT MSS, TM, and Advanced Very High Resolution Radiometer (AVHRR) data were recorded during the 1985 ice free period. The data coincided with shipboard measurements acquired by Inner Shelf Transfer and Recycling (ISTAR) project scientists. An integrated model of the distribution of turbid water discharged from the Yukon River was compiled. A similar model is also being compiled for the Alaskan Coastal and Bering Shelf/Anadyr water masses based on their thermal expressions seen on AVHRR imagery.

Dean, K.↗

Application of optical interferometry in compressible flows

Interferometry methods were applied to the investigation of steady and unsteady flows in large scale transonic wind tunnels. Holographic interferometry was demonstrated to provide reliable flow visualization and quantitative results for a number of two-dimensional flows. These conclusions were based on extensive comparisons with results obtained by other means. Data obtained on a NACA 64A010 airfoil with an oscillating flap installed in the Ames 11-foot transonic tunnel are presented. Interferograms were recorded at a free stream Mach number of 0.8, flap frequency of 30 Hertz and chord Reynolds numbers of 6.6 x 10 to the 6th and 12.3 x 10 to the 6th. The interferometric results were reduced to dynamic surface pressures, Mach contours and wake flow profiles. A new interferometry method that is capable of providing real-time interferometry data is also discussed.

Bachalo, W. D.↗

Spaceborne imaging radar research in the 90's

The imaging radar experiments on SEASAT and on the space shuttle (SIR-A and SIR-B) have led to a wide interest in the use of spaceborne imaging radars in Earth and planetary sciences. The radar sensors provide unique and complimentary information to what is acquired with visible and infrared imagers. This includes subsurface imaging in arid regions, all weather observation of ocean surface dynamic phenomena, structural mapping, soil moisture mapping, stereo imaging and resulting topographic mapping. However, experiments up to now have exploited only a very limited range of the generic capability of radar sensors. With planned sensor developments in the late 80's and early 90's, a quantum jump will be made in our ability to fully exploit the potential of these sensors. These developments include: multiparameter research sensors such as SIR-C and X-SAR, long-term and global monitoring sensors such as ERS-1, JERS-1, EOS, Radarsat, GLORI and the spaceborne sounder, planetary mapping sensors such as the Magellan and Cassini/Titan mappers, topographic three-dimensional imagers such as the scanning radar altimeter and three-dimensional rain mapping. These sensors and their associated research are briefly described.

Elachi, Charles↗

Influence of the Yukon River on the Bering Sea

The purpose is to use satellite data to study relationships between discharge of the Yukon River to currents and biologic productivity in the northern Bering Sea. Amended specific objectives are: to develop thermal, sediment and chlorophyll surface maps using thematic mapping (TM) data of the discharge of the Yukon River and the Alaska Coastal Current during the ice free season; to develop a historical model of the distribution of the Yukon River discharge and the Alaska Coastal Current using LANDSAT multispectral scanner (MMS) and NOAA satellite imagery; and to use high resolution TM data to define the surface dynamics of the front between the Alaska Coastal Current and the Bering Shelf/Anadyr Current. LANDSAT MSS and TM, and Advanced Very High Resolution Radiometer (AVHRR) data were recorded during the 1985 ice-free period. The satellite data coincided with shipboard measurements acquired by Inner Self Transfer and Recycling scientists. Circumstances were such, that on July 5 and July 22, all three sensors recorded data that has been registered to a common map projection and map base, then contrast stretched, color composited, and density sliced.

Dean, K.↗

One-dimensional wave propagation in rods of variable cross section: A WKBJ solution

As an important step in the characterization of a particular dynamic surface displacement transducer (IQI Model 501), a one-dimensional wave propagation in isotropic nonpiezoelectric and piezoelectric rods of variable cross section are presented. With the use of the Wentzel-Kramers-Brillouin-Jeffreys (WKBJ) approximate solution technique, an approximate formula, which relates the ratio of the amplitudes of a propagating wave observed at any two locations along the rod to the ratio of the cross sectional radii at these respective locations, is derived. The domains of frequency for which the approximate solution is valid are discussed for piezoelectric and nonpiezoelectric materials.

Ochi, Simeon C. U.↗

Analysis of a rotating advanced-technology space station for the year 2025

An analysis is made of several aspects of an advanced-technology rotating space station configuration generated under a previous study. The analysis includes examination of several modifications of the configuration, interface with proposed launch systems, effects of low-gravity environment on human subjects, and the space station assembly sequence. Consideration was given also to some aspects of space station rotational dynamics, surface charging, and the possible application of tethers.

Queijo, M. J.↗

Characterization of noncontact piezoelectric transducer with conically shaped piezoelement

The characterization of a dynamic surface displacement transducer (IQI Model 501) by a noncontact method is presented. The transducer is designed for ultrasonic as well as acoustic emission measurements and, according to the manufacturer, its characteristic features include a flat frequency response range which is from 50 to 1000 kHz and a quality factor Q of less than unity. The characterization is based on the behavior of the transducer as a receiver and involves exciting the transducer directly by transient pulse input stress signals of quasi-electrostatic origin and observing its response in a digital storage oscilloscope. Theoretical models for studying the response of the transducer to pulse input stress signals and for generating pulse stress signals are presented. The characteristic features of the transducer which include the central frequency f sub o, quality factor Q, and flat frequency response range are obtained by this noncontact characterization technique and they compare favorably with those obtained by a tone burst method which are also presented.

Williams, James H., Jr.↗

Modelling the SIR-B image response to partially coherent seas

A mathematical model of transient seas modulated by coherent swells is developed as a Rayleigh-Poisson random process subject to deterministic correlations of scattering sites, as they appear in a time window defined by a SAR's range-Doppler measurements of the surface coordinates. This model of SAR response to sea surface dynamics is discussed as a Fourier domain predictor/corrector of a dynamic motion blur.

Tilley, D. G.↗