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At least 217 records · Page 12

Tropical Cumulus Convection and Upward Propagating Waves in Middle Atmospheric GCMs

It is recognized that the resolved tropical wave spectrum can vary considerably between general circulation models (GCMs) and that these differences can have an important impact on the simulated climate. A comprehensive comparison of the waves is presented for the December-January-February period using high-frequency (three-hourly) data archives from eight GCMs and one simple model participating in the GCM Reality Intercomparison Project for SPARC (GRIPS). Quantitative measures of the structure and causes of the wavenumber-frequency structure of resolved waves and their impacts on the climate are given. Space-time spectral analysis reveals that the wave spectrum throughout the middle atmosphere is linked to variability of convective precipitation, which is determined by the parameterized convection. The variability of the precipitation spectrum differs by more than an order of magnitude between the models, with additional changes in the spectral distribution (especially the frequency). These differences can be explained primarily by the choice of different, cumulus par amet erizations: quasi-equilibrium mass-flux schemes tend to produce small variability, while the moist-convective adjustment scheme is most active. Comparison with observational estimates of precipitation variability suggests that the model values are scattered around the truth. This result indicates that a significant portion of the forcing of the equatorial quasi-biennial oscillation (QBO) is provided by waves with scales that are not resolved in present-day GCMs, since only the moist convective adjustment scheme (which has the largest transient variability) can force a QBO in models that have no parameterization of non-stationary gravity waves. Parameterized cumulus convection also impacts the nonmigrating tides in the equatorial region. In most of the models, momentum transport by diurnal nonmigrating tides in the mesosphere is larger than that by Kelvin waves, being more significant than has been thought. It is shown that the equatorial semi-annual oscillation in the models examined is driven mainly by gravity waves with periods shorter than three days, with at least some contribution from parameterized gravity waves; the contribution from the ultra-fast zonal wavenumber-1 Kelvin waves is negligible.

Horinouchi, T.↗

Computer-based video digitizer analysis of surface extension in maize roots: kinetics of growth rate changes during gravitropism

We used a video digitizer system to measure surface extension and curvature in gravistimulated primary roots of maize (Zea mays L.). Downward curvature began about 25 +/- 7 min after gravistimulation and resulted from a combination of enhanced growth along the upper surface and reduced growth along the lower surface relative to growth in vertically oriented controls. The roots curved at a rate of 1.4 +/- 0.5 degrees min-1 but the pattern of curvature varied somewhat. In about 35% of the samples the roots curved steadily downward and the rate of curvature slowed as the root neared 90 degrees. A final angle of about 90 degrees was reached 110 +/- 35 min after the start of gravistimulation. In about 65% of the samples there was a period of backward curvature (partial reversal of curvature) during the response. In some cases (about 15% of those showing a period of reverse bending) this period of backward curvature occurred before the root reached 90 degrees. Following transient backward curvature, downward curvature resumed and the root approached a final angle of about 90 degrees. In about 65% of the roots showing a period of reverse curvature, the roots curved steadily past the vertical, reaching maximum curvature about 205 +/- 65 min after gravistimulation. The direction of curvature then reversed back toward the vertical. After one or two oscillations about the vertical the roots obtained a vertical orientation and the distribution of growth within the root tip became the same as that prior to gravistimulation. The period of transient backward curvature coincided with and was evidently caused by enhancement of growth along the concave and inhibition of growth along the convex side of the curve, a pattern opposite to that prevailing in the earlier stages of downward curvature. There were periods during the gravitropic response when the normally unimodal growth-rate distribution within the elongation zone became bimodal with two peaks of rapid elongation separated by a region of reduced elongation rate. This occurred at different times on the convex and concave sides of the graviresponding root. During the period of steady downward curvature the elongation zone along the convex side extended farther toward the tip than in the vertical control. During the period of reduced rate of curvature, the zone of elongation extended farther toward the tip along the concave side of the root. The data show that the gravitropic response pattern varies with time and involves changes in localized elongation rates as well as changes in the length and position of the elongation zone. Models of root gravitropic curvature based on simple unimodal inhibition of growth along the lower side cannot account for these complex growth patterns.

NASA Discipline Plant Biology↗

Ultrafast Carrier Self-Trapping Driven by Strong Exciton–Phonon Coupling in 2D MA 3 Bi 2 I 6 Cl 3 Perovskite

Two-dimensional (2D) hybrid bismuth halide perovskites have emerged as promising lead-free materials for optoelectronic applications due to their solution processability and tunable structures. Here, in this study, we investigate 2D layered hybrid perovskite MA 3 Bi 2 I 6 Cl 3 using temperature-dependent photoluminescence (PL) and femtosecond transient absorption spectroscopy. Our results reveal strong coupling between excitons and phonons, evidenced by giant Huang–Rhys factors, coherent phonon oscillations, and ultrafast carrier self-trapping into small-polaron and self-trapped exciton (STE) states. These processes appear as time-dependent ground-state bleach and photoinduced absorption features, highlighting the influence of the lattice in carrier dynamics. Wavelength- and time-resolved measurements reveal that PL emission is dominated by STEs, while free exciton emission is weak and short-lived. By comparing 2D MA 3 Bi 2 I 6 Cl 3 with 0D MA 3 Bi 2 I 9 , which contains molecularly isolated [BiI 6 ] 3− octahedra and 2D MA 3 Bi 2 Br 9 perovskites, we demonstrate how halide composition and structural dimensionality influence the balance between free exciton populations and carrier localization. These insights uncover the intrinsic kinetic landscape of photoexcited states in MA 3 Bi 2 I 6 Cl 3 . Overall, our study contributes to a mechanistic understanding of exciton–phonon interactions in lead-free 2D perovskites.

Pradeep, Kodimana Ramakrishnan [Northwestern Univ.↗

Oscillatory combustion of monopropellant droplets

A theoretical study of combustion response to imposed pressure oscillations was conducted for monopropellant droplets and sprays. A first-order perturbation analysis was used, yielding the linear response. Transient gas phase phenomena were considered in some cases, but the bulk of the calculations assume a quasi-steady gas phase. The calculations employed properties representative of hydrazine decomposition. Calculated steady combustion results and response predictions for large hydrazine droplets agreed favorably with earlier measurements. Droplet and spray response factors in excess of unity were found. High response was associated with high pressures (1000-10,000 kN/sq m), large droplets, large mean liquid temperature gradients, and frequencies near the characteristic frequency of the liquid phase thermal wave. Spray response factors are lower than the response factor of the largest injected drop, however, a small percentage of large drops can still provide substantial response for the combustion process.

Chanin, S. P.↗

A simulation model of time-dependent plasma-spacecraft interactions

A plasma simulation code is presented that models the time-dependent plasma properties in the vicinity of a spherical, charged spacecraft. After showing agreement with analytic, steady-state theories and ATS-6 satellite data, the following three problems are treated: (1) transient pulses from photoemission at various emission temperatures and ambient plasma conditions, (2) spacecharge limited emission, and (3) simulated plasma oscillations in the long wavelength limit.

Rothwell, P. L.↗

Impact cratering in viscous targets - Laboratory experiments

To determine the effects of target yield strength and viscosity on the formation and morphology of Martian multilobed, slosh and rampart-type impact craters, 75 experiments in which target properties and impact energies were varied were carried out for high-speed motion picture observation in keeping with the following sequence: (1) projectile initial impact; (2) crater excavation and rise of ejecta plume; (3) formation of a transient central mound which generates a surge of material upon collapse that can partly override the plume deposit; and (4) oscillation of the central mound with progressively smaller surges of material leaving the crater. A dimensional analysis of the experimental results indicates that the dimensions of the central mound are proportional to (1) the energy of the impacting projectile and (2) to the inverse of both the yield strength and viscosity of the target material, and it is determined that extrapolation of these results to large Martian craters requires an effective surface layer viscosity of less than 10 to the 10th poise. These results may also be applicable to impacts on outer planet satellites composed of ice-silicate mixtures.

Greeley, R.↗

Stability testing of a modified Space Shuttle Main Engine

The testing of the combustion stability characteristics of Space Shuttle Main Engine (SSME) 0208 is described in terms of augmenting the technology base for large O/H thrust-chamber assemblies. The throat area is increased by 12 percent over that of the flight SSMEs, and the thrust chamber assembly does not include stability aids. Acoustic modes in the chamber are excited by means of rapid pressure generators employed in the start-transient through mainstage operations. Stability characteristics are determined by damp times which are facilitated by high-frequency instrumentation measuring oscillations and locating stable operating regions. All vibration modes are damped to within the requirements for a chamber mode set forth by the Chemical Propulsion Information Agency. No sustained chamber acoustic oscillations are exhibited in engine 0208's combustion chamber configuration in spite of the absence of baffles and acoustic cavities.

Dennis, H.↗

EAS Optical Cherenkov Signatures of Tau Neutrinos for Space and Suborbital Detectors

Multi-messenger observations of transient astrophysical sources have the potential to characterize the highest energy accelerators and the most extreme environments in the Universe. Detection of neutrinos, in particular tau neutrinos generated by neutrino oscillations in transit from their sources to Earth, is possible for neutrino energies above 10 PeV using optical Cherenkov detectors imaging upward-moving extensive air showers (EAS). These EAS are produced from Earth-interacting tau neutrinos leading to tau leptons that subsequently decay in the atmosphere. We compare neutrino detection sensitivities for generic short- and long-burst transient neutrino sources and sensitivities to the diffuse neutrino flux for the second generation Extreme Universe Space Observatory on a Super-Pressure Balloon (EUSO-SPB2) balloon-borne mission and the proposed space-based Probe of Extreme Multi-Messenger Astrophysics (POEMMA) mission.

Mary Hall Reno↗

AToM: Advanced Tokamak Modeling Environment

Stability constraints play an important role in integrated modeling. The global plasma stability and macro-instabilities such as internal kink modes, neoclassical tearing modes, and edge localized perturbations limit the plasma performance and can result in large-scale transient events and plasma disruptions. These macro-instabilities can be also beneficial to the plasma performance. For example, the peeling models often lead to the edge localized modes (ELMs). However, the formation of stationary edge harmonic oscillations (EHOs) due to nonlinear interaction of peeling modes can result in a transition to the Quiescent H-mode (QH-mode) without ELMs. The profiles predicted with transport models need to be refined using the MHD stability constraints. This is important especially for transient and nonlinear stages of discharges such as ramp-up access to hybrid and steady state operation, and L- to H-mode transition as well as transition to the QH-mode. Several stability and MHD codes are already included in the OMFIT framework. These codes include BALOO, ELITE, GATO, M3DC1, MARS, and NIMROD. However, the verifications of stability constraints are currently mostly excluded from transport modeling workflows. The only exception is the EPED module which includes the ELITE predictions to limit the pedestal height. Here, we improved the OMFIT workflow to include stability calculations. Including the stability conditions to the integrated modeling workflow improved the robustness of the predictive modeling discharges. Being implemented in the workflow, the stability conditions can be also used for the stability analysis of experimental data. This improved the physics understanding of various discharge scenarios and can be used in experiment planning.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Search for Transient Gravitational Waves in Coincidence with Short-Duration Radio Transients During 2007-2013

We present an archival search for transient gravitational-wave bursts in coincidence with 27 single-pulse triggers from Green Bank Telescope pulsar surveys, using the LIGO (Laser Interferometer Gravitational Wave Observatory), Virgo (Variability of Solar Irradiance and Gravity Oscillations) and GEO (German-UK Interferometric Detector) interferometer network. We also discuss a check for gravitational-wave signals in coincidence with Parkes fast radio bursts using similar methods. Data analyzed in these searches were collected between 2007 and 2013. Possible sources of emission of both short-duration radio signals and transient gravitational-wave emission include star quakes on neutron stars, binary coalescence of neutron stars, and cosmic string cusps. While no evidence for gravitational-wave emission in coincidence with these radio transients was found, the current analysis serves as a prototype for similar future searches using more sensitive second-generation interferometers.

Abbott, B. P.↗

Oscillation Risks of Grid-Following and Grid-Forming Inverter-Based Resources in Series-Compensated Networks

Here, this paper investigates the dynamic behavior of a grid-connected inverter-based resource (IBR) when connected radially to a series compensated line. Potential interactions between the series compensation and the IBR have been identified for both types: grid-following (GFL) or grid-forming (GFM). The study begins with electromagnetic transient (EMT) simulations to demonstrate stability issues. Subsequently, nonlinear analytical models are formulated in the dq frame, validated against the EMT simulation, and leveraged to assess eigenvalues and participation factors. Influencing factors of the dominant oscillation modes have been identified. The analysis results show that series compensation may make a mode associated with the synchronization unit unstable. Furthermore, customized feedback systems are built for the synchronizing loop. Series compensation can increase the sensitivity of the voltage phase angle towards the synchronizing angle, and introduce phase lag in the real power response towards the synchronizing angle. These factors may cause interactions with the phase-locked loop in GFL-IBR systems and with power-based synchronization in GFM-IBR systems, potentially leading to instability.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Electrical Systems of Pumped Storage Hydropower Plants: Electrical Generation, Machines, Power Electronics, and Power Systems

Adjustable-speed (AS) pumped storage hydropower (PSH) technology has the potential to become a large, consistent contributor to grid stability enabling higher penetrations of wind and solar energy on the future U.S. power system. AS-PSH has high-value characteristics, such as fast response to provide ancillary services to the grid, because it is a power converter interface with the grid (like battery storage), but at the same time it has the energy content large enough to supply both short-term (seconds-to-minutes) and long-term (minutes-to-hours) of energy needs, like more conventional power plants. However, designs must be optimized to lower the capital expenditure (CapEx) and to provide a high-quality grid interface capability (e.g. power quality, ancillary service provider, fault-tolerant or fault ride-through capability), which is a primary factor in the acceptance of AS-PSH into a utility’s generation mix. This CapEx will be greatly affected by the cost savings associated with the civil structure, turbine design, power electronics, control systems, or unique generator designs. A holistic design must be considered to get a full picture of the benefits of the technology proposed. The AS-PSH can be controlled to reduce the impact of transient disturbance on a power system and at the same time can be controlled to minimized subsequent component fatigue and potential oscillation modes within the plant, with the overall impact in reducing the operational expenditures (OpEx).Generating clean power to meet standards such as Institute of Electrical and Electronics Engineers (IEEE) 519 and International Electrotechnical Commission (IEC) 1000-3-2 will be a continuing challenge. For many technology developers, however, improved AS-PSH technologies will become a key component of generator-storage systems of the future given the prospects of increased performance and decreasing costs, and the ever-increasing penetration of renewables (e.g wind power and solar power).

13 HYDRO ENERGY↗

Midlatitude disturbances in the Martian atmosphere - A second Mars year

Time spectral and cross-spectral analyses of Viking Lander 2 meteorological data from the fall and winter seasons of a second Mars annual cycle were conducted to determine transient disturbance characteristics with periods longer than a Martian day. It was found that phase relationships among pressure, wind, and temperature oscillations are similar to those of the first year, and consistent with the expected eastward baroclinic waves centered north of the Lander 2 site. Composites constructed for two highly regular subperiods show no evidence of sharp frontal structures, though pressure and temperature waves are clearly asymmetric, and estimates of wavenumbers and phase speeds are found to be in agreement with those obtained from the spectral analysis.

Barnes, J. R.↗

Time simulation of flutter with large stiffness changes

Time simulation of flutter, involving large local structural changes, is formulated with a state-space model that is based on a relatively small number of generalized coordinates. Free-free vibration modes are first calculated for a nominal finite-element model with relatively large fictitious masses located at the area of structural changes. A low-frequency subset of these modes is then transformed into a set of structural modal coordinates with which the entire simulation is performed. These generalized coordinates and the associated oscillatory aerodynamic force coefficient matrices are used to construct an efficient time-domain, state-space model for a basic aeroelastic case. The time simulation can then be performed by simply changing the mass, stiffness, and damping coupling terms when structural changes occur. It is shown that the size of the aeroelastic model required for time simulation with large structural changes at a few apriori known locations is similar to that required for direct analysis of a single structural case. The method is applied to the simulation of an aeroelastic wind-tunnel model. The diverging oscillations are followed by the activation of a tip-ballast decoupling mechanism that stabilizes the system but may cause significant transient overshoots.

Karpel, Mordechay↗

Time simulation of flutter with large stiffness changes

Time simulation of flutter, involving large local structural changes, is formulated with a state-space model that is based on a relatively small number of generalized coordinates. Free-free vibration modes are first calculated for a nominal finite-element model with relatively large fictitious masses located at the area of structural changes. A low-frequency subset of these modes is then transformed into a set of structural modal coordinates with which the entire simulation is performed. These generalized coordinates and the associated oscillatory aerodynamic force coefficient matrices are used to construct an efficient time-domain, state-space model for basic aeroelastic case. The time simulation can then be performed by simply changing the mass, stiffness and damping coupling terms when structural changes occur. It is shown that the size of the aeroelastic model required for time simulation with large structural changes at a few a priori known locations is similar to that required for direct analysis of a single structural case. The method is applied to the simulation of an aeroelastic wind-tunnel model. The diverging oscillations are followed by the activation of a tip-ballast decoupling mechanism that stabilizes the system but may cause significant transient overshoots.

Karpel, M.↗

Control-nonlinear-nonstationary structural response and radiation near a supersonic jet

This paper is on the control of nonlinear-nonstationary vibration of a frame-stringer structure resulting from high levels of excitation from a nearby supersonic jet exhaust. The structure exhibits periodic, chaotic, or random behaviors when forced by high-intensity sound from a supersonic jet exhaust with 'shock' loading superimposed on a broadband response. The time history of the pressure, showing the rotation and flapping of the shock structure in the jet column due to large-scale instabilities, indicates that the response is not only nonlinear but also nonstationary. The acoustic pressure radiated by the structure also contains shocks and the formation of harmonics with distance. Control of the structural response is achieved by actively forcing the structure with an actuator at the shock oscillation frequency whose amplitude is locked into a self-control cycle. Results show that the peak power level is reduced by a factor of 63, or 18 dB. As a result, new broadband components emerge with at least four harmonics. At accelerating and decelerating supersonic speeds, the exhaust from the jet induces higher transient loading on the nearby flexible structure due to the occurrence of multiple shock from the jet.

TRT-EXPERIMENTAL↗

Accelerated Steam Methane Reforming by Dynamically Applied Charges

Catalyst design has traditionally focused on tuning active site properties to optimally bind reaction intermediates and balance the kinetic requirements of multiple competing chemical processes, as necessitated by the Sabatier principle. It has recently been proposed that for reactions following certain potential energy landscapes, the activity limit imposed by the Sabatier principle may be overcome by using programmed oscillations of surface electron density at the timescales of surface reactions (i.e., “catalytic resonance”). Here, we use a combination of density functional theory (DFT) simulations and transient kinetic models (TKMs) to simulate the kinetics of steam methane reforming (SMR) on Ru(211) surfaces under statically and dynamically applied charges. DFT-calculated binding energies of SMR intermediates and transition states exhibit strong sensitivity to positively applied charges and follow unique scaling relationships that deviate from linear periodic trends across transition metals. Our simulations demonstrate that applying a small positive charge to Ru dramatically enhances the steady-state turnover frequency (TOF) of SMR by up to 5 orders of magnitude above the TOF observed over neutral Ru. Thus, statically charging Ru catalysts may be an effective strategy to lower the temperature requirements for SMR. Dynamic square-wave oscillations in charge resulted in SMR catalytic resonance with an onset frequency f ∼ 106 Hz and the corresponding average TOFs exceeding the statically charged Ru surface by an additional 15%. Here, based on sensitivity analyses performed for the two end points of oscillation, we propose that dynamic TOF improvement beyond the Sabatier maximum can be expected when the system oscillates between two kinetic regimes that are uniquely controlled by distinct elementary steps.

Catalysts↗

Biexciton and trion dynamics in InP/ZnSe/ZnS quantum dots

Transient absorption (TA) and time-resolved photoluminescence (PL) spectroscopies have been used to elucidate the hole tunneling and Auger dynamics in biexcitons and negative trions in high-quality InP/ZnSe/ZnS quantum dots (QDs). In a previous paper [Nguyen et al., J. Phys. Chem. C 125, 15405–15414 (2021)], we showed that under high-intensity photoexcitation, two types of biexcitons are formed: those having two conduction band electrons and two valence band holes (designated as an XX state) and those having two conduction band electrons, one valence band hole, and an additional trapped hole (designated as an XT state). In the present paper, we show that both types of biexcitons can undergo Auger processes, with those of the XT state being a factor of four to five slower than those of the XX state. In addition, the trapped holes can undergo tunneling into the valence band, converting an XT state to an XX state. The relative amplitudes of the fast (XX) and slow (XT) components are different in the TA and PL kinetics, and these differences can be quantitatively understood in terms of oscillator strengths and electron–hole overlap integrals of each state. XT to XX hole tunneling rates are obtained from the comparison of the XT state lifetimes with those of the negative trions. This comparison shows that the tunneling times decrease with decreasing core size and shell thickness. Furthermore, these times are about 2 ns for the thinnest shell red-emitting QDs and decrease to 330 ps for QDs that luminesce in the yellow.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗