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At least 217 records · Page 12

Tropical Tropopause Structure and Processes as Observed with GPS Radio Occultation

The vertical temperature structure of the tropical atmosphere has been explained as controlled by the combined effect of three green house gases: water vapor, carbon dioxide, and ozone. Absorption by water vapor of the light reflected off the Earth's surface would determine the temperature lapse rate in the lower troposphere up to the bottom of the Tropical Transition Layer (TTL); radiative absorption by carbon dioxide would dominate the temperature lapse rate between the bottom of the TTL and the coldest point in the upper-troposphere, the cold point tropopause (CPT), and; absorption of incoming solar radiation by ozone would control the temperature above the CPT. The TTL region can thus be very sensitive to changes in the relative abundances of these greenhouse gases. In this contribution we describe the seasonal evolution of temperature profiles in the TTL and their longitudinal structure using GPS radio occultation.

global positioning system (GPS)↗

A field investigation and numerical simulation of coastal fog

A field investigation of the microphysical and micrometeorological features of fogs occurring near Los Angeles and Vandenberg, California was conducted. Observations of wind speed and direction, temperature, dew point, vertical wind velocity, dew deposition, drop-size distribution, liquid water content, and haze and cloud nucleus concentration were obtained. These observations were initiated in late evening prior to fog formation and continued until the time of dissipation in both advection and radiation fogs. Data were also acquired in one valley fog and several dense haze situations. The behavior of these parameters prior to and during fog are discussed in detail. A two-dimensional numerical model was developed to investigate the formation and dissipation of advection fogs under the influence of horizontal variations in surface temperature. The model predicts the evolution of potential temperature, water vapor content, and liquid water content in a vertical plane as determined by vertical turbulent transfer and horizontal advection. Results are discussed from preliminary numerical experiments on the formation of warm-air advection fog and dissipation by natural and artificial heating from the surface.

Mack, E. J.↗

The Second Most Distant Cluster of Galaxies in the Extended Medium Sensitivity Survey

We report on our ASCA, Keck, and ROSAT observations of MS 1137.5+6625, the second most distant cluster of galaxies in the Einstein Extended Medium Sensitivity Survey (EMSS), at redshift 0.78. We now have a full set of X-ray temperatures, optical velocity dispersions, and X-ray images for a complete, high-redshift sample of clusters of galaxies drawn from the EMSS. Our ASCA observations of MS 1137.5 +6625 yield a temperature of 5.7 (+2.1)(-1.1) keV and a metallicity of 0.43 (+40)(-3.7) solar, with 90% confidence limits. Keck II spectroscopy of 22 cluster members reveals a velocity dispersion of 884 (+185)(-124) km 24/s. This cluster is the most distant in the sample with a detected iron line. We also derive a mean abundance at z = 0.8 by simultaneously fitting X-ray data for the two z = 0.8 clusters, and obtain an abundance of Z(sub Fe) = 0.33 (+.26)(-.23). Our ROSAT observations show that MS 1137.5+6625 is regular and highly centrally concentrated. Fitting of a Beta model to the X-ray surface brightness yields a core radius of only 71/h kpc (q(sub o) = 0.1) with Beta = 0.70(+.45)(-.15) The gas mass interior to 0.5/h Mpc is thus 1.2 (+0.2)(-0.3) X 10(exp 13) h(exp - 5/2) Solar Mass (q(sub o) = 0.1). If the cluster's gas is nearly isothermal and in hydrostatic equilibrium with the cluster potential, the total mass of the cluster within this same region is 2.1(+1.5)(-0.8) X 10exp 14)/h Solar Mass, giving a gas fraction of 0.06 +/-0.04 h (exp -3/2). This cluster is the highest redshift EMSS cluster showing evidence for a possible cooling flow (about 20-400 Solar Mass/yr). The velocity dispersion, temperature, gas fraction, and iron abundance of MS 1137.5+6625 are all statistically the same as those properties in lower red- shift clusters of similar luminosity. With this cluster's temperature now in hand, we derive a high-redshift temperature function for EMSS clusters at 0.5 < z < 0.9 and compare it with temperature functions at lower redshifts, showing that the evolution of the temperature function is relatively modest. Supplementing our high-redshift sample with other data from the literature, we demonstrate that neither the cluster luminosity-temperature relation, nor cluster metallicities, nor the cluster gas evolved with redshift. The very modest degree of evolution in the luminosity-temperature relation inferred from these data is inconsistent with the absence of evolution in the X-ray luminosity functions derived from ROSAT cluster surveys if a critical density structure formation model is assumed.

Donahue, Megan↗

Multiscale structural analysis of polymorphic phase boundaries in doped antiferroelectric sodium niobate

In the current work, we have performed multiscale structural analysis of a Pb-free sodium niobate-based smart system, i.e., 0.9⁢NaNbO 3 –0.1⁢Ba 0.9 ⁢Ca 0.1 ⁢TiO 3 (NN-10BCT) reported earlier for its high ferroelectric response. We have investigated the temperature-dependent evolution of crystal structure at long, medium, and short ranges using synchrotron x-ray diffraction (SXRD), Raman scattering, and pair distribution function(PDF) techniques in conjunction with dielectric studies. Temperature-dependent synchrotron x-ray diffraction data combined with dielectric analysis suggest two unique polymorphic phase boundaries (PPB) with two coexisting ferroelectric phases stable in the wide temperature ranges. These PPBs are stable in different regions viz. (i) cryogenic temperatures with coexisting R3c and Pmc⁢2 1 phases (ii) vicinity of room temperatures with coexisting Pmc⁢2 1 and Amm2 phases. In contrast to the conclusions drawn from SXRD, PDF reveals structures having lower symmetry (with coexisting Cc+ Pmc2 1 phases at 1.7 ≤r≤ 20 Å) at short ranges for these PPBs. In conclusion, the presence of different long- and short-range symmetries (accommodating tilt-oriented ferroelectric phases) in the unique polymorphic phase boundaries makes them thermally stable and advantageous for technological applications.

36 MATERIALS SCIENCE↗

An international study on THM modelling of the full-scale heater experiment at Mont Terri laboratory

We present results from an international model comparison study of the Full-Scale Emplacement (FE) experiment in Opalinus Clay at the Mont Terri Laboratory, Switzerland. Based on a provided parameter set the teams decided which parameters they adopted for their models, whether they considered the excavation and the ventilation phase in addition to the heating phase and if they included technical features like the shotcrete or the EDZ. The teams were able to reproduce the measured parameters temperature, relative humidity and pore pressure. The modelled results for temperature agree very closely between the teams especially in the sensors in Opalinus Clay. All teams were able to reproduce the redistribution of water in the bentonite backfill due to heating. The evolution of the relative humidity showed similar trends with differences in the intensity of the dry out effect. To model the pore pressure evolution is more complex because it comprises the full interaction of the coupled THM processes. The spread between the pore pressure modelled by the teams was larger, with some teams overestimating the pressure increase due to heating and some teams overestimating the extent of drainage. The agreement of modelled results with measurements improves with larger distance to the heater. We conclude that the EDZ and the shotcrete potentially influence the behaviour of the rock causing higher differences closer to the heater. Further research is needed to better implement those influences into the models. Based on the calibrated models, the future evolution of temperature, relative humidity and pore pressure was predicted over the next 10 years following a change of the heat power applied in 2023 and 2024. Again, the predicted temperatures agree very closely between the teams. Most teams do not expect an increase in relative humidity during the next 10 years after the initial dry-out.

58 GEOSCIENCES↗

Defining Computational Emissivity Uncertainty Over Large Temperature Scales Due to Surface Evolution

There is a dearth in the literature on how to capture the uncertainty generated by material surface evolution in thermal modeling. This leads to inadequate or highly variable uncertainty representations for material properties, specifically emissivity when minimal information is available. Inaccurate understandings of prediction uncertainties may lead decision makers to incorrect conclusions, so best engineering practices should be developed for this domain. In order to mitigate the aforementioned issues, this study explores different strategies to better capture the thermal uncertainty response of engineered systems exposed to fire environments via defensible emissivity uncertainty characterizations that can be easily adapted to a variety of use cases. Here, two unique formulations (one physics-informed and one mathematically based) are presented. The formulations and methodologies presented herein are not exhaustive but more so are a starting point and give the reader a basis for how to customize their uncertainty definitions for differing fire scenarios and materials. Lastly, the impact of using this approach versus other commonly used strategies and the usefulness of adding rigor to material surface evolution uncertainty is demonstrated.

97 MATHEMATICS AND COMPUTING↗

Thinking of biology: asteroid impacts, microbes, and the cooling of the atmosphere

The authors examine the cooling of the Earth's surface from 3.75 to 1 billion years ago. Three effects of the bombardment of Earth by asteroids and comets that may have delayed surface cooling include time to form continents, volatilization of carbonate rocks which released carbon dioxide into the atmosphere, and inability of microbes to inhabit land masses during large impact events. Continental microbes may have helped reduce high temperatures from 3.75 to 3.5 billion years ago. If so, the evolutionary sequence of microbes is proposed to be anaerobic heterotrophs, chemoautotrophs, and then photoautotrophs.

Non-NASA Center↗

Self-consistent equilibrium and transport simulations for NSTX-U plasmas enhanced via machine learning surrogate models

The Control-Oriented Transport SIMulator (COTSIM) is an advanced equilibrium and transport code designed for simulating tokamak discharges at computational speeds suitable for control applications. COTSIM’s modular framework enables users to select models that balance accuracy with speed according to specific needs, allowing the code to operate from fast to faster-than-real-time performance levels. This work presents recent enhancements to COTSIM’s predictive accuracy for NSTX-U scenarios, achieved by integrating neural-network-based surrogate models and self-consistent equilibrium calculations. To improve source deposition predictions, a surrogate model for NUBEAM has been incorporated. Additionally, a surrogate model for the Multi-Mode Module (MMM) now supports predictions of anomalous thermal, momentum, and particle diffusivities—key factors for modeling the evolution of temperature and rotation. Each surrogate model was specifically trained for the NSTX-U operational regime to enhance COTSIM’s accuracy while maintaining computational efficiency. Moreover, COTSIM now couples fixed-boundary equilibrium solvers with its transport solvers, enabling self-consistent predictions of plasma profiles and equilibrium evolution over the discharge. Simulation results demonstrate strong agreement between COTSIM and TRANSP predictions for NSTX-U discharges. These substantial advancements expand COTSIM’s utility in model-based control applications for NSTX-U. Potential applications include simultaneous optimization of equilibrium and transport scenarios, integration into digital twins, real-time profile estimation (e.g., temperature and rotation) from limited or noisy measurements, and advanced feedback-based scenario control.

Equilibrium and transport modeling↗

Electronic Structure and Safety Insights into Prussian Blue Analog Cathode Behavior at Elevated Temperatures in Sodium-Ion Batteries

Prussian blue analogs (PBAs) represent promising cathode materials for sodium-ion batteries (SIBs) due to their high theoretical capacity, open framework structure, and use of earth-abundant elements. However, the high-temperature structural evolution, water content effects, and thermal safety of PBAs, particularly in charged states, remain poorly understood, hindering their practical deployment. Here, we investigate Na 2 Fe[Fe(CN) 6 ]·2H 2 O using thermogravimetric analysis (TGA), ex situ and in situ temperature-dependent X-ray absorption spectroscopy (XAS), and accelerated rate calorimetry (ARC). TGA and ex situ XAS confirm water loss between 150 and 200 °C, resulting in Fe 2+ oxidation, enhanced local symmetry, and uniform redox behavior that improves electrochemical performance. In situ XAS reveals irreversible structural changes above 240 °C, including ligand loss, Fe site distortion, and increased disorder, while ARC on charged electrodes shows minimal self-heating rates (<0.1 °C/min) up to 300 °C, indicating exceptional thermal stability without lattice oxygen release. These insights elucidate PBA thermal dynamics, demonstrating improved electrochemical performance of water-deficient PBAs and informing future material design and safety assessment for SIB applications.

batteries↗

An analysis of the temperature distribution in finite solid-state laser rods

An expression for the time-dependent temperature distribution in a finite solid-state laser rod, for an arbitrary distribution of pump energy, has been derived. The specific case of end pumping by circular (constant) or Gaussian beams is included. This formulation was used to predict the time evolution of temperature in Ti:sapphire laser rods and in Nd:YAG rods of specific dimensions.

Farrukh, Usamah O.↗

Analysis of Properties of the North Polar Layered Deposits: THEMIS Data in Context of MGS Data

One of the many questions of Martian exploration is to uncover the history of Mars, through analysis of the polar layered deposits (PLD). Martian polar ice caps hold most of the exposed water on the surface on Mars and yet their history and physical processed involved in their formation are unclear. We will attempt to contribute to our knowledge of the composition and stratigraphy of the polar deposits. In this work we present the latest imaging data acquired by the Mars Odyssey THermal EMission Imaging System (THEMIS) and place it into context of the Mars Global Surveyor (MGS) data. THEMIS provides capabilities for imaging in both thermal IR and visible color wavelengths. These observations are affected by atmospheric scattering and topography. The Mars Orbiter Laser Altimeter (MOLA) and Thermal Emission Spectrometer (TES) instruments on board of the MGS spacecraft can provide context information for THEMIS data. Of particular interest are Mars Orbiter Camera (MOC) images, which provide high resolution data. We are primarily interested in the seasonal evolution of ice cap temperatures during the first northern summer of THEMIS observations. Morphology, stratigraphy and composition of the layered deposits can be addressed by THEMIS VIS color images, along with MOC high resolution data and MOLA Digital Elevation Models (DEM). This work is intentionally descriptive. Based on the knowledge obtained by the orbiting spacecraft and described here, we will attempt to expose major directions for modeling and further understanding of of the physical processes involved in the formation of the polar layered terrain 2 Available data 2.1 THEMIS IR The THEMIS IR camera has 10 bands from 6 to 15 m. Due to to signal-to-noise restrictions the most useful band for polar observations is band 9 (12.57 m ). Band 10 (14.88 m ) data can be used for atmospheric calibration. An example of seasonal evolution observed by the THEMIS IR subsystem is shown in Figure 1. We have projected all IR images, covering a small area near 86N and 90E into a polar stereographic projection and then sampled time dimension in order to look at temperature evolution over the course of the summer. We are plotting averaged temperature data over two 1km2 regions of interest: layered material inside the trough and the surface of the residual ice cap. High resolution THEMIS IR data allows us to distinguish properties of bulk of layered terrain and ice. We were not able yet to distinguish properties of individual layers.

A B Ivanov↗

Experimental Study of Unsupported Nonane fuel Droplet Combustion in Microgravity

Soot formation in droplet flames is the basic component of the particulate emission process that occurs in spray combustion. The complexity of soot formation motivates a one-dimensional transport condition which has obvious advantages in modeling. Recent models of spherically symmetric droplet combustion have made this assumption when incorporating such aspects as detailed chemistry and radiation. Interestingly, spherical symmetry does not necessarily restrict the results because it has been observed that the properties of carbon formed in flames are not strongly affected by the nature of the fuel or flaming configuration. What is affected, however, are the forces acting on the soot aggregates and where they are trapped by a balance of drag and thermophoretic forces. The distribution of these forces depends on the transport conditions of the flame. Prior studies of spherical droplet flames have examined the droplet burning history of alkanes, alcohols and aromatics. Data are typically the evolution of droplet, flame, extinction, and soot shell diameters. These data are only now just beginning to find their way into comprehensive numerical models of droplet combustion to test proposed oxidation schemes for fuels such as methanol and heptane. In the present study, we report new measurements on the burning history of unsupported nonane droplets in a convection-free environment to promote spherical symmetry. The far-field gas is atmospheric pressure air at room temperature. The evolution of droplet diameter was measured using high speed cine photography of a spark-ignited, droplet within a confined volume in a drop tower. The initial droplet diameters varied between 0.5 mm and 0.6 mm. The challenge of unsupported droplets is to form, deploy and ignite them with minimal disturbance, and then to keep them in the camera field of view. Because of the difficulty of this undertaking, more sophisticated diagnostics for studying soot than photographic were not used. Supporting the test droplet by a fiber fixes the droplet position but the fiber can perturb the burning process especially for a sooting fuel. Prior studies on heptane showed little evidence for soot formation due to g-droplets of similar size the relationship between sooting and droplet diameter. For nonane droplets we expect increased sooting due to the greater number of carbon atoms. As a sooting droplet burns and its diameter decreases, proportionally less soot should form. This reduced soot, as well as the influence of soot formed earlier in the burning process which collects in a 'shell', on heat transport to the flame offers the potential for a time-varying burning rate. Such an effect was investigated and revealed in results reported here. Speculation is offered for the cause of this effect and its possible relation to soot formation.

Callahan, B. J.↗

Asymmetry in the Seasonal Cycle of Zonal-Mean Surface Air Temperature

At most latitudes, the seasonal cycle of zonal-mean surface air temperature is notably asymmetric: the length of the warming season is not equal to the length of the cooling season. The asymmetry varies spatially, with the cooling season being ∼40 days shorter than the warming season in the subtropics and the warming season being ∼100 days shorter than the cooling season at the poles. Furthermore, the asymmetry differs between the Northern Hemisphere and the Southern Hemisphere. Here, we show that these observed features are broadly captured in a simple model for the evolution of temperature forced by realistic insolation. The model suggests that Earth's orbital eccentricity largely determines the hemispheric contrast, and obliquity broadly dictates the meridional structure. Clouds, atmospheric heat flux convergence, and time-invariant effective surface heat capacity have minimal impacts on seasonal asymmetry. This simple, first-order picture has been absent from previous discussions of the surface temperature seasonal cycle.

seasonal cycle↗

Development of a Laser Ultrasonics-based Approach for Rapid Screening of High Entropy Alloys

This project utilized a laser ultrasonic technique to systematically study temperature-induced evolution of material properties in a set of interrelated binary alloys and a high entropy alloy (HEA) fabricated using arc-melting and spark plasma sintering processes. This technique involved the use of a nanosecond duration, high-intensity pulsed laser to thermo-elastically generate ultrasonic waves that propagate in the bulk of the metal alloy. Sub-nanometer-scale displacements associated with the propagating bulk ultrasonic waves were detected along the epicenter on the opposite surface of the sample using a 1 GHz bandwidth photorefractive interferometer. Phase transformations and microstructural changes were inferred from the temperature-dependent trends in the bulk acoustic velocities and features in the ultrasonic epicentral waveforms measured in the binary alloys. These inferences were then correlated with electron/optical microscopy observations and predictions using calculations of phase diagrams (CALPHAD). The results showed that the laser-generated ultrasonic pulses were strongly influenced by changes in material microstructure and could accurately track thermally driven phase transformations and detect the presence of microscale heterogeneities (grain boundaries, dendritic structures, etc.) in the set of binary alloy samples. The measurement approach was then applied to a quinary HEA sample for estimating phase transition temperature and determining microstructural heterogeneity. The rapid, non-contact and non-destructive ultrasonic testing approach demonstrated here is amenable to high throughput combinatorial investigations that can be applied to graded composition HEAs produced using advanced manufacturing methods. When paired with atomistic simulations and CALPHAD modeling, this approach can overcome the bottlenecks faced by current material characterization methods in efficiently screening the vast discovery space of HEAs that spans over a hundred million unique quinary alloy compositions.

36 MATERIALS SCIENCE↗

Diagnostic Comparison of Meteorological Analyses during the 2002 Antarctic Winter

Several meteorological datasets, including U.K. Met Office (MetO), European Centre for Medium-Range Weather Forecasts (ECMWF), National Centers for Environmental Prediction (NCEP), and NASA's Goddard Earth Observation System (GEOS-4) analyses, are being used in studies of the 2002 Southern Hemisphere (SH) stratospheric winter and Antarctic major warming. Diagnostics are compared to assess how these studies may be affected by the meteorological data used. While the overall structure and evolution of temperatures, winds, and wave diagnostics in the different analyses provide a consistent picture of the large-scale dynamics of the SH 2002 winter, several significant differences may affect detailed studies. The NCEP-NCAR reanalysis (REAN) and NCEP-Department of Energy (DOE) reanalysis-2 (REAN-2) datasets are not recommended for detailed studies, especially those related to polar processing, because of lower-stratospheric temperature biases that result in underestimates of polar processing potential, and because their winds and wave diagnostics show increasing differences from other analyses between similar to 30 and 10 hPa (their top level). Southern Hemisphere polar stratospheric temperatures in the ECMWF 40-Yr Re-analysis (ERA-40) show unrealistic vertical structure, so this long-term reanalysis is also unsuited for quantitative studies. The NCEP/Climate Prediction Center (CPC) objective analyses give an inferior representation of the upper-stratospheric vortex. Polar vortex transport barriers are similar in all analyses, but there is large variation in the amount, patterns, and timing of mixing, even among the operational assimilated datasets (ECMWF, MetO, and GEOS-4). The higher-resolution GEOS-4 and ECMWF assimilations provide significantly better representation of filamentation and small-scale structure than the other analyses, even when fields gridded at reduced resolution are studied. The choice of which analysis to use is most critical for detailed transport studies (including polar process modeling) and studies involving synoptic evolution in the upper stratosphere. The operational assimilated datasets are better suited for most applications than the NCEP/CPC objective analyses and the reanalysis datasets.

stratosphere↗

Experimental demonstration of real-time electron temperature profile control in DIII-D

Future tokamak reactor operation will require the ability to maintain a given plasma scenario for extended periods of time. This will necessitate the capability to react to changes in the plasma state and return the plasma to the target scenario; the principal method to achieve this is through feedback control. Thus, it is necessary to develop and test feedback controllers for the plasma profiles that define a target scenario. In this work, a feedback controller for the electron temperature (Te) profile is tested experimentally in DIII-D. This experiment relied on the ability to ascertain the electron temperature profile in real time, which was achieved using an observer algorithm. The observer relies on both diagnostic data and a predictive model of the electron temperature profile evolution; this predictive model includes contributions from neural network surrogate models. Because of these dependencies, a number of capabilities needed to be added to the real-time PCS for DIII-D in order to support the Te profile control experiment. The neural network surrogates needed to be integrated into the PCS to be called in real time. An observer algorithm for the Te profile needed to be added and connected to the Thomson scattering system to allow access to the current state of the profile in real time. When tested, the observer was shown to produce Te profiles that are consistent with the shape of the Thomson scattering data while rejecting much of the noise in the diagnostic data. Finally, the controller itself was tested in real time. This experiment showed that the controller is capable of tracking the electron temperature target at locations across the spatial profile.

Morosohk, Shira [Oak Ridge Associated Universities↗