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At least 217 records · Page 12

Space stable thermal control coatings

Both pigment and paint studies were conducted to determine the effect of calcination conditions on optical properties of Zn2TiO4. Paint studies were concerned with the effects of spraying technique, of pigment to binder ratio, and of thickness on the properties of finished coatings. The results are reviewed in detail. Pigments prepared by calcination at 600 deg. to 800 deg. were evaluated. Low temperature syntheses were conducted to determine; (1) extent of ZnO + TiO2 reaction; and (2) the potential of higher peak reflectance with finer particle size powder obtained at lower temperatures.

Harada, Y.↗

Space stable thermal control coatings

The studies discussed are designed to yield a Zn2TiO4 paint as an engineering material for use on future spacecraft. Zn2TiO4 pigment powders were synthesized and paint studies were performed.

Harada, Y.↗

Two-Layer Glass Thermal-Control Coating

Optical properties endure high temperatures. Coating has outer scattering layer and inner high emissivity layer. Absorptivity/emissivity ratio less than 0.4. Coating withstands repeated exposure to temperatures in excess of 2,000 degrees F. Coating has industrial uses in solar-energy equipment, high temperature chemical processing systems, laboratory equipment and high temperature instrumentation.

Stewart, D. A.↗

Space stable thermal control coatings

A specification quality zinc orthotitanate coating was developed. This silicate-bonded Zn2TiO4 coating is discussed. The effects of precursor chemistry, precursor mixing procedures, stoichiometry variations, and of different heat treatments on the physical and optical properties of Zn2TiO4 are investigated. Inorganic silicates are compared to organic silicone binder systems. The effects of pigment to binder ratio, water content, and of different curing procedures on the optical and physical properties of Zn2TiO4 potassium silicate coatings are also studied. Environmental tests were conducted to determine the UV vacuum stability of coatings for durations up to 5000 equivalent Sun hours.

Harada, Y.↗

Requirements and test results for the qualification of thermal control coatings

Paint type coatings are often used as engineering materials in critical satellite temperature control applications. The functional features of coatings used for temperature control purposes must remain stable throughout the satellite manufacturing process and the satellite mission. The selection of a particular coating depends on matching coating characteristics to mission requirements. The use of paint coatings on satellites, although having an extensive history, requires that the paint be qualified to each application on an individual basis. Thus, the qualification process through testing serves to ensure that paint coatings as engineering materials will fulfill design requirements.

Brzuskiewicz, J. E.↗

Spacecraft thermal control coatings (AO 138-6)

The experiment A0 138-6 was located on the trailing edge of LDEF as part of the Experiment FRECOPA. Material specimens 2 x 2 cm, independently mounted in sample-holders with their surface in the same reference plane, were exposed to space. Materials include paints (conductive or not), SSMs, polymeric films, surface coatings, composite materials, and metals. The results show that for some materials the degradation was higher for samples in the canister than for those directly mounted on the tray; contamination problems were ruled out, the higher temperature experienced by the samples inside the canister probably explains this phenomenon.

Paillous, Alain↗

Spacecraft thermal control coatings

The Experiment AO 138-6 was located on the trailing edge of the Long Duration Exposure Facility as part of the French Cooperative Payload (FRECOPA) Experiment. It was purely passive in nature: material specimens 2 x 2 cm, independently mounted in sample-holders, with their surface in the same reference plane, were exposed to space. Thirty samples were set in a vacuum-tight canister which was opened in space a few days after LDEF deployment and closed while still in orbit ten months later; twenty-four samples were directly exposed to space for the total flight duration (preflight handling, shuttle bay environment, separation from shuttle, shuttle environment, LEO environment, docking, descent, transfer to KSC). Materials included paints (conductive or nonconductive), SSM's, polymeric films, surface coatings, composite materials, and metals. After sample retrieving, inspection and measurements were carried out in atmospheric laboratory conditions on each sample: observation with binocular lenses and scanning electron microscopy, spectral relectance and transmittance using an integrating sphere in the wavelength range 280-2300 nm, emissivity by the means of a Gier & Dunkle portable reflectometer, electron spectroscopy for chemical analysis-x-ray photoelectron spectroscopy (ESCA-XPS), and Rutherford backscattering spectroscopy (RBS) measurements on some selected samples. The results obtained from flight were compared to laboratory data obtained in UV-irradiation tests when these data were available. As a general statement a good spectral concordance is observed for all samples not in the canister so long as air recoveries are taken into account. For one material, the degradation is more important for the sample in the canister than for those of the same material mounted at the surface of the tray; for most samples in the canister the degradation is slightly higher than the one which can be predicted from laboratory standard irradiations. Contamination problems having been ruled out, the higher temperature experience by the samples on the inside of canister probably explains these phenomena.

Guillaumon, Jean-Claude↗

Flouorescence measurements of the thermal control coatings on LDEF experiments S0069 and A0114

Strong fluorescence emissions were observed, during post flight ultraviolet light inspection of experiments S0069 and A0114, from some of the surfaces exposed to the space environment. Subsequent wavelength measurements of the fluorescence emission characteristics, indicated large changes occurred between controls and exposed materials. Black urethane based coatings, especially ones having a silicone atomic oxygen protective overcoat, appear bright yellow under ultraviolet exposure. Measurements showed that the urethane based coatings had their emission spectra shifted into the visible wavelength range. In contrast, zinc oxide pigment type coatings showed a different effect, which was a quenching or reduction of their fluorescence versus exposure time. Silver Teflon bonded to aluminum with acrylic adhesive also showed a slight measurable fluorescence, which was found to originate in the acrylic adhesive.

Zwiener, James M.↗

Spacecraft thermal control coatings: Comparison between flight results obtained on LDEF and MIR

The COMES experiment was installed outside of the MIR space station during an extravehicular activity. The experiment was exposed to vacuum, atomic oxygen, and ultraviolet radiation (UV) for 1.1 years. Due to a lack of knowledge about the spacecrafts actual attitude, there is a large uncertainty in the atomic oxygen fluence and the UV dose that was experienced by COMES. Additionally, contaminants of many different origins were observed on the COMES samples.

Guillaumon, Jean-Claude↗

The effects of simulated low Earth orbit environments on spacecraft thermal control coatings

Candidate Space Station Freedom radiator coatings including Z-93, YB-71, anodized aluminum and SiO(x) coated silvered Teflon have been characterized for optical properties degradation upon exposure to environments containing atomic oxygen, vacuum ultraviolet (VUV) radiation, and/or silicone contamination. YB-71 coating showed a blue-gray discoloration, which has not been observed in space, upon exposure in atomic oxygen facilities which also provide exaggerated VUV radiation. This is evidence that damage mechanisms occur in these ground laboratory facilities which are different from those which occur in space. Radiator coatings exposed to an electron cyclotron resonance (ECR) atomic oxygen source in the presence of silicone-containing samples showed severe darkening from the intense VUV radiation provided by the ECR and from silicone contamination. Samples exposed to atomic oxygen from the ECR source and to VUV lamps, simultaneously, with in situ reflectance measurement, showed that significantly greater degradation occurred when samples received line-of-site ECR beam exposure than when samples were exposed to atomic oxygen scattered off of quartz surfaces without line-of-site view of the ECR beam. For white paints, exposure to air following atomic oxygen/VUV exposure reversed the darkening due to VUV damage. This illustrates the importance of in situ reflectance measurement.

Dever, Joyce A.↗

Space Environmental Effects on Thermal Control Coatings

The study of long term near ultra-violet (NUV) effects in a vacuum atmosphere, is a crucial element for space applications. NUV radiation causes significant changes in the reflectance of many coatings and types of materials. An ultra high vacuum NUV system was assembled in order to investigate various coatings and materials in this hostile environment. The vacuum is an ion pump that maintains a minimum vacuum in the mid 10(exp -9) range. The system has a base pressure of 10(exp -9) torr and this base pressure is maintained with the ion pump. The NUV exposure was maintained at 2-3 suns which allows accelerated NUV exposure without overheating the samples. The goal of this test was to maintain an intensity of 3.4 x 10(exp -2) Watts/cm(exp 2) which equals 2.9 NUV suns. An NUV sun is defined as 1.16 Watts/cm(exp 2) integrated over wavelength of 200-400 nanometers.

OBrien, Susan K.↗

Optical Properties of Thermal Control Coatings After Weathering, Simulated Ascent Heating, and Simulated Space Radiation Exposure

Spacecraft radiators reject heat to their surroundings and coatings play an important role in this heat rejection. The coatings provide the combined optical properties of low solar absorptance and high infrared emittance. The coatings are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an applique. Not designed for a terrestrial weathering environment, the durability of spacecraft paints, coatings, and appliques upon exposure to weathering and subsequent exposure to ascent heating, solar wind, and ultraviolet radiation was studied. In addition to traditional aluminum panels, new isocyanate ester composite panels were exposed for a total of 90 days at the Atmospheric Exposure Site of Kennedy Space Center's (KSC) Beach Corrosion Facility for the purpose of identifying their durability to weathering. Selected panel coupons were subsequently exposed to simulated ascent heating, solar wind, and vacuum ultraviolet (UV) radiation to identify the effect of a simulated space environment on as-weathered surfaces. Optical properties and adhesion testing were used to document the durability of the paints, coatings, and appliques.

Jaworske, Donald A.↗

Testing and Optimization of Electrically Conductive Spacecraft Coatings

This is the final report discussing the work done for the Space Environments and Effects (SEE) Program. It discusses test chamber design, coating research, and test results on electrically thermal control coatings. These thermal control coatings are being developed to have several orders of magnitude higher electrical conductivity than most available thermal control coatings. Most current coatings tend to have a range in surface resistivity from 1,011 to 1,013 ohms/sq. Historically, spacecraft have had thermal control surfaces composed of dielectric materials of either polymers (paints and metalized films) or glasses (ceramic paints and optical solar reflectors). Very seldom has the thermal control surface of a spacecraft been a metal where the surface would be intrinsically electrically conductive. The poor thermal optical properties of most metals have, in most cases, stopped them from being used as a thermal control surface. Metals low infrared emittance (generally considered poor for thermal control surfaces) and/or solar absorptance, have resulted in the use of various dielectric coatings or films being applied over the substrate materials in order to obtain the required optical properties.

Mell, R. J.↗

Chapter 9: MEMS Applications in Spacecraft Thermal Control and Chapter 13: Handling and Contamination Control Considerations for Critical Space Applications

Thermal control systems (TCS) are an integral part of all spacecraft and instruments. To operate properly all spacecraft components must be maintained within a specified temperature band, which in some instances can be quite tight (less than 1 degree C). Traditionally this is accomplished by "passive" designs, but with modem spacecraft and instruments it is increasingly necessary to use active thermal control technologies. Microelectromechanical System (MEMS) can be useful in developing an active TCS, and may be especially useful for small spacecraft. As the MEMS knowledge matures, the applications of MEMS in spacecraft thermal control emerges as a viable technology for thermal engineers. Potential applications include specialized thermal control coatings, thermal switches, and specialized filters for instruments. Although MEMS technology demonstrates benefits, it also poses challenges for thermal en,oineers due to the lack of in-flight MEMS data. As a consequence, in order to design a MEMS thermal control device and receive the full advantage, it is important to understand the potential impact of the space environment on MEMS devices and the design/operational constraints imposed in their use. An entire chapter is devoted to handling and contamination controls for Micro Electro Mechanical Systems (MEMS) in space applications due to the importance of the topic area to final mission success. Handling and contamination control is discussed relative to the full life cycle from the very basic wafer level processing up through on orbit deployment. MEMS packaging will drive the need to tailor the Handling and Contamination Control Plan in order to assure adequacy of the overall program on a program by program basis. Plan elements are discussed at length to assist the user in preparing and implementing effective plans for both handling and contamination control to prevent deleterious effects.

Osiander, Robert↗