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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

A self-consistent interpretation of the solar flare extreme-ultraviolet to hard X-ray ratio in large events

This paper shows quantitatively that when a limiting X-ray yield is considered, a universal area of 10 to the 17th sq cm used in the thick-target electron bombardment model of McClymont and Canfield (1986) cannot explain the observed hard X-ray flux in large solar flare events without recourse to extreme values of the physical parameters of the flaring corona. The return current ohmic heating produced by a beam of flux 10 to the 13th ergs/sq cm/s results in a coronal temperature in excess of 100 million K. In this case, the thermal hard X-ray emission dominates the nonthermal emission and the EUV-to-hard X-ray ratio would not decrease with increasing hard X-ray flux, as observed. Hence, any model that requires a beam flux of 10 to the 13th ergs/sq cm/s is untenable. It is proposed that these apparently contradictory results can be reconciled if the X-ray emitting area is substantially larger than the area of the chromospheric precipitation site.

Larosa, T. N.↗

Research and development of HgZnTe as an infrared material

Interfacial morphology and Fermi level pinning behavior at the interfaces of Al, Ag, and Pt with UHV-cleaved CdTe and ZnTe have been studied using X-ray and ultraviolet photoemission spectroscopies. Results are compared to metal/HgCdTe interface formation, where the weak HgTe bond and consequent ease of Hg loss strongly influence semiconductor disruption and metal-semiconductor intermising. For Al/CdTe, the strong Al-Te reaction yields a significantly more extensive Al-Te reacted region than has been observed for HgCdTe. The Al/ZnTe interface is observed to be more abrupt than Al/CdTe. The final Fermi level pinning positions, Ef-Evbm for Al, Ag, and Pt on p-type CdTe and p-ZnTe have been determined. Efi is found to be roughly the same for both CdTe and ZnTe, with the value for ZnTe lying approximately 0.2 eV closer to the VBM for all three metals. From these results, one would expect Schottky barriers of about the same height for these metals on p-CdTe and p-ZnTe; and also that, in principle, metal interfaces with the two alloys HgCdTe and HgZnTe would have the same properties. Comparisons and implications for electrical behavior of metal contacts to the alloys are discussed.

Wahi, A. K.↗

Review of model sensor studies on Pd/SnO2(110) surfaces

Studies performed at the National Institute of Standards and Technology on the model gas sensor system, Pd/SnO2(110), are reviewed. Adsorption and interfacial effects play a primary role in the gas sensing process, as they do in catalysis. For this reason, researchers have used a variety of surface sensitive techniques in the research, including x ray and ultraviolet photoelectron spectroscopies (XPS and UPS), low energy electron diffraction (LEED), and ion scattering spectroscopy (ISS). By combining these complementary techniques with in situ gas response (conductance) measurements, researchers were able to correlate directly sensor activity with the composition and structure of the Pd/SnO2 interface. Although the intent of this work is to develop an understanding of gas sensing mechanisms, its relevance to Pt/SnO2 catalytic systems is obvious.

Fryberger, Teresa B.↗

ROSAT: An international mission exploring the high energy universe

ROSAT was designed specifically to detect high energy radiation, by using its telescopes to study x ray and ultraviolet emissions, regions of the electromagnetic spectrum that cannot be seen and that cannot penetrate the Earth's atmosphere. ROSAT is an international astronomical observatory project. ROSAT's science mission is divided into two phases. With its in-orbit checkout period complete, ROSAT has begun phase one of its mission, an all sky survey to map the heavens. When the 6 month mapping survey is complete, the satellite will begin phase two and be pointed at selected objects, studying individual targets, for the remainder of its mission.

Source record↗

Synchrotron radiation - Applications in the earth sciences

Synchrotron-radiation sources and their characteristics are overviewed along with recent synchrotron-based research on earth materials and future earth-science applications utilizing the next generation of synchrotron-radiation sources presently under construction. Focus is placed on X-ray scattering studies of earth materials (crystalline and noncrystalline) under ambient conditions, diffraction studies of earth materials at high pressures and/or temperatures, spectroscopic studies, primarily X-ray absorption spectroscopy, and spatially resolved X-ray fluorescence studies of compositional variations in earth materials. It is noted that other synchrotron-based methods, such as X-ray tomography and topography may become important in characterizing earth materials, while soft X-ray/vacuum ultraviolet radiation from synchrotron sources can be applied to problems involving the structural environments of low-atomic-number elements and the characterization of surface reactions of minerals with liquids and gases.

Bassett, W. A.↗

Workshop Proceedings: Sensor Systems for Space Astrophysics in the 21st Century, Volume 2

In 1989, the Astrophysics Division of the Office of Space Science and Applications initiated the planning of a technology development program, Astrotech 21, to develop the technological base for the Astrophysics missions developed in the period 1995 to 2015. The Sensor Systems for Space Astrophysics in the 21st Century Workshop was one of three Integrated Technology Planning workshops. Its objectives were to develop an understanding of the future comprehensive development program to achieve the required capabilities. Program plans and recommendations were prepared in four areas: x ray and gamma ray sensors, ultraviolet and visible sensors, direct infrared sensors, and heterodyne submillimeter wave sensors.

Wilson, Barbara A.↗

Sensor technology workshop: Structure and goals

The Astrotech 21 charter for the second of three workshops is described. The purpose was to identify technology needs in the areas of electromagnetic radiation sensors, and to recommend a plan to develop the required capabilities that are not currently available. The panels chosen for this workshop focused specifically on those technologies needed for the Astrotech 21 Program including: gamma ray and x ray sensors, ultraviolet and visible sensors, direct infrared sensors, and heterodyne submillimeter wave sensors.

Wilson, Barbara A.↗

Predatory Microorganisms Would Help Reclaim Water

Wastewater-reclamation systems of proposed type use predatory, nonpathogenic microorganisms to consume pathogenic microorganisms. Unlike some other wastewater-reclamation systems, these systems do not require use of toxic chemicals, intense heat, or ionizing radiation (conductivity rays or ultraviolet) to destroy microorganisms.

Benjaminson, Morris A.↗

Evaluation and Selection of Replacement Thermal Control Materials for the Hubble Space Telescope

The mechanical and optical properties of the metallized Teflon(Registered Trademark) FEP thermal control materials on the Hubble Space Telescope (HST) have degraded over the nearly seven years the telescope has been in orbit. Given the damage to the outer layer of the multi-layer insulation (MLI) that was apparent during the second servicing mission (SM2), the decision was made to replace the outer layer during subsequent servicing missions. A Failure Review Board was established to investigate the damage to the MLI and identify a replacement material. The replacement material had to meet the stringent thermal requirements of the spacecraft and maintain structural integrity for at least ten years. Ten candidate materials were selected and exposed to ten-year HST-equivalent doses of simulated orbital environments. Samples of the candidates were exposed sequentially to low and high energy electrons and protons, atomic oxygen, x-ray radiation, ultraviolet radiation and thermal cycling. Following the exposures, the mechanical integrity and optical properties of the candidates were investigated using Optical Microscopy, Scanning Electron Microscopy (SEM), and a Laboratory Portable Spectroreflectometer (LPSR). Based on the results of these simulations and analyses, the FRB selected a replacement material and two alternates that showed the highest likelihood of providing the requisite thermal properties and surviving for ten years in orbit.q

Townsend, Jacqueline A.↗

Ground-Based Testing of Replacement Thermal Control Materials for the Hubble Space Telescope

The mechanical and optical properties of the metallized Teflon FEP thermal control materials on the Hubble Space Telescope (HST) have degraded over the nearly seven years the telescope has been in orbit. Given the damage to the outer layer of the multi-layer insulation (MLI) that was apparent during the second servicing mission (SM2), the decision was made to replace the outer layer during subsequent servicing missions. A Failure Review Board was established to investigate the damage to the MLI and identify a replacement material. The replacement material had to meet the stringent thermal requirements of the spacecraft and maintain mechanical integrity for at least ten years. Ten candidate materials were selected and exposed to ten-year HST-equivalent doses of simulated orbital environments. Samples of the candidates were exposed sequentially to low and high energy electrons and protons, atomic oxygen, x-ray radiation, ultraviolet radiation and thermal cycling. Following the exposures, the mechanical integrity and optical properties of the candidates were investigated using Optical Microscopy, Scanning Electron Microscopy (SEM), a Laboratory Portable Spectroreflectometer (LPSR) and a Lambda 9 Spectroreflectometer. Based on the results of these simulations and analyses, the Failure Review Board selected a replacement material and two alternates that showed the highest likelihood of providing the requisite thermal properties and surviving for ten years in orbit.

Townsend, Jacqueline A.↗

ROSAT PSPC observations of NGC 7469 and Ark 120

We present spatial, temporal and spectral analyses of ROSAT Position Sensitive Proportional Counter (PSPC) observations of the Seyfert 1 galaxies NGC 7469 and Ark 120. Both of these sources show evidence for excess emission and more complex 0.1- 2.5 keV spectra than are predicted by simple extrapolations of higher energy power laws. We find that the spectrum of NGC 7469 can be explained by models that have secondary power-law, secondary bremsstrahlung, secondary blackbody or emission-line components. We find evidence for 0.1-2.5 keV intensity variability of NGC 7469. The spectrum of Ark 120 is better described by models with secondary continuum components than by models with sharper spectral features. We discuss the agreement between X-ray and ultraviolet observations of these sources and examine the observations in the context of accretion disc reflection models. The inner parts of discs are likely to be reflective below approximately 0.24 keV, and this reflectivity complicates simple models of the soft excess.

Brandt, W. N.↗

Bright Points and Subflares in Ultraviolet Lines and X-Rays

We have analyzed an active region which was observed in H.alpha (Multichannel Subtractive Double Pass Spectrograph), in UV lines (SMM/UVSP), and in X-rays (SMM/HXIS). In this active region there were only a few subflares and many small bright points visible in UV and in X-rays. Using an extrapolation based on the Fourier transform, we have computed magnetic field lines connecting different photospheric magnetic polarities from ground-based magnetograms. Along the magnetic inversion lines we find two different zones: (1) a high-shear region (> 70 deg) where subflares occur, and (2) a low-shear region along the magnetic inversion line where UV bright points are observed. In these latter regions the magnetic topology is complex with a mixture of polarities. According to the velocity field observed in the Si IV lamda.1402 line and the extrapolation of the magnetic field, we notice that each UV bright point is consistent with emission from low-rising loops with downflows at both ends. We notice some hard X-ray emissions above the bright-point regions with temperatures up to 8 x 10(exp 6) K, which suggests some induced reconnection due to continuous emergence of new flux. This reconnection is also enhanced by neighboring subflares.

Rovira, M.↗

Multi-Wavelength Superoutburst Observations of T Leonis

We present results of simultaneous superoutburst observations in the X-ray, Extreme Ultraviolet (EUV), optical, and IR bands of the tremendous outburst amplitude dwarf novae T Leonis. Near peak luminosity, a single blackbody represents a good fit to T Leo's observed continuum in the EUV spectral region, yielding a boundary layer temperature of 71,000 to 97,000K. Inclusion of the longer wavelength observations, UV to the IR, indicates that a blackbody fit is inappropriate. A single temperature fit to only the UV and red-ward data for T Leo works well, but yields a much lower temperature, near 28,000K. Using our own observations and previously obtained EUV, UV and optical (super)outburst observations for the dwarf novae U Gem and SS Cyg, the SU UMa star VW Hyi, and the TOADS, TV Crv, BC UMa, and SW UMa, we find that in all cases, high energy observations yield high temperature, small emitting regions, while fits to UV and red-ward data produce cooler temperatures from much larger emitting regions. These results are consistent with the idea that high energy data provide a direct measurement of the boundary layer while the lower energy data measure a much larger, multi-temperature region, likely to be dominated by the outburst heated inner accretion disk. High energy outburst observations show that the boundary layer temperature decreases with decreasing orbital period and UV outburst observations provide evidence for a missing or weak inner disk in the TOADs. We present a simple model of mass accretion onto the white dwarf during (super)outburst which can account for the observed correlation between temperature.

Howell, Steve B.↗

The Interstellar Production of Biologically Important Organics

One of the primary tasks of the Astrochemistry Laboratory at Ames Research Center is to use laboratory simulations to study the chemical processes that occur in dense interstellar clouds. Since new stars are formed in these clouds, their materials may be responsible for the delivery of organics to new habitable planets and may play important roles in the origin of life. These clouds are extremely cold (less than 50 kelvin), and most of the volatiles in these clouds are condensed onto dust grains as thin ice mantles. These ices are exposed to cosmic rays and ultraviolet (UV) photons that break chemical bonds and result in the production of complex molecules when the ices are warmed (as they would be when incorporated into a star-forming region). Using cryovacuum systems and UV lamps, this study simulates the conditions of these clouds and studies the resulting chemistry. Some of the areas of progress made in 1999 are described below. It shows some of the types of molecules that may be formed in the interstellar medium. Laboratory simulations have already confirmed that many of these compounds are made under these conditions.

Sandford, Scott A.↗

Survival of endospores of Bacillus subtilis on spacecraft surfaces under simulated martian environments: implications for the forward contamination of Mars

Experiments were conducted in a Mars simulation chamber (MSC) to characterize the survival of endospores of Bacillus subtilis under high UV irradiation and simulated martian conditions. The MSC was used to create Mars surface environments in which pressure (8.5 mb), temperature (-80, -40, -10, or +23 degrees C), gas composition (Earth-normal N2/O2 mix, pure N2, pure CO2, or a Mars gas mix), and UV-VIS-NIR fluence rates (200-1200 nm) were maintained within tight limits. The Mars gas mix was composed of CO2 (95.3%), N2 (2.7%), Ar (1.7%), O2 (0.2%), and water vapor (0.03%). Experiments were conducted to measure the effects of pressure, gas composition, and temperature alone or in combination with Mars-normal UV-VIS-NIR light environments. Endospores of B. subtilis, were deposited on aluminum coupons as monolayers in which the average density applied to coupons was 2.47 x 10(6) bacteria per sample. Populations of B. subtilis placed on aluminum coupons and subjected to an Earth-normal temperature (23 degrees C), pressure (1013 mb), and gas mix (normal N2/O2 ratio) but illuminated with a Mars-normal UV-VIS-NIR spectrum were reduced by over 99.9% after 30 sec exposure to Mars-normal UV fluence rates. However, it required at least 15 min of Mars-normal UV exposure to reduce bacterial populations on aluminum coupons to non-recoverable levels. These results were duplicated when bacteria were exposed to Mars-normal environments of temperature (-10 degrees C), pressure (8.5 mb), gas composition (pure CO2), and UV fluence rates. In other experiments, results indicated that the gas composition of the atmosphere and the temperature of the bacterial monolayers at the time of Mars UV exposure had no effects on the survival of bacterial endospores. But Mars-normal pressures (8.5 mb) were found to reduce survival by approximately 20-35% compared to Earth-normal pressures (1013 mb). The primary implications of these results are (a) that greater than 99.9% of bacterial populations on sun-exposed surfaces of spacecraft are likely to be inactivated within a few tens of seconds to a few minutes on the surface of Mars, and (b) that within a single Mars day under clear-sky conditions bacterial populations on sun-exposed surfaces of spacecraft will be sterilized. Furthermore, these results suggest that the high UV fluence rates on the martian surface can be an important resource in minimizing the forward contamination of Mars. c2003 Elsevier Inc. All rights reserved.

Bacillus subtilis/growth & development/physiology/↗

Functional nanocomposites prepared by self-assembly and polymerization of diacetylene surfactants and silicic acid

Conjugated polymer/silica nanocomposites with hexagonal, cubic, or lamellar mesoscopic order were synthesized by self-assembly using polymerizable amphiphilic diacetylene molecules as both structure-directing agents and monomers. The self-assembly procedure is rapid and incorporates the organic monomers uniformly within a highly ordered, inorganic environment. By tailoring the size of the oligo(ethylene glycol) headgroup of the diacetylene-containing surfactant, we varied the resulting self-assembled mesophases of the composite material. The nanostructured inorganic host altered the diacetylene polymerization behavior, and the resulting nanocomposites show unique thermo-, mechano-, and solvatochromic properties. Polymerization of the incorporated surfactants resulted in polydiacetylene (PDA)/silica nanocomposites that were optically transparent and mechanically robust. Molecular modeling and quantum calculations and (13)C spin-lattice relaxation times (T(1)) of the PDA/silica nanocomposites indicated that the surfactant monomers can be uniformly organized into precise spatial arrangements prior to polymerization. Nanoindentation and gas transport experiments showed that these nanocomposite films have increased hardness and reduced permeability as compared to pure PDA. Our work demonstrates polymerizable surfactant/silica self-assembly to be an efficient, general approach to the formation of nanostructured conjugated polymers. The nanostructured inorganic framework serves to protect, stabilize, and orient the polymer, mediate its performance, and provide sufficient mechanical and chemical stability to enable integration of conjugated polymers into devices and microsystems.

NASA Discipline Life Support Systems↗

Tetracycline rapidly reaches all the constituent cells of uropathogenic Escherichia coli biofilms

We have developed a method for visualizing Escherichia coli cells that are exposed to tetracycline in a biofilm, based on a previous report that liposomes containing the E. coli TetR(B) protein fluoresce when exposed to this antibiotic. By our method, cells devoid of TetR(B) also exhibited tetracycline-dependent fluorescence. At 50 microg of tetracycline ml(-1), planktonic cells of a uropathogenic E. coli (UPEC) strain developed maximal fluorescence after 7.5 to 10 min of exposure. A similar behavior was exhibited by cells in a 24- or 48-h UPEC biofilm, as examined by confocal laser microscopy, regardless of whether they lined empty spaces or occupied densely packed regions. Further, a comparison of phase-contrast and fluorescent images of corresponding biofilm zones showed that all the cells fluoresced. Thus, all the biofilm cells were exposed to tetracycline and there were no pockets within the biofilm where the antibiotic failed to reach. It also appeared unlikely that niches of reduced exposure to the antibiotic existed within the biofilms.

Non-NASA Center↗

Poly(ethylene glycol) hydrogel microstructures encapsulating living cells

We present an easy and effective method for the encapsulation of cells inside PEG-based hydrogel microstructures fabricated using photolithography. High-density arrays of three-dimensional microstructures were created on substrates using this method. Mammalian cells were encapsulated in cylindrical hydrogel microstructures of 600 and 50 micrometers in diameter or in cubic hydrogel structures in microfluidic channels. Reducing lateral dimension of the individual hydrogel microstructure to 50 micrometers allowed us to isolate 1-3 cells per microstructure. Viability assays demonstrated that cells remained viable inside these hydrogels after encapsulation for up to 7 days.

Non-NASA Center↗