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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Inspection of next-generation EUV resists with nano-projectile secondary ion mass spectrometry

There is a rapidly growing need for new materials for extreme ultraviolet (EUV) lithography, which incorporate high EUV absorbing elements. Hybrid resists, which are a combination of inorganic and organic moieties, are promising as they offer both high EUV sensitivity and high etch resistance. However, there is a glaring lack of methods to examine the uniformity of these important materials at the nanoscale. We examine the capabilities of nano-projectile secondary ion mass spectrometry (NP-SIMS) to investigate hybrid resists. NP-SIMS is a mass spectrometry-based technique with high lateral resolution. Using NP-SIMS, a surface is probed stochastically with a suite of individual projectiles, 10 6 to 10 7 in total, separated in time and space. Examining these individual mass spectra allows for nanoscale investigation of the uniformity of the surface. We evaluated the performance of NP-SIMS using samples of poly(methyl methacrylate) (PMMA) infiltrated with varying amounts of InO x via vapor-phase infiltration (VPI), an organic–inorganic hybridization method derived from atomic layer deposition. Here, we found that NP-SIMS measurements contained abundant characteristic ions related to both the PMMA and infiltrated In. The intensity of In atomic ions increased linearly with the number of infiltration cycles; however, the uniformity of In and PMMA varied with the number of infiltration cycles. After one cycle, we found that both the PMMA and In were relatively inhomogeneous. The homogeneity improved with subsequent infiltration cycles. In addition, NP-SIMS measurements contained characteristic ions related to the infiltration reaction and provided insights into the VPI mechanism. Overall, the results show that NP-SIMS is capable of examining both the inorganic and organic moieties in a hybrid resist and will be an important method for understanding the performance of these materials for use in EUV lithography.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Achieving ultrahigh modulus of resilience and enhanced thermal stability in ZnO x /SU-8 interpenetrating network polymer nanocomposite nanopillars

The modulus of resilience, a mechanical property that quantifies the maximum strain energy density a material can store during elastic deformation, is a crucial parameter for materials used in flexible displays, micro/nano-electro-mechanical system (M/NEMS) actuators, and ultra-sensitive pressure sensors. In this study, ZnO x /SU-8 nanocomposite nanopillars with a diameter of 300 nm, fully infiltrated with a uniformly distributed, interpenetrating amorphous ZnO x filler network, were synthesized via vapor-phase infiltration (VPI). In-situ uniaxial nano-compression tests revealed that the modulus of resilience of ZnO x /SU-8 reaches ∼ 12 MJ/m 3 , which is an ultrahigh value among all engineering materials with comparable strength. In addition, the synthesis fidelity, inorganic infiltration depth, and mechanical performance were all significantly improved compared to VPI-synthesized AlO x nanocomposites. Thermal stability, another key requirement for M/NEMS device materials operating under extreme environments, was also notably enhanced. Furthermore, partial crystallization of the amorphous ZnO x fillers during annealing contributed to an additional increase in modulus of resilience, reaching up to ∼ 13.9 MJ/m 3 . This work presents an effective fabrication strategy for producing nanostructured organic–inorganic hybrid nanocomposites with ultrahigh modulus of resilience and superior thermal stability, paving the way for their integration into next-generation flexible displays and high-performance M/NEMS devices working under harsh environments.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Atomically Fine-Tuning Organic–Inorganic Carbon Molecular Sieve Membranes for Hydrogen Production

Polymeric membranes with great processability are attractive for the H 2 /CO 2 separation required for hydrogen production from renewable biomass with carbon capture for utilization and sequestration. However, it remains elusive to engineer polymer architectures to obtain desired sub-3.3 Å ultramicropores to efficiently sieve H 2 from CO 2 . Herein, we demonstrate a scalable way of carbonizing polybenzimidazole (PBI) at low temperatures, followed by vapor phase infiltration (VPI) to atomically narrow ultramicropores throughout the films, forming hybrid organic–inorganic carbon molecular sieves (CMSs). One VPI cycle (100 s) for the PBI carbonized at 500 °C remarkably increases H 2 /CO 2 selectivity from 9.6 to 83 at 100 °C, surpassing Robeson’s upper bound. The CMS demonstrates a stable H 2 /CO 2 separation performance when challenged with simulated syngas streams and can be fabricated into thin-film composite membranes, outperforming state-of-the-art membranes. Finally, the scalable approach can be ubiquitous to molecularly fine-tune ultramicropores of leading polymeric membranes to further improve their size-sieving ability and thus separation efficiency.

36 MATERIALS SCIENCE↗
NASA NTRS1976

Shock wave ignition of metal powders

The interaction between isolated metal particles and shock-induced flowfields is analyzed to characterize physical events and determine experimental feasibility for shock wave ignition studies. Emphasis is placed on incident shock wave phenomenon as opposed to reflected shock wave. A pre-ignition particle-flow interaction is hypothesized which presumes a vapor phase ignition reaction and an absence of significant vaporization prior to particle melting and erosion. Rapid vaporization of eroded mass is expected, with ignition reaction in the particle wakes. Experimental observation of the 6438-A Cd line and the 3721-A MgO band support the ignition mechanism hypothesized. Scattered cloud data are believed to substantiate the hypothesis that ignition delays could be correlated with predicted melting times.

Fox, T. W.↗
NASA NTRSDate not supplied

Validation of a Two-Phase CFD Model for Autogenous Pressurization and Expulsion

This paper presents a two-phase computational fluid dynamics (CFD) model for simulating autogenous pressurization and expulsion in a cryogenic liquid hydrogen storage tank, utilizing a volume-of-fluid (VOF) approach combined with the kinetics-based Schrage equation to accurately capture the phase boundary and interfacial heat, mass, and momentum transfer between liquid and vapor phases. The model is validated against experimental data from NASA's K-site tank facility, specifically experimental case 225, which involved pressurization and controlled expulsion of liquid hydrogen. Various turbulence models are evaluated to assess their influence on model accuracy. The CFD simulations successfully replicate key thermodynamic behaviors observed during the experiments, including pressure evolution, temperature profiles, and phase-change dynamics at the vapor-liquid interface. The predicted tank pressures, temperatures, and pressurant requirements agree with experimental data, with pressurant mass predictions within 16\% of observed values. This study highlights the importance of selecting appropriate turbulence models to accurately simulate complex flow and heat transfer phenomena during tank pressurization and expulsion. By enhancing the accuracy and reliability of CFD models for liquid hydrogen under cryogenic conditions, this research contributes to developing efficient cryogenic propellant management strategies for future space missions.

Computational Fluid Dynamics↗
NASA NTRS1981

The infrared spectrum of ammonia hydrate - Explanation for a reported ammonia phase

A number of anomalous spectra of solid NH3 deposited from the vapor phase have appeared in the literature. These spectra have been ascribed to a new phase of NH3. In the experiment reported here these anomalous spectra were reproduced by depositing a thin film from a mixture of gaseous NH3 and H2O and annealing this film at a temperature of 162 K. The thin film spectra showed excellent agreement with recent data on NH3.H2O. The anomalous 'NH3' spectra are, therefore, seen to be caused by H2O contamination of solid NH3 with formation of NH3 hydrate.

Still, G.↗
NASA NTRS2009

The Thermal Electrical Conductivity Probe (TECP) for Phoenix

The Thermal and Electrical Conductivity Probe (TECP) is a component of the Microscopy, Electrochemistry, and Conductivity Analyzer (MECA) payload on the Phoenix Lander. TECP will measure the temperature, thermal conductivity and volumetric heat capacity of the regolith. It will also detect and quantify the population of mobile H2O molecules in the regolith, if any, throughout the polar summer, by measuring the electrical conductivity of the regolith, as well as the dielectric permittivity. In the vapor phase, TECP is capable of measuring the atmospheric H2O vapor abundance, as well as augment the wind velocity measurements from the meteorology instrumentation. TECP is mounted near the end of the 2.3 m Robotic Arm, and can be placed either in the regolith material or held aloft in the atmosphere. This paper describes the development and calibration of the TECP. In addition, substantial characterization of the instrument has been conducted to identify behavioral characteristics that might affect landed surface operations. The greatest potential issue identified in characterization tests is the extraordinary sensitivity of the TECP to placement. Small gaps alter the contact between the TECP and regolith, complicating data interpretation. Testing with the Phoenix Robotic Arm identified mitigation techniques that will be implemented during flight. A flight model of the instrument was also field tested in the Antarctic Dry Valleys during the 2007-2008 International Polar year. 2

Zent, Aaron P.↗
NASA NTRS2017

X-Ray Diffraction (XRD) Characterization Methods for Sigma=3 Twin Defects in Cubic Semiconductor (100) Wafers

An X-ray defraction (XRD) characterization method for sigma=3 twin defects in cubic semiconductor (100) wafers includes a concentration measurement method and a wafer mapping method for any cubic tetrahedral semiconductor wafers including GaAs (100) wafers and Si (100) wafers. The methods use the cubic semiconductor's (004) pole figure in order to detect sigma=3/{111} twin defects. The XRD methods are applicable to any (100) wafers of tetrahedral cubic semiconductors in the diamond structure (Si, Ge, C) and cubic zinc-blend structure (InP, InGaAs, CdTe, ZnSe, and so on) with various growth methods such as Liquid Encapsulated Czochralski (LEC) growth, Molecular Beam Epitaxy (MBE), Organometallic Vapor Phase Epitaxy (OMVPE), Czochralski growth and Metal Organic Chemical Vapor Deposition (MOCVD) growth.

Park, Yeonjoon↗
NASA NTRSDate not supplied

Validation of Cryogenic Propellant Tank Self-Pressurization by Leveraging Reduced Order Modeling within Computational Fluid Dynamics Simulation

Validation of cryogenic propellant tank self-pressurization was performed using a hybrid Computational Fluid Dynamics (CFD) and reduced order modeling methodology. Data from a liquid hydrogen ground test conducted at the K-site facility at the National Aeronautics and Space Administration (NASA) Glenn Research Center was used for the validation effort. Liquid phase dynamics were explicitly resolved with a CFD tool. Vapor phase dynamics were modeled as a point mass that communicated heat from the tank wall to the liquid phase via a boundary condition used at the gas-liquid interface. The method proved to be more accurate, robust, and efficient than explicit resolution of the dynamics using a standard Volume of Fluid (VOF) methodology. The subject pressurization process was found to be heavily dependent upon both the relatively high liquid temperature gradient near the gas-liquid interface and the natural convection flow path. Modeling the gas-liquid interface as an immovable surface eliminated temperature gradient destroying gas-liquid interface velocities observed in VOF simulations, and correspondingly enabled more rapid simulation since interface advection was not allowed. The single phase computational domain also facilitated the ability to demonstrate spatial resolution convergence of natural convection cells within the liquid which significantly impacted the tank pressurization rate. This work was used to demonstrate the critical physics for tank self-pressurization and numerical methodologies that may be used to best resolve those physics. The findings informed development and operation of production level CFD tools used in the Fluid Dynamics Branch at NASA Marshall Space Flight Center.

J. M. Brodnick↗
NASA NTRS2023

Universal Two-Phase Convection Heat Transfer Correlations for Cryogenic Pipe Chilldown

This paper presents a set of universal two-phase convection heat transfer correlations for modeling boiling heat transfer during pipe chilldown fit over the widest available range of cryogenic fluids and thermodynamic conditions. The correlations improve upon prior correlations that were developed separately for liquid nitrogen (LN2) and liquid hydrogen (LH2) pipe quenching datasets. The new correlations include equations to calculate the single-phase vapor heat transfer, film boiling heat transfer, transition boiling heat transfer, nucleate boiling heat transfer, single-phase liquid heat transfer, bulk vapor temperature during high quality film boiling, Leidenfrost temperature, critical heat flux, critical heat flux temperature, and the onset of nucleate boiling temperature. The correlations were validated against LH2, LN2, liquid methane, liquid oxygen, and liquid argon pipe quenching datasets. The eight datasets cover the following parameter ranges: pipe lengths of 0.1 to 6.5m; outer pipe diameters of 12.7 to 25.4 mm; pipe wall thicknesses from 0.51 to 1.64 mm; flow directions of upward, downward, and horizontal; gravity levels of 1g and 0g±0.01g. A numerical model assumes homogeneous mixing between the vapor and liquid and implicitly integrates the coupled energy equations for the pipe and fluid, as well as continuity for the fluid. The model was used to estimate the equilibrium quality and fluid mass accumulation along the pipes during chilldown from estimates of the fluid-pipe heat transfer extracted from temperature measurements. The correlations can be implemented in lumped parameter codes such as SINDA/FLUINT and the Generalized Fluid System Simulation Program (GFSSP) to improve the accuracy of chilldown time and chilldown boiloff mass predictions. Such predictions are useful for designing ground or in-space cryogenic liquid transfer systems.

Universal Correlations↗
NASA NTRS1988

High-Performance Ambient-Temperature Heat Pipe

Heat pipe with two channels designed for regulation of temperature in enclosed spaces. Made of aluminum, heat-transfer material is ammonia. Contains two channels: one for vapor phase and one for liquid phase of ammonia. Porous wick of sintered aluminum powder lines vapor channel and fills slot between two channels. Design confers several advantages.

Keddy, Michael D.↗
NASA NTRS1993

STARDUST - A simulation experiment of cosmic dust analogues production in microgravity conditions

The condensation of solid materials from the vapor phase is important in several scientific fields such as chemical vapor deposition, air pollution and the formation of refractory cosmic dust around stars. Conventional studies of refractory grain formation, using high temperature furnace and shock tube techniques, are restricted to short time scales and suffer from buoyancy induced convection that limit their accuracy. In order to simulate more accurately the condensation of refractory grains near stars and to investigate the advantages of performing condensation studies in microgravity conditions, an experimental investigation was undertaken. This work reports the experimental equipment currently used. The results from the first flight series and particle aggregation modelling efforts are presented briefly.

Ferguson, Frank T.↗
NASA NTRS1993

An augmented Young-Laplace model of an evaporating meniscus in a micro-channel with high heat flux

High flux evaporations from a steady meniscus formed in a 2 micron channel is modeled using the augmented Young-Laplace equation. The heat flux is found to be a function of the long range van der Waals dispersion force which represents interfacial conditions between heptane and various substrates. Heat fluxes of (1.3-1.6) x 10(exp 6) W/m(exp 2) based on the width of the channel are obtained for heptane completely wetting the substrate at 100 C. Small channels are used to obtain these large fluxes. Even though the real contact angle is 0 deg, the apparent contact angle is found to vary between 24.8 deg and 25.6 deg. The apparent contact angle, which represents viscous losses near the contact line, has a large effect on the heat flow rate because of its effect on capillary suction and the area of the meniscus. The interfacial heat flux is modeled using kinetic theory for the evaporation rate. The superheated state depends on the temperature and the pressure of the liquid phase. The liquid pressure differs from the pressure of the vapor phase due to capillarity and long range van der Waals dispersion forces which are relevant in the ultra think film formed at the leading edge of the meniscus. Important pressure gradients in the thin film cause a substantial apparent contact angle for a complete wetting system. The temperature of the liquid is related to the evaporation rate and to the substrate temperature through the steady heat conduction equation. Conduction in the liquid phase is calculated using finite element analysis except in the vicinity of the thin film. A lubrication theory solution for the thin film is combined with the finite element analysis by the method of matched asymptotic expansions.

Wayner, P. C., Jr.↗
NASA NTRS1988

Evolution of polar stratospheric clouds during the Antarctic winter

The occurrence of Polar Stratospheric Clouds (PSCs), initially inferred from satellite measurements of solar extinction, have now also been noted by the recent scientific expeditions in the Antarctic. The presence of such clouds in the Antarctic has been postulated to play a significant role in the depletion of ozone during the transition from winter to spring. The mechanisms suggested involve both dynamical and chemical processes which, explicity or implicitly, are associated with the ice particles constituting the PSCs. It is, thus, both timely and necessary to investigate the evolution of these clouds and ascertain the nature and magnitude of their influences on the state of the Antarctic stratosphere. To achieve these objectives, a detailed microphysical model of the processes governing the growth and sublimation of ice particles in the polar stratosphere was developed, based on the investigations of Ramaswamy and Detwiler. The present studies focus on the physical processes that occur at temperatures below those required for the onset of ice deposition from the vapor phase. Once these low temperatures are attained, the deposition of water vapor onto nucleation particles becomes extremely significant. First, the factors governing the magnitude of growth and the growth rate of ice particles at various altitudes are examined. Second, the ice phase mechanisms are examined in the context of a column model with altitudes ranging from 100 to 5 mb pressure levels. The column microphysical model was used to perform simulations of the cloud evolution, using the observed daily temperatures. The effect due to the growth of the particles on the radiation fields are also investigated using a one dimensional radiative transfer model. Specifically, the perturbations in the longwave cooling and that in the shortwave heating for the late winter/early spring time period are analyzed.

Ramaswamy, V.↗
NASA NTRS1991

Lunar oxygen production by pyrolysis of regolith

Oxygen represents one of the most desirable products of lunar mining and manufacturing. Among the many processes which have been proposed for oxygen production, pyrolysis stands out as one which is uncomplicated and easy to bootstrap. Pyrolysis or vapor-phase reduction involves heating regolith to temperatures sufficient to allow partial decomposition and vaporization. Some metal oxides give up oxygen upon heating, either in the gas phase to form reduced gaseous species or in the condensed phase to form a metallic phase. Based on preliminary experiments and equilibrium calculations, the temperatures needed for pyrolysis are expected to be in the range of 2000 to 2200 K, giving total gas pressures of 0.001 to 0.1 torr. Bulk regolith can be used as a feedstock without beneficiation with concentrated solar radiation supplying most of energy needed. Further, selective condensation of metal-containing species from the gas phase may yield metallic iron and silicon as byproducts.

Senior, Constance L.↗
NASA NTRS1984

Another Look at the Optimum Frequencies for a Water Vapor Radiometer

A water vapor radiometer is used to estimate the columnar content of atmospheric water vapor or equivalently the line-of-sight path delay due to water vapor. Two measurement channels are used in order to separate the effects of the liquid and vapor phases of water. The efficiency of the path delay or columnar vapor estimate is dependent on the choice of on-line frequency channel. Previous analysis of this problem has suggested frequencies from 20.3 to 21 GHz. The frequency that yields the minimum error in the inversion algorithm is shown here to be both site and season dependent. Hence, the concept of an optimum frequency must represent an averaging process over the entire range of meteorological conditions that is expected. For a range of sites and condition representing a cross section of the continental United States the optimum on-line frequency seems to be 20.6 GHz.

Resch, G. M.↗
NASA NTRS1973

The problems of growth of single crystals of rhenium and iridium dioxides

Research is reported on the following: (1) growth of IrO2 and ReOx by the vapor phase method, in which a measured flow of oxygen gas carries the vapor products of the pure metals from a hot zone to a cold zone in a two temperature zone furnace; and (2) growth of IrO2 and Re2O7 single crystals by the chemical vapor transport method.

Source record↗