Search NASA⌕ Search

SEARCH · Search NASA

Results for “Waste Characterization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 217 records · Page 12

Williston Basin Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Program

The U.S. Department of Energy’s (DOE’s) Office of Fossil Energy awarded 13 Carbon Ore, Rare-Earth and Critical Minerals (CORE-CM) programs as part of the CORE-CM Initiative, designed to develop the technology and upstream and midstream supply chains to extract rare-earth elements (REEs) and CMs from the nation’s coal supplies. The intent is to catalyze regional economic growth and job creation while strengthening the use of domestic resources. The Williston Basin CORE-CM Program aims to drive the expansion and transformation of coal and coal-based resource usage within the Williston Basin to produce REEs, CMs, and nonfuel carbon-based products (CBPs). The work constitutes Phase 1 of a long-term program. The objectives of Phase 1 are to identify the existing knowledge base and gaps and to develop a series of assessments/plans, including an initial basinal assessment; a characterization and data acquisition plan; a waste stream reuse plan; a basinal strategies assessment for infrastructure, industries, and business; a technology assessment, development, and field-testing plan; a technology innovation center plan(s); and a stakeholder outreach and education plan. Originally, the CORE-CM programs were to do little if any sample collection as part of the Phase 1 program. As part of the ongoing interactions with DOE regarding the progress of the 13 CORE-CM programs, DOE has decided to extend Phase 1 with additional funding to allow all of the Phase 1 CORE-CM programs to collect and characterize more samples that have potential to be sources of REEs and CMs. The goal of this project is to initiate the development of a new industry in the resource-rich Williston Basin that will generate economic growth and job creation through a coalition team of private industry; university; and state, local, and federal government entities. A coalition team of nearly 30 private industry; university; and state, local, and federal government partners was formed for this program. Partners include the University of North Dakota Energy & Environmental Research Center, Institute for Energy Studies, and Nistler College; North Dakota State University; Montana Tech University; Pacific Northwest National Laboratory; Critical Materials Institute; North Dakota Geological Survey; South Dakota Geological Survey; U.S. Geological Survey; North American Coal Corporation; BNI Energy; Basin Electric Power Cooperative; Minnkota Power Cooperative; and many more.

Kay, John P.↗

Characterization Results for the March 2023 Tank Farm 2H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents characterization results for the March 2023 2H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), and iodine-129 ( 129 I) with the radionuclide concentration limits specified by the WAC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization Results for the April 2022 Tank Farm 2H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents characterization results for the April 2022 2H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), and iodine-129 ( 129 I) with the radionuclide concentration limits specified by the WAC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization Results for the March 2022 Tank Farm 3H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents characterization results for the March 2022 3H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), and iodine-129 ( 129 I) with the radionuclide concentration limits specified by the WAC. These analyses were performed on a single sample replicate. A summary of the analytical results for the 3H evaporator overhead sample includes the following. The measured cesium-137 activity in the 3H evaporator overhead sample is 4.59E+02 dpm/mL which is above the ETP WAC limit of 3.28E+02 dpm/mL. The strontium-90 activity in the 3H evaporator overhead sample is <2.95E+01 dpm/mL. This is below the ETP WAC limit of 1.76E+02 dpm/mL. The iodine-129 activity in the 3H evaporator overhead sample is <1.92E-02 dpm/mL. This is below the ETP WAC limit of 1.00E+00 dpm/mL.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization Results for the October 2024 Tank Farm 3H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents characterization results for the October 2024 3H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 (137Cs), strontium-90 (90Sr), and iodine-129 (129I) with the radionuclide concentration limits specified by the WAC. These analyses were performed in duplicate, and a summary of the analytical results for this 3H evaporator overhead sample includes the following: The measured cesium-137 activity in the 3H evaporator overhead sample averaged 6.72E+01 dpm/mL, (3.90E+00 %RSD), which is below the ETP WAC limit of 1.30E+03 dpm/mL. The strontium-90 activity in the 3H evaporator overhead sample averaged <2.72E+00 dpm/mL, which is below the ETP WAC limit of 1.76E+02 dpm/mL. The iodine-129 activity in the 3H evaporator overhead sample averaged <1.63E-01 dpm/mL, which is below the ETP WAC limit of 1.00E+00 dpm/mL.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The HRA/Solarium Project: Feedback Based on 20 Years of Experience in Treatment of Medium Level Waste - 20185

Since the 1980's the management of the historical site of Mol has been transferred to the National Agency for Radioactive Waste and Enriched Fissile Materials (ONDRAF/NIRAS). Belgoprocess is entrusted by ONDRAF/NIRAS with the operational waste management and site remediation. One of the major challenges has been the characterization, treatment and conditioning of approximately 200 m{sup 3} of medium level waste. These waste packages were stored in poor conditions in storage vaults ('HRA') or concrete containers ('Solarium'). They have been produced in various research programs and reactor operations at the Belgian nuclear energy research centre SCK.CEN, isotope production, decontamination and dismantling operations from the 1960's up to the 1980's. Despite the limited volume, this historical waste consists of a great variation of waste characteristics and waste configurations. To tackle these liabilities, a new processing facility was built in the 1990's to allow safe transfers, handling, characterization and treatment of these packages. Also some auxiliary facilities have been built to deal with the by-products, like emptied concrete containers. The engineering of the installation, safety procedures and (characterization) methodology that has been developed generically have been proved to be successful. Nevertheless, the specific nature of some items made it necessary to organize a step-by-step treatment in distinct campaigns in which some relevant extra (safety) measures had to be taken into account. This dynamic approach made it possible to process a great variety of waste types in order to to ensure that this legacy is no longer left for subsequent generations. After about 20 years of operations, there has been a great build-up of experience and feed-back concerning the waste management of these specific waste streams. Some cases will be highlighted to specify the approach followed for treatment of e.g.: - Na/NaK containing equipment; - spent radioactive sources; - fuel element residues; - medium level waste originating from activation experiments; - radium bearing medium level waste originating from Ac-227 production research. (authors)

07 ISOTOPE AND RADIATION SOURCES↗

Analysis of Defense Waste Processing Facility Sample: Slurry Mix Evaporator Condensate Tank Sample Batch 4638

The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR, now Savannah River Mission Completion (SRMC)), through a Technical Task Request, to characterization the “as-received” Slurry Mix Evaporator Condensate Tank (SMECT) sample identified as sample batch 4638, which was delivered to SRNL Shielded Cells on March 19, 2021. The SMECT characterization data will be used as input to the Defense Waste Processing Facility (DWPF) Recycle Diversion Project. This SMECT report is the second of three sample characterization reports that will be used for this DWPF Project. The other two DWPF characterization reports involve the characterization of the Recycle Collection Tank (RCT) sample and the future Off-Gas Condensate Tank (OGCT) characterization report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Synthesis and characterization of super occluded LiCl-KCl in zeolite-4A as a chloride salt waste form intermediate

Here, this paper reports the hygroscopic properties of eutectic LiCl-KCl after absorption into zeolite-4A, up to salt loadings of 75 wt%. Samples of the salt occluded zeolite were hydrated in a humidity chamber at constant temperature and relative humidity for up to 100 h. At up to 45 wt% salt loading, the un-occluded phase of salt consisted primarily of NaCl, which forms when the Na + ions present in the zeolite framework exchange with Li + and K + ions from the eutectic LiCl-KCl. This results in minimal water absorption and corrosion of contacted stainless steel. At greater than 45 wt% salt loading, water absorption and corrosion progressively worsened. The mixture has a significant amount of excess LiCl-KCl, making it highly hygroscopic. This study reveals an option for the intermediate treatment of waste salt from spent nuclear fuel electrorefiners that could facilitate it to be stored in a non-inert atmosphere for extended periods of time before final conversion into a permanent waste form.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Williston Basin Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Program

The U.S. Department of Energy’s Office of Fossil Energy awarded 13 CORE-CM programs as part of the CORE-CM Initiative, designed to develop the technology and upstream and midstream supply chains to extract rare-earth elements (REEs) and critical minerals (CMs) from the nation’s coal supplies. The intent is to catalyze regional economic growth and job creation while strengthening the use of domestic resources. The Williston Basin CORE-CM Program aims to drive the expansion and transformation of coal and coal-based resource usage within the Williston Basin to produce REEs, CMs, and nonfuel carbon-based products (CBPs). The work constitutes Phase 1 of a long-term program. The objectives of Phase 1 are to identify the existing knowledge base and gaps and to develop a series of assessments/plans, including an initial basinal assessment; a characterization and data acquisition plan; a waste stream reuse plan; a basinal strategies assessment for infrastructure, industries, and business; a technology assessment, development, and field testing plan; a technology innovation center plan(s); and a stakeholder outreach and education plan. The goal of this project is to initiate the development of a new industry in the resource-rich Williston Basin that will catalyze economic growth and job creation through a coalition team of private industry, university, and state, local, and federal government entities. A coalition team of nearly 30 private industry, university, and state, local, and federal government partners was formed for this program. Partners include the University of North Dakota Energy & Environmental Research Center, Institute for Energy Studies, and Nistler College; North Dakota State University; Montana Tech University; Pacific Northwest National Laboratory; Critical Materials Institute; North Dakota Geological Survey; South Dakota Geological Survey; U.S. Geological Survey; North American Coal Corporation; BNI Energy; Basin Electric Power Cooperative; Minnkota Power Cooperative; and many more.

Kay, John P.↗

Characterization of Precipitate Reactor Feed Tank (PRFT) Batches 15, 22, and 26 from the Defense Waste Processing Facility (DWPF)

The Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) processes a Monosodium Titanate/Sludge Solids (MST/SS) waste stream received from the Salt Waste Processing Facility (SWPF) via the Precipitate Reactor Feed Tank (PRFT). During processing, DWPF is required to provide evidence of compliance with the Waste Acceptance Product Specifications (WAPS) to ensure acceptance of their vitrified high-level waste (HLW) into the Civilian Radioactive Waste Management System. Production Records must document the constituents of the MST/SS material in the PRFT from each salt batch (StB) processed at SWPF. Savannah River Mission Completion (SRMC) has requested Savannah River National Laboratory (SRNL) to analyze PRFT samples representing each SWPF salt batch for thirty-two radionuclides. Additionally, elemental analysis of PRFT slurry and MST/SS solids was performed to aid SRMC in further refinement of the inputs and assumptions used in future frit development and Material Tracking Program calculations. The analyses of PRFT Batches 15, 22, and 26, which corresponds to material from the processing of StB4, StB5, and StB7, respectively, are reported herein. The unwashed dried solids of the PRFT batches were found to be 86-87% MST. Additionally, the total sulfur values are well below the assumed 982 mg of sulfate/kg of PRFT slurry used in Material Tracking Program calculations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Could Road Constructions Be More Hazardous Than an Earthquake in Terms of Mass Movement?

Roads can have a significant impact on the frequency of mass wasting events in mountainous areas. However, characterizing the extent and pervasiveness of mass movements over time has rarely been documented due to limitations in available data sources to consistently map such events. We monitored the evolution of a road network and assessed its effect on mass movements for a 11-year window in Arhavi, Turkey. The main road construction projects run in the area are associated with a hydroelectric power plant as well as other road extension works and are clearly associated with the vast majority (90.1%) of mass movements in the area. We also notice that the overall number and size of the mass movements are much larger than in the naturally-occurring comparison area. This means that the sediment load originating from the anthropogenically induced mass movements is larger than its counterpart associated with naturally occurred landslides. Notably, this extra sediment load could cause river channel aggregation, reduce accommodation space and as a consequence, it could lead to an increase in the probability and severity of flooding along the river channel. This marks a strong and negative effect of human activities on the natural course of earth surface processes. We also compare frequency-area distributions of human-induced mass movements mapped in this study and co-seismic landslide inventories from the literature. By doing so, we aim to better understand the consequences of human effects on mass movements in a comparative manner. Our findings show that the damage generated by the road construction in terms of sediment loads to river channels is compatible with the possible effect of a theoretical earthquake with a magnitude greater than Mw=6.0.

Hakan Tanyas↗

BETO 2021 Peer Review - Waste Carbon Gas Upgrading via Acetogens 2.3.2.106

Waste carbon gas represents a large and diverse set of feedstocks that could be captured and turned into useful products. This includes waste gas emitted from industrial activity, syngas from burned plant biomass or processed municipal waste, and electrochemical reduction of CO2. Currently, carbon gas is being microbially converted to ethanol as a main product. However, ethanol is a lower value product with a limited market size. While these microbes can make other higher value products, there are no commercial processes for generating these other products, leaving a gap in understanding potential implementation for commercialization. Expanding the products microbially produced from waste carbon gas requires several steps before commercial implementation. We are studying the acetogen Clostridium ljungdahlii as a biocatalyst to convert waste carbon gas to the chemical 3-hydroxybutyrate (3HB), a plastic monomer and fuel precursor. For that, we are studying and engineering microbial characteristics for novel 3HB product formation from waste gas streams. This includes metabolic characterization, genetic engineering, gas fermentation scaling, as well as technoeconomic and life cycle analysis.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Organic Waste Resource Assessment for the Detroit Region

This study summarizes major sources of organic wastes in the Detroit region to (1) characterize target feedstock magnitudes and distribution in support of techno-economic analysis (TEA), and (2) guide the design of blended feedstock conversion experiments using hydrothermal liquefaction (HTL). Feedstocks considered in this review include municipal wastewater sludge solids (untreated) and scum; bulk municipal solid waste (MSW); the organic fraction of municipal solid waste (OF-MSW); residential food waste, non-residential food waste including institutional, industrial, and commercial (IIC) sources; confined animal manures (i.e., lactating dairy, feedlot beef, and market swine); waste fats, oils and greases (FOG); agricultural residues; forest residues. The scope of the investigation was limited to existing modeled or publicly available reporting datasets. Bulk MSW data were only collected for context and to generate estimates of OF-MSW by waste type and should not be included in total organic waste estimates. Because the TEA analysis boundary was not defined prior to conducting the resource assessment, the data are summarized within six spatial contexts (boundaries), including (1) city of Detroit (census); (2) Great Lakes Water Authority (GLWA) service area; “Tri-county” urban area (census); “Metro” Detroit-Warren-Dearborn Metropolitan Statistical Area (MSA) (census); Detroit-Warren-Ann Arbor Combined Statistical Area (CSA) (census); and the Michigan Councils of Government (COG) Region-1. All of the spatial contexts are entirely within the State of Michigan, and some overlap one another. A broader context could be developed to include data from surrounding states or Canada.

09 BIOMASS FUELS↗

LAW Glass Formulation to Support Melter Runs with Simulants

The major objective of this work was to prepare and characterize glass formulations in order to develop and select formulations that are compliant with contractual and processing requirements to support melter tests with each of the LAW Sub-Envelopes. Glasses that cover composition ranges of interest were prepared and characterized to ensure that selected glass compositions can tolerate expected composition variations resulting from process errors without adversely affecting processing characteristics or product quality. Glass compositions that are expected to result during transitions from one waste stream to another were also prepared and characterized. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, and identification of glass formulation issues with respect to contract specifications and processing requirements.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analysis of Defense Waste Processing Facility Sample: Recycle Collection Tank Sample Batch 4945

The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (now Savannah River Mission Completion (SRMC)), through a Technical Task Request, to characterization the “as-received” Recycle Collection Tank (RCT) Sample identified as sample batch 4945 [Sludge Receipt and Adjustment Tank (SRAT) batch 796)], which was delivered to SRNL Shielded Cells on January 28, 2021. The RCT characterization data will be used as input to the Defense Waste Processing Facility (DWPF) Recycle Diversion Project. This RCT report is the first of three sample characterization reports that will be used for this DWPF Project. The other DWPF reports will involve the characterization of the Off-Gas Condensate Tank (OGCT) and the Slurry Mix Evaporator Condensate Tank (SMECT) samples.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analysis of Defense Waste Processing Facility Sample: Recycle Collection Tank Sample Batch 4945

The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (now Savannah River Mission Completion (SRMC)), through a Technical Task Request, to characterization the “as-received” Recycle Collection Tank (RCT) Sample identified as sample batch 4945 [Sludge Receipt and Adjustment Tank (SRAT) batch 796)], which was delivered to SRNL Shielded Cells on January 28, 2021. The RCT characterization data will be used as input to the Defense Waste Processing Facility (DWPF) Recycle Diversion Project. This RCT report is the first of three sample characterization reports that will be used for this DWPF Project. The other DWPF reports will involve the characterization of the Off-Gas Condensate Tank (OGCT) and the Slurry Mix Evaporator Condensate Tank (SMECT) samples.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

AI-powered municipal solid waste management: a comprehensive review from generation to utilization

The accumulation of municipal solid waste (MSW) continues to rise due to burgeoning population, rapid global urbanization and economic growth, intensifying ecological concerns associated with landfills and greenhouse gas (GHG) emissions. Over the past 2 decades, global waste generation has surged by 50%, with one-third remaining uncollected and about 70% sent to landfills. This review examines the critical role of integrating emerging technologies, such as advanced sensors and artificial intelligence (AI), into end-to-end MSW management to alleviate landfill burdens. The suitability of various AI tools for different stages of MSW management is assessed, alongside the deployment of advanced sensors including hyperspectral cameras, computer vision systems, and internet of things (IoT) devices for material identification. Applications of genetic algorithms and reinforcement learning for optimizing collection routes, reducing costs, and lowering emissions are highlighted. Life cycle assessment (LCA) across all stages of MSW management is also reviewed, along with future trends in leveraging generative AI, natural language processing (NLP), and agent-based AI systems to analyze waste generation patterns and public sentiment. Efficient collection and handling can be enhanced through route optimization with geographic information systems and real-time bin-level monitoring. Furthermore, sensor-embedded, real-time object detection systems paired with robotics enable material characterization and automated sorting, thereby lowering costs and diverting waste from landfills into value-added products for diverse industrial sectors including packaging, chemicals, textiles, metals and glass, transportation, and electronics industries. Without intervention, global waste is projected to reach 4.54 billion tons by 2050, contributing direct economic costs of $\$$400 billion and roughly 2.38 billion tons of CO 2 -equivalent emissions annually. This review demonstrates how AI-driven, end-to-end solutions for MSW management can mitigate economic and environmental challenges, while directly supporting the United Nations Sustainable Development (UNDP) goals related to innovation and infrastructure (SDG 9), sustainable cities (SDG 11), responsible consumption and production (SDG 12), and climate action (SDG 13).

09 BIOMASS FUELS↗