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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

High Energy, Narrow Linewidth 1572nm Eryb-Fiber Based MOPA for a Multi-Aperture CO2 Trace-Gas Laser Space Transmitter

Accurate global measurements of tropospheric CO2 mixing ratios are needed to study CO2 emissions and CO2 exchange with the land and oceans. NASA Goddard Space Flight Center (GSFC) is developing a pulsed lidar approach for an integrated path differential absorption (IPDA) lidar to allow global measurements of atmospheric CO2 column densities from space. Our group has developed, and successfully flown, an airborne pulsed lidar instrument that uses two tunable pulsed laser transmitters allowing simultaneous measurement of a single CO2 absorption line in the 1570 nm band, absorption of an O2 line pair in the oxygen A-band (765 nm), range, and atmospheric backscatter profiles in the same path. Both lasers are pulsed at 10 kHz, and the two absorption line regions are sampled at typically a 300 Hz rate. A space-based version of this lidar must have a much larger lidar power-area product due to the x40 longer range and faster along track velocity compared to airborne instrument. Initial link budget analysis indicated that for a 400 km orbit, a 1.5 m diameter telescope and a 10 second integration time, a 2 mJ laser energy is required to attain the precision needed for each measurement. To meet this energy requirement, we have pursued parallel power scaling efforts to enable space-based lidar measurement of CO2 concentrations. These included a multiple aperture approach consists of multi-element large mode area fiber amplifiers and a single-aperture approach consists of a multi-pass Er:Yb:Phosphate glass based planar waveguide amplifier (PWA). In this paper we will present our laser amplifier design approaches and preliminary results.

micropulse lidar↗
NASA NTRS1980

Longitudinal variability of methane and ammonia bands on Jupiter

Results of a quantitative study of the longitudinal variations of methane and ammonia absorption on Jupiter are presented. A total of 78 high signal-to-noise ratio photoelectric spectra in the range 6000 to 6600 A were obtained on two consecutive nights, with complete longitudinal equatorial coverage each night through 9-min exposures covering a total of over 9 h. Analysis of the equivalent widths of the CH4 6190 A and NH3 6450 A absorption bands by means of a blind, automated, self-consistent method of continuum determination reveals large equivalent widths in both bands near longitudes of 35 and 340 deg and small equivalent widths near 150 deg, with a high degree of correlation between the equivalent widths of the bands. Continuum molecular absorption is found to be slightly negatively correlated with band equivalent widths. Radiative transfer calculations based on the model of Sato and Hansen (1979) using a doubling and adding technique indicate that the observed longitudinal variables of equivalent widths and continuum reflectivity are the results of longitudinal variations in ammonia cloud altitude.

Cochran, W. D.↗
NASA NTRS1991

Cloud area determination from AVIRIS data using water vapor channels near 1 micron

Fractional cloud area is derived from spectral images collected by the Airborne Visible-IR Imaging Spectrometer (AVIRIS). The derivation is made by ratioing radiances near the 0.94- and the 1.14-microns water vapor band centers against those in the intermediate atmospheric window regions. The derivation makes use of the facts that (1) the reflectances of most ground targets vary approximately linearly with wavelength in the 0.94- and the 1.14-micron water vapor band absorption regions, and (2) the peak absorptions of the water vapor band over cloudy areas are smaller than those over nearby clear surface areas because of the rapidly decreasing atmospheric water vapor concentration with height. The band ratioing technique effectively discriminates among clouds and surface areas having similar reflectance values.

Gao, Bo-Gai↗
NASA NTRS1999

Detection of Water Ice on Saturn's Satellite Phoebe

The near-infrared reflectance spectrum of Saturn's satellite Phoebe shows a broad absorption band at 2.0 micrometers and absorption at lambda > 2.2 micrometers, both characteristic of H2O ice. We have successfully modeled the surface of Phoebe with an intimate (granular) mix of H2O ice (3% by weight, grain size 500 micrometers) mixed with fine grains of H2O ice (0.25%) with amorphous carbon (grain size 900 micrometers) as the dominant component. This model reproduces the shape of the measured spectrum and the observed albedo of 0.10 for Phoebe, but it is not unique. The presence of ice establishes Phoebe as an original member of the outer Solar System rather than a renegade asteroid.

Owen, T. C.↗
NASA NTRS2024

Molecules in Cool Stars: The A 2 Π − X 2 Σ + and the B 2 Σ + − X 2 Σ + Band Systems of CaCl

Cool red giant stars exhibit absorption bands of calcium monochloride (CaCl) in the optical region. In this work, the bands of CaCl corresponding to the A 2 Π − X 2 Σ + transition with v' ≤ 4 and v'' ≤ 4, and B 2 Σ + − X 2 Σ + transition with v' ≤ 2 and v'' ≤ 2 are rotationally analyzed with PGOPHER, a multipurpose program for simulating and fitting molecular spectra. All bands were analyzed using high-resolution absorption spectra collected at the National Solar Observatory in 1985, calibrated with atomic lines from a high-resolution emission spectrum obtained in a separate hollow cathode experiment. The results are compared with previous laser-induced fluorescence measurements. Overall, the accuracy of spectroscopic constants for the A2Π and B2Σ+ states is improved. Scaled transition dipole moment calculations were used to obtain line strengths. Line lists are provided with Einstein A coefficients and oscillator strengths, which can be used to determine CaCl stellar abundances. Additionally, isotope splittings allowed us to estimate band origins for the 40 Ca 37 Cl isotopologue based on band-head positions.

Léo Lavy↗
NASA NTRS1974

Stellar content of the nuclei of elliptical galaxies determined from 2.3 micron CO band strengths

Observations of the luminosity sensitive CO absorption band at 2.3 micron are presented for the nuclei of 16 epsilon and SO galaxies. Preliminary data on the radial variation of the CO index in 6 galaxies are also given. The data show that the 2-u radiation from the nuclei is dominated by high luminosity stars of integrated spectral type later than K5. There is only a small variation in the CO absorption from galaxy to galaxy, and only a slight variation with measuring aperture size from 17.5 in. to 59 in. The data can be used to synthesize stellar populations for elliptical galaxy nuclei.

Frogel, J. A.↗
NASA NTRS2014

The Surface Compositions of Pluto and Charon

The surface of Pluto as it is understood on the eve of the encounter of the New Horizons spacecraft (mid-2015) consists of a spatially heterogeneous mix of solid N2, CH4, CO, C2H6, and an additional component that imparts color, and may not be an ice. The known molecular ices are detected by near-infrared spectroscopy. The N2 ice occurs in the hexagonal crystalline b-phase, stable at T greater than 35.6 K. Spectroscopic evidence for wavelength shifts in the CH4 bands attests to the complex mixing of CH4 and N2 in the solid state, in accordance with the phase diagram for N2 + CH4. Spectra obtained at several aspects of Plutos surface as the planet rotates over its 6.4-day period show variability in the distribution of CH4 and N2 ices, with stronger CH4 absorption bands associated with regions of higher albedo, in correlation with the visible rotational light curve. CO and N2 ice absorptions are also strongly modulated by the rotation period; the bands are strongest on the anti-Charon hemisphere of Pluto. Longer term changes in the strengths of Plutos absorption bands occur as the viewing geometry changes on seasonal time-scales, although a complete cycle has not been observed. The non-ice component of Plutos surface may be a relatively refractory material produced by the UV and cosmic-ray irradiation of the surface ices and gases in the atmosphere, although UV does not generally penetrate the atmospheric CH4 to interact with the surface. Laboratory simulations indicate that a rich chemistry ensues by the irradiation of mixtures of the ices known to occur on Pluto, but specific compounds have not yet been identified in spectra of the planet. Charons surface is characterized by spectral bands of crystalline H2O ice, and a band attributed to one or more hydrates of NH3. Amorphous H2O ice may also be present; the balance between the amorphization and crystallization processes on Charon remains to be clarified. The albedo of Charon and its generally spatially uniform neutral color indicate that a component, not yet identified, is mixed in some way with the H2O and NH3nH2O ices. Among the many known small bodies in the transneptunian region, several share characteristics with Pluto and Charon, including the presence of CH4, N2, C2H6, H2O ices, as well as components that yield a wide variety of surface albedo and color. The New Horizons investigation of the Pluto-Charon system will generate new insight into the physical properties of the broader transneptunian population, and eventually to the corresponding bodies expected in the numerous planetary systems currently being discovered elsewhere in the Galaxy.

surface composition↗
NASA NTRS1984

Satellite observation of SO2 from El Chichon - Identification and measurement

Absorption bands between 300 nm and 315 nm were observed in spectral scans of the atmospheric albedo made by the solar backscattered ultraviolet instrument (SBUV) on Nimbus 7 following the eruption of El Chichon. It is shown that these bands coincide with peaks in the absorption coefficient spectrum of SO2 and use the magnitude of the absorption to estimate the column content of SO2 present. A maximum concentration of 15 matm-cm of SO2 was observed west of Hawaii on April 15; the minimum detectable amount of SO2 in a single scan is about 1 matm-cm. The disappearance of the band structure at wavelengths below 300 nm indicates that the SO2 was between 20 km and 30 km altitude. An excess albedo was also observed near 300 nm which was attributed to increased scattering from volcanic aerosols; the wavelength of the scattering feature indicates that the aerosols also were near 25 km altitude.

Mcpeters, R. D.↗
NASA NTRS1987

Analysis of SO2 signals in SBUV/TOMS data

Absorption bands between 300 nm and 315 nm were observed in spectral scans of the atmospheric albedo made by the Solar Backscatter Ultraviolet (SBUV) spectrometer following the eruption of El Chichon. It is shown that those bands coincide with peaks in the absorption coefficient spectrum of SO sub 2. The magnitude of the absorption is used to the column content of present SO sub 2. These observations confirm that the differential absorption between 312.5 nm and 317.5 nm in Total Ozone Mapping Spectrometer (TOMS) data can be used to measure SO sub 2 with high spatial resolution. A maximum concentration of SO sub 2 of 15 matm-cm was observed by SBUV on April 15, 1982. The measurement based on direct measurement of band intensity can be used to calibrate the TOMS algorithm for deriving SO sub 2 amounts.

Mcpeters, Richard↗
NASA NTRS1986

Quantitative VUV spectroscopy of Cl2

The photoabsorption and fluorescence cross sections of Cl2 were measured in the 105-145 nm region using synchrotron radiation as a light source. The oscillator strengths for the major absorption bands were calculated from the measured absorption cross sections. The measured oscillator strengths for the 2 3Pi u and 2 1Pi u - X 1Sigma(+)g transitions agree quite well with the theoretical values. The absorption spectrum was analyzed in accord with the excited electronic states calculated by Peyerimhoff and Buenker (1981). The Rydberg series converging to the first and second ionization potentials were classified. The vibrational levels of the 2 1Sigma(+)u ionic state were determined up to v prime = 15 from the fluorescence excitation spectrum. It was observed that a band with peak at 108.3 nm produces VUV fluorescence, but it produces UV fluorescence only by a collisional excitation process.

Lee, L. C.↗
NASA NTRS2012

Relationship Between Iron Valence States of Serpentine in CM Chondrites and Their Aqueous Alteration Degrees

The 0.6-0.7 micron absorption band observed for C-type asteroids is caused by the presence of Fe(3+) in phyllosilicates . Because Fe-bearing phyllosilicates, especially serpentine, are the most dominant product of aqueous alteration in the most abundant carbonaceous chondrites, CM chondrites, it is important to understand the crystal chemistry of serpentine in CM chondrites to better understand spectral features of C-type asteroids. CM chondrites show variable degrees of aqueous alteration, which should be related to iron valences in serpentine. It is predicted that the Fe(3+)/Sum of (Fe) ratios of serpentine in CM chondrites decrease as alteration proceeds by Si and Fe(3+) substitutions from end-member cronstedtite to serpentine, which should be apparent in the absorption intensity of the 0.6-0.7 micron band from C-type asteroids. In fact, the JAXA Hayabusa 2 target (C-type asteroid: 1993 JU3) exhibits heterogeneous spectral features (0.7 micron absorption band disappears by rotation). From these points of view, we have analyzed iron valences of matrix serpentine in several CM chondrites which span the entire observed range of aqueous alteration using Synchrotron Radiation X-ray Absorption Near-Edge Structure (SR-XANES). In this abstract we discuss the relationship between obtained Fe(3+)/Sum of (Fe) ratios and alteration degrees by adding new data to our previous studies

Mikouchi, T.↗