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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Research on Spectroscopy, Opacity, and Atmospheres

For planetary and telluric atmosphere projects the solar irradiance spectrum is required as the input at the top of the atmosphere. It has never been observed. People ask me to compute it. I can compute it theoretically using both known and predicted lines and get agreement averaged over a nanometer but there is no way to predict the resolved spectrum when only half the lines are known. In other stars the situation is worse because the signal-to-noise and resolution of the observations are worse. Logically one has to know a priori what is in the spectrum in order to interpret it; there is not enough information in the observed spectrum itself (qualifiers are given). Basically we need a list of all the energy levels of all atoms and molecules that matter. From that list can be generated all the lines. With the energy levels and line positions known, one can measure gf values, lifetimes, damping, or one can determine a theoretical or semiempirical Hamiltonian whose eigenvalues and eigenvectors produce a good match to the observed data, and that can then be used to generate additional radiative and collisional data for atoms or molecules.

Kurucz, Robert L.↗

Experimental and Semiclassical Stark Widths and Shifts for Spectral Lines of Neutral and Ionized Atoms (A Critical Review of Experimental and Semiclassical Data for the Period 2008 through 2020)

This Review Article compares new experimental and corresponding semiclassical Stark broadened data for non-hydrogenic spectral lines of neutral atoms and positive ions. This Review covers the period 2008 until the end of 2020 and presents the continuation of previous critical reviews from 1976 (two), 1984 (two), 1990, 2002, and one from 2009. This Review reports the Stark broadening parameters of 1665 spectral lines belonging to 35 elements with 61 different atomic and ion species. The data are taken from 60 papers. Experimental data are arranged by elements and spectra, and these are reported in tables in alphabetical and numerical order, respectively. Each experimental Stark broadening parameter is followed with estimated accuracy. The experimental Stark broadening and shift data presented in the tables are compared with the corresponding semiclassical results available in the literature. In addition, for comparison experiments versus semiclassical theoretical Stark broadening parameters, a numerically improved theoretical approach developed based on Griem and co-workers’ theory is used to evaluate Stark widths and shifts of all studied lines whenever required atomic energy levels data and transition probabilities are available. At the end of the text report, for each analyzed neutral or ion species, the information about the location of the same species data in preceding reviews is given.

Plasma line broadening↗

Stellar spectral synthesis in the ultraviolet

A computer program for spectral synthesis has been developed, based on a list of data for atomic lines described by Kurucz, Peytremann, and Avrett (1973). To demonstrate the usefulness of this program, we present a sample calculation of the region around the C IV resonance doublet at 155 nm, which is a feature in rocket and satellite spectra of B stars. The calculation indicates that the observed feature is a blend of many lines in addition to C IV, so that detailed calculations are necessary for the correct interpretation of the observational data.

Kurucz, R. L.↗

Cloud Impacts on Photochemistry: Building a Climatology of Photolysis Rates from the Atmospheric Tomography Mission

Measurements from actinic flux spectroradiometers on board the NASA DC-8 during the Atmospheric Tomography (ATom) mission provide an extensive set of statistics on how clouds alter photolysis rates (J values) throughout the remote Pacific and Atlantic Ocean basins. J values control tropospheric ozone and methane abundances, and thus clouds have been included for more than three decades in tropospheric chemistry modeling. ATom made four profiling circumnavigations of the troposphere capturing each of the seasons during 2016–2018. This work examines J values from the Pacific Ocean flights of the first deployment, but publishes the complete Atom-1 data set (29 July to 23 August 2016). We compare the observed J values (every 3 s along flight track) with those calculated by nine global chemistry– climate/transport models (globally gridded, hourly, for a mid-August day). To compare these disparate data sets, we build a commensurate statistical picture of the impact of clouds on J values using the ratio of J -cloudy (standard, sometimes cloudy conditions) to J -clear (artificially cleared of clouds). The range of modeled cloud effects is inconsistently large but they fall into two distinct classes: (1) models with large cloud effects showing mostly enhanced J values aloft and or diminished at the surface and (2) models with small effects having nearly clear-sky J values much of the time. The ATom-1 measurements generally favor large cloud effects but are not precise or robust enough to point out the best cloud-modeling approach. The models here have resolutions of 50–200 km and thus reduce the occurrence of clear sky when averaging over grid cells. In situ measurements also average scattered sunlight over a mixed cloud field, but only out to scales of tens of kilometers. A primary uncertainty remains in the role of clouds in chemistry, in particular, how models average over cloud fields, and how such averages can simulate measurements.

actinic flux spectroradiometers↗

An Overview of NASA's Risk of Cardiovascular Disease from Radiation Exposure

The association between high doses of radiation exposure and cardiovascular damage is well established. Patients that have undergone radiotherapy for primary cancers of the head and neck and mediastinal regions have shown increased risk of heart and vascular damage and long-term development of radiation-induced heart disease [1]. In addition, recent meta-analyses of epidemiological data from atomic bomb survivors and nuclear industry workers has also shown that acute and chronic radiation exposures is strongly correlated with an increased risk of circulatory disease at doses above 0.5 Sv [2]. However, these analyses are confounded for lower doses by lifestyle factors, such as drinking, smoking, and obesity. The types of radiation found in the space environment are significantly more damaging than those found on Earth and include galactic cosmic radiation (GCR), solar particle events (SPEs), and trapped protons and electrons. In addition to the low-LET data, only a few studies have examined the effects of heavy ion radiation on atherosclerosis, and at lower, space-relevant doses, the association between exposure and cardiovascular pathology is more varied and unclear. Understanding the qualitative differences in biological responses produced by GCR compared to Earth-based radiation is a major focus of space radiation research and is imperative for accurate risk assessment for long duration space missions. Other knowledge gaps for the risk of radiation-induced cardiovascular disease include the existence of a dose threshold, low dose rate effects, and potential synergies with other spaceflight stressors. The Space Radiation Program Element within NASA's Human Research Program (HRP) is managing the research and risk mitigation strategies for these knowledge gaps. In this presentation, we will review the evidence and present an overview of the HRP Risk of Cardiovascular Disease and Other Degenerative Tissue Effects from Radiation Exposure.

Patel, Zarana S.↗

Measurement of absolute cross sections for excitation of the 2s(2) S-1 -> 2s2p P-1 degrees transition in O+4

Experimental cross sections are reported for the 1s(2)2s(2) S-1 -> 1s(2)2s2p P-1(o) transition in O+4 located at 19.689 eV. Use is made of the electron energy-loss method, using a merged electron-ion beam geometry. The center-of-mass interaction energies for the measurements in the S-1 -> P-1(o) transition are in the range 18 eV ( below the threshold) to 30 eV. Data are compared with other previous electron energy-loss measurements and with results of a 26 term R-matrix calculation that includes fine structure explicitly via the Breit-Pauli Hamiltonian. Clear resonance enhancement is observed in all experimental and theoretical results near the threshold for this S-1 -> P-1(o) transition.

atomic processes↗

Atomic oxygen effects on boron nitride and silicon nitride: A comparison of ground based and space flight data

The effects of atomic oxygen on boron nitride (BN) and silicon nitride (Si3N4) were evaluated in a low Earth orbit (LEO) flight experiment and in a ground based simulation facility. In both the inflight and ground based experiments, these materials were coated on thin (approx. 250A) silver films, and the electrical resistance of the silver was measured in situ to detect any penetration of atomic oxygen through the BN and Si3N4 materials. In the presence of atomic oxygen, silver oxidizes to form silver oxide, which has a much higher electrical resistance than pure silver. Permeation of atomic oxygen through BN, as indicated by an increase in the electrical resistance of the silver underneath, was observed in both the inflight and ground based experiments. In contrast, no permeation of atomic oxygen through Si3N4 was observed in either the inflight or ground based experiments. The ground based results show good qualitative correlation with the LEO flight results, indicating that ground based facilities such as the one at Los Alamos National Lab can reproduce space flight data from LEO.

Cross, J. B.↗

Ceramic research

X-ray diffraction micrography data on atomic structure of magnesium oxide grain boundaries

X-RAY ANALYSIS↗

The interstellar line spectra of zeta Ophiuchi and zeta Persei and their relation to the short wavelength microwave background radiation

Thirty-one high dispersion Coude spectrograms of zeta Ophiuchi and seven of zeta Persei were numerically synthesized to produce high resolution, low noise spectra in the interval 3650 A to 4350 that yield data on atomic and molecular absorption in well-defined regions of the interstellar medium. The detection threshold is improved by as much as a factor 5 over single plates. Several interstellar lines were discovered in the zeta Oph - 15km/sec cloud and the zeta Per + 13 km/sec cloud.

Bortolot, V. J., Jr.↗

Charge exchange in the Venus ionosphere as the source of the hot exospheric hydrogen

A global Monte Carlo model of the exosphere of Venus, simulating the normal exospheric processes, as well as the production of a 'hot' hydrogen component by charge exchange of H(+) with H and O, has been computed. The resulting altitude profiles of atomic hydrogen concentration over both the day and night hemispheres are in reasonable agreement with Mariner 5 and Mariner 10 observations of Lyman-alpha, showing that the ionospheric charge exchange reactions are a significant source of 'hot' hydrogen, possibly the dominant source. However, the uncertainties in the available atomic hydrogen data allow for production of a similar amount of nonthermal H by chemical processes involving H2 as suggested by Kumar and Hunten (1974).

Hodges, R. R., Jr.↗

Diagnostics of solar and astrophysical plasmas - Dependent on autoionization phenomena

The application of autoionization calculations to problems in solar and astrophysical plasma diagnostics is discussed. Attention is given to space plasmas having high spectral resolution, particularly in the wavelength region between about 300 and 1100 A. It is shown that atomic resonance data can be used to calculate many of the spectral line intensities in solar plasmas in order to obtain information concerning the physical properties of the emitting gas, including temperature, density, ionization balance, and atmospheric structure and dynamics. Recent spectral observations of nonsolar plasmas are also discussed. A list of the major high-resolution astrophysical plasma spectrometers and spectrographs is provided.

Doschek, G. A.↗

CNO abundances in novae ejecta

Isotope production, particularly CNO, which are enhanced in novae events and the interstellar medium (ISM) by novae are discussed in terms of emission-line data taken a few weeks after novae events. The emission-line abundances emerge only after the fading of absorption spectrum, and are also detectable in thin shells which sometimes, though rarely, form after novae. CNO abundances in these shells are equivalent to those observed in fading novae, with CNO/H ratios being 100 times solar values. Possible heavy element production pathways in the events and their shrinking are discussed, along with observation techniques for detecting CNO isotopes through absorption data on atomic transitions in novae ejecta and the ISM.

Williams, R. E.↗

Constraints on gravity wave induced diffusion in the middle atmosphere

A review of the important constraints on gravity wave induced diffusion of chemical tracers, heat and momentum is given. Ground-based microwave spectroscopy measurements of H2O and CO and rocket-based mass spectrometer measurements of Ar constrain the eddy diffusion coefficient for constituent transport (K sub zz) to be (1-3) x 10 to the 5th sq cm/sec in the upper mesosphere. Atomic oxygen data also limits K sub zz to a comparable value in the mesopause. From the energy balance of the upper mesosphere the eddy diffusion coefficient for heat transport (D sub H) is, at most, 6 x 10 to the 5th sq cm/sec at the mesopause and decreasing substantially with decreasing altitude. The available evidence for mean wind deceleration and the corresponding eddy diffusion coefficient for momentum stresses (D sub M) suggests that it is at least 1 x 10 to the 6th sq cm/sec in the upper mesosphere. Consequently the eddy Prandtl number for macroscopic scale lengths is greater than 3.

Strobel, Darrell F.↗

Spray drop size and velocity measurements using the Phase/Doppler Particle Analyzer

Detailed measurements of the drop size and velocity distributions were obtained for a swirl chamber pressure atomizer. These data were obtained with the Phase/Doppler Particle Analyzer manufactured by Aerometrics, Inc. Direct measurements of the size distributions revealed the evolving characteristics of the spray. Size velocity correlations were used to evaluate the effect of velocity relaxation on the size distributions. The simultaneous measurement of drop size and velocity was of major importance in accurately describing the changes in the local drop size distributions and mass flux.

Bachalo, W. D.↗

Constraints on gravity wave induced diffusion in the middle atmosphere

A review of the important constraints on gravity wave induced diffusion of chemical tracers, heat and momentum is given. Ground-based microwave spectroscopy measurements of H20 and CO and rocket-based mass spectrometer measurements of Ar constrain the eddy diffusion coefficient for constituent transport (K sub zz) to be (1-3) x 10 to the 5th sq cm/sec in the upper mesosphere. Atomic oxygen data also limits K sub zz to a comparable value in the mesopause. From the energy balance of the upper mesosphere the eddy diffusion coefficient for heat transport (D sub H) is at most, 6 x 10 to the 5th sq cm/sec at the mesopause and decreasing substantially with decreasing altitude. The available evidence for mean wind deceleration and the corresponding eddy diffusion coefficient for momentum stresses (D sub M) suggests that it is at least 1 x 10 to the 6th sq cm/sec in the upper mesosphere. Consequently the eddy Prandtl number for macroscopic scale lengths is greater than 3.

Strobel, Darrell F.↗

Soft X-ray spectrographs for solar observations

Recent advances in soft X-ray spectrometery are reviewed, with emphasis on techniques for studying the windowless region from roughly 1-100 A. Recent technological developments considered include multilayer mirrors, large-format CCD detectors which are sensitive to X-rays, position-sensitive photon counting detectors, new kinds of X-ray films, and optical systems based on gratings with nonuniform ruling spacings. Improvements in the extent and accuracy of the atomic physics data sets on which the analysis of spectroscopic observatons depend are also discussed.

Bruner, M. E.↗

Modeling the ultraviolet photospheric spectrum of cool giant stars. I - Arcturus. II - Gamma Crucis

The UV photospheric spectra of cool giants are modeled analytically to facilitate the identification of UV spectral features and aid in the measurement of actual chromospheric flux at different wavelengths. Atomic line data derived experimentally and semiempirically are used with LTE model atmospheres by means of the SYNTHE FORTRAN code to generate the synthetic spectra. Surface flux spectra are determined and fitted to the absorption features of observed IUE high resolution spectra, and the modeled results are compared to the observed spectra of the cool giants Arcturus and the cooler Gamma Crucis. It is shown that the synthetic spectra can be produced for the stars, and chromospheric emission lines are thought to account for significant discrepancies between observed and calculated values. Two new fluorescence mechanisms are identified by modeling the ultraviolet photospheric spectrum of Gamma Crucis.

Carpenter, Kenneth G.↗