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An isotopic study of biogeochemical relationships between carbonates and organic carbon in the Greenhorn Formation

Carbon-isotopic compositions of total carbonate, inoceramid carbonate, micritic carbonate, secondary cements, total organic carbon, and geoporphyrins have been measured in 76 different beds within a 17-m interval of a core through the Greenhorn Formation, an interbedded limestone and calcareous shale unit of Cretaceous age from the Western Interior Seaway of North America. Results are considered in terms of variations in the processes of primary production and in secondary processes. It is shown that the porphyrin isotopic record reflects primary isotopic variations more closely than the TOC isotopic record and that, in these sediments, TOC is enriched in C-13 relative to its primary precursor by 0.6 to 2.8 percent. This enrichment is attributed to isotope effects within the consumer foodweb and is associated with respiratory heterotrophy. Variation in this secondary enrichment are correlated with variations in the isotopic composition of marine carbonate.

Hayes, J. M.↗

Cycling phosphorus on the Archean Earth: Part II. Phosphorus limitation on primary production in Archean ecosystems

Several lines of evidence point to low rates of net primary production (NPP) in Archean oceans. However, whether Archean NPP was limited by electron donors or nutrients, particularly phosphorus (P), and how these factors might have changed over a billion years of recorded Archean history, remains contentious. One major challenge is to understand quantitatively the biogeochemical cycling of P on the early Earth. In Part I of this series (Hao et al., 2020), we estimated the weathering flux of P to the oceans as a function of temporally increasing continental emergence and elevation through Archean time. In Part II, we conduct thermodynamic and kinetic simulations to understand key processes of P cycling within the Archean ocean, including seafloor weathering, recycling of organic P, the solubility and precipitation of secondary phosphate minerals, and the burial diagenesis of P precipitates. Our calculations suggest low solubilities of apatite minerals in Archean seawater, primarily due to nearly neutral pH and high levels of Ca. This low solubility, in turn, implies a negligible contribution of apatite dissolution to P bioavailability in Archean seawater. We also simulate the solubility limits of common secondary P-bearing minerals, showing that vivianite would have been the least soluble P mineral in ferruginous Archean seawater (0.1–0.3 µM), even at moderate supersaturation states (Ω = 100 or 1000). If vivianite precipitation was kinetically favorable by microbial activities and mineral adsorption, the sinking flux of P as vivianite in Archean seawater could have reached the modern sinking flux, implying that vivianite precipitation was a potentially major sink for P in Archean oceans. During burial diagenesis, however, vivianite in porewater would have become less stable than Ca-phosphates of lower solubility. At elevated temperatures (>100 °C) associated with burial diagenesis and low-grade metamorphism, vivianite is predicted to react irreversibly with calcite to form apatite. Optimistic assumptions about the recycling efficiency of P on the Archean Earth lead us to estimate that by the end of the eon the total flux of P (continental weathering + recycling) could have supported NPP at levels up to 7% of the modern. The total flux of P would have been much lower on the early and middle Archean Earth, whereas fluxes of electron donors could have been higher, suggesting very low productivity and P-limitation of marine ecosystems during much of the eon. Comparing our estimates of NPP as limited by P supply with the estimate by Ward et al. (2019), in which NPP was limited by electron donors and metabolic efficiency, there could have been a transition between P-limited productivity in the early to middle Archean to electron donor-limitation closer to the eon’s end (assuming no oxygenic photosynthesis). Once oxygenic photosynthesis reached ecological significance, probably near the end of the Archean, our estimated flux of P would allow rapid oxidation of atmosphere.

Vivianite↗

The Plankton, Aerosol, Cloud, Ocean Ecosystem (Pace) Mission Overview: From Concept to Launch

Abstract for Technical Review: The Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a strategic climate continuity mission that was defined in the 2010 document Responding to the Challenge of Climate and Environmental Change: NASA’s Plan for Climate-Centric Architecture for Earth Observations and Applications from Space (referred to as the “Climate Initiative”). Launched in February 2024, the PACE mission represents NASA’s next investment in ocean biology, clouds, and aerosol data records. PACE will extend the high quality ocean ecological, ocean biogeochemical, cloud, and aerosol particle data records begun by NASA in the 1990s, building on the exceptional heritages of the Sea-Viewing Wide Field-of-View Sensor (SeaWiFS), the Moderate Resolution Imaging Spectroradiometer (MODIS), the Multi-angle Imaging SpectroRadiometer (MISR), and the Visible Infrared Imaging Radiometer Suite (VIIRS). NASA Headquarters directed the mission development and implementation to the NASA Goddard Space Flight Center (GSFC) with guidance to utilize a Design-to-Cost (DTC) process. Mission studies were conducted to define appropriate approaches within and across elements while maximizing science capabilities at a high cost confidence. Mission baseline requirements development is also embedded within the DTC process, as these requirements were not established at the onset of the mission concept development. The PACE project office at NASA’s GSFC was responsible for the satellite development, launch and commissioning. The NASA Headquarters PACE Program Science office is responsible for supporting the science data processing system and assembling competed community science teams, which includes field-based vicarious calibration and data product validation efforts to support the PACE Project Science team. The PACE observatory is comprised of three instruments, the Ocean Color Instrument (OCI) and two polarimeters, the Hyper-Angular Rainbow Polarimeter 2 (HARP2) and the Spectro-Polarimeter for Exploration (SPEXone) and the PACE spacecraft. The observatory has been commissioned and is performing on-orbit science data collection operations. Summary for Program: The Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a strategic climate continuity mission that was defined in the 2010 document Responding to the Challenge of Climate and Environmental Change: NASA’s Plan for Climate-Centric Architecture for Earth Observations and Applications from Space (referred to as the “Climate Initiative”). Launched in February 2024 under the leadership of the NASA Goddard Space Flight Center (GSFC), the PACE mission represents NASA’s next investment in ocean biology, clouds, and aerosol data records. PACE will extend the high quality ocean ecological, ocean biogeochemical, cloud, and aerosol particle data records begun by NASA in the 1990s. The PACE observatory is comprised of the Ocean Color Instrument (OCI), the Hyper-Angular Rainbow Polarimeter 2 (HARP2) and the Spectro-Polarimeter for Exploration (SPEXone), along with the PACE spacecraft.

Robert H Estep, Jr↗

Mission Overview and Status from Concept to Launch

The Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a strategic climate continuity mission that was defined in the 2010 document Responding to the Challenge of Climate and Environmental Change: NASA’s Plan for Climate-Centric Architecture for Earth Observations and Applications from Space (referred to as the “Climate Initiative”). Launched in February 2024, the PACE mission represents NASA’s next investment in ocean biology, clouds, and aerosol data records. PACE will extend the high quality ocean ecological, ocean biogeochemical, cloud, and aerosol particle data records begun by NASA in the 1990s, building on the exceptional heritages of the Sea-Viewing Wide Field-of-View Sensor (SeaWiFS), the Moderate Resolution Imaging Spectroradiometer (MODIS), the Multi-angle Imaging SpectroRadiometer (MISR), and the Visible Infrared Imaging Radiometer Suite (VIIRS). NASA Headquarters directed the mission development and implementation to the NASA Goddard Space Flight Center (GSFC) with guidance to utilize a Design-to-Cost (DTC) process. Mission studies were conducted to define appropriate approaches within and across elements while maximizing science capabilities at a high cost confidence. Mission baseline requirements development is also embedded within the DTC process, as these requirements were not established at the onset of the mission concept development. The PACE project office at NASA’s GSFC was responsible for the satellite development, launch and commissioning. The NASA Headquarters PACE Program Science office is responsible for supporting the science data processing system and assembling competed community science teams, which includes field-based vicarious calibration and data product validation efforts to support the PACE Project Science team. The PACE observatory is comprised of three instruments, the Ocean Color Instrument (OCI) and two polarimeters, the Hyper-Angular Rainbow Polarimeter 2 (HARP2) and the Spectro-Polarimeter for Exploration (SPEXone) and the PACE spacecraft. The observatory has been commissioned and is performing on-orbit science data collection operations. Summary for Program: The Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a strategic climate continuity mission that was defined in the 2010 document Responding to the Challenge of Climate and Environmental Change: NASA’s Plan for Climate-Centric Architecture for Earth Observations and Applications from Space (referred to as the “Climate Initiative”). Launched in February 2024 under the leadership of the NASA Goddard Space Flight Center (GSFC), the PACE mission represents NASA’s next investment in ocean biology, clouds, and aerosol data records. PACE will extend the high quality ocean ecological, ocean biogeochemical, cloud, and aerosol particle data records begun by NASA in the 1990s. The PACE observatory is comprised of the Ocean Color Instrument (OCI), the Hyper-Angular Rainbow Polarimeter 2 (HARP2) and the Spectro-Polarimeter for Exploration (SPEXone), along with the PACE spacecraft.

Robby Estep↗

Estimating pixel-level uncertainty in ocean color retrievals from MODIS

The spectral distribution of marine remote sensing reflectance, R(rs), is the fundamental measurement of ocean color science, from which a host of bio-optical and biogeochemical properties of the water column can be derived. Estimation of uncertainty in these derived properties is thus dependent on knowledge of the uncertainty in satellite-retrieved R(rs) (u(c)(R(rs))) at each pixel. Uncertainty in R(rs), in turn, is dependent on the propagation of various uncertainty sources through the R(rs) retrieval process, namely the atmospheric correction (AC). A derivative-based method for uncertainty propagation is established here to calculate the pixel-level uncertainty in R(rs), as retrieved using NASA’s multiple-scattering epsilon (MSEPS) AC algorithm and verified using Monte Carlo (MC) analysis. The approach is then applied to measurements from the Moderate Resolution Imaging Spectroradiometer (MODIS) on the Aqua satellite, with uncertainty sources including instrument random noise, instrument systematic uncertainty, and forward model uncertainty. The uc(Rrs) is verified by comparison with statistical analysis of coincident retrievals from MODIS and in situ Rrs measurements, and our approach performs well in most cases. Based on analysis of an example 8-day global products, we also show that relative uncertainty in R(rs) at blue bands has a similar spatial pattern to the derived concentration of the phytoplankton pigment chlorophyll-a (chl-a), and around 7.3%, 17.0%, and 35.2% of all clear water pixels (chl-a ≤ 0.1 mg/cu.m) with valid u(c)(R(rs)) have a relative uncertainty ≤ 5% at bands 412 nm, 443 nm, and 488 nm respectively, which is a common goal of ocean color retrievals for clear waters. While the analysis shows that u(c)(R(rs)) calculated from our derivative-based method is reasonable, some issues need further investigation, including improved knowledge of forward model uncertainty and systematic uncertainty in instrument calibration.

Pixel-level uncertainty↗

Future remote sensing instruments and systems

Scientific requirements for terrestrial remote-sensing satellites in the 1990's and instrument packages to meet them are discussed, summarizing the results of a preliminary study conducted by the NASA System Z Science and Mission Requirements Working Group. Major questions regarding atmospheric chemistry and circulation, global climate, ocean dynamics, biogeochemical cycles, ice-budget and hydrological cycles, continental geology, biomass dynamics, and land cover and use are listed along with the observational frequency and resolution necessary to answer them, and an instrument use matrix is presented. Large essentially permanent man-tended arrays of instruments serving multiple functions and linked to the users via advanced information-processing networks and (possibly including expert systems) are recommended, and a basic payload and two supplemental packages are outlined.

Broome, D. R., Jr.↗

Biogeochemical Considerations

Some questions relating to biogeochemical cycles and the nature of the biosphere driving them is best approached by means of remote (satellite) monitoring. Important among these are the distribution of various ecosystems and the boundaries between them, the extent and rate of modification of ecosystems by human or other factors, and various climatic and physical factors affecting ecosystem performance as influenced by human or natural processes.

Delwiche, C. C.↗

NASA Tech Briefs, March 2010

Topics covered include: Software Tool Integrating Data Flow Diagrams and Petri Nets; Adaptive Nulling for Interferometric Detection of Planets; Reducing the Volume of NASA Earth-Science Data; Reception of Multiple Telemetry Signals via One Dish Antenna; Space-Qualified Traveling-Wave Tube; Smart Power Supply for Battery-Powered Systems; Parallel Processing of Broad-Band PPM Signals; Inexpensive Implementation of Many Strain Gauges; Constant-Differential-Pressure Two-Fluid Accumulator; Inflatable Tubular Structures Rigidized with Foams; Power Generator with Thermo-Differential Modules; Mechanical Extraction of Power From Ocean Currents and Tides; Nitrous Oxide/Paraffin Hybrid Rocket Engines; Optimized Li-Ion Electrolytes Containing Fluorinated Ester Co-Solvents; Probabilistic Multi-Factor Interaction Model for Complex Material Behavior; Foldable Instrumented Bits for Ultrasonic/Sonic Penetrators; Compact Rare Earth Emitter Hollow Cathode; High-Precision Shape Control of In-Space Deployable Large Membrane/Thin-Shell Reflectors; Rapid Active Sampling Package; Miniature Lightweight Ion Pump; Cryogenic Transport of High-Pressure-System Recharge Gas; Water-Vapor Raman Lidar System Reaches Higher Altitude; Compact Ku-Band T/R Module for High-Resolution Radar Imaging of Cold Land Processes; Wide-Field-of-View, High-Resolution, Stereoscopic Imager; Electrical Capacitance Volume Tomography with High-Contrast Dielectrics; Wavefront Control and Image Restoration with Less Computing; Polarization Imaging Apparatus; Stereoscopic Machine-Vision System Using Projected Circles; Metal Vapor Arcing Risk Assessment Tool; Performance Bounds on Two Concatenated, Interleaved Codes; Parameterizing Coefficients of a POD-Based Dynamical System; Confidence-Based Feature Acquisition; Algorithm for Lossless Compression of Calibrated Hyperspectral Imagery; Universal Decoder for PPM of any Order; Algorithm for Stabilizing a POD-Based Dynamical System; Mission Reliability Estimation for Repairable Robot Teams; Processing AIRS Scientific Data Through Level 3; Web-Based Requesting and Scheduling Use of Facilities; AutoGen Version 5.0; Time-Tag Generation Script; PPM Receiver Implemented in Software; Tropospheric Emission Spectrometer Product File Readers; Reporting Differences Between Spacecraft Sequence Files; Coordinating "Execute" Data for ISS and Space Shuttle; Database for Safety-Oriented Tracking of Chemicals; Apparatus for Cold, Pressurized Biogeochemical Experiments; Growing B Lymphocytes in a Three-Dimensional Culture System; Tissue-like 3D Assemblies of Human Broncho-Epithelial Cells; Isolation of Resistance-Bearing Microorganisms; Oscillating Cell Culture Bioreactor; and Liquid Cooling/Warming Garment.

Source record↗

Coastal Zone Color Scanner

The Coastal Zone Color Scanner (CZCS) spacecraft ocean color instrument is capable of measuring and mapping global ocean surface chlorophyll concentration. It is a scanning radiometer with multiband capability. With new electronics and some mechanical, and optical re-work, it probably can be made flight worthy. Some additional components of a second flight model are also available. An engineering study and further tests are necessary to determine exactly what effort is required to properly prepare the instrument for spaceflight and the nature of interfaces to prospective spacecraft. The CZCS provides operational instrument capability for monitoring of ocean productivity and currents. It could be a simple, low cost alternative to developing new instruments for ocean color imaging. Researchers have determined that with global ocean color data they can: specify quantitatively the role of oceans in the global carbon cycle and other major biogeochemical cycles; determine the magnitude and variability of annual primary production by marine phytoplankton on a global scale; understand the fate of fluvial nutrients and their possible affect on carbon budgets; elucidate the coupling mechanism between upwelling and large scale patterns in ocean basins; answer questions concerning the large scale distribution and timing of spring blooms in the global ocean; acquire a better understanding of the processes associated with mixing along the edge of eddies, coastal currents, western boundary currents, etc., and acquire global data on marine optical properties.

Johnson, B.↗

Simulating PACE Global Ocean Radiances

The NASA PACE mission is a hyper-spectral radiometer planned for launch in the next decade. It is intended to provide new information on ocean biogeochemical constituents by parsing the details of high resolution spectral absorption and scattering. It is the first of its kind for global applications and as such, poses challenges for design and operation. To support pre-launch mission development and assess on-orbit capabilities, the NASA Global Modeling and Assimilation Office has developed a dynamic simulation of global water-leaving radiances, using an ocean model containing multiple ocean phytoplankton groups, particulate detritus, particulate inorganic carbon (PIC), and chromophoric dissolved organic carbon (CDOC) along with optical absorption and scattering processes at 1 nm spectral resolution. The purpose here is to assess the skill of the dynamic model and derived global radiances. Global bias, uncertainty, and correlation are derived using available modern satellite radiances at moderate spectral resolution. Total chlorophyll, PIC, and the absorption coefficient of CDOC (aCDOC), are simultaneously assimilated to improve the fidelity of the optical constituent fields. A 5-year simulation showed statistically significant (P < 0.05) comparisons of chlorophyll (r = 0.869), PIC (r = 0.868), and a CDOC (r =0.890) with satellite data. Additionally, diatoms (r = 0.890), cyanobacteria (r = 0.732), and coccolithophores (r = 0.716) were significantly correlated with in situ data. Global assimilated distributions of optical constituents were coupled with a radiative transfer model (Ocean-Atmosphere Spectral Irradiance Model, OASIM) to estimate normalized water-leaving radiances at 1 nm for the spectral range 250-800 nm. These unassimilated radiances were within 0.074 mW/sq cm/micron/sr of MODIS-Aqua radiances at 412, 443, 488, 531, 547, and 667 nm. This difference represented a bias of 10.4% (model low). A mean correlation of 0.706 (P < 0.05) was found with global distributions of MODIS radiances. These results suggest skill in the global assimilated model and resulting radiances. The reported error characterization suggests that the global dynamical simulation can support some aspects of mission design and analysis. For example, the high spectral resolution of the simulation supports investigations of band selection. The global nature of the radiance representations supports investigations of satellite observing scenarios. Global radiances at bands not available in current and past missions support investigations of mission capability. PACE, ocean color, water-leaving radiances, biogeochemical model, radiative transfer model

PIC↗

U.S. Eastern Continental Shelf Carbon Cycling (USECoS): Modeling, Data Assimilation, and Analysis

Although the oceans play a major role in the uptake of fossil fuel CO2 from the atmosphere, there is much debate about the contribution from continental shelves, since many key shelf fluxes are not yet well quantified: the exchange of carbon across the land-ocean and shelf-slope interfaces, air-sea exchange of CO2, burial, and biological processes including productivity. Our goal is to quantify these carbon fluxes along the eastern U.S. coast using models quantitatively verified by comparison to observations, and to establish a framework for predicting how these fluxes may be modified as a result of climate and land use change. Our research questions build on those addressed with previous NASA funding for the USECoS (U.S. Eastern Continental Shelf Carbon Cycling) project. We have developed a coupled biogeochemical ocean circulation model configured for this study region and have extensively evaluated this model with both in situ and remotely-sensed data. Results indicate that to further reduce uncertainties in the shelf component of the global carbon cycle, future efforts must be directed towards 1) increasing the resolution of the physical model via nesting and 2) making refinements to the biogeochemical model and quantitatively evaluating these via the assimilation of biogeochemical data (in situ and remotely-sensed). These model improvements are essential for better understanding and reducing estimates of uncertainties in current and future carbon transformations and cycling in continental shelf systems. Our approach and science questions are particularly germane to the carbon cycle science goals of the NASA Earth Science Research Program as well as the U.S. Climate Change Research Program and the North American Carbon Program. Our interdisciplinary research team consists of scientists who have expertise in the physics and biogeochemistry of the U.S. eastern continental shelf, remote-sensing data analysis and data assimilative numerical models.

Mannino, Antonio↗

A Comprehensive Plan for the Long-Term Calibration and Validation of Oceanic Biogeochemical Satellite Data

The primary objective of this planning document is to establish a long-term capability and validating oceanic biogeochemical satellite data. It is a pragmatic solution to a practical problem based primarily o the lessons learned from prior satellite missions. All of the plan's elements are seen to be interdependent, so a horizontal organizational scheme is anticipated wherein the overall leadership comes from the NASA Ocean Biology and Biogeochemistry (OBB) Program Manager and the entire enterprise is split into two components of equal sature: calibration and validation plus satellite data processing. The detailed elements of the activity are based on the basic tasks of the two main components plus the current objectives of the Carbon Cycle and Ecosystems Roadmap. The former is distinguished by an internal core set of responsibilities and the latter is facilitated through an external connecting-core ring of competed or contracted activities. The core elements for the calibration and validation component include a) publish protocols and performance metrics; b) verify uncertainty budgets; c) manage the development and evaluation of instrumentation; and d) coordinate international partnerships. The core elements for the satellite data processing component are e) process and reprocess multisensor data; f) acquire, distribute, and archive data products; and g) implement new data products. Both components have shared responsibilities for initializing and temporally monitoring satellite calibration. Connecting-core elements include (but are not restricted to) atmospheric correction and characterization, standards and traceability, instrument and analysis round robins, field campaigns and vicarious calibration sites, in situ database, bio-optical algorithm (and product) validation, satellite characterization and vicarious calibration, and image processing software. The plan also includes an accountability process, creating a Calibration and Validation Team (to help manage the activity), and a discussion of issues associated with the plan's scientific focus.

Hooker, Stanford B.↗

Bio-Optical Measurement and Modeling of the California Current and Polar Oceans

The principal goals of our research are to validate standard or experimental products through detailed bio-optical and biogeochemical measurements, and to combine ocean optical observations with advanced radiative transfer modeling to contribute to satellite vicarious radiometric calibration and advanced algorithm development. To achieve our goals requires continued efforts to execute complex field programs globally, as well as development of advanced ocean optical measurement protocols. We completed a comprehensive set of ocean optical observations in the California Current, Southern Ocean, Indian Ocean requiring a large commitment to instrument calibration, measurement protocols, data processing and data merger. We augmented separately funded projects of our own, as well as others, to acquire ill situ data sets we have collected on various global cruises supported by separate grants or contracts. In collaboration with major oceanographic ship-based observation programs funded by various agencies (CalCOFI, US JGOFS, NOAA AMLR, INDOEX and Japan/East Sea) our SIMBIOS effort has resulted in data from diverse bio-optical provinces. For these global deployments we generate a high-quality, methodologically consistent, data set encompassing a wide-range of oceanic conditions. Global data collected in recent years have been integrated with our on-going CalCOFI database and have been used to evaluate SeaWiFS algorithms and to carry out validation studies. The combined database we have assembled now comprises more than 700 stations and includes observations for the clearest oligotrophic waters, highly eutrophic blooms, red-tides and coastal case 2 conditions. The data has been used to validate water-leaving radiance estimated with SeaWiFS as well as bio-optical algorithms for chlorophyll pigments. The comprehensive data is utilized for development of experimental algorithms (e.g. high-low latitude pigment transition, phytoplankton absorption, and cDOM). During this period we completed 9 peer-reviewed publications in high quality journals, and presented aspects of our work at more than 10 scientific conferences.

Mitchell, B. Greg↗

Earth's Earliest Ecosystems in the C: The Use of Microbial Mats to Demonstrate General Principles of Scientific Inquiry and Microbial Ecology

Microbial mats are living examples of the most ancient biological communities on Earth. As Earth's earliest ecosystems, they are centrally important to understanding the history of life on our planet and are useful models for the search for life elsewhere. As relatively compact (but complete) ecosystems, microbial mats are also extremely useful for educational activities. Mats may be used to demonstrate a wide variety of concepts in general and microbial ecology, including the biogeochemical cycling of elements, photosynthesis and respiration, and the origin of the Earth's present oxygen containing atmosphere. Microbial mats can be found in a number of common environments accessible to teachers, and laboratory microbial mats can be constructed using materials purchased from biological supply houses. With funding from NASA's Exobiology program, we have developed curriculum and web-based activities centered on the use of microbial mats as tools for demonstrating general principles in ecology, and the scientific process. Our web site (http://microbes.arc.nasa.gov) includes reference materials, lesson plans, and a "Web Lab", featuring living mats maintained in a mini-aquarium. The site also provides information as to how research on microbial mats supports NASA's goals, and various NASA missions. A photo gallery contains images of mats, microscopic views of the organisms that form them, and our own research activities. An animated educational video on the web site uses computer graphic and video microscopy to take students on a journey into a microbial mat. These activities are targeted to a middle school audience and are aligned with the National Science Standards.

Bebout, Brad M.↗

How life affects the geochemical cycle of carbon

Developing a quantitative understanding of the biogeochemical cycles of carbon as they have worked throughout Earth history on various time scales, how they have been affected by biological evolution, and how changes in the carbon content of ocean and atmosphere may have affected climate and the evolution of life are the goals of the research. Theoretical simulations were developed that can be tuned to reproduce such data as exist and, once tuned, can be used to predict properties that have not yet been observed. This is an ongoing process, in which models and results are refined as new data and interpretations become available and as understanding of the global system improves. Results of the research are described in several papers which were published or submitted for publication. These papers are summarized. Future research plans are presented.

Walker, James C. G.↗

Mission Overview and Status IGARSS Conference

The Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a strategic climate continuity mission that was defined in the 2010 document Responding to the Challenge of Climate and Environmental Change: NASA’s Plan for Climate-Centric Architecture for Earth Observations and Applications from Space (referred to as the “Climate Initiative”). Scheduled for launch in January 2024, the PACE mission represents NASA’s next investment in ocean biology, clouds, and aerosol data records [1]. PACE will extend the high quality ocean ecological, ocean biogeochemical, cloud, and aerosol particle data records begun by NASA in the 1990s, building on the exceptional heritages of the Sea-Viewing Wide Field-of-View Sensor (SeaWiFS), the Moderate Resolution Imaging Spectroradiometer (MODIS), the Multi-angle Imaging SpectroRadiometer (MISR), and the Visible Infrared Imaging Radiometer Suite (VIIRS). The PACE project office at NASA’s GSFC is responsible for the satellite development, launch and operations. The NASA Headquarters PACE Program Science office is responsible for supporting the science data processing system and assembling competed community science teams, which will include field-based vicarious calibration and data product validation efforts to support the PACE Project Science team. The mission is planned for launch into a Sun synchronous polar orbit at 676.5 km with an inclination of 98 degrees and a 1 pm local ascending node crossing time. The PACE observatory is comprised of three instruments, an Ocean Color Instrument (OCI) and two polarimeters, the Hyper-Angular Rainbow Polarimeter 2 (HARP2) and the Spectro-Polarimeter for Exploration (SPEXone). The OCI is the primary instrument on the observatory and is being developed at Goddard Space Flight Center (GSFC). The OCI is a hyperspectral scanning radiometer designed to measure spectral radiances from the ultraviolet to shortwave infrared (SWIR) to enable advanced ocean color and heritage cloud and atmospheric aerosol science [2]. The HARP2 and SPEXone are complimentary instruments on the PACE observatory, acquired outside of GSFC. The HARP2 is multi-spectral, wide swath (supporting atmospheric correction of OCI), and hyper-angular, with capabilities for cloud science that exceed what is capable from OCI alone. The SPEXone is narrow swath, multi-angular, and hyperspectral, with capabilities for atmospheric aerosol science that exceed what can be accomplished with OCI. NASA Headquarters directed the mission development to be guided by a Design-to-Cost (DTC) process. All elements of the mission, other than the cost, are in the DTC trade space. At the heart of the DTC process are the mission studies, performed across all the mission elements. The mission studies were used to define appropriate approaches within and across elements while maximizing science capabilities at a high cost confidence. Mission baseline requirements development is also embedded within the DTC process, as these requirements were not established at the onset of the mission concept development. Baseline mission requirements are a product of the mission studies and are defined by the project office as part of the DTC process. At the time of this writing, OCI, HARP2 and SPEXone are integrated onto the PACE spacecraft, creating the PACE observatory. The instruments and spacecraft subsystems are undergoing combined functional performance testing in preparation for observatory-level environmental testing prior to shipment to the launch site. Here, we will provide an update on science capabilities and observatory readiness for its early 2024 launch.

remote sensing↗

State of Wildfires

Fire is an essential component of ecosystems and acts as key driver of biogeochemical cycling with impacts on vegetation structure and composition, soil conditions, and climate feedbacks. Fire behavior and effects vary based on the types of fuel, fuel dryness, and frequency of ignition. Due to changing climate and land use patterns, fire danger is increasing in many regions globally, and fires are having increasingly devastating impacts on human health, infrastructure, and ecosystem services. Recurrent fires help to determine the distribution of trees and grasses, and overall fuel load, which inform the behavior of future fires. Process-based models can be used to capture multi-scale impacts at the forest stand-level up to the landscape level, and across minutes to centuries, but must capture variation in fire behavior and intensity as a function of the fuel and climate, from high intensity forest crown fires within boreal regions to low intensity rapid grass fires of the tropics. Fire model development demonstrates our ability to capture large scale fire influenced biogeography and vegetation distribution at the earth system scale through vegetation traits and fire feedbacks. At the individual stand scale the importance of interactions and feedbacks between above and below ground process is essential to capturing the vegetation dynamics across boreal forest systems. Improving the mechanics of including plant physiology and specifically live fuel moisture content is the next step to advancing the capability of process based models to inform fire research. Advances in the testing and creation of a mechanistic live fuel moisture model demonstrate the foundation for future live fuel dynamics research that can be informed by field and remote sensing information. Improved remote sensing, technological and modeling capabilities support a more comprehensive and cohesive fire response that will be better equipped to overcome current barriers and anticipate the new reality of fires in a warming world.

wildfires↗

Biogeochemical cycles of carbon, sulfur, and free oxygen in a microbial mat

Complete budgets for carbon and oxygen have been constructed for cyanobacterial mats dominated by Microcoleus chthonoplastes from the evaporating ponds of a salt works. We infer from the data the various sinks for O2 as well as the sources of carbon for primary production. Although seasonal variability exists, a major percentage of the O2 produced during the day did not diffuse out of the mat but was used within the mat to oxidize both organic carbon and the sulfide produced by sulfate reduction. At night, most of the O2 that diffused into the mat was used to oxidize sulfide, with O2 respiration of minor importance. During the day, the internal mat processes of sulfate reduction and O2 respiration generated as much or more inorganic carbon (DIC) for primary production as diffusion into the mat. Oxygenic photosynthesis was the most important process of carbon fixation. At night, the DIC lost from the mat was mostly from sulfate reduction. Elemental fluxes across the mat/brine interface indicated that carbon with an oxidation state of greater than zero was taken up by the mat during the day and liberated from the mat at night. Overall, carbon with an average oxidation state of near zero accumulated in the mat. Both carbon fixation and carbon oxidation rates varied with temperature by a similar amount.

Canfield, Donald E.↗