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At least 217 records · Page 12

Wyoming Carbon Blueprint A Roadmap for Statewide Carbon Capture and Storage

Wyoming stands at a pivotal point in defining its energy future, and the Wyoming Carbon Blueprint positions the state to lead the nation in carbon management through a coordinated buildout of carbon capture, transportation, utilization, and geologic storage. Building on Wyoming’s long history as a major producer of coal, oil, and natural gas, and supported by favorable policies, skilled labor, and robust subsurface resources, the Blueprint outlines a pathway to develop one of the world’s first open-access carbon hubs capable of capturing between 10 and 25 million tonnes of CO₂ per year within five years, and up to 45 million tonnes within a decade. In doing so, it advances the concept of “No Carbon Left Behind”: a statewide strategy that prevents stranded CO₂ by aligning capture, transport, and storage systems into a single coherent infrastructure network.

54 ENVIRONMENTAL SCIENCES↗

Radioiodine sorbent selection criteria

Methods for preventing radioiodine from entering the environment are needed in processes related to nuclear energy and medical isotope production. The development and performance of many different types of sorbents to capture iodine have been reported on for decades; however, there is yet to be a concise overview on the important parameters that should be considered when selecting a material for chemically capturing radioiodine. This paper summarizes several criteria that should be considered when selecting candidate sorbents for implementation into real-world systems. The list of selection criteria discussed are 1) optimal capture performance, 2) kinetics of adsorption, 3) performance under relevant process conditions, 4) properties of the substrate that supports the getter, and 5) environmental stability and disposition pathways for iodine-loaded materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Competitive formation of intercalated versus supported metal nanoclusters during deposition on layered materials with surface point defects

Intercalated metal nanoclusters (NCs) can be formed under the surface of graphite after sputtering to generate surface “portal” defects that allow deposited atoms to reach the subsurface gallery. Although, there is a competition between formation of supported NCs on top of the surface and intercalated NCs under the surface, the latter only dominating at sufficiently high temperature. A stochastic model incorporating appropriate system thermodynamics and kinetics is developed to capture this complex and competitive nucleation and growth process. Kinetic Monte Carlo simulation shows that the model captures experimental trends observed for Cu and other metals and reveals that higher temperatures are needed to facilitate detachment of atoms from supported NCs enabling them to reach the gallery.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Multidimensional perspectives of geo-epidemiology: from interdisciplinary learning and research to cost–benefit oriented decision-making

Research typically promotes two types of outcomes (inventions and discoveries), which induce a virtuous cycle: something suspected or desired (not previously demonstrated) may become known or feasible once a new tool or procedure is invented and, later, the use of this invention may discover new knowledge. Research also promotes the opposite sequence—from new knowledge to new inventions. This bidirectional process is observed in geo-referenced epidemiology—a field that relates to but may also differ from spatial epidemiology. Geo-epidemiology encompasses several theories and technologies that promote inter/transdisciplinary knowledge integration, education, and research in population health. Based on visual examples derived from geo-referenced studies on epidemics and epizootics, this report demonstrates that this field may extract more (geographically related) information than simple spatial analyses, which then supports more effective and/or less costly interventions. Actual (not simulated) bio-geo-temporal interactions (never captured before the emergence of technologies that analyze geo-referenced data, such as geographical information systems) can now address research questions that relate to several fields, such as Network Theory. Thus, a new opportunity arises before us, which exceeds research: it also demands knowledge integration across disciplines as well as novel educational programs which, to be biomedically and socially justified, should demonstrate cost-effectiveness. Grounded on many bio-temporal-georeferenced examples, this report reviews the literature that supports this hypothesis: novel educational programs that focus on geo-referenced epidemic data may help generate cost-effective policies that prevent or control disease dissemination.

59 BASIC BIOLOGICAL SCIENCES↗

Demonstration of a Continuous Motion Direct Air Capture System

Global Thermostat (GT) has developed a process that addresses the primary technical challenges associated with direct air capture (DAC): the ability to process enormous volumetric flowrates of air and provide the energy for regeneration at acceptable cost. However, at current, there is opportunity for improvement in overall capture costs and especially in capital costs. While GT has advanced its base technology to TRL levels supporting commercial deployments, its research strategy includes alternative technology embodiments that enable substantial reductions in the cost per tonne of CO 2 removed. The objective of this project is to advance the most promising of these embodiments, where a DAC plant is operated in a continuous fashion rather than a discrete stepwise fashion (GT’s commercial scale technology approach). The Continuous Motion Direct Air Capture (cDAC) System’s advantages over the GT baseline stepwise DAC platform have been proposed primarily as a reduction in the complexity required for starting and stopping a movement system, relaxing requirements for other components designed for a rapid switching application, and a flattening of the sharp instantaneous fluid flowrates into steady-state mass & energy flows to enable smoother operation and easier heat integration. These advantages can lead to shorter cycle times, greater plant reliability, and lower capital expense. The primary objective of this project is the design, construction, commissioning, and operation of a field-test unit (FTU) at a scale in the range of ~200 tons CO 2 per year. Data generated from the operation campaign would then be used in a prescreening techno-economic analysis (TEA) and life cycle analysis (LCA), allowing this process to be compared to other carbon capture technologies.

42 ENGINEERING↗

Fuel Performance Modeling Plan to Support the Advance Gas Reactor Program

This report documents the current status of the fuel performance modeling initiative to support the Advanced Gas Reactor (AGR) program in the development of tristructural isotropic (TRISO) coated fuel particles. A brief summary of the modeling codes that have been developed to support TRISO modeling is included along with a summary of the behavior of fuel particles during irradiation and the modeling used to capture these effects. In addition, this report identifies further modeling and material property needs that have been identified for further development based on experience from previously performed AGR experiments. In general, the remaining activities to support fuel performance modeling for the AGR program include continued AGR experiment support for AGR-3/4 and AGR-5/6/7 as well as modeling improvements identified throughout the course of the program. These modeling improvements can be summarized as the following: Fission product transport Thermomechanical particle behavior Additional modeling needs may be identified during the processing the data collected during the AGR post-irradiation examination (PIE) campaign and may lead to further modeling improvements that are not included in this report.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Summary Report of the Reactive CO 2 Capture: Process Integration for the New Carbon Economy Workshop, February 18-19, 2020

This report provides a summary of feedback from the “Reactive CO 2 Capture: Process Integration for the New Carbon Economy” workshop held February 18-19, 2020. The focus of this workshop was to discuss approaches for merging carbon dioxide (CO 2 ) capture and CO 2 conversion/utilization systems into an integrated "reactive capture" strategy. By the workshop’s definition, reactive capture (RC) of CO 2 is the coupled process of capturing CO 2 from a mixed gas stream and converting it into a valuable product without going through a purified CO 2 intermediate. Participants were able to identify four key themes and associated calls to action for the reactive capture community: (1) essential role of partnerships; (2) critical challenges; (3) defining the value proposition; and (4) approach to support technological advancement.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Monitoring Avian Productivity and Survivorship at the Sandia Wetlands at Los Alamos National Laboratory (2014-2019)

Biologists at Los Alamos National Laboratory completed six years (2014–2019) of demographic monitoring of passerines (songbirds) during the breeding season in Los Alamos, New Mexico. We captured songbirds at a mist netting station located in the Sandia Wetlands in Sandia Canyon (Technical Areas 60 and 61). We identified, measured, and then banded captured birds with federal migratory bird bands. Banding operations took place between May and August of each year, with 10 mist netting sessions annually. We conducted this project as part of the implementation of the Biological Resources Management Plan. The project complies with the 2013 Memorandum of Understanding between the United States Fish and Wildlife Service (USFWS) and the United States Department of Energy regarding the implementation of Executive Order 13186. The overall number of birds and species captured was variable, and we saw no decreases over the course of six years in bird species diversity, abundance, or the percentage of breeding birds. Our results indicate that the Sandia Wetlands support numerous species of breeding birds, including species of conservation concern. We did not see a declining trend for the top 10 most-captured species or for any of the species of conservation concern over time; however, we need more years of data to make robust conclusions about population trends through time. Our results indicated that adult recapture rates at the Sandia Wetlands are at least twice as low when compared with estimated adult survival in migratory passerines from peer-reviewed literature. We also did not recapture any birds that were banded as juveniles in subsequent years throughout the entire six-year period. Low recapture rates for adults and the non-existent recapture rates for juveniles should be explored further. To accurately assess individual species survival rates for adults and juveniles using mark-recapture models, we need a longer dataset, which would allow for a more robust analysis.

59 BASIC BIOLOGICAL SCIENCES↗

Barriers and Opportunities for Energy Technology Adoption in Juneau, Alaska

This report presents findings from a qualitative study examining barriers and opportunities for air source heat pump (ASHP) and electric vehicle (EV) adoption in Juneau, Alaska, with a particular focus on manufactured and multifamily housing. The analysis draws on community insights from end users and middle actors to better understand how technology adoption unfolds in contexts with distinct logistical, infrastructural, and housing constraints. The report is organized according to key barriers and opportunities identified through stakeholder input, providing a structured understanding of adoption dynamics across technologies and housing types. These insights are intended to inform program design and support more effective electrification strategies tailored to local conditions. The study team employed qualitative methods to capture both in-depth and high-level perspectives on technology adoption. Data collection included: 1) two 2-hour focus groups with a total of five end users and seven middle actors, enabling detailed and structured discussion and 2) ten semistructured interviews with manufactured home owners, multifamily landlords, and one tenant, providing complementary insights across housing contexts. Focus groups captured accounts of shared challenges and opportunities while interviews offered more concise reflections on individual experiences. Together, these methods enabled a more comprehensive understanding of both systemic barriers and lived experiences with ASHPs and EVs. The findings reveal that adoption of electrification technologies is shaped by a combination of economic, logistical, and informational factors that vary across housing types, technology characteristics, user groups, and other demographic factors. Addressing these factors requires tailored strategies that reflect local conditions and user experiences. The insights in this report can provide a foundation for organizations such as AEL&P to refine program design, support more effective outreach, and anticipate shifts in energy demand associated with increased electrification. More broadly, the study highlights the importance of incorporating community perspectives when developing electrification initiatives to ensure they are both practical and responsive to real-world constraints.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Performance Degradation of Amine-Infused Fiber Sorbents for Direct Air Capture: Mechanisms and Solutions

Sorbent stability poses significant impacts on longterm performance of direct air capture (DAC) of CO 2 and levelized cost of capture (LCOC). We report the DAC performance degradation of amine-infused fiber sorbents based on poly(ethylenimine) (PEI), mesoporous SiO 2 , and cellulose acetate (CA) over CO 2 cyclic sorption cycles in a nonoxidative environment. Infrared and nuclear magnetic resonance spectra indicate that the aminolysis reactions between CA ester moieties and PEI amine sites lead to the formation of acetamides and hence lower CO 2 affinities of the sorbents. This stability issue can be remedied by hydrolysis treatment of the CA fiber sorbents before PEI impregnation or replacing CA with poly(ether sulfone). This study underscores the importance of selecting proper support or additive materials of DAC contactors that are compatible with active species of CO 2 capture.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Safety-Related Instrumentation and Control Pilot Upgrade: Conceptual - Detailed Design Phase Report and Lessons Learned

Historically, regulatory barriers have precluded nuclear plant safety-related (SR) Instrumentation and Control (I&C) system modernizations. These barriers have been largely addressed by industry and United States Nuclear Regulatory Commission (NRC) efforts, including development of the License Amendment Request (LAR) Alternate Review (AR) process for digital I&C upgrades. The U.S. Department of Energy (DOE) and the Idaho National Laboratory (INL) are supporting a SR I&C pilot upgrade at the Limerick Generating Station (LGS) to demonstrate this process and capturing associated lessons learned for the benefit of industry. In 2021, a paper summarizing lessons learned as captured in INL/EXT-20-59809, Safety Related Instrumentation & Control Pilot Upgrade Initial Scoping Phase Implementation Report and Lessons Learned was presented at the 12th NPIC & HMIT conference. It is recommended that readers of this paper review reference 1 or the associated Nuclear Journal paper for context. This paper summarizes activities performed and lessons learned for the conceptual design phase and portions of the detailed design phase as captured in INL/RPT-23-XXXX, “Safety-Related Instrumentation and Control Pilot Upgrade: Conceptual - Detailed Design Phase Report and Lessons Learned.” The portions of the effort covered by reference 2 include conceptual design phase activities from December 2020, through completion in November 2021, and detailed design activities through September 2022. These efforts and associated detailed documentation in reference 3 are intended to support similar industry upgrades as a foundation stone for a Digital Transformation that will improve plant safety, reliability, and operational performance while lowering plant total cost of ownership.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Molecular-level solvation and selectivity behavior of Na + , K + , and Li + within glycerol-derived solvents

Ether-based acyclic solvents have a tendency to confine positively charged atoms, forming structures called podands. Due to the stability of these structures, podands have been identified as promising candidates for several different electrochemical applications. In this work, we use molecular dynamics simulations to investigate the solvation and selectivity of Na + , K + , and Li + by different glycerol-derived solvents. The structural properties suggest that the solvent-cation association is stable over a very wide temperature range. Further, a strong correlation is observed between the more electronegative oxygen sites and preferential interaction with the cations, which suggests that the electrostatic oxygen-ion interactions dominate the coordination between these species. Significantly more intense interactions are observed between the solvents and Li + , versus Na + or K + . These molecular-level thermodynamic insights provide fundamental support for further exploring the performance of glycerol-derived podand complexes in Li + capture applications and/or electrolyte formulations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Scaling of oxygen-methane reacting coaxial jets using x-ray fluorescence to measure mixture fraction

Stoichiometric mixing length L s of reacting coaxial jet flames is a critical scaling parameter for liquid rocket engine combustors. Previous studies have shown that L s for shear coaxial flames can be scaled like their non-reacting counterparts using a non-dimensional momentum flux ratio J. In addition, stoichiometric mixing lengths of reacting and nonreacting coaxial jets collapse upon a single line by altering J using an effective outer flow gas density. This effective density is calculated from a modified version of the equivalence principle, originally developed by Tacina and Dahm [1, 2] and accounts for the effects of heat release on mixing. However, previous studies also required a second nonphysical scaling constant S c for the reacting jets, which is not predicted by the equivalence principle [3]. It was originally hypothesized that S c is attributed to the limitation of hydroxyl (OH) planar laser-induced fluorescence, which only infers L s . Direct quantitative measurement of conserved scalar fields using conventional optical diagnostics is difficult due to the lack of a tracer that easily fluoresces, survives high temperature oxygen flames, and is not dominated by quenching effects. To measure a conserved scalar field, this work implements x-ray fluorescence of Kr and Ar tracers to obtain quantitative mixture fraction fields. From these mixture fraction fields, stoichiometric mixing lengths for two CH 4 /O 2 flames are calculated and scaled against nonreacting coaxial mixing lengths using the equivalence principle. By directly measuring the stoichiometric mixing length, it is established that the additional constant is a byproduct of the OH measurement technique and the equivalence principle fully captures the scaling. Finally, comparison with high-fidelity simulation of the flame further supports this conclusion. In addition to further strengthening this scaling method, this work represents the first use of x-ray fluorescence to make quantitative conserved scalar measurements in turbulent flames.

33 ADVANCED PROPULSION SYSTEMS↗

In Vivo Molecular Insights into Syntrophic Geobacter Aggregates

Direct interspecies electron transfer (DIET) has been considered as a novel and highly efficient strategy in both natural anaerobic environments and artificial microbial fuel cells. A syntrophic model consisting of Geobacter metallireducens and Geobacter sulfurreducens was studied in this work. We conducted in vivo molecular mapping of the outer surface of the syntrophic community as the interface of nutrients and energy exchange. System for Analysis at the Liquid Vacuum Interface combined with time-of-flight secondary ion mass spectrometry was employed to capture the molecular distribution of syntrophic Geobacter communities in the living and hydrated state. Principal component analysis with selected peaks revealed that syntrophic Geobacter aggregates were well differentiated from other control samples, including syntrophic planktonic cells, pure cultured planktonic cells, and single population biofilms. Our in vivo imaging indicated that a unique molecular surface was formed. Specifically, aromatic amino acids, phosphatidylethanolamine components, and large water clusters were identified as key components that favored the DIET of syntrophic Geobacter aggregates. Moreover, the molecular changes in depths of the Geobacter aggregates were captured using dynamic depth profiling. Our findings shed new light on the interface components supporting electron transfer in syntrophic communities based on in vivo molecular imaging.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Magnetic electron collimation in three-dimensional semi-metals

While electrons moving perpendicular to a magnetic field are confined to cyclotron orbits, they can move freely parallel to the field. This simple fact leads to complex current flow in clean, low carrier density semi-metals, such as long-ranged current jets forming along the magnetic field when currents pass through point-like constrictions. Occurring accidentally at imperfect current injection contacts, the phenomenon of "current jetting" plagues the research of longitudinal magneto-resistance, which is particularly important in topological conductors. Here we demonstrate the controlled generation of tightly focused electron beams in a new class of micro-devices machined from crystals of the Dirac semi-metal Cd 3 As 2 . The current beams can be guided by tilting a magnetic field and their range tuned by the field strength. Finite element simulations quantitatively capture the voltage induced at faraway contacts when the beams are steered towards them, supporting the picture of controlled electron jets. These experiments demonstrate direct control over the highly non-local signal propagation unique to 3D semi-metals in the current jetting regime, and may lead to applications akin to electron optics in free space.

36 MATERIALS SCIENCE↗

Eureka: Enabling Fine-Grained Access and Range Queries on Compressed Scientific Data via Data-Index Co-Compression

Handling large-scale scientific data in high-performance computing (HPC) environments poses significant challenges, including excessive I/O, high storage costs, and slow query performance. Traditional approaches often require full data decompression and scans, making them impractical for real-time or interactive analysis. To address these limitations, we introduce Eureka, a unified data-index co-compression framework that enables fine-grained access and efficient range queries on compressed scientific datasets. Eureka integrates spatial domain decomposition with block-wise error-bounded lossy compression to support selective decompression. It constructs a hierarchical AVL-tree index during compression to capture block-level value ranges, enabling fast pruning during query execution. To reduce metadata overhead, the index itself is also compressed while ensuring recall-preserving results. Experiments on six diverse HPC simulation datasets show that Eureka achieves up to 25x data compression and over 300x index compression, surpassing state-of-the-art compressors such as SZ3 and ZFP in rate-distortion performance. Additionally, Eureka delivers over 30x speedup for low-selectivity range queries, making it a scalable and efficient solution for modern scientific data analysis.

Yan, Ning↗

Appalachian Hydrogen Infrastructure Analysis

As large-scale efforts to decarbonize the global economy ramp up in earnest, hydrogen is being positioned as a critical solution for numerous sectors. Hydrogen produced from fossil energy resources with carbon capture and storage (CCS) is viewed as a bridge in the clean energy transition, enabling the development of midstream infrastructure and downstream demand. This report highlights the potential for the Appalachian region to develop a hydrogen economy with fossil-derived hydrogen with CCS production (hydrogen from natural gas with carbon capture and storage). Specifically, the report provides hydrogen transport and storage infrastructure pathways in support of a broader hydrogen economy. These pathways are consistent with existing and potential technologies and regulations and provide valuable guidance for the investment and research and development potential for transportation and storage of hydrogen in Appalachia.

08 HYDROGEN↗

Detecting flash drought events to inform adaptive water management

Abstract: Flash droughts are characterized by a rapid onset of drought conditions, a common feature among various indicators of these events. The lack of a standardized definition and indicator makes flash droughts particularly challenging to predict and manage. We test six state-of-the-art flash drought indicators using 41 years of daily data across all Hydrological Unit Code 4 (HUC4) regions in the contiguous United States. Our results show substantial disagreements among indicators, suggesting that the detection of a flash drought event strongly depends on the choice of indicator. From the perspective of informing management and operations, an open challenge remains: which flash drought indicator should be used to trigger operational adaptations? To this end, we propose a methodological framework that informs adaptive actions by regionally assessing the level of agreement between different indicators. The regional differences in hydroclimatic conditions are expected to be reflected in the level of agreement between indicators. To better inform adaptive actions, the framework will also consider the impacted sectoral water uses and their varying response times. The insights gained from this study improve the understanding of how these different flash drought indicators capture the different aspects of regional differences and impacted sectors. Furthermore, this information can support more targeted adaptive actions to mitigate adverse impacts through improved preparedness and response strategies.

climate resilience↗