Search NASA⌕ Search

SEARCH · Search NASA

Results for “clean hydrogen”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Modeling of H2 Dispersion at ARIES

Hydrogen is a versatile and clean energy carrier that can be produced from various renewable sources such as wind, solar, and hydropower and help decarbonize electricity grids, industry, and transportation. Using the Hydrogen Research Facility under Advanced Research on Integrated Energy Systems (ARIES) at the National Renewable Energy Laboratory's (NREL) Flatirons campus as a test bench, the study examines the feasibility, useability, and value of using computational fluid dynamics (CFD) techniques to model hydrogen dispersion. The ARIES facility was chosen because controlled hydrogen releases can be performed at a rate of 27 kg-H2/hr. Site-specific atmospheric and weather condition data such as wind speed and temperature were used as inputs to the model. The results show statistical distributions and ranges of hydrogen concentrations at locations throughout the domain. Wind conditions are found to significantly impact the release behavior, including the hydrogen cloud's direction and concentrations. At low wind speeds (below 1 mph), hydrogen forms a cloud and at higher wind speeds (> 2-4 mph) hydrogen plume stretches in the direction of wind momentum. From >100 simulations for ARIES site-specific conditions, statistical quantities combined with a clustering algorithm were used to propose sensor location at various elevations from ground.

dispersion↗
DOE OSTI2024

An Emerging Trend in the Synthesis of Iron Titanate Photocatalyst Toward Water Splitting

Hydrogen gas is a prominent focus in pursuing renewable and clean alternative energy sources. The quest for maximizing hydrogen production yield involves the exploration of an ideal photocatalyst and the development of a simple, cost-effective technique for its generation. Iron titanate has garnered attention in this context due to its photocatalytic properties, affordability, and non-toxic nature. Over the years, different synthesis routes, different morphologies, and some modifications of iron titanate have been carried out to improve its photocatalytic performance by enhancing light absorption in the visible region, boosting charge carrier transfer, and decreasing recombination of electrons and holes. The use of iron titanate photocatalyst for hydrogen evolution reaction has seen an upward trend in recent times, and based on available findings, more can be done to improve the performance. This review paper provides a comprehensive overview of the fundamental principles of photocatalysis for hydrogen generation, encompassing the synthesis, morphology, and application of iron titanate-based photocatalysts. The discussion delves into the limitations of current methodologies and present and future perspectives for advancing iron titanate photocatalysts. By addressing these limitations and contemplating future directions, the aim is to enhance the properties of materials fabricated for photocatalytic water splitting.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Request for Information on Establishing a New Manufacturing Institute (DE-FOA-0002564)

Deep decarbonization of major industries such as metals manufacturing requires extensive process integration and controls to manage feedstocks, side reactions, heat, water, and waste streams. The scale of the energy and capital investment requires that process integration be validated to a high level of confidence with no bias. Industries such as steel production have very thin profit margins. Therefore, lack of confidence in process integration, product quality, and economics is a major deterrence to changes in manufacturing capital investment. Public sector investment in reconfigurable pilot testbeds and a first-of-a-kind plant would be necessary to de-risk technical and financial barriers prior to industry-wide buildout. DOE should consider a National Lab-led hub for the testbeds. Lab testbeds could be utilized in campaigns and allow multiple industrial partners to evaluate and validate technologies prior to making major capital investments.

08 HYDROGEN↗
DOE OSTI2020

2018 Renewable Energy Data Book

The 2018 Renewable Energy Data Book provides facts and figures on energy and electricity use, renewable electricity in the United States, global renewable energy development, wind power, solar power, geothermal power, biopower, hydropower, marine and hydrokinetic power, battery storage, hydrogen, renewable fuels, voluntary procurement and clean energy investment.

2018 data↗
DOE OSTI2024

A Highly Efficient and Affordable Hybrid System for Hydrogen and Electricity Production (Final Project)

The pursuit of clean, secure, and sustainable energy has sparked significant interest in fuel cells for power generation and electrolyzer cells for hydrogen production. Among all types of fuel and electrolyzer cells, solid oxide cells (SOCs) have emerged as promising candidates due to their high efficiency and versatility. However, conventional oxygen-ion conductive SOCs face several challenges related to their performance and durability associated with their high-temperature operation (≥ 800 ºC). This has led to a growing interest in intermediate-temperature (≤ 650 ºC) proton-conducting solid oxide cells (p-SOCs) as potential alternatives. In collaboration between Phillips 66 and Georgia Tech, this project aims to achieve a 1 kW p-SOCs system to demonstrate the commercial viability of efficient SOC systems. This report addresses four primary areas and key challenges we overcame: (1) development of efficient and durable proton-conducting electrolyte (e.g., BaHf 0.1 Ce 0.7 Yb 0.2 O 3-δ ) and electrode/catalyst materials, (2) large area cell fabrication (10 x 10 cm 2 ), (3) scalable stack design and building (250 W and 1 kW), and (4) demonstration of a 1 kW prototype system. Notably, significant challenges faced during the large area cell fabrication process were addressed by achieving cell flatness, improving fabrication yield, and ensuring electrode/electrolyte interfacial adhesion. Stack designs were also developed, focusing on reducing contact resistance and optimizing stack components (e.g., sealants). These efforts resulted in the achievement of high performance and durability with promising outputs of 250 W and 1 kW. Furthermore, the integration of these stacks into a fuel-powered system was explored, with refinements made to heat management, as well as to pressure and heating conditions. The results demonstrated the potential applicability of our p-SOC technology in commercial energy storage and power generation systems. Additionally, the report discusses techno-economic analysis and a market transformation plan, aiming to evaluate and advance the commercial feasibility of this technology.

25 ENERGY STORAGE↗
DOE OSTI2021

Net-Zero Carbon Microgrids

The microgrid concept has been effective in creating aggregations of distributed energy resources—generation, storage and loads—for resiliency, in the form of energy security. The success of microgrids in bringing energy security to a wide range of customers—from individual residences to commercial and industrial installations to military bases—has been exemplified during power disruptions and extended outages due to extreme weather events, cybersecurity attacks, and equipment failures. Now microgrids have an opportunity to meet the challenges of climate change and contribute to a carbon-free power delivery system. The transition to net-zero starts within microgrids themselves. In fact, today’s microgrids are largely dominated by generators using fossil fuels, natural gas and diesel, with high greenhouse gas emissions. In short, the transition to net-zero means replacing fossil fueled generators with renewable generation in microgrids. This transition is extended by including new dispatchable generation technologies that are 100% carbon-free and that offer additional advantage of a more-dependable and sustainable source of energy and power. Basically, the decarbonization of microgrids requires three elements: 1) maximizing generation from renewable energy resources, 2) management of storage and flexible loads to balance the variability and intermittency of renewable energy resources, and 3) introducing new clean power sources, including hydrogen-based generation and small modular reactors. This report affirms a need for specific focus by governmental agencies at national, regional, and local levels to establish technology, policy, and investment in this area. The intention of the Net-Zero Microgrid (NZM) Program is to inform these constituencies with cross-cutting research and tools for the reduction of GHG in microgrids – to net-zero in the near term eventually to zero in the longer term. The NZM Program is committed to achieving decarbonization for resiliency and for providing clean energy at the local or distribution level, from remote communities to underserved communities, and large industrial and military facilities. The NZM Planning and Design Platform is a core tool to be developed as an early deliverable of the NZM Program because only a fully integrated microgrid-design approach will ensure maximum carbon reduction in energy production.

13 HYDRO ENERGY↗
DOE OSTI2025

Boosting H I -Galaxy Cross-Clustering Signal through Higher-Order Cross-Correlations

After reionization, neutral hydrogen (${\rm H\, \small {I}}$) traces the large-scale structure (LSS) of the Universe, enabling ${\rm H\, \small {I}}$ intensity mapping (IM) to capture the LSS in 3D and constrain key cosmological parameters. We present a new framework utilizing higher-order cross-correlations to study ${\rm H\, \small {I}}$ clustering around galaxies, tested using real-space data from the IllustrisTNG300 simulation. This approach computes the joint distributions of k-nearest neighbor (kNN) optical galaxies and the ${\rm H\, \small {I}}$ brightness temperature field smoothed at relevant scales (the kNN-field framework), providing sensitivity to all higher-order cross-correlations, unlike two-point statistics. To simulate ${\rm H\, \small {I}}$ data from actual surveys, we add random thermal noise and apply a simple foreground cleaning model, filtering out Fourier modes of the brightness temperature field with k ∥ < k min,∥ . Under current levels of thermal noise and foreground cleaning, typical of a Canadian Hydrogen Intensity Mapping Experiment (CHIME)-like survey, the ${\rm H\, \small {I}}$-galaxy cross-correlation signal in our simulations, using the kNN-field framework, is detectable at >30σ across r = [3, 12] h –1 Mpc. In contrast, the detectability of the standard two-point correlation function (2PCF) over the same scales depends strongly on the foreground filter: a sharp k ∥ filter can spuriously boost detection to 8σ due to position-space ringing, whereas a less sharp filter yields no detection. Nonetheless, we conclude that kNN-field cross-correlations are robustly detectable across a broad range of foreground filtering and thermal noise conditions, suggesting their potential for enhanced constraining power over 2PCFs.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Reticular Chemistry for Highly Porous Metal–Organic Frameworks: The Chemistry and Applications

Current global crises related to clean energy and the environment entail the development of materials that are capable of addressing these challenges. Metal–organic frameworks (MOFs), a class of functional materials assembled from metal-containing nodes and organic ligands via coordination bonds, have been successfully developed for various applications, including catalysis, toxic chemical removal, and gas storage and separation, as a result of their highly tailorable nature and precisely engineered pore structures. In particular, the exceptionally high surface areas and porosities of MOFs are two of their most attractive characteristics and place them among the best porous materials for the storage of clean energy gases, such as hydrogen and methane. Reticular chemistry stands out as a prominent approach to the design of MOFs as this strategy allows for the rational top-down design of frameworks guided by topological nets to afford extended framework structures with precise architectural arrangements at the molecular level. Furthermore, bridging the gap between reticular chemistry design strategies and highly porous MOFs can facilitate the development of next-generation high-performance materials through state-of-the-art chemical design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Large-scale physically accurate modelling of real proton exchange membrane fuel cell with deep learning

Proton exchange membrane fuel cells, consuming hydrogen and oxygen to generate clean electricity and water, suffer acute liquid water challenges. Accurate liquid water modelling is inherently challenging due to the multi-phase, multi-component, reactive dynamics within multi-scale, multi-layered porous media. In addition, currently inadequate imaging and modelling capabilities are limiting simulations to small areas (<1 mm 2 ) or simplified architectures. Herein, an advancement in water modelling is achieved using X-ray micro-computed tomography, deep learned super-resolution, multi-label segmentation, and direct multi-phase simulation. The resulting image is the most resolved domain (16 mm 2 with 700 nm voxel resolution) and the largest direct multi-phase flow simulation of a fuel cell. This generalisable approach unveils multi-scale water clustering and transport mechanisms over large dry and flooded areas in the gas diffusion layer and flow fields, paving the way for next generation proton exchange membrane fuel cells with optimised structures and wettabilities.

25 ENERGY STORAGE↗
DOE OSTI2023

Cutting-edge methods for amplifying the oxygen evolution reaction during seawater electrolysis: a brief synopsis

Electrochemical water splitting has been considered a clean and continual way for hydrogen (H 2 ) production. Direct seawater electrolysis is a potentially attractive technology due to the ample access to seawater and scarce freshwater resources in some regions. However, the presence of impurities (e.g., Cl - , Mg 2+ ) and the resulting corrosion and side reactions, such as the chloride oxidation reaction (ClOR), makes seawater electrocatalysis more challenging than that of fresh or alkaline water due to competition with the oxygen evolution reaction (OER) at the anode. Consequently, much effort has been devoted to developing approaches to enhance OER performance and suppress the ClOR. In this minireview, we summarize three general strategies for enhancing OER activity and selectivity in seawater electrolysis based on three different concepts: (1) the sole development of robust and high-performance OER catalysts in pure seawater electrolytes, (2) the introduction of additives to seawater electrolytes (e.g., alkalis and/or salts without chloride) to enhance the potential equilibrium gap between the ClOR and OER in combination with regular highly active OER catalysts, and (3) a combination of approaches (1) and (2). Finally, the current challenges and potential opportunities for green H 2 production from seawater electrolysis are briefly presented.

08 HYDROGEN↗
DOE OSTI2024

Optimizing the combustion synthesis of FeAlxOy catalysts for microwave-assisted thermocatalytic dehydrogenation of fossil fuels

The growing demand for hydrogen requires the development of clean and energy-efficient technologies for its synthesis. Microwave-assisted thermocatalytic dehydrogenation of fossil fuels has demonstrated the potential to produce H2 with high yield and selectivity, and simultaneously generate valuable nanostructured carbon byproducts. In prior work, iron-based alumina (FeAlxOy) catalysts for this process were made via solution combustion synthesis (SCS). However, the effect of SCS parameters on the dehydrogenation performance is not well understood. The present study investigates this by varying the SCS fuel, Fe:Al molar ratio, and heating mode. The results show subtle changes of these parameters can result in significant differences in the phase composition, specific surface area, and microwave absorbing properties of FeAlxOy, which all affect microwave-assisted dehydrogenation. Notably, H2 selectivity can be increased from 30% to 74%. Statistical testing determined that the SCS fuel used was the most significant SCS parameter affecting dehydrogenation performance.

Chanoi, Zachary A.↗
DOE OSTI2025

Geologic hydrogen as an emerging fuel: experimental insights, thermodynamics, kinetics, and reactive transport modeling

Geologic hydrogen (GeoH 2 ) is emerging as a viable clean energy source. It is largely produced through serpentinization, a geological process in which ultramafic rocks react with water under suitable temperature and pressure. Here, this review synthesizes the current understanding of H 2 generation by serpentinization, with an emphasis on reaction mechanisms, kinetics, and thermodynamics, as well as on modeling flow and transport of reacting fluids in geological formations. We describe the role of mineral assemblages, such as olivine and pyroxene, fluid-rock interactions, and catalytic surfaces, in influencing GeoH 2 yield and reaction rates. By integrating models of reaction kinetics, subsurface reactive flow and transport, and the serpentinization process, and by accounting for the thermodynamic state of the system, this review aims to guide future GeoH 2 research and to evaluate the potential of natural hydrogen as a sustainable clean energy source.

Moradi, Rasoul [Univ. of Southern California, Los ↗
DOE OSTI2025

Developing Stable Critical Materials and Microstructure for High-Flux and Efficient Hydrogen Production through Reversible Solid Oxide Cells

Reversible Solid Oxide Cells (RSOCs), which operate as either Solid Oxide Fuel Cells (SOFCs) or Solid Oxide Electrolytic Cells (SOECs), hold great promise for clean, high-efficiency energy conversion and hydrogen production. However, their commercial potential is hindered by stability issues arising from temperature-induced materials degradation. While substantial progress has been made in developing durable, reduced-temperature SOFCs - bringing them closer to commercial deployment, SOECs still exhibit substantially higher degradation rates at both the cell and stack levels under practical operating conditions.

08 HYDROGEN↗
DOE OSTI2024

Hydrogen Generation and Industrial Heat Opportunities for Nuclear Plants in the Gulf Coast

The United States (U.S.) nuclear-generation fleet stands as a critical national strategic asset, playing a pivotal role in achieving climate goals. Operating on light-water reactor (LWR) technologies, this fleet provides the largest share of U.S. carbon-free electrical generation, ensuring 24/7 clean-energy stability. With a proven track record of reliability while operating at high-capacity factors, consistently above 90%, the existing nuclear fleet serves as a cornerstone for sustainable energy. The Department of Energy’s (DOE’s) Light Water Reactor Sustainability (LWRS), Flexible Plant Operations and Generation pathway addresses U.S. nuclear power plant (NPP) grid integration challenges in the face of evolving energy landscapes. Research at Idaho National Laboratory (INL) highlights the potential synergy between high-temperature steam-electrolysis (HTSE) technology and nuclear steam and electricity during periods of high renewable grid penetration. Large-scale nuclear-integrated hydrogen production through HTSE presents significant potential for decarbonizing such energy-intensive sectors as oil refining, petrochemicals, ammonia, and fertilizers. The strategic advantage lies in the nuclear sector’s capability to deliver clean electrical and/or steam output during periods of low demand. Nuclear-produced hydrogen—with its ability to provide high-purity clean H 2 well below the national standard of 1 kg of CO 2 per kg of H 2 —represents a breakthrough methodology. This emphasizes the crucial role NPPs can fill in addressing the increasing need for clean hydrogen, establishing them as essential contributors to decarbonization. This report specifically delves into hydrogen-generation opportunities from the U.S. Gulf Coast region. This study aims to assess NPP capabilities for hydrogen production and to identify practical nearby industrial and pipeline-operator off-takers for nuclear-integrated hydrogen production as well as to present some specific case-study analysis showing the conditions under which nuclear hydrogen production and sale can be profitable. Also considered in this report is preliminary analysis of nuclear-heat opportunities accessible near Waterford NPP via transportation of hypothetical steam pipelines and heat-exchange equipment.

08 HYDROGEN↗
DOE OSTI2020

Hydrogen Contamination Detector: Protecting the future of zero-emission fuel cell energy [Brief]

Los Alamos National Laboratory developed an electrochemical detector to protect zero-emission hydrogen fuel cells from contaminated fuels. Fuel cells power environmentally clean vehicles, fork lifts, drones, and provide auxiliary power. High-purity hydrogen is essential to avoid poisoning fuel cells. Current analysis methods are costly and cannot detect impurities in realtime. The Hydrogen Contamination Detector measures the two highest impact Department of Energy-identified impurities with a simple, low-cost unit that provides 24/7, point-of-service analysis. Los Alamos partnered with H2Frontiers to conduct field trials at hydrogen refueling stations and with Skyre LLC for commercialization through a DOE Technology Commercialization Fund project.

08 HYDROGEN↗
DOE OSTI2023

Rational Materials and Structure Design for Improving the Performance and Durability of High Temperature Proton Exchange Membranes (HT-PEMs)

Hydrogen energy as the next-generation clean energy carrier has attracted the attention of both academic and industrial fields. A key limit in the current stage is the operation temperature of hydrogen fuel cells, which lies in the slow development of high-temperature and high-efficiency proton exchange membranes. Currently, much research effort has been devoted to this field, and very innovative material systems have been developed. The authors think it is the right time to make a short summary of the high-temperature proton exchange membranes (HT-PEMs), the fundamentals, and developments, which can help the researchers to clearly and efficiently gain the key information. In this paper, the development of key materials and optimization strategies, the degradation mechanism and possible solutions, and the most common morphology characterization techniques as well as correlations between morphology and overall properties have been systematically summarized.

08 HYDROGEN↗
DOE OSTI2020

Surface effects on deuterium permeation through vanadium membranes

Dense vanadium-based membranes offer high permeability and perfect selectivity to hydrogen isotopes, maintain favorable neutronic properties, and are compatible with liquid metals such as PbLi. These properties make vanadium membranes a promising fusion fuel cycle technology for processes such as tritium extraction from PbLi and exhaust processing. Surface contamination has a deleterious effect on the gas-phase hydrogen permeation through vanadium, and the reported permeabilities range from 10 -14 to 10 -7 mol m -1 s -1 Pa -0.5 . Thin dense films of palladium applied to clean vanadium surfaces enable a consistently high hydrogen permeability. In this study, uncoated vanadium resulted in deuterium permeabilities ranging from 2.8 × 10 -11 to 6.4 × 10 -9 mol m -1 s -1 Pa -0.5 at 300 °C–700 °C, respectively. Post-test analysis revealed a VO x surface layer and VC x subsurface layer formed on the feed side, while the as-received surface oxide dissolved leaving a submonolayer oxide on the permeate surface. Furthermore, the Pd-coated V resulted in a maximum deuterium permeability of 2.1 × 10 -7 m -1 s -1 Pa -0.5 at 375 °C upon activation of the Pd surface by oxidation and reduction. The deuterium permeation declined upon heating to 500 °C due to intermetallic diffusion between the Pd and V. The Mo 2 C-coated V resulted in deuterium permeabilities ranging from 2.7 × 10 -10 to 1.8 × 10-9 at 500 °C–700 °C, respectively, and a post-test analysis found the carbon in the Mo 2 C layer had dissolved into the V near the interface.

13 HYDRO ENERGY↗