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At least 217 records · Page 12

Mechanical Model Development for Composite Structural Supercapacitors

Novel composite structural supercapacitor concepts have recently been developed as a means both to store electrical charge and to provide modest mechanical load carrying capability. Double-layer composite supercapacitors are often fabricated by impregnating a woven carbon fiber fabric, which serves as the electrodes, with a structural polymer electrolyte. Polypropylene or a glass fabric is often used as the separator material. Recent research has been primarily limited to evaluating these composites experimentally. In this study, mechanical models based on the Multiscale Generalized Method of Cells (MSGMC) were developed and used to calculate the shear and tensile properties and response of two composite structural supercapacitors from the literature. The modeling approach was first validated against traditional composite laminate data. MSGMC models for composite supercapacitors were developed, and accurate elastic shear/tensile properties were obtained. It is envisioned that further development of the models presented in this work will facilitate the design of composite components for aerospace and automotive applications and can be used to screen candidate constituent materials for inclusion in future composite structural supercapacitor concepts.

Micromechanics↗

Plasma density features associated with strong convection in the winter high-latitude F region

A single plasma convection model was combined with an ionospheric-atmospheric composition model to study plasma density features associated with string convection in the winter high-latitude F region. Time dependent, three-dimensional, ion density distributions for NO(+), O2(+), N2(+), O(+) and He(+) were produced, and the ionosphere above 42 deg N magnetic latitude was covered for 24 hours. The study found that for strong and weak convection, electron density exhibited a variation with altitude, latitude, longitude and universal time. Ionospheric features were evident for strong convection, but modified in comparison with those found for slow convection. Also found for strong convection was a more pronounced tongue of ionization, the appearance of a new polar hole in the polar cap, and a midlatitude electron density trough that was not as deep as found for a weak convection. In addition, good agreement was found between predictions and Atmosphere Explorer measurements of ion composition variation with latitude and local time.

Sojka, J. J.↗

Iron abundance and magnetic permeability of the moon

A set of simultaneous data from the Apollo 12 lunar surface magnetometer and the Explorer 35 Ames magnetometer are used to construct a whole-moon hysteresis curve, from which a new value of global lunar permeability is determined to be mu = 1.012 + or - 0.006. The corresponding global induced dipole moment is 2.1 x 10 to the 18th power gauss-cucm for typical inducing fields of .1000 gauss in the lunar environment. From the permeability measurement, lunar free iron abundance is determined to be 2.5 + or - 2.0 wt. %. Total iron abundance is calculated for two assumed compositional models of the lunar interior: a free iron/orthopyroxene lunar composition and a free iron/olivine composition. The overall lunar total iron abundance is determined to be 9.0 + or - 4.7 wt. %. Other lunar models with a small iron core and with a shallow iron-rich layer are discussed in light of the measured global permeability. Effects on permeability and iron content calculations due to a possible lunar ionosphere are also considered.

Parkin, C. W.↗

Iron abundance and magnetic permeability of the moon

A larger set of simultaneous data from the Apollo 12 lunar surface magnetometer and the Explorer 35 Ames magnetometer are used to construct a whole-moon hysteresis curve, from which a new value of global lunar permeability is determined to be mu = 1.012 + or - 0.006. The corresponding global induced dipole moment is 2.1 x 10 to the 18th power gauss-cu cm for typical inducing fields of .0001 gauss in the lunar environment. From the permeability measurement, lunar free iron abundance is determined to be 2.5 + or - 2.0 wt. %. Total iron abundance (sum of iron in the ferromagnetic and paramagnetic states) is calculated for two assumed compositional models of the lunar interior: a free iron/orthopyroxene lunar composition and a free iron/olivine composition. The overall lunar total iron abundance is determined to be 9.0 + or - 4.7 wt. %. Other lunar models with a small iron core and with a shallow iron-rich layer are discussed in light of the measured global permeability.

Parkin, C. W.↗

Iron abundance and magnetic permeability of the moon

A larger set of simultaneous data from the Apollo 12 lunar surface magnetometer and the Explorer 35 Ames magnetometer are used to construct a whole-moon hysteresis curve, from which a new value of global lunar permeability is determined to be mu = 1.012 + or - 0.006. The corresponding global induced dipole moment is 2.1 times ten to the eighteenth power gauss-cu cm for typical inducing fields of one ten-thousandth gauss in the lunar environment. From the permeability measurement, lunar free iron abundance is determined to be 2.5 + or - 2.0 wt %. Total iron abundance (sum of iron in the ferromagnetic and paramagnetic states) is calculated for two assumed compositional models of the lunar interior: a free iron/orthopyroxene lunar composition and a free iron/olivine composition. The overall lunar total iron abundance is determined to be 9.0 + or - 4.7 wt %. Other lunar models with a small iron core and with a shallow iron-rich layer are discussed in light of the measured global permeability. Effects on permeability and iron content calculations due to a possible lunar ionosphere are also considered.

Parkin, C. W.↗

A theoretical study of the high-latitude winter F region at solar minimum for low magnetic activity

A simple plasma convection model is combined with an ionospheric-atmospheric composition model in order to study the high-latitude winter F region at the solar minimum for low magnetic activity. The high latitude ionospheric features, such as the main trough, the ionization hole, the tongue of ionization, the aurorally produced ionization peaks, and the universal time effects are a natural consequence of the competition between the various chemical and transport processes known to be operating in the high-latitude ionosphere. In the polar hole, the F region peak electron density is below 300 km, and the dominant process at 300 km for NO(+) ions is diffusion.

Sojka, J. J.↗

High-latitude ionospheric model - First step towards a predictive capability

In order to study the plasma density features associated with both weak and strong convection in the winter high-latitude F-region, a simple plasma convection model was combined with an ionospheric-atmospheric composition model. In a model calculation, a field tube of plasma is followed as it moves along a convection trajectory through a moving, neutral atmosphere. The altitude profiles of the ion densities are obtained by solving the appropriate continuity, momentum and energy equations, including many high-latitude processes. The result of following many such plasma field tubes is a time-dependent, three-dimensional ion density distribution for the ions NO(+), O2(+), O(+), N(+), and He(+). The high-latitude ionosphere is covered over one complete day above 42 deg N magnetic latitude, at altitudes of 160-800 km.

Schunk, R. W.↗

Seasonal variations of the high-latitude F region for strong convection

A plasma convection model is combined with an ionospheric-atmospheric composition model in order to study the seasonal variations of the high-latitude F region for geomagnetic conditions leading to strong convection. In a model calculation, a field tube of plasma is followed as it moves along a convection trajectory through a moving neutral atmosphere. Altitude profiles of the ion densities are obtained by solving the appropriate continuity, momentum, and energy equations including numerous high-latitude processes. It is found that the high-latitude ionosphere exhibits a significant UT variation both during the winter and summer. In general, the electron density at high-latitudes is lower in winter than in summer. In both summer and winter, the major region of low electron density is associated with the 'main' or mid-latitude' trough.

Sojka, J. J.↗

Expansion of the Direct Feed High-Level Waste Glass Composition in the High Al Range

Baseline glass compositions have been developed and demonstrated for successful immobilization of Hanford high-level waste (HLW) prepared through a pretreatment process. Recent enhanced waste glass formulations have shown promise to increase the waste loading of pretreated sludge compositions from a broader range of HLW feeds. This project proposes to increase the loading of minimally pretreated Hanford HLW in glass by expanding the existing database and glass property-composition models. Estimated direct-feed high level waste (DFHLW) compositions were generated by the Hanford Tank Operations Contractor and used by Pacific Northwest National Laboratory to determine target glass compositions. Gaps in existing data were identified including one high-priority gap in the high Al compositional region. This report summarizes the data collected during the characterization of the DFHLW High Al Glass Matrix. These glasses were intentionally designed with high aluminum concentrations (15 to 30 wt%) and a high likelihood of nepheline formation, which is known to negatively affect glass durability. Some glasses were expected to either fail or approach property constraints to fill data gaps in poorly understood regions of the compositional space due to lack of data. Out of the 50 glasses tested, 14 glasses formed nepheline, while the model predicted nepheline formation in 20 glasses. All quenched glasses met the product consistency test durability constraint; however, 8 glasses failed this constraint after undergoing the canister centerline cooling treatment. Additionally, 17 glasses did not meet the viscosity constraints, 4 failed the EC constraints, and 2 exceeded the allowable T2% for spinel crystal formation. All glasses satisfied the SO 3 solubility limit. The resulting dataset provides valuable information to improve model accuracy and reduce prediction uncertainty. These insights will ultimately support the development of more robust glass formulation strategies, enabling higher waste loadings, reducing operational risks, and expanding the processing envelope.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hierarchic models for laminated composites

The principles governing the formulation of hierarchic models for laminated composites are discussed. The essential features of the hierarchic models described herein are: (1) the exact solutions corresponding to the hierarchic sequence of models converge to the exact solution of the corresponding problem of elasticity for a fixed laminate thickness; and (2) the exact solution of each model converges to the same limit as the exact solution of the corresponding problem of elasticity with respect to the laminate thickness approaching zero. Hierarchic models make the computation of any engineering data possible to an arbitrary level of precision within the framework of the theory of elasticity.

Babuska, Ivo↗

The moon - Composition determined by nebular processes

The Ganapathy-Anders seven-component model is used as the basis for an analysis of conditions in the early solar nebula as they pertain to the formation of the moon. Calculations incorporating improved geological data and petrological constraints are presented in terms of a model moon which meets trace element restrictions and conforms to known parameters of heat flow, density, and moment of inertia ratio, ie., 40 ppb U, and a core of 2% by weight. It is noted that a melt of the model composition approximates that of Apollo 15 green glass, together with a residuum of olivine, plus 3-4% spinel.

Morgan, J. W.↗

A search for the 10-micron silicate feature in periodic Comet Grigg-Skjellerup

A 10-micron spectrum of periodic Comet Grigg-Skjellerup was obtained on 22 June 1982 with the UCL array spectrometer at the United Kingdom Infrared Telescope, Mauna Kea. No emission feature is obvious in the spectrum. The observed spectrum can be fit equally well by a model of small hot absorbing grains or by a composite model with less than or equal to 30 percent (3sigma) warm, 'dirty' silicate grains. The latter model is consistent with the silicate abundance in Comet Kohoutek, which did display an emission feature at 10 microns.

Hanner, M.↗

Compositional Segregation in Unidirectionally Solidified Solid Solution Crystals

A computer program was developed to model compositional segregation in unidrectionally solidified solid-solution-semiconducting crystals. The program takes into account the variations of the interface segregation constant and solidification rate with composition. Calculations are performed for the HgCdTe solid solution system that is compared with experimental data.

Wang, J. C.↗

Three-Dimensional High Fidelity Progressive Failure Damage Modeling of NCF Composites

Performance prediction of off-axis laminates is of significant interest in designing composite structures for energy absorption. Phenomenological models available in most of the commercial programs, where the fiber and resin properties are smeared, are very efficient for large scale structural analysis, but lack the ability to model the complex nonlinear behavior of the resin and fail to capture the complex load transfer mechanisms between the fiber and the resin matrix. On the other hand, high fidelity mesoscale models, where the fiber tows and matrix regions are explicitly modeled, have the ability to account for the complex behavior in each of the constituents of the composite. However, creating a finite element model of a larger scale composite component could be very time consuming and computationally very expensive. In the present study, a three-dimensional mesoscale model of non-crimp composite laminates was developed for various laminate schemes. The resin material was modeled as an elastic-plastic material with nonlinear hardening. The fiber tows were modeled with an orthotropic material model with brittle failure. In parallel, new stress based failure criteria combined with several damage evolution laws for matrix stresses were proposed for a phenomenological model. The results from both the mesoscale and phenomenological models were compared with the experiments for a variety of off-axis laminates.

Aitharaju, Venkat↗

Unified Material-Environment Interaction Model for Binary UHTC Composites

A new model for the surface chemistry of zirconium and hafnium diborides containing silicon-carbide when exposed to high temperature conditions in air is formulated. Oxidation dynamics are simplified by considering the diffusion-limited equilibrium regime within the material at elevated temperatures. This model is first assessed against experimental mass-gain data taken from UHTC samples heated to high temperature in an oxygen environment. Then, further evaluations of the new model are conducted using hypersonic CFD simulations to analyze conditions experienced by HfB2-SiC in arc jet experiments conducted at NASA Ames Research Center. Measurements of stagnation point heat transfer and pressure are then used to calibrate the simulations. Results of coupled CFD-material response simulations are then compared to the surface temperatures measured during the Ames arc jet test. Results support the use of the proposed model while highlighting the need for improved gas-phase data on the additional constituents considered.

ultra high temperature ceramic↗

Organic chemistry on Titan

Features taken from various models of Titan's atmosphere are combined in a working composite model that provides environmental constraints within which different pathways for organic chemical synthesis are determined. Experimental results and theoretical modeling suggest that the organic chemistry of the satellite is dominated by two processes: photochemistry and energetic particle bombardment. Photochemical reactions of CH4 in the upper atmosphere can account for the presence of C2 hydrocarbons. Reactions initiated at various levels of the atmosphere by cosmic rays, Saturn 'wind', and solar wind particle bombardment of a CH4-N2 atmospheric mixture can account for the UV-visible absorbing stratospheric haze, the reddish appearance of the satellite, and some of the C2 hydrocarbons. In the lower atmosphere photochemical processes will be important if surface temperatures are sufficiently high for gaseous NH3 to exist. It is concluded that the surface of Titan may contain ancient or recent organic matter (or both) produced in the atmosphere.

Chang, S.↗

Models of Sector Flows Under Local, Regional and Airport Weather Constraints

Recently, the ATM community has made important progress in collaborative trajectory management through the introduction of a new FAA traffic management initiative called a Collaborative Trajectory Options Program (CTOP). FAA can use CTOPs to manage air traffic under multiple constraints (manifested as flow constrained areas or FCAs) in the system, and it allows flight operators to indicate their preferences for routing and delay options. CTOPs also permits better management of the overall trajectory of flights by considering both routing and departure delay options simultaneously. However, adoption of CTOPs in airspace has been hampered by many factors that include challenges in how to identify constrained areas and how to set rates for the FCAs. Decision support tools providing assistance would be particularly helpful in effective use of CTOPs. Such DSTs tools would need models of demand and capacity in the presence of multiple constraints. This study examines different approaches to using historical data to create and validate models of maximum flows in sectors and other airspace regions in the presence of multiple constraints. A challenge in creating an empirical model of flows under multiple constraints is a lack of sufficient historical data that captures diverse situations involving combinations of multiple constraints especially those with severe weather. The approach taken here to deal with this is two-fold. First, we create a generalized sector model encompassing multiple sectors rather than individual sectors in order to increase the amount of data used for creating the model by an order of magnitude. Secondly, we decompose the problem so that the amount of data needed is reduced. This involves creating a baseline demand model plus a separate weather constrained flow reduction model and then composing these into a single integrated model. A nominal demand model is a flow model (gdem) in the presence of clear local weather. This defines the flow as a function of weather constraints in neighboring regions, airport constraints and weather in locations that can cause re-routes to the location of interest. A weather constrained flow reduction model (fwx-red) is a model of reduction in baseline counts as a function of local weather. Because the number of independent variables associated with each of the two decomposed models is smaller than that with a single model, need for amount of data is reduced. Finally, a composite model that combines these two can be represented as fwx-red (gdem(e), l) where e represents non-local constraints and l represents local weather. The approaches studied to developing these models are divided into three categories: (1) Point estimation models (2) Empirical models (3) Theoretical models. Errors in predictions of these different types of models have been estimated. In situations when there is abundant data, point estimation models tend to be very accurate. In contrast, empirical models do better than theoretical models when there is some data available. The biggest benefit of theoretical models is their general applicability in wider range situations once the degree of accuracy of these has been established.

Kulkarni, Deepak↗

Models of Sector Aircraft Counts in the Presence of Local, Regional and Airport Constraints

Recently, the ATM community has made important progress in collaborative trajectory management through the introduction of a new FAA traffic management initiative called a Collaborative Trajectory Options Program (CTOP). FAA can use CTOPs to manage air traffic under multiple constraints (manifested as flow constrained areas or FCAs) in the system, and it allows flight operators to indicate their preferences for routing and delay options. CTOPs also permits better management of the overall trajectory of flights by considering both routing and departure delay options simultaneously. However, adoption of CTOPs in airspace has been hampered by many factors that include challenges in how to identify constrained areas and how to set rates for the FCAs. Decision support tools providing assistance would be particularly helpful in effective use of CTOPs. Such DSTs tools would need models of demand and capacity in the presence of multiple constraints. This study examines different approaches to using historical data to create and validate models of maximum flows in sectors and other airspace regions in the presence of multiple constraints. A challenge in creating an empirical model of flows under multiple constraints is a lack of sufficient historical data that captures diverse situations involving combinations of multiple constraints especially those with severe weather. The approach taken here to deal with this is two-fold. First, we create a generalized sector model encompassing multiple sectors rather than individual sectors in order to increase the amount of data used for creating the model by an order of magnitude. Secondly, we decompose the problem so that the amount of data needed is reduced. This involves creating a baseline demand model plus a separate weather constrained flow reduction model and then composing these into a single integrated model. A nominal demand model is a flow model (gdem) in the presence of clear local weather. This defines the flow as a function of weather constraints in neighboring regions, airport constraints and weather in locations that can cause re-routes to the location of interest. A weather constrained flow reduction model (fwx-red) is a model of reduction in baseline counts as a function of local weather. Because the number of independent variables associated with each of the two decomposed models is smaller than that with a single model, need for amount of data is reduced. Finally, a composite model that combines these two can be represented as fwx-red (gdem(e), l) where e represents non-local constraints and l represents local weather. The approaches studied to developing these models are divided into three categories: (1) Point estimation models (2) Empirical models (3) Theoretical models. Errors in predictions of these different types of models have been estimated. In situations when there is abundant data, point estimation models tend to be very accurate. In contrast, empirical models do better than theoretical models when there is some data available. The biggest benefit of theoretical models is their general applicability in wider range situations once the degree of accuracy of these has been established.

Kulkarni, Deepak↗