Velocity autocorrelation functions of Lennard-Jones fluids
By a self-consistent procedure, the velocity autocorrelation functions of both liquid and gaseous argon have been calculated without introducing any arbitrary parameters. The results are in satisfactory agreement with computer experiments. The correlation functions are primarily determined by the nearest-neighbor coordination. Because of the strong hard-core repulsion, the behaviors are more vibratory and damp out quickly at high densities and are more diffusive at lower densities.