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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Electrochemically Regenerated Solvent for Direct Air Capture with Co-generation of Hydrogen at Bench-scale

The goal of this final project report is to summarize the work conducted on project DE-FE0032125. In accordance with the Statement of Project Objectives (SOPO), the University of Kentucky Institute for Decarbonization and Energy Advancement (UK IDEA) (Recipient) developed an intensified process to capture CO 2 from ambient conditions (415 ppm CO 2 ). The process combines low-temperature solvent-aided membrane capture with electrochemically-mediated solvent regeneration to simultaneously capture ambient CO 2 while regenerating the solvent. The technology employs only two primary units, a regenerator and an absorber/contactor, while generating high purity hydrogen as a co-product that can be sold, used for energy storage, or cost-saving depolarization of the direct air capture (DAC) system during the grid peak demand, allowing for flexible operation. Since the technology is powered directly by DC electricity, it can seamlessly tie in with power sources like solar cells without the need for AC/DC converters, therefore allowing for a remote operation to further mitigate greenhouse gas generation toward deploying a negative carbon emissions technology that is completely decoupled from the carbon emissions from the power source for the DAC unit. The completion of the project results in significant progress toward the Department of Energy’s (DOE’s) goal of advancing lab and bench-scale DAC systems to a sufficient maturity level that can justify their continued scale-up through the verification testing of the electrochemically regenerated solvent system for DAC with co-generation of hydrogen at bench-scale. The technology addressed the complexities of incumbent DAC systems by demonstrating at ambient conditions (1) low gas-side pressure-drop facile CO 2 capture via an intensified membrane absorber with in-situ regenerated hydroxide as capture solvent, (2) multi-functional electrochemical regenerator for hydroxide regeneration, CO 2 concentration and hydrogen production at less than 3 V, and (3) stable DAC performance including >90% capture with air influent at the CFM scale. The data from this project enables the completion of Techno-Economic Analysis (TEA) and Life Cycle Assessment (LCA). TEA and LCA demonstrate the potential of the proposed electrochemical solvent-based process to be a viable DAC option. The analysis did not identify any obvious concern for the bench-scale operation and no apparent barriers to implementing UK IDEA carbon capture and solvent regeneration system at a larger scale.

08 HYDROGEN↗

Electrolyzer and Fuel Cell Recycling for a Circular Hydrogen Economy

Abstract Electrolyzers and fuel cells will be crucial for achieving global clean hydrogen and industrial decarbonization goals. However, the nascent clean hydrogen sector faces uncertainties around material supply chains and technology end‐of‐life management. This work aims to guide the transition to a circular hydrogen economy by using process modeling, techno‐economic analysis, and life cycle assessment to evaluate the material cost, energy use, greenhouse gas (GHG) emissions, toxicity, and water use of five potential recycling strategies for proton exchange membrane electrolyzers (PEMWE) and fuel cells (PEMFC). Hydrometallurgy, acid dissolution, and electrochemical dissolution are shown to offer 2–7 times improvement across all assessed metrics relative to the manufacturing of PEMWE and PEMFC from raw materials. Recycling can also lower the raw material demand, material cost, energy use, and GHG emissions associated with PEMWE and PEMFC deployment in the United States in 2050 by 23%, 19%, 21%, and 16%, respectively. This study provides key insights into the costs, benefits, and complexities of recycling strategies for PEMWE and PEMFC, aiding the development of a circular economy that is synergistic with clean hydrogen deployment.

08 HYDROGEN↗

Impact of gel concentration on filter fluxes in microfiltration of Hanford tank wastes and simulants

Abstract Treatment processes have been proposed that will utilize crossflow filtration to concentrate sludge waste streams at the Department of Energy's Hanford Site. Challenges associated with solid–liquid separation of the waste streams drive a necessary evaluation of available Hanford high level waste (HLW) filtration data. Limiting flux conditions during crossflow filtration are elucidated with the formation of a cake layer on the membrane surface. A mass transfer coefficient between the gel and bulk concentrations plays a critical role in determining filter flux. A correlation between the gel concentration and mass transfer coefficient is made to assist in determining filter performance of select HLW streams. As a process alternative to crossflow filtration, gravity settling of waste streams may be deployed as a solid–liquid separation technique. However, this results in a contrasting performance with the centrifuged solids concentration. A method was developed to estimate expected filtration and settling performance based on physical characterization data for Hanford tank waste samples. By assessing the estimated processing performance of HLW, technical support can be provided during flowsheet planning.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Advancements in Direct Air Capture: Unveiling a Simple and Robust Synthesized Fibrous Amine-functionalized Matrix (FAM) Sorbent for Commercial Scale-up

The escalating challenge of climate change necessitates innovative solutions in the realm of carbon management, particularly in mitigating the impact of fossil fuel emissions. Direct Air Capture (DAC) technology emerges as a critical component within the spectrum of Carbon Capture and Sequestration (CCS) solutions, offering the distinct advantage of directly removing CO2 from the atmosphere irrespective of the source. This attribute grants DAC systems unparalleled flexibility in deployment location sand the potential to make substantial contributions to lowing atmospheric CO2 levels. The success of DAC technologies significantly depends on the development of efficient, economical sorbent capable of selective and durable CO2 capture from ambient air. Recent advancements in material science have led to the exploration of amine-functionalized sorbents, hollow fiber sorbents and membranes, and other novel materials designed to meet these criteria. This study introduces a significant advancement in DAC technology with the development of a Fibrous Amine-functionalized Matrix (FAM) sorbent. The FAM sorbent distinguished itself through its mechanical robustness, a streamlined synthesis process, and the capability for low-temperature regeneration. Its exceptional adsorption-desorption kinetics enable swift CO2 capture and release, crucial for the viability of DAC on a commercial scale.

Wang, Qiuming↗

Innovations in Direct Air Capture: Unveiling a Simple and Robust Synthesized Fibrous Amine-functionalized Matrix (FAM) Sorbent for Commercial Scale-up

The escalating challenge of climate change necessitates innovative solutions in the realm of carbon management, particularly in mitigating the impact of fossil fuel emissions. Direct Air Capture (DAC) technology emerged as a critical component within the spectrum of Carbon Capture and Sequestration (CCS) solutions, offering the distinct advantage of directly removing CO2 from the atmosphere irrespective of the source. This attribute grants DAC systems unparalleled flexibility in deployment locations and the potential to make substantial contributions to lowing atmospheric CO2 levels. The success of DAC technologies significantly depends on the development of an efficient, economical sorbent capable of selective and durable CO2 capture from ambient air. Recent advancements in material science have led to the exploration of amine-functionalized sorbents, hollow fiber sorbents and membranes, and other novel materials designed to meet these criteria. This study explores a novel Fibrous Amine-functionalized Matrix (FAM) sorbent. The FAM sorbent distinguished itself through its mechanical robustness, a streamlined synthesis process, and the capability for low-temperature regeneration (is 90 oC really low temperature?). FAM’s exceptional adsorption-desorption kinetics enable swift CO2 capture and release, crucial for the viability of DAC on a commercial scale. The synthesis process involves a simple dip-coating technique, allowing crosslinked amines to coat glass substrates.

Wang, Qiuming↗

Carbonate Management to Enable Energy- and Carbon-Efficient CO 2 Electrolysis (Final Technical Report)

The rapid growth and plummeting cost of solar energy have spurred growing interest in using CO 2 electrolysis to produce chemicals and fuels as an alternative to conventional petrochemical processes. High-temperature (>800 °C) solid oxide electrolyzers that convert CO 2 into CO and O 2 have recently become commercially available. Low-temperature electrolysis cells offer the prospect of more convenient and flexible operation, which is critical for utilizing intermittent solar energy, and provide access to more valuable C 2+ products such as ethylene, ethanol, and propanol. Over the past 10 years, research in this area has yielded substantial progress in both fundamental understanding of the requisite electrocatalytic reactions and design of prototype devices. Leveraging insights from fuel cells and membrane water electrolyzers, researchers have developed electrolysis cells with gas diffusion electrodes (GDE) that have demonstrated high CO 2 electrolysis current densities (>100 mA cm –2 ) as well as promising selectivity and stability. Despite these advances, the energy efficiency (electrical energy-to-product) and carbon efficiency (CO 2 -to-product) of low-temperature CO 2 electrolysis remain far too low for large-scale deployment. A preponderance of evidence indicates that the principal source of efficiency losses is the rapid and thermodynamically favorable reaction of CO 2 with hydroxide (OH – ) to form carbonate (CO 3 2– ). Carbonate formation imposes steady-state electrolysis conditions that result in large voltage and CO 2 losses for all known (photo)electrochemical CO 2 cells. While much current research remains focused on CO 2 reduction catalyst design, this largely overlooked CO 3 2– problem presents a fundamental scientific barrier to creating a viable electrochemical option for converting solar energy into chemicals and fuels. The project pursues an integrated, multi-PI research effort that establishes a fundamental science of CO 3 2– management. PI Kanan and Co-PI Mani’s contribution to the project is to evaluate strategies to mitigate the CO 3 2– problem by changing the properties of the electrolyte and the environment in which CO 2 reduction catalysis takes place. Experimental studies showed that electrolytes composed of a high concentration of both CO 3 2– and HCO 3 – , which serve as moderately alkaline buffers, improved the cell voltage by compared to all-HCO 3 – electrolytes, but these buffered systems still show substantial CO 2 uptake that reduces pH over time. Computational studies developed a homogenized model of a CO 2 reduction catalyst layer that permits a low-cost exploration of the high-dimensional parameter space associated with catalyst layers on gas diffusion electrodes. The model was validated by accurately reproducing experimental data for the related but simpler reaction of CO reduction and then used to probe the effects of catalyst layer architecture on CO 2 reduction. Minimizing the size of catalyst and hydrophobic domains in the catalyst layer is predicted to mitigate CO 3 2– formation and thereby enable prolonged operation at elevated pH. In support of the CO 2 electrolysis studies, a new method for rapidly prototyping electrochemical cells was developed and validated. The method uses a combination of 3D printing and electroless plating to generate conductive cell components for evaluating new cell designs. The carbonate problem encompasses mass transport processes and acid-base reactions that are relevant to many other electrochemical systems. Investigation of strategies to address the carbonate problem led to an additional line of inquiry into the physicochemical phenomena that determine the efficiency of electrochemical acid-base production, which has numerous applications in the broader field of carbon management. New strategies for using the supporting electrolyte to inhibit H + /OH – recombination in electrochemical acid-base production were evaluated, leading to the development of a novel acid-base producing system that eliminates the need for ion exchange membranes and exhibits promising efficiency and current densities for scalable applications.

25 ENERGY STORAGE↗

A technique for thick polymer coating of inertial-confinement-fusion targets

A technique to coat a stalk-mounted inertial-confinement fusion (ICF) target with a thick polymer layer has been successfully demonstrated. The polymer solution is first atomized, allowed to coalesce into a droplet, and positioned in a stable acoustic levitating field. The stalk-mounted ICF target is then moved into the acoustic field by manipulating a 3-D positioner to penetrate the surface membrane of the droplet, thus immersing the target in the levitated coating solution. The target inside the droplet is maintained at the center of the levitated liquid using the 3-D positional information provided by two orthogonally placed TV cameras until the drying process is completed. The basic components of the experimental apparatus, including an acoustic levitator, liquid sample deployment device, image acquisition instrumentation, and 3-D positioner, are briefly described.

Lee, M. C.↗

Novel In-Space Manufacturing Concepts for the Development of Large Space Telescopes

There is a continuous demand for larger, lighter, and higher quality telescopes. Over the past several decades, we have seen the evolution from launchable 2 meter-class telescopes (such as Hubble), to today s demand for deployable 6 meter-class telescopes (such as JWST), to tomorrow s need for up to 150 meter-class telescopes. As the apertures continue to grow, it will become much more difficult and expensive to launch assembled telescope structures. To address this issue, we are seeing the emergence of new novel structural concepts, such as inflatable structures and membrane optics. While these structural concepts do show promise, it is very difficult to achieve and maintain high surface figure quality. Another potential solution to develop large space telescopes is to move the fabrication facility into space and launch the raw materials. In this paper we present initial in-space manufacturing concepts to enable the development of large telescopes. This includes novel approaches for the fabrication of both the optical elements and the telescope support structure. We will also discuss potential optical designs for large space telescopes and describe their relation to the fabrication methods. These concepts are being developed to meet the demanding requirements of DARPA s LASSO (Large Aperture Space Surveillance Optic) program which currently requires a 150 meter optical aperture with a 17 degree field of view.

Mooney, James T.↗

Prospects for Geostationary Doppler Weather Radar

A novel mission concept, namely NEXRAD in Space (NIS), was developed for detailed monitoring of hurricanes, cyclones, and severe storms from a geostationary orbit. This mission concept requires a space deployable 35-m diameter reflector that operates at 35-GHz with a surface figure accuracy requirement of 0.21 mm RMS. This reflector is well beyond the current state-of-the-art. To implement this mission concept, several potential technologies associated with large, lightweight, spaceborne reflectors have been investigated by this study. These spaceborne reflector technologies include mesh reflector technology, inflatable membrane reflector technology and Shape Memory Polymer reflector technology.

Precipitation Radar↗

Overview of Contamination Control for the James Webb Space Telescope Launch Campaign

The James Webb Space Telescope (JWST) is a large, infrared space telescope operating at Lagrange point 2. JWST is a joint effort between NASA, ESA, and CSA and was launched from the Centre Spatial Guyanais (CSG) on an Ariane 5 rocket in December 2021. The three-month launch campaign utilized enhanced contamination controls to meet JWST’s strict cleanliness requirements. Prior to launch, JWST was permitted to only be exposed to ISO Class 7 cleanrooms, whereas the processing facilities at CSG are ISO Class 8. NASA, ESA, Arianespace, and CNES implemented temporary upgrades to the nominal contamination control operations for the launch campaign unique to JWST, including the use of vetted, portable High Efficiency Particulate Air (HEPA) filter walls, pre-entrance cleanliness acceptance surveys of each facility and the intra-plant transporter, tightened cleanroom protocols, upgraded garmenting and laundering techniques, cleaning of Self-Contained Atmospheric Protection Ensemble (SCAPE) suits, increased maintenance, staffed pre-cleaning stations, adaptation of the house purge network, and a contamination control enclosure atop the Ariane 5 launcher prior to fairing encapsulation. The Ariane 5 fairing interior and Vehicle Equipment Bay membrane also received multiple cleanings, detailed inspections, and verification sampling to achieve necessary cleanliness levels. The fairing itself was specially sealed to protect the inner environment with just a small, doored porthole accessible via diving board for final closeout of the purge interface. All these enhancements together allowed JWST to meet its contamination requirements for launch, ensuring successful post-separation deployments and mission science.

James Webb Space Telescope↗

Overview of Contamination Control for the James Webb Space Telescope Launch Campaign

The James Webb Space Telescope (JWST) is a large, infrared space telescope operating at Lagrange point 2. JWST is a joint effort between NASA, ESA, and CSA and was launched from the Centre Spatial Guyanais (CSG) on an Ariane 5 rocket in December 2021. The three-month launch campaign utilized enhanced contamination controls to meet JWST’s strict cleanliness requirements. Prior to launch, JWST was permitted to only be exposed to ISO Class 7 cleanrooms, whereas the processing facilities at CSG are ISO Class 8. NASA, ESA, Arianespace, and CNES implemented temporary upgrades to the nominal contamination control operations for the launch campaign unique to JWST, including the use of vetted, portable High Efficiency Particulate Air (HEPA) filter walls, pre-entrance cleanliness acceptance surveys of each facility and the intra-plant transporter, tightened cleanroom protocols, upgraded garmenting and laundering techniques, cleaning of Self-Contained Atmospheric Protection Ensemble (SCAPE) suits, increased maintenance, staffed pre-cleaning stations, adaptation of the house purge network, and a contamination control enclosure atop the Ariane 5 launcher prior to fairing encapsulation. The Ariane 5 fairing interior and Vehicle Equipment Bay membrane also received multiple cleanings, detailed inspections, and verification sampling to achieve necessary cleanliness levels. The fairing itself was specially sealed to protect the inner environment with just a small, doored porthole accessible via diving board for final closeout of the purge interface. All these enhancements together allowed JWST to meet its contamination requirements for launch, ensuring successful post-separation deployments and mission science.

James Webb Space Telescope, launch, contamination,↗

Inflatable Antenna for CubeSat: A New Spherical Design for Increased X-Band Gain

Interplanetary CubeSats and small satellites have potential to provide means to explore space and to perform science in a more affordable way. As the goals for these spacecraft become more ambitious in space exploration, the communication systems currently implemented will need to be improved to support those missions. One of the bottlenecks is the antennas’ size, due to the close relation between antenna gain and dimensions. Hence, a possible solution is to develop inflatable antennas which can be packaged efficiently, occupying a small amount of space, and they can provide, once deployed, large dish dimension and correspondent gain. A prototype of a 1 m inflatable antenna for X-Band has been developed in a joint effort between JPL and ASU. After initial photogrammetry tests and radiation tests, it was discovered that the design was not able to meet the required gain. As a result, a new design, based on a spherical inflatable membrane, is proposed. This new design will allow reaching a more stable inflatable surface, hence improving the electromagnetic performance. This paper will detail the principle challenges in developing this new antenna focusing on: design, EM analysis, fabrication and tests.

Babuscia, Alessandra↗

An Overview of Contamination Control for the James Webb Space Telescope Launch Campaign

The James Webb Space Telescope (JWST) is a large, infrared space telescope operating at Lagrange point 2. JWST is a joint effort between NASA, ESA, and CSA and was launched from the Centre Spatial Guyanais (CSG) on an Ariane 5 rocket in December 2021. The three-month launch campaign utilized enhanced contamination controls to meet JWST’s strict cleanliness requirements. Prior to launch, JWST was permitted to only be exposed to ISO Class 7 cleanrooms, whereas the processing facilities at CSG are ISO Class 8. NASA, ESA, Arianespace, and CNES implemented temporary upgrades to the nominal contamination control operations for the launch campaign unique to JWST, including the use of vetted, portable High Efficiency Particulate Air (HEPA) filter walls, pre-entrance cleanliness acceptance surveys of each facility and the intra-plant transporter, tightened cleanroom protocols, upgraded garmenting and laundering techniques, cleaning of Self-Contained Atmospheric Protection Ensemble (SCAPE) suits, increased maintenance, staffed pre-cleaning stations, adaptation of the house purge network, and a contamination control enclosure atop the Ariane 5 launcher prior to fairing encapsulation. The Ariane 5 fairing interior and Vehicle Equipment Bay membrane also received multiple cleanings, detailed inspections, and verification sampling to achieve necessary cleanliness levels. The fairing itself was specially sealed to protect the inner environment with just a small, door porthole accessible via diving board for final closeout of the purge interface. All of these enhancements together allowed JWST to meet its contamination requirements for launch, ensuring successful post-separation deployments and mission science.

Contamination Control↗

E-Glider: Active Electrostatic Flight for Airless Body Exploration

The environment near the surface of asteroids, comets, and the Moon is electrically charged due to the Sun's photoelectric bombardment and lofting dust, which follows the Sun illumination as the body spins. Chargeddust is ever present, in the form of dusty plasma, even at high altitudes, following the solar illumination. If abody with high surface resistivity is exposed to the solar wind and solar radiation, sun-exposed areas andshadowed areas become differentially charged. The E-Glider (Electrostatic Glider) is an enabling capability foroperation at airless bodies, a solution applicable to many types of in-situ mission concepts, which leverages thenatural environment. With the E-Glider, we transform a problem (spacecraft charging) into an enablingtechnology, i.e. a new form of mobility in microgravity environments using new mechanisms and maneuveringbased on the interaction of the vehicle with the environment. Consequently, the vision of the E-Glider is toenable global scale airless body exploration with a vehicle that uses, instead of avoids, the local electricallycharged environment. This platform directly addresses the "All Access Mobility" Challenge, one of the NASA'sSpace Technology Grand Challenges. Exploration of comets, asteroids, moons and planetary bodies is limitedby mobility on those bodies. The lack of an atmosphere, the low gravity levels, and the unknown surface soilproperties pose a very difficult challenge for all forms of know locomotion at airless bodies. This E-Gliderlevitates by extending thin, charged, appendages, which are also articulated to direct the levitation force in themost convenient direction for propulsion and maneuvering. The charging is maintained through continuouscharge emission. It lands, wherever it is most convenient, by retracting the appendages or by firing a cold-gasthruster, or by deploying an anchor. The wings could be made of very thin Au-coated Mylar film, which areelectrostatically inflated, and would provide the lift due to electrostatic repulsion with the naturally chargedasteroid surface. Since the E-glider would follow the Sun's illumination, the solar panels on the vehicle wouldconstantly charge a battery. Further articulation at the root of the lateral strands or inflated membrane wings,would generate a component of lift depending on the articulation angle, hence a selective maneuveringcapability which, to all effects, would lead to electrostatic (rather than aerodynamic) flight. Preliminarycalculations indicate that a 1 kg mass can be electrostatically levitated in a microgravity field with a 2 mdiameter electrostatically inflated ribbon structure at 19kV, hence the need for a "balloon-like" system. Due tothe high density and the photo-electron sheath and associate small Debye length, significant power is requiredto levitate even a few kilograms. The power required is in the kilo-Watt range to maintain a constant chargelevel.

Electrostatic Flight↗

Polyimides From a-BPDA and Aromatic Diamines

Polymers having low color and a favorable combination of other properties, including high glass-transition temperature (Tg) and high mechanical properties (strength, tensile modulus, and toughness) will find use in a variety of terrestrial and space applications. Some of the space applications will be in thin films used as membranes on antennas, solar concentrators, coatings on second-surface mirrors, solar sails, sunshades, thermal and optical coatings, and multi-layer thermal insulation blankets. Depending upon the application, the film will be required to exhibit a unique combination of such properties as resistance to degradation by ultraviolet light, visible light, and electrons; low color and/or low solar absorptivity; resistance to tearing and/or wrinkling during packaging and deployment; and high mechanical properties (e.g. high strength, stiffness, and toughness).

Hergenrother, Paul M.↗

STS-41 Space Shuttle mission report

The STS-41 Space Shuttle Program Mission Report contains a summary of the vehicle subsystem activities on this thirty-sixth flight of the Space Shuttle and the eleventh flight of the Orbiter vehicle, Discovery (OV-103). In addition to the Discovery vehicle, the flight vehicle consisted of an External Tank (ET) (designated as ET-39/LWT-32), three Space Shuttle main engines (SSME's) (serial numbers 2011, 2031, and 2107), and two Solid Rocket Boosters (SRB's), designated as BI-040. The primary objective of the STS-41 mission was to successfully deploy the Ulysses/inertial upper stage (IUS)/payload assist module (PAM-S) spacecraft. The secondary objectives were to perform all operations necessary to support the requirements of the Shuttle Backscatter Ultraviolet (SSBUV) Spectrometer, Solid Surface Combustion Experiment (SSCE), Space Life Sciences Training Program Chromosome and Plant Cell Division in Space (CHROMEX), Voice Command System (VCS), Physiological Systems Experiment (PSE), Radiation Monitoring Experiment - 3 (RME-3), Investigations into Polymer Membrane Processing (IPMP), Air Force Maui Optical Calibration Test (AMOS), and Intelsat Solar Array Coupon (ISAC) payloads. The sequence of events for this mission is shown in tabular form. Summarized are the significant problems that occurred in the Orbiter subsystems during the mission. The official problem tracking list is presented. In addition, each Orbiter problem is cited in the subsystem discussion.

Camp, David W.↗

Adaptive responses of marine diatoms to zinc scarcity and ecological implications

Scarce dissolved surface ocean concentrations of the essential algal micronutrient zinc suggest that Zn may influence the growth of phytoplankton such as diatoms, which are major contributors to marine primary productivity. However, the specific mechanisms by which diatoms acclimate to Zn deficiency are poorly understood. Using global proteomic analysis, we identified two proteins (ZCRP-A/B, Zn/Co Responsive Protein A/B) among four diatom species that became abundant under Zn/Co limitation. Characterization using reverse genetic techniques and homology data suggests putative Zn/Co chaperone and membrane-bound transport complex component roles for ZCRP-A (a COG0523 domain protein) and ZCRP-B, respectively. Metaproteomic detection of ZCRPs along a Pacific Ocean transect revealed increased abundances at the surface (<200 m) where dZn and dCo were scarcest, implying Zn nutritional stress in marine algae is more prevalent than previously recognized. These results demonstrate multiple adaptive responses to Zn scarcity in marine diatoms that are deployed in low Zn regions of the Pacific Ocean.

54 ENVIRONMENTAL SCIENCES↗

Energy-efficient carbon capture from industrial point sources via commercially available green solvent and hollow fiber membrane contactors

Solvent-based absorption systems have emerged in the carbon capture space due to their high absorption capacities, reusability, and favorable energy requirements. Using diethyl sebacate as a solvent for pre- and post-combustion carbon capture has advantages over other solvents, including high hydrophobicity, low viscosity, low vapor pressure, high CO 2 solubility, high CO 2 selectivity, and being commercially available in large quantities. Despite these advantageous properties, the use of diethyl sebacate as a solvent for post-combustion carbon capture has not been studied in detail. To examine the capability of diethyl sebacate, a scalable, energy-efficient, hollow fiber membrane (microporous polypropylene and polyvinylidene fluoride) contactor (HFMC)-based process with low-cost and high surface area is investigated. A purity of 95.3 % CO 2 with 46 % recovery in one absorption stage was achieved, with a permeate flux over one magnitude greater than using a deep eutectic solvent in the same system. Technoeconomic analysis determined a ∼ 0.8 GJ per ton of CO 2 at a processing cost of ∼$93 per ton of CO 2 . Results from this work underscore the potential for utilizing green solvents in HFMC-based separation processes for effective carbon capture and provide a pathway towards practical deployment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗