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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Litter removal impacts on soil biodiversity and eucalypt plantation development in the seasonal tropics

The little layer of tree plantations provides primary nutrients for uptake, buffers changes in soil moisture, and provides habitat and substrate to soil epigeic fauna. However, this layer in eucalypt plantations is often removed to reduce fuel load during the fire season in the Brazilian savanna (Cerrado). Therefore, it is necessary to quantify the effects of changes in litter dynamics on the function of these plantations, on key nutrient cycling processes and on epigeic fauna diversity and abundance. In two adjacent stands (one juvenile and one mature), the consequences of two years of litter removal were quantified as monthly litterfall, leaf and fine wood litter decomposition, epigeic fauna abundance and diversity, soil biogeochemical variables, and tree diameter and basal area increments. Monthly litterfall rates in juvenile and mature stands did not change with litter removal over the study period. Annual litterfall ranged from 4.1 to 4.9 Mg ha -1 a -1 in litter removal plots and from 3.9 to 4.8 Mg ha -1 a -1 in control plots. Fine wood litter decomposition was slower in litter removal plots compared to controls, while leaf decomposition rates were similar in both. Two years of litter removal in the juvenile stand did not affect topsoil biogeochemical parameters but decreased available phosphorus at 20–40 cm depth relative to controls. In the mature stand, total cation exchange capacity (0–20 cm) was higher in controls (6.4 cmol c dm -3 ) relative to litter removal plots (6.3 cmol c dm -3 ), while soil moisture (0–40 cm depth) was lower in litter removal (25.45 m 3 m -3 ) compared to control plots (26 m 3 m -3 ) in the dry season. A non-metric multidimensional scaling ordination revealed an increased homogeneity in epigeic fauna where litter was removed. Litterfall, decomposition, diameter increment, four soil physical parameters and fourteen chemical parameters at 0–20 and 20–40 cm depth explained the differences in soil epigeic fauna composition between litter removal and control plots. Diameter increment decreased with litter removal only in the juvenile stand, which had reached its growth peak. The results indicate that removing excess litter to decrease fuel volume can alter soil biodiversity and edaphic conditions that negatively affect nutrient cycling and tree growth.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Experimental investigation of the effect of pore size distribution on nano-particle capture efficiency within ceramic particulate filters

The effect of the pore size distribution on size-resolved filtration efficiency was investigated for two ceramic particulate filters using particulate matter (PM) generated by a spark-ignition direct-injection engine fueled with gasoline. The cordierite filter tested had a porosity of 43%, a median pore diameter (d_50) of 12 µm, and a wide pore size distribution with a lognormal standard deviation (s’) of 0.3. The aluminum titanate filter had very similar porosity, d_50, and thickness, but significantly narrower pore size distribution (s’ = 0.1). The testing of two filters under identical experimental conditions enabled the impact of the pore size distribution on filtration performance to be evaluated. Filtration experiments were performed focusing on just the filter wall, starting from a clean filter until the transition to cake filtration (filtration efficiency > 99%). Time-resolved particle size distribution measurements were used to evaluate the progression of filtration performance and estimate trapped mass within the filter. The aluminum titanate filter, with a narrow pore size distribution, exhibited significantly better diffusion capture efficiency. The negative impact of higher flow velocity on diffusion capture efficiency was more pronounced for a narrower pore size distribution. Flow distributions measured using capillary-flow porometry were used to develop a cylindrical pore flow model to understand the impact of the differences in pore size distribution on observed trends in diffusion capture efficiency within a clean filter. The model helps demonstrate how large pores on the high end of a wider pore size distribution can carry a large fraction of the flow, with less efficient capture of small particles by diffusion. The experimental results and data demonstrate that the bubble point diameter and width of the pore size distribution significantly influence diffusion capture efficiencies for filters with very similar median pore diameter, porosity, and thickness.

aerosol filtration, Aftertreatment, ceramic exhaus↗
DOE OSTI2021

Implementation of two-phase gas transport into VERA for molten salt reactor analysis

Molten salt reactors (MSRs) are a class of next-generation nuclear reactors that have received recent industrial and research interest. A generalized species transport solver was implemented in the Virtual Environment for Reactor Applications (VERA) computing suite to extend this tool to analyze liquid-fueled MSRs. This core simulator has been extended to model the transport of fission product gases into a collection of circulating gas bubbles with the purpose of removing the gases. This paper presents the governing species transport equation, along with various nuclear source terms. Development of the source term for phase migration is discussed, along with a simplified interfacial area tracking method. Finally, a case study on a simplified MSR loop is presented in which modeling parameters were varied to assess their impact on gas removal. The steady state results show that parameters such as bubble diameter, gas injection rate and mass transfer coefficient have a low to moderate effect on the fraction of xenon in the core region. Removal efficiency has the greatest effect on the fraction in the core region. After the pump bowl, bubble diameter has a minor effect on the fraction of xenon in the gas void. Finally, these results point out that increasing parameters such as mass transfer coefficient, gas injection rate, and removal efficiency drives the xenon into the circulating gas void, while decreasing bubble diameter also drives xenon into the gas void by increasing interfacial area.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2024

Optimization-Inspired Pin-Fin Array for Supercritical Carbon Dioxide Recuperator

Additively manufactured heat exchangers are one possible route to cost-effective sCO 2 power cycles. In this paper, experimental results are obtained for two helical pin fin tubes that were designed following parametric optimization of the fin array. Neither the numerical optimization nor the experimental testing have been previously reported in the literature. The two tube designs were, (1) the optimization inspired design, and (2) the optimization-inspired design with a fin diameter increased by a factor of 2. To characterize the print, the designs were scanned using X-ray computed tomography to measure feature sizes and heat transfer area. The optimization was conducted in a commercial, computational fluid dynamics code. The code solved the Reynolds Averaged Navier-Stokes (RANS) and energy equations with turbulence closure provided by the shear stress transport (SST) k-ω model. In the experiments, the Nusselt number augmentation was measured using the Wilson plot technique and the friction factor was determined with mass flow and pressure drop measurements. The experimental testing indicated that the optimization-inspired design had a friction factor that was four times less than the baseline tube design at equal Nusselt number. Additionally, the optimization-inspired design had a 14% improvement in Nusselt number, at equal friction factor, relative to the best performing computational fluid dynamics (CFD) trial points. Tube design (2), with the larger diameter pin fins, had similar performance, within experimental error, as the tube with the smaller diameter pin fins (1). Both tubes achieved overall fin array efficiencies near 1. A performance factor, V/V 0 , equal to the volume of the enhanced heat exchanger divided by the volume of the baseline (no-fins) heat exchanger, is recommended to quantify internal cooling performance. In conclusion, the experimental shell and tube heat exchanger, using the additively manufactured tube, is competitive with printed circuit heat exchangers in its pressure drop class and could be further improved by optimizing a shell-and-tube heat exchanger utilizing this heat transfer enhancement feature.

42 ENGINEERING↗
DOE OSTI2021

Early development of multifilament polyacrylonitrile-derived structural hollow carbon fibers from a segmented arc spinneret

Carbon fiber is a highly desired material for structural applications requiring high strength and stiffness and low weight but has seen only incremental improvements in properties over the last few decades. Further increases in carbon fiber specific properties, including specific strength and specific modulus, would further propel its unique capabilities. One method to produce high specific property carbon fibers for structural applications is the development of hollow carbon fibers. In this work, we report on the early development of polyacrylonitrile-derived structural hollow carbon fibers. Here, multifilament, continuous tow, polyacrylonitrile-based precursor hollow fibers were successfully produced utilizing a segmented arc spinneret approach. When batch oxidized, the hollow precursor fibers demonstrated evidence of oxidation proceeding from both the interior and exterior of the filament. Further results suggested that reducing the precursor hollow fiber wall thickness would allow for complete, homogeneous oxidation, thereby avoiding the skin-core structure often observed in commercial carbon fiber. Here, hollow carbon fibers were as small as 35 µm outer diameter, 22 µm inner diameter (6.5 µm wall thickness). At these diameters, the hollow carbon effective fiber specific strength was 0.54 N/tex and the effective specific modulus was 120 N/tex, approaching the effective specific modulus of T700S at 136 N/tex.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Experimental performance of ejector heat pump operating in the sub-critical mode

Ejector heat pump (EHP) is an efficient-energy technology with a promising potential to replace the vapor compression cycle in heating and cooling applications. It can be powered by low-grade waste heat and uses environmentally friendly working fluids. EHP has also become a viable solution in research seeking cooling applications. However, little attention has been paid to using EHP for heating purposes. In order to investigate this, a steam EHP for domestic water heating was designed and built. The coefficient of performance (COP) is evaluated at various operating and design conditions in sub-critical operational modes to achieve higher condensation temperatures. Two primary nozzles with a throat diameter of 1.5 mm and 2.0 mm were investigated. The primary nozzle is movable along the ejector’s axis, allowing investigation of its positional effects on the EHP’s COP. Further, experimental measurements revealed that using a smaller throat diameter results in a high COP and low back pressure. The EHP COP and back pressure increase when the LTE temperature increases. Using a throat diameter of 1.5 mm, the EHP COP increases as the nozzle exit position (NXP) becomes closer to the constant area section. A COP of 2.42 and a back pressure of 4.28 kPa are achieved at a high-temperature evaporator (HTE) temperature of 130 °C and a low-temperature evaporator (LTE) temperature of 30 °C using a primary nozzle with 1.5 mm.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2022

Particle emissions from mobile sources: Discussion of ultrafine particle emissions and definition

There is no universally agreed upon definition for ultrafine particles (UFP). Commonly used definitions for UFP are either particle number below 100 nm or total particle number, but without an agreed upon lower cut point. For example, a lower cut point of 3 nm compared to 10 nm could result in a substantially higher count. Another definition for UFP is total particle mass but without a commonly agreed upon aerodynamic diameter upper cut point, e.g., below 100 nm, 200 nm, 300 nm, etc. Yet another definition is lung deposited surface area weighted by lung deposition fraction, found mainly in the particle mobility diameter range from 20 to 400 nm. It is clear from these definitions that there are inconsistencies in the way UFP is used and defined in the literature. Sometimes these metrics are well correlated, sometimes not. In this paper we suggest three exposure metrics: UFP-N, UFP-M, and UFP-S, that we believe will add clarity. These metrics represent total number, mass, and surface area below 500 nm, respectively. For surface area and mass, the 500 nm cut point can be either aerodynamic or mobility diameter depending upon measurement methodology. For all metrics, this cut point captures nearly all of the primary particle emissions from mobile sources. Furthermore, UFP-N would include a lower cut point of 3–6 nm and would not require an upper size cut point because there is very little particle number above 500 nm or even above 100 nm. Thus, our definition of UFP-N is consistent with the current definition of ultrafine number except for, importantly, the specification of a lower cut point. These exposure metrics can help facilitate consistency in the characterization of both short- and long-term UFP ambient exposures and associated health effects in epidemiological studies.

42 ENGINEERING↗
DOE OSTI2026

Hygroscopic growth of UO 2 F 2 nanoparticles

Hygroscopicity is an important physicochemical property of aerosol that describes the ability of a particle to uptake water. The hygroscopic properties of uranyl fluoride (UO 2 F 2 ) aerosol generated from a UF 6 hydrolysis reactor was investigated for the first time using a custom-built Humidified Tandem Differential Mobility Analyzer (HTDMA). The HTDMA is capable of measuring UO 2 F 2 nanoparticle growth determined by mobility size over a wide range of atmospheric humidity from dry conditions at <10% relative humidity (RH) to 85% RH. The hygroscopic properties were determined for nanoparticles as small as 3.5 nm in this study. Although the largest size of UO 2 F 2 nanoparticles was 80 nm, monodisperse aerosol with a mobility diameter of up to approximately 500 nm can be investigated using the HTDMA. Anhydrous UO 2 F 2 nanoparticles with a mobility diameter of 3.5 nm were shown to be highly hygroscopic with a deliquescence relative humidity (DRH) of 10%. Hydrates with a larger mobility diameter from 10 to 80 nm were non-hygroscopic with no observable DRH and limited water uptake up to 85% RH. Here, these results demonstrate the hygroscopic properties of UO 2 F 2 nanoparticles are highly variable and based on both the mobility size and hydration state. Hygroscopicity affects the physicochemical properties of UO 2 F 2 nanoparticles, including the aerosol phase state and viscosity, with impacts on aerosol growth, coagulation, and deposition that is critical for understanding the fate and transport of UO 2 F 2 nanoparticles in the atmosphere.

Hygroscopicity↗
DOE OSTI2022

Leak-tight crack repair for 304L stainless steel using friction surfacing

Here, friction surfacing (FS) was investigated as a method for sealing 50 μm wide thru-cracks in 3-mm-thick 304L stainless steel (304L) plate. Friction surfacing was performed using two sizes of 304L consumable rod, with diameters of 9.52 mm and 12.7 mm, on two substrate conditions (clean and oxidized). Friction surfacing was able to deposit a 600 μm thick coating and repair cracks to a depth of 100 μm - 200 μm below the original surface, when using the 12.7-mm-diameter consumable rod for both substrate conditions. Helium leak rates of 10 -10 atm-cc/s were achieved on crack repairs, designating them as leak-tight by the ANSI N14.5 standard. Optical and scanning electron microscopy were used to investigate the coating microstructure and bond interfaces. In this study, the 12.7-mm-diameter rod performed better with disruption of the oxide layer on the oxidized substrate and providing a more homogenous coating. Mechanical properties of the coated samples were evaluated by performing micro-indentation, tensile, bending, and adhesion testing. Higher hardness in the coatings was observed due to the fine equiaxed grains resulting from dynamic recrystallization. Complete consolidation of plastically deformed material on the substrate and a strong diffusion bond across the interface was observed. This was reflected in tensile and bending properties of the FS coatings being comparable to those of uncoated specimen. No delamination of the FS coating was observed during adhesion testing. The results demonstrate that friction surfacing is a viable option to seal cracks in stainless steels.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Characterization of fluidized bed chemical vapor deposition ZrC coatings on PyC/YSZ kernels deposited under differing conditions

In this study, coated fuel particle architectures with ZrC coatings are candidate fuels for advanced power reactors and space nuclear propulsion (SNP) concepts. Owing to its relevance to SNP, the composition, microstructure, and mechanical properties of eight ZrC coatings prepared by fluidized bed chemical vapor deposition were evaluated. Evaluation by SEM and EBSD showed that all grains were columnar. Across the various examined samples, minor axis diameters varied between 0.3 and 1.1 μm, and major axis diameters varied between 0.4 and 2.3 μm. Major and minor diameters increased with thickness particularly at higher deposition temperatures in which the major grain axis (from an ellipse fit to the grain shape) increased by 2.5 μm over the entire coating. Coatings with higher reactive gas flows and Zr/C concentrations closer to 1 were observed to contain nanocrystalline graphite deposits. Reactive gas flow doubling led to increases in coating thickness from around 10–15 μm to around 22–27 μm.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

Burst pressure models and validations for thick-walled pipelines containing corrosion defects

Corrosion is one major threat to pipeline integrity. Over the past decades, many corrosion models have been developed for determining the remaining strength of corroded pipelines, including ASME B31.G, Modified B31.G, LPC, PCORRC and their modified models. All these corrosion models are applicable only to large diameter, thin-walled pipelines with a diameter to wall thickness ratio D/t ≥ 20. In practice, many pipelines have a small diameter and thick wall with a D/t ratio < 20, and thus an adequate corrosion model is needed for assessing remaining strength for corroded thick-walled pipelines. This paper briefly reviews the theoretical burst pressure models for defect-free thin and thick-walled pipelines and four representative corrosion assessment models for thin-walled corroded pipelines. On this basis, two modified corrosion models are proposed to thick-walled pipelines in terms of the average shear stress yield theory. To verify the proposed corrosion models, comprehensive validations are performed. Numerical validations include the elastic-plastic finite element analysis to determine burst pressure for pipelines without and with corrosion defects and the model evaluation using a large dataset of available FEA results of burst pressure for machined defects. Experimental validations include a set of burst pressure tests for defect-free thick-walled pipes with different thicknesses and the model evaluation using one large burst dataset for machined defects with flat bottoms and another large dataset for real corrosion defects with curved river bottom profiles. Both numerical and experimental validations show that the proposed corrosion models can more accurately predict the remaining strength for corroded thin and thick-walled pipelines.

Pipeline↗
DOE OSTI2022

A novel active veto prototype detector with an inner target for improved rare event searches

Here, we report the fabrication and performance of an annular, cryogenic, phonon-mediated veto detector that can host an inner target detector, allowing substantial reduction in radiogenic backgrounds for rare event search experiments. A germanium veto detector of mass ~500g with an outer diameter of 76 mm and an inner diameter of 28 mm was produced inside of which was mounted a 25 mm diameter germanium inner target detector of mass ~10g. The detector was designed using inputs from a GEANT4 based simulation, where it was modeled to be sandwiched between two germanium detectors. The simulation showed that the background rates (dominated by gamma interactions) could be reduced by >90%, and that such an arrangement is sufficient for aggressive background reduction needed for neutrino and dark matter search experiments. Operating at mK temperatures at the experimental site, the veto detector prototype achieved a baseline resolution of 1.24±0.02 keV while hosting a functional inner target detector. The baseline resolution of the inner target detector was 147±2 eV. The experimental results of an identical detector arrangement are in excellent agreement with the simulation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Miniature DC electromagnetic pumps of molten lead and sodium to support development of Gen-IV nuclear reactors

This work developed designs of submerged, dual-regions, miniature DC-EM pumps for circulating molten lead and liquid sodium at ≤500 °C without active cooling for use in ex-pile and in-pile test loops to support of materials and fuel developments for Gen-IV sodium and molten lead fast nuclear reactor. These pumps with two pumping regions are 57 mm, 66.8 mm, 95.4 mm, and 133.5 mm in diameter and have two Alnico 5 permanent magnets with Hiperco-50 pole pieces for focusing the magnetic field lines in the flow duct. The Equivalent Circuit Model (ECM) linked to the Finite Element Method Magnetics (FEMM) software in MATLAB platform calculated the pumps characteristics for a wide range of parameters. Also determined are the pumps dimensions for the highest cumulative pumping power and peak efficiency. These dimensions are the height, width, and length of the flow duct, the thickness of the Alnico magnets, the length of current electrodes, and the separation distance between the two pumping regions. For molten lead, the pumping power increases from 368 W to 728 W, and the peak efficiency from 14.7% to 31.6% with increased pump diameter from 57 mm to 133.5 mm. In conclusion, for liquid sodium, both the pumping power and peak efficiency are higher, increasing from 392 W to 767 W and from 44.3 to 51.2%, respectively, with increased pump diameter from 57 mm to 133.5 mm.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2020

Understanding the transport and break up of reactive ejecta

This manuscript investigates reactive- versus hydrodynamic-breakup processes of ejecta. For this paper, the reactive metal is cerium (Ce) and the nonreactive metal is tin (Sn), the nonreactive gas is helium (He) and the reactive gas is deuterium (D 2 ) or hydrogen (H 2 ). Experiments were performed in vacuum and the reactive- and nonreactive-gases at various pressures, where we endeavored to match the post-shock gas densities to differentiate between reactive- versus hydrodynamic-breakup processes. Hydrodynamic breakup sensitively links to the Weber number (gas density, liquid fragment diameter, surface tension, and the square of the relative velocity between the fragment and the gas), whereas reactive breakup links to the reactive dynamics which includes two processes. In one case the reactive metal breaks up into smaller fragments as rapidly as the reaction rate, and in the other a crust grows on the liquid fragments as the reactions occur, a diffusion limited process. In the latter case, the particle diameters increase with time as the crust grows. In this process, which is indicated by the data, particles breakup as the CeD 2 loses strength with increasing temperature, leaving an exponentially increasing diameter.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Combustion characteristics and detailed simulations of surrogates for a Tier II gasoline certification fuel

An experimental and numerical study of combustion of a gasoline certification fuel (‘indolene’), and four (S4) and five (S5) component surrogates for it, is reported for the configurations of an isolated droplet burning with near spherical symmetry in the standard atmosphere, and a single cylinder engine designed for advanced compression ignition of pre-vaporized fuel. The intent was to compare performance of the surrogate for these different combustion configurations and to assess the broader applicability of the kinetic mechanism and property database for the simulations. A kinetic mechanism comprised of 297 species and 16,797 reactions was used in the simulations that included soot formation and evolution, and accounted for unsteady transport, liquid diffusion inside the droplet, radiative heat transfer, and variable properties. The droplet data showed a clear preference for the S5 surrogate in terms of burning rate. The simulations showed generally very good agreement with measured droplet, flame, and soot shell diameters. Measurements of combustion timing, in-cylinder pressure, and mass-averaged gas temperature were also well predicted with a slight preference for the S5 surrogate. Preferential vaporization was not evidenced from the evolution of droplet diameter but was clearly revealed in simulations of the evolution of mixture fractions inside the droplets. Here, the influence of initial droplet diameter (D o ) on droplet burning was strong, with S5 burning rates decreasing with increasing D o due to increasing radiation losses from the flame. Flame extinction was predicted for D o =3.0 mm as a radiative loss mechanism but not predicted for smaller D o for the conditions of the simulations.

42 ENGINEERING↗
DOE OSTI2023

Lighting and visual comfort performance of commercially available tubular daylight devices

Tubular daylight devices (TDDs) require a much smaller roof opening than conventional skylights and, because of their highly reflective tube, they can deliver daylight farther away from the building envelope. This can provide lighting energy savings, increasing resilience in new and existing buildings. Different types and configurations are available amongst commercially available TDDs, including domes/diffusers with varying optical properties and the diameter of the TDD. This paper presents a comprehensive experimental evaluation of the lighting and visual comfort performance of multiple configurations of commercially available TDDs, varying dome type (prismatic and clear), diffuser type (Fresnel and prismatic), and diameter (53 and 35 cm), under a range of environmental conditions (different times of day/year, sky cover). Based on illuminance measurements, estimated lighting energy use is also presented. Results indicate that, for clear sky, light levels increase and energy use decreases with solar altitude (e.g., 16 Wh/m 2 daily energy use intensity on a high maximum daily solar altitude (MDSA) day and 34 Wh/m 2 on a low MDSA day) and TDD diameter (e.g., 34 Wh/m 2 and 69 Wh/m 2 for 53 cm and 35 cm TDDs, respectively, for low MDSA). The daily illuminance profile is more rounded for prismatic domes and has higher peaks for clear domes; this translates into a somewhat higher average daily useful daylight illuminance (DUDI) for prismatic domes (86 %) when compared to clear domes (80 %). No clear impact of diffuser type was apparent. In conclusion, measurements indicated no discomfort glare for any of the conditions tested.

14 SOLAR ENERGY↗
DOE OSTI2020

Three-Dimensional Analysis of Particle Distribution on Filter Layers inside N95 Respirators by Deep Learning

The global COVID-19 pandemic has changed many aspects of daily lives. Wearing personal protective equipment, especially respirators (face masks), has become common for both the public and medical professionals, proving to be effective in preventing spread of the virus. Nevertheless, a detailed understanding of respirator filtration-layer internal structures and their physical configurations is lacking. Here, we report three-dimensional (3D) internal analysis of N95 filtration layers via X-ray tomography. Using deep learning methods, we uncover how the distribution and diameters of fibers within these layers directly affect contaminant particle filtration. The average porosity of the filter layers is found to be 89.1%. Contaminants are more efficiently captured by denser fiber regions, with fibers <1.8 μm in diameter being particularly effective, presumably because of the stronger electric field gradient on smaller diameter fibers. This study provides critical information for further development of N95-type respirators that combine high efficiency with good breathability.

42 ENGINEERING↗