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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Disruptive Chemical Approach to Modify Perovskites for Chemical and Biological Sensors

We have been investigating CaCu3Ti4O12 class of perovskites for variety of applications due to its very large dielectric constant. Several mechanisms have been proposed for the existence of the high dielectric constant based on grain boundaries and oxygen deficiencies. We will report the results of the effects of monovalent substitution to replace calcium. This will alter the size to distort the perovskite structure. In addition, we used this system as a sensor for organic agents. There were very large changes in dielectric constant and resistivity indicating this system as a very good sensor material.

Perovskites↗

Disruption of the 2022-2023 stratospheric circulation by the Hunga Tonga-Hunga Ha'apai volcano

In January 2022 the Hunga Tonga-Hunga Ha'apai (HTHH) volcano erupted, injecting an unprecedented amount of water vapor into the stratosphere that increased the total stratospheric water burden by ~10%. As the initial plume of water vapor spread throughout the stratosphere, radiative heating and cooling anomalies affected the stratospheric circulation altering the climatological mean residual circulation. Here we compare the 1980-2021 MERRA-2 (Modern Era Reanalysis for Research and Applications, Version 2) mean residual circulation climatology to the years 2022-2023 to identify stratospheric circulation changes associated with the anomalous water vapor. The HTHH water vapor is explicitly tracked using the M2-SCREAM (MERRA-2 Stratospheric Composition Reanalysis of Aura Microwave Limb Sounder) water vapor analysis. Anomalies in temperature, jet location, polar vortex strength and ozone advection in response to the HTHH water vapor anomaly are also documented. These results reveal details of the evolution of the HTHH induced stratospheric circulation anomalies with special emphasis on how these circulation anomalies affected the 2023 ozone hole.

Lawrence Coy↗

Disruption of the 2022-2023 Stratospheric Circulation By the Hunga Tonga-Hunga Ha'apai Volcano

In January 2022 the Hunga Tonga-Hunga Ha'apai (HTHH) volcano erupted, injecting an unprecedented amount of water vapor into the stratosphere that increased the total stratospheric water burden by ~10%. As the initial plume of water vapor spread throughout the stratosphere, radiative heating and cooling anomalies affected the stratospheric circulation altering the climatological mean residual circulation. Here we compare the 1980-2021 MERRA-2 (Modern Era Reanalysis for Research and Applications, Version 2) mean residual circulation climatology to the years 2022-2023 to identify stratospheric circulation changes associated with the anomalous water vapor. The HTHH water vapor is explicitly tracked using the M2-SCREAM (MERRA-2 Stratospheric Composition Reanalysis of Aura Microwave Limb Sounder) water vapor analysis. Anomalies in temperature, jet location, polar vortex strength and ozone advection in response to the HTHH water vapor anomaly are also documented. These results reveal details of the evolution of the HTHH induced stratospheric circulation anomalies with special emphasis on how these circulation anomalies affected the 2023 ozone hole.

Lawrence Coy↗

ENSO Disrupts Boreal Winter CRE Feedback

Twenty years of satellite-based cloud and radiation observations allow us to examine the observed cloud radiative effect (CRE) feedback (i.e., CRE change per unit change in global mean surface temperature). By employing a decomposition method to separate the contribution of “internal changes” and “relative-frequency-of-occurrence (RFO) changes” of distinct cloud regime (CR) groups, notable seasonal contrasts of CRE feedback characteristics emerge. Boreal winter CRE feedback is dominated by the positive shortwave CRE (SWCRE) feedback of oceanic low-thick clouds, due to their decreasing RFO as temperature rises. This signal is most likely due to El Niño-Southern Oscillation (ENSO) activity. When ENSO signals are excluded, boreal winter CRE feedback becomes qualitatively similar to the boreal summer feedback, where several CR groups contribute to the total CRE feedback more evenly. Most CR groups’ CRE feedbacks largely come from changing RFO: e.g., the predominant transition from oceanic cumulus to broken clouds and more occurrences of higher convective clouds with warming temperature. At the same time, low-thick and broken clouds experience optical thinning and decreasing cloud fraction, and these features are more prominent in boreal summer than winter. Overall, the seasonally asymmetric patterns of CRE feedback, primarily due to ENSO, introduce complexity in assessments of CRE feedback.

ENSO↗