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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Rare Earth and Transition Metal Containing Glasses

Transition metal (TM) and rare earth (RE) ions have been incorporated into many glass systems such as silicate, phosphate, and borosilicate-based oxide glasses, as well as in halide and chalcogenide glasses, that find applications ranging from optical, photonic, and magnetic devices, solid-state battery, to nuclear waste disposal. Understanding the structural role of RE and TM in these glasses can help to develop glass compositions for targeted applications with either high-optical emission efficiency, electrical conductivity, or chemical durability. In this chapter, we first provide a general introduction of the applications and structural features of RE and TM in glasses, then the critical aspects of molecular dynamics (MD) simulations of these glasses such as interatomic potentials, structural analysis tools to study RE and TM ions in glasses and their clustering behaviors, Quantitative Structure–Property Analysis (QSPR), diffusion and dynamic property calculations, and electronic structure calculations to understand electronic defects such as charge trapping and radiation effects are introduced. Three representative case studies are presented: the first one is on MD simulations of erbium- and europium-doped silica and silicate glasses, as well as cerium doped aluminophosphate glasses, that revealed the effect of glass composition on RE ion local structure and clustering behavior. Electronic structure calculations of cerium-doped glass show how the existence of multioxidation states help to mediate radiation-induced damages caused by excited electron–hole pairs was also discussed. The second one focuses on alkali vanadophosphate glasses where the existence of two vanadium oxidation states help to provide electronic conduction in the glasses while alkali ions provide ionic conduction. MD simulations were used to understand vanadium environments and other structural aspects in the phosphate glasses, as well as the ionic transport behaviors of alkali ions. The third case study is on zirconium-containing borosilicate and aluminosilicate glasses that find wide applications in nuclear waste disposal. MD simulations help to provide structural details of zirconium ions that are validated by diffraction and EXAFS spectra. The structural information was used to interpret changes of mechanical properties and chemical durability by using QSPR and other analyses-based MD-generated structure models.

Du, Jincheng↗
NASA NTRS1963

Lunar Flight Study Series: Volume 7. Earth-Moon Transit Studies Based on Ephemeris Data and Using Best Available Computer Program: Principles for Reducing Earth-Moon Trajectory Analysis to Fundamentals - 2

This report presents an empirical investigation of earth-to-moon trajectories. The primary objective is to uncover relationships that result in the reduction of mission analysis or trajectory analysis problems to fundamentals. It is considered imperative that the results be accurate to the extent that any relationships that are uncovered are not brought about by simplifying or unrealistic assumptions. Consequently, the model used is as accurate as is presently available for use and the computations are performed under strict error controls. Procedures are reasonable from the engineering viewpoint. Some very helpful principles are uncovered. These may be briefly stated as follows: 1) Trajectories of constant flight time to the moon (in the 66 hour to 90 hour range), and arriving within a few minutes of the same time pass over a common point on the moon regardless of the arrival altitude and inclination, This common point of passage for such a family of trajectories is arbitrarily referred to as a VERTEX point; 2) These VERTEX points lie within a bounded region on the lunar surface as arrival time varies throughout the years, for a given flight time or flight time spread; 3) Increasing flight time results primarily in a longitude shift of the VERTEX point for a given arrival time; 4) Launch azimuth should be treated as a strong parameter regarding its influence on the vertex. Launch azimuth variations up to +/- 20 degrees about 90 degrees can shift the vertex as much as 3 degrees in latitude even when one is free to pick launch time, coast time, and S-IVB burn time appropriately with launch azimuth; and 5) The locus of periselenum, as arrival inclination takes on all possible values, is nearly circular about the vertex point for a given arrival altitude. A publication is now in preparation that applies these principles to much advantage in the solution of various trajectory analysis problems.

LUNAR FLIGHT↗
NASA NTRS1973

Acquisition/expulsion system for earth orbital propulsion system study. Volume 5: Earth storable design

A comprehensive analysis and parametric design effort was conducted under the earth-storable phase of the program. Passive Acquisition/expulsion system concepts were evaluated for a reusable Orbital Maneuvering System (OMS) application. The passive surface tension technique for providing gas free liquid on demand was superior to other propellant acquisition methods. Systems using fine mesh screens can provide the requisite stability and satisfy OMS mission requirements. Both fine mesh screen liner and trap systems were given detailed consideration in the parametric design, and trap systems were selected for this particular application. These systems are compatible with the 100- to 500-manned mission reuse requirements.

Source record↗
NASA NTRS1973

Earth resources applications of the Synchronous Earth Observatory Satellite (SEOS)

The results are presented of a four month study to define earth resource applications which are uniquely suited to data collection by a geosynchronous satellite. While such a satellite could also perform many of the functions of ERTS, or its low orbiting successors, those applications were considered in those situations where requirements for timely observation limit the capability of ERTS or EOS. Thus, the application presented could be used to justify a SEOS.

Lowe, D. S.↗
NASA NTRS1982

Complementary rare earth element patterns in unique achondrites, such as ALHA 77005 and shergottites, and in the earth

Abundances of major, minor, and trace elements are determined in the Antarctic achondrite Allan Hills (ALHA) 77005 via sequential instrumental and radiochemical neutron activation analysis. The rare earth element (REE) abundances of ALHA 77005 reveal a unique chondritic normalized pattern; that is, the REEs are nearly unfractionated from La to Pr at approximately 1.0X chondrites, monotonically increased from Pr to Gd at approximately 3.4X with no Eu anomaly, nearly unfractionated from Gd and Ho and monotonically decreased from Ho to Lu at approximately 2.2X. It is noted that this unique REE pattern of ALHA 77005 can be modeled by a melting process involving a continuous melting and progressive partial removal of melt from a light REE enriched source material. In a model of this type, ALHA 77005 could represent either a crystallized cumulate from such a melt or the residual source material. Calculations show that the parent liquids for the shergottites could also be derived from a light REE enriched source material similar to that for ALHA 77005.

Ma, M.-S.↗
NASA NTRS1983

On the determination of the coefficients of the Gaussian general theory of the Earth's magnetism for the year 1885 and about the relationship of the three Earth-magnetic elements

An attempt is made to judge the value of the Gaussian series for the Earth's magnetism. The computation employed to do this uses the method of the least and greatest coefficients. The number of unknown which had to be calculated from the individual groups was at most only four. All symbols of Gauss were retained.

Fritsche, H.↗
NASA NTRS1983

The measurement of the earth's radiation budget as a problem in information theory - A tool for the rational design of earth observing systems

The measurement of the earth's radiation budget has been chosen to illustrate the technique of objective system design. The measurement process is an approximately linear transformation of the original field of radiant exitances, so that linear statistical techniques may be employed. The combination of variability, measurement strategy, and error propagation is presently made with the help of information theory, as suggested by Kondratyev et al. (1975) and Peckham (1974). Covariance matrices furnish the quantitative statement of field variability.

Barkstrom, B. R.↗